KR20200098579A

KR20200098579A - 살생물제 상호반응을 통한 조절 방출형 방오 코팅 조성물

살생물제 상호반응을 통한 조절 방출형 방오 코팅 조성물 Download PDF

Info

Publication number: KR20200098579A
Authority: KR; South Korea
Prior art keywords: coating composition; poly; oxyalkylene; coat; metal
Prior art date: 2017-12-14

Application number

KR1020207019511A

Other languages

English (en)

Korean (ko)

Inventor

넬리다 기메노 고마즈

에두아르도 안드레스 마르티네즈

Original Assignee

헴펠 에이/에스

Priority date

2017-12-14

Filing date

2018-12-14

Publication date

2020-08-20

2018-12-14 Application filed by 헴펠 에이/에스 filed Critical 헴펠 에이/에스

2020-08-20 Publication of KR20200098579A publication Critical patent/KR20200098579A/ko

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239000008199 coating composition Substances 0.000 title claims abstract description 133
230000003373 anti-fouling effect Effects 0.000 title claims abstract description 85
239000003139 biocide Substances 0.000 title claims abstract description 84
230000003115 biocidal effect Effects 0.000 title claims description 54
238000013270 controlled release Methods 0.000 title description 2
230000003993 interaction Effects 0.000 title description 2
239000011230 binding agent Substances 0.000 claims abstract description 140
-1 poly(oxyalkylene) Polymers 0.000 claims abstract description 133
229910052751 metal Inorganic materials 0.000 claims abstract description 81
239000002184 metal Substances 0.000 claims abstract description 81
238000000576 coating method Methods 0.000 claims abstract description 62
150000001298 alcohols Chemical class 0.000 claims abstract description 58
239000011248 coating agent Substances 0.000 claims abstract description 58
229920001296 polysiloxane Polymers 0.000 claims abstract description 33
QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 29
239000005751 Copper oxide Substances 0.000 claims abstract description 17
229910000431 copper oxide Inorganic materials 0.000 claims abstract description 17
QHNCWVQDOPICKC-UHFFFAOYSA-N copper;1-hydroxypyridine-2-thione Chemical compound [Cu].ON1C=CC=CC1=S.ON1C=CC=CC1=S QHNCWVQDOPICKC-UHFFFAOYSA-N 0.000 claims abstract description 16
229940043810 zinc pyrithione Drugs 0.000 claims abstract description 14
PICXIOQBANWBIZ-UHFFFAOYSA-N zinc;1-oxidopyridine-2-thione Chemical compound [Zn+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S PICXIOQBANWBIZ-UHFFFAOYSA-N 0.000 claims abstract description 14
RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 41
KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 34
KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 34
239000004166 Lanolin Chemical class 0.000 claims description 27
125000004432 carbon atom Chemical group C* 0.000 claims description 27
229940039717 lanolin Drugs 0.000 claims description 27
229930182558 Sterol Chemical class 0.000 claims description 25
235000003702 sterols Nutrition 0.000 claims description 25
150000003432 sterols Chemical class 0.000 claims description 24
238000000034 method Methods 0.000 claims description 23
239000006185 dispersion Substances 0.000 claims description 18
235000019388 lanolin Nutrition 0.000 claims description 18
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 17
235000014113 dietary fatty acids Nutrition 0.000 claims description 15
239000000194 fatty acid Substances 0.000 claims description 15
229930195729 fatty acid Natural products 0.000 claims description 15
229910052802 copper Inorganic materials 0.000 claims description 12
239000010949 copper Substances 0.000 claims description 12
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
GRJISGHXMUQUMC-UHFFFAOYSA-N silyl prop-2-enoate Chemical compound [SiH3]OC(=O)C=C GRJISGHXMUQUMC-UHFFFAOYSA-N 0.000 claims description 8
229910052725 zinc Inorganic materials 0.000 claims description 8
239000011701 zinc Substances 0.000 claims description 8
JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims description 7
239000001257 hydrogen Substances 0.000 claims description 7
229910052739 hydrogen Inorganic materials 0.000 claims description 7
150000002989 phenols Chemical class 0.000 claims description 7
BERDEBHAJNAUOM-UHFFFAOYSA-N copper(i) oxide Chemical compound [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims description 6
150000003839 salts Chemical class 0.000 claims description 6
125000005702 oxyalkylene group Chemical group 0.000 claims description 5
229920001223 polyethylene glycol Polymers 0.000 claims description 5
229910052717 sulfur Inorganic materials 0.000 claims description 4
239000012990 dithiocarbamate Substances 0.000 claims description 3
229920001451 polypropylene glycol Polymers 0.000 claims description 3
241000790917 Dioxys <bee> Species 0.000 claims description 2
XPLSDXJBKRIVFZ-UHFFFAOYSA-L copper;prop-2-enoate Chemical compound [Cu+2].[O-]C(=O)C=C.[O-]C(=O)C=C XPLSDXJBKRIVFZ-UHFFFAOYSA-L 0.000 claims description 2
239000011159 matrix material Substances 0.000 claims description 2
229910001092 metal group alloy Inorganic materials 0.000 claims description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
239000005977 Ethylene Substances 0.000 claims 1
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 1
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 1
125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 abstract description 54
239000011717 all-trans-retinol Substances 0.000 abstract description 27
235000019169 all-trans-retinol Nutrition 0.000 abstract description 27
238000005498 polishing Methods 0.000 abstract description 8
AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 abstract description 7
XDUPUJNNHFTMQS-UHFFFAOYSA-N copper;1-oxidopyridine-2-thione Chemical compound [Cu+2].[O-]N1C=CC=CC1=S.[O-]N1C=CC=CC1=S XDUPUJNNHFTMQS-UHFFFAOYSA-N 0.000 abstract description 3
230000003628 erosive effect Effects 0.000 abstract description 2
239000000178 monomer Substances 0.000 description 67
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 47
239000010410 layer Substances 0.000 description 43
239000000306 component Substances 0.000 description 39
239000000758 substrate Substances 0.000 description 35
239000002253 acid Substances 0.000 description 34
239000003973 paint Substances 0.000 description 34
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239000002904 solvent Substances 0.000 description 23
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239000000654 additive Substances 0.000 description 15
239000000203 mixture Substances 0.000 description 15
229910016551 CuPt Inorganic materials 0.000 description 13
125000000217 alkyl group Chemical group 0.000 description 13
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 11
239000002987 primer (paints) Substances 0.000 description 10
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
150000002148 esters Chemical class 0.000 description 9
150000004665 fatty acids Chemical class 0.000 description 9
150000002430 hydrocarbons Chemical class 0.000 description 9
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 8
239000004593 Epoxy Substances 0.000 description 8
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
230000000694 effects Effects 0.000 description 8
238000002474 experimental method Methods 0.000 description 8
229920000642 polymer Polymers 0.000 description 8
VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 7
PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 7
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
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238000005260 corrosion Methods 0.000 description 6
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SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
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DTPCFIHYWYONMD-UHFFFAOYSA-N decaethylene glycol Chemical compound OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO DTPCFIHYWYONMD-UHFFFAOYSA-N 0.000 description 5
238000007306 functionalization reaction Methods 0.000 description 5
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
239000011976 maleic acid Substances 0.000 description 5
125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 5
LCPDWSOZIOUXRV-UHFFFAOYSA-N phenoxyacetic acid Chemical compound OC(=O)COC1=CC=CC=C1 LCPDWSOZIOUXRV-UHFFFAOYSA-N 0.000 description 5
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