FR3041347B1 - Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede - Google Patents

Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede Download PDF

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Publication number
FR3041347B1
FR3041347B1 FR1558808A FR1558808A FR3041347B1 FR 3041347 B1 FR3041347 B1 FR 3041347B1 FR 1558808 A FR1558808 A FR 1558808A FR 1558808 A FR1558808 A FR 1558808A FR 3041347 B1 FR3041347 B1 FR 3041347B1
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FR
France
Prior art keywords
carbon atoms
polyol polymer
mixture
initiators
preparation
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Active
Application number
FR1558808A
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English (en)
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FR3041347A1 (fr
Inventor
Shenglin ZOU
Bin Ji
Peng Dai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
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Arkema France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1558808A priority Critical patent/FR3041347B1/fr
Application filed by Arkema France SA filed Critical Arkema France SA
Priority to PCT/FR2016/052357 priority patent/WO2017046544A1/fr
Priority to KR1020187007067A priority patent/KR20180056645A/ko
Priority to BR112017026319-0A priority patent/BR112017026319A2/pt
Priority to US15/760,261 priority patent/US10882941B2/en
Priority to EP16781503.4A priority patent/EP3350230A1/fr
Priority to MX2018002777A priority patent/MX2018002777A/es
Priority to CN201680054032.7A priority patent/CN108026198B/zh
Publication of FR3041347A1 publication Critical patent/FR3041347A1/fr
Application granted granted Critical
Publication of FR3041347B1 publication Critical patent/FR3041347B1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/42—Nitriles
    • C08F220/44—Acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/28—Oxygen or compounds releasing free oxygen
    • C08F4/32—Organic compounds
    • C08F4/38—Mixtures of peroxy-compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

La présente invention concerne un mélange d'initiateurs, une composition, leur utilisation, un procédé de préparation d'un polymère polyol et un polymère polyol obtenu par le procédé. Le mélange d'initiateurs comprend : un premier peroxyde de formule (I) R1-O-O-R2, dans laquelle R1 et R2 représentent indépendamment un groupe alkyle ou un groupe alcanoyle comprenant 1 à 30 atomes de carbone, de préférence 3 à 20 atomes de carbone, et de manière davantage préférée 4 à 20 atomes de carbone ; et un deuxième peroxyde de formule (II) R3-O-O-R4-O-O-R5, dans laquelle R3 et R5 représentent indépendamment un groupe alkyle comprenant 1 à 30 atomes de carbone, de préférence 3 à 20 atomes de carbone et de manière davantage préférée 5 à 10 atomes de carbone, et R4 représente un groupe cycloalkylène comprenant 3 à 30 atomes de carbone, de préférence 4 à 20 atomes de carbone, et de manière davantage préférée 5 à 10 atomes de carbone.
FR1558808A 2015-09-18 2015-09-18 Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede Active FR3041347B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1558808A FR3041347B1 (fr) 2015-09-18 2015-09-18 Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede
KR1020187007067A KR20180056645A (ko) 2015-09-18 2016-09-16 개시제 혼합물, 조성물, 이의 용도, 폴리올 폴리머의 제조 방법, 및 상기 방법에 의해 수득된 폴리올 폴리머
BR112017026319-0A BR112017026319A2 (pt) 2015-09-18 2016-09-16 mistura de iniciadores, composição, sua utilização, processo de preparação de um polímero poliol e polímero poliol obtido pelo processo
US15/760,261 US10882941B2 (en) 2015-09-18 2016-09-16 Initiator mixture, composition, the use thereof, polyol polymer preparation method, and polyol polymer obtained by the method
PCT/FR2016/052357 WO2017046544A1 (fr) 2015-09-18 2016-09-16 Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede
EP16781503.4A EP3350230A1 (fr) 2015-09-18 2016-09-16 Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede
MX2018002777A MX2018002777A (es) 2015-09-18 2016-09-16 Mezcla de iniciador, composicion, su uso, proceso de preparacion de polimero de poliol y polimero de poliol obtenido por el proceso.
CN201680054032.7A CN108026198B (zh) 2015-09-18 2016-09-16 引发剂混合物，组合物，其用途，制备多元醇聚合物的方法和由该方法获得的多元醇聚合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1558808A FR3041347B1 (fr) 2015-09-18 2015-09-18 Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede
FR1558808 2015-09-18

Publications (2)

Publication Number Publication Date
FR3041347A1 FR3041347A1 (fr) 2017-03-24
FR3041347B1 true FR3041347B1 (fr) 2020-02-14

Family

ID=54707955

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1558808A Active FR3041347B1 (fr) 2015-09-18 2015-09-18 Melange d'initiateurs, composition, leur utilisation, procede de preparation d'un polymere polyol et polymere polyol obtenu par le procede

Country Status (8)

Country Link
US (1) US10882941B2 (fr)
EP (1) EP3350230A1 (fr)
KR (1) KR20180056645A (fr)
CN (1) CN108026198B (fr)
BR (1) BR112017026319A2 (fr)
FR (1) FR3041347B1 (fr)
MX (1) MX2018002777A (fr)
WO (1) WO2017046544A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT3872110T (pt) * 2020-02-25 2022-06-22 Repsol Sa Processo para preparar polióis poliméricos
CN115340644B (zh) * 2022-09-23 2024-05-03 万华化学集团股份有限公司 用于聚合物多元醇的引发剂及制备聚合物多元醇的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6172164B1 (en) * 1999-04-01 2001-01-09 Basf Corporation Process for making graft polyols using t-amyl peroxy free radical initiator
AU2003205599A1 (en) 2002-05-15 2003-12-02 Basf Aktiengesellschaft Graft polyols prepared by a continuous process
US7605216B2 (en) * 2004-11-10 2009-10-20 Basf Corporation Method of reducing a content of a residual styrene monomer in a polyol
FR2946653B1 (fr) * 2009-06-15 2012-08-03 Arkema France Procede de fabrication d'une composition melange-maitre comprenant un peroxyde organique
DE102011003382A1 (de) * 2011-01-31 2012-08-02 United Initiators Gmbh & Co. Kg Peroxidabmischungen für die beschleunigte Vernetzung von Ethylenvinylacetat
WO2014034671A1 (fr) * 2012-08-31 2014-03-06 旭硝子株式会社 Composition durcissable et procédé de production de film durcissable

Also Published As

Publication number Publication date
FR3041347A1 (fr) 2017-03-24
KR20180056645A (ko) 2018-05-29
EP3350230A1 (fr) 2018-07-25
US20180258211A1 (en) 2018-09-13
MX2018002777A (es) 2018-04-13
BR112017026319A2 (pt) 2019-05-14
CN108026198A (zh) 2018-05-11
US10882941B2 (en) 2021-01-05
WO2017046544A1 (fr) 2017-03-23
CN108026198B (zh) 2021-04-06

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