KR20180056645A - 개시제 혼합물, 조성물, 이의 용도, 폴리올 폴리머의 제조 방법, 및 상기 방법에 의해 수득된 폴리올 폴리머 - Google Patents
개시제 혼합물, 조성물, 이의 용도, 폴리올 폴리머의 제조 방법, 및 상기 방법에 의해 수득된 폴리올 폴리머 Download PDFInfo
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- KR20180056645A KR20180056645A KR1020187007067A KR20187007067A KR20180056645A KR 20180056645 A KR20180056645 A KR 20180056645A KR 1020187007067 A KR1020187007067 A KR 1020187007067A KR 20187007067 A KR20187007067 A KR 20187007067A KR 20180056645 A KR20180056645 A KR 20180056645A
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- 239000000203 mixture Substances 0.000 title claims abstract description 86
- 239000003999 initiator Substances 0.000 title claims abstract description 79
- 229920005862 polyol Polymers 0.000 title claims abstract description 54
- 150000003077 polyols Chemical class 0.000 title claims abstract description 54
- 229920000642 polymer Polymers 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 77
- 150000002978 peroxides Chemical class 0.000 claims abstract description 50
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 19
- -1 caproyl Chemical group 0.000 claims description 50
- 239000000178 monomer Substances 0.000 claims description 26
- 239000012986 chain transfer agent Substances 0.000 claims description 24
- 239000011541 reaction mixture Substances 0.000 claims description 16
- 150000003573 thiols Chemical class 0.000 claims description 16
- 125000002252 acyl group Chemical group 0.000 claims description 8
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 7
- UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 claims description 7
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 7
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Chemical group CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 6
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 6
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
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- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 4
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- YQTCQNIPQMJNTI-UHFFFAOYSA-N 2,2-dimethylpropan-1-one Chemical group CC(C)(C)[C]=O YQTCQNIPQMJNTI-UHFFFAOYSA-N 0.000 claims description 3
- IFXDUNDBQDXPQZ-UHFFFAOYSA-N 2-methylbutan-2-yl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)CC IFXDUNDBQDXPQZ-UHFFFAOYSA-N 0.000 claims description 3
- 125000001124 arachidoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
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- 125000004979 cyclopentylene group Chemical group 0.000 claims description 3
- 125000004980 cyclopropylene group Chemical group 0.000 claims description 3
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 claims description 3
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 125000000297 undecanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/38—Mixtures of peroxy-compounds
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- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1558808A FR3041347B1 (fr) | 2015-09-18 | 2015-09-18 | Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede |
| FR1558808 | 2015-09-18 | ||
| PCT/FR2016/052357 WO2017046544A1 (fr) | 2015-09-18 | 2016-09-16 | Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20180056645A true KR20180056645A (ko) | 2018-05-29 |
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Family Applications (1)
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| KR1020187007067A Withdrawn KR20180056645A (ko) | 2015-09-18 | 2016-09-16 | 개시제 혼합물, 조성물, 이의 용도, 폴리올 폴리머의 제조 방법, 및 상기 방법에 의해 수득된 폴리올 폴리머 |
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| US (1) | US10882941B2 (enExample) |
| EP (1) | EP3350230A1 (enExample) |
| KR (1) | KR20180056645A (enExample) |
| CN (1) | CN108026198B (enExample) |
| BR (1) | BR112017026319A2 (enExample) |
| FR (1) | FR3041347B1 (enExample) |
| MX (1) | MX2018002777A (enExample) |
| WO (1) | WO2017046544A1 (enExample) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT3872110T (pt) * | 2020-02-25 | 2022-06-22 | Repsol Sa | Processo para preparar polióis poliméricos |
| CN115340644B (zh) * | 2022-09-23 | 2024-05-03 | 万华化学集团股份有限公司 | 用于聚合物多元醇的引发剂及制备聚合物多元醇的方法 |
| CN115894819A (zh) * | 2022-12-29 | 2023-04-04 | 山东蓝星东大有限公司 | 低单体残留的聚合物多元醇的生产方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6172164B1 (en) * | 1999-04-01 | 2001-01-09 | Basf Corporation | Process for making graft polyols using t-amyl peroxy free radical initiator |
| MXPA04010960A (es) | 2002-05-15 | 2005-01-25 | Basf Corp | Polioles de injerto preparados por un proceso continuo. |
| US7605216B2 (en) * | 2004-11-10 | 2009-10-20 | Basf Corporation | Method of reducing a content of a residual styrene monomer in a polyol |
| FR2946653B1 (fr) * | 2009-06-15 | 2012-08-03 | Arkema France | Procede de fabrication d'une composition melange-maitre comprenant un peroxyde organique |
| DE102011003382A1 (de) * | 2011-01-31 | 2012-08-02 | United Initiators Gmbh & Co. Kg | Peroxidabmischungen für die beschleunigte Vernetzung von Ethylenvinylacetat |
| SG11201501508UA (en) * | 2012-08-31 | 2015-04-29 | Asahi Glass Co Ltd | Curable composition and method for producing cured film |
-
2015
- 2015-09-18 FR FR1558808A patent/FR3041347B1/fr active Active
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2016
- 2016-09-16 KR KR1020187007067A patent/KR20180056645A/ko not_active Withdrawn
- 2016-09-16 CN CN201680054032.7A patent/CN108026198B/zh active Active
- 2016-09-16 BR BR112017026319-0A patent/BR112017026319A2/pt not_active Application Discontinuation
- 2016-09-16 EP EP16781503.4A patent/EP3350230A1/fr active Pending
- 2016-09-16 MX MX2018002777A patent/MX2018002777A/es unknown
- 2016-09-16 WO PCT/FR2016/052357 patent/WO2017046544A1/fr not_active Ceased
- 2016-09-16 US US15/760,261 patent/US10882941B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN108026198A (zh) | 2018-05-11 |
| FR3041347B1 (fr) | 2020-02-14 |
| MX2018002777A (es) | 2018-04-13 |
| CN108026198B (zh) | 2021-04-06 |
| US10882941B2 (en) | 2021-01-05 |
| BR112017026319A2 (pt) | 2019-05-14 |
| FR3041347A1 (enExample) | 2017-03-24 |
| US20180258211A1 (en) | 2018-09-13 |
| EP3350230A1 (fr) | 2018-07-25 |
| WO2017046544A1 (fr) | 2017-03-23 |
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