KR20180018061A - Perfume composition for expressing the fragrance of a mandarine plantation in jeju island - Google Patents

Abstract

The present invention relates to a fragrance composition mimicking spatial scent of a tangerine plantation in Jeju Island. More specifically, the present invention relates to a fragrance composition. By selecting a proper solvent based on fragrant components inherent in the tangerine plantation in Jeju Island among spatial scent components and also by deriving optimized additional components, the fragrance composition ensures excellent taste while mimicking spatial scent of the tangerine plantation in Jeju Island.

Description

TECHNICAL FIELD [0001] The present invention relates to a perfume composition that reproduces the spatial flavor of a citrus planting field in Jeju Island.

The present invention relates to a perfume composition recreating the spatial fragrance of a citrus planting field in Jeju Island. The present invention provides a perfume composition that reproduces the spatial fragrance of the citrus planting field of Jeju Island. Based on the intrinsic fragrance components of the citrus cultivation field of Jeju Island, The present invention relates to a perfume composition having excellent palatability.

The desire to spend the time of healing in the nature leaving the everyday space to the modern people living busy life is getting bigger, but there are many modern people who do not even have enough time to leave the forest and leave for the forest. The present inventors have conceived the present invention to provide a method of easily healing time within a short time by providing a space-recreating perfume composition that appears to be in a real forest.

The present inventors have selected a citrus cultivation area of Jeju Island as a region having a Korean beauty and healing sensation, and perfume composition which gives an image of space and a distinctive feeling by completing a fragrance composition recreating the spatial fragrance of this region.

Citrus unshiu ( Citrus unshiu ) belongs to the genus Tang and citrus, height is 3 ~ 5m, branches spread and no thorns. Leaves are alternate, oval, flat edge or wavy sawtooth. The wings of petiole are not clear. The flowers bloom in June. There are five calyxes and petals, several stamens, and one pistil.

The fruit is small ball-shaped, 5 ~ 8cm in diameter and ripened in a yellowish red color. The peel is peeled off, the center axis is empty, and it eats the fruit. The most common cultivars in Korea are ten kinds such as early-life, mid-life, and late-life.

Jeju Island is a major distribution area of citrus trees, and the climate of Jeju Island is favorable for the growth of citrus trees.

There are many ways to reproduce spatial incoherence. For example, a solvent extraction method in which a plant in the space is collected by a commonly used method to make a fragrance ingredient into an absolute form, and a steam distillation method in which a fragrance ingredient is made into an essential oil. However, the above methods require high heat in the extraction process, or the process is complicated and takes a lot of time, which may be different from the original flavor. In addition, it does not meet the object of the present invention because it reproduces the fragrance of the plant rather than reproducing the perfume of the space itself.

In the present invention, the dynamic headspace method used for analyzing the spatial fragrance component does not require a solvent and does not require a pretreatment step, so that the fragrance component in the actual space can be directly analyzed.

The dynamic headspace method is a method of circulating air through a resin for a predetermined period of time by using a collection device equipped with a resin capable of adsorbing fragrance to an air pump, analyzing components adsorbed on the resin, The fragrance ingredients contained in a trace amount can be measured.

In addition to various fragrance and flavor components such as terpene, phenol, ketone, and ester, the analyzed aroma components include volatile organic chemical components generally present in the air and allergen components that can cause an allergic reaction. Ingredients such as limonene, hexyl cinnamic acid, linalool, benzyl alcohol, geraniol and the like are fragrance ingredients and can induce allergy. When these ingredients are incorporated into the perfume composition as they are, they may cause problems such as allergic reaction.

Accordingly, the present inventors analyzed the spatial flavor components of the citrus plant cultivated in Jeju Island collected through the dynamic headspace method, and then, based on the other flavor components excluding the atmospheric and allergen components, the perfume composition .

Further, the present inventors have perfected the fragrance composition having a high degree of preference while reproducing the spatial flavor of the citrus cultivation field in Jeju Island by adjusting the content of the fragrance ingredient and using a suitable solvent.

Accordingly, a problem to be solved by the present invention is to provide a fragrance composition recreating the spatial flavor of a citrus cultivation field in Jeju Island.

Another object of the present invention is to provide a perfume composition recreating the spatial flavor of a citrus planting field of Jeju Island which does not induce an allergic reaction by excluding the allergen component from the components collected by the dynamic headspace method.

Another object to be solved by the present invention is to provide a fragrance composition which reproduces the spatial flavor of the citrus cultivation field of Jeju Island and has a high preference degree by selecting a suitable solvent and adjusting the content of the fragrance ingredient.

Another object of the present invention is to provide a cosmetic composition comprising the perfume composition.

Another object of the present invention is to provide a perfume composition comprising the perfume composition.

Another object to be solved by the present invention is to provide a composition for external application for skin comprising the perfume composition.

In order to solve the above problems, the present invention provides a perfume composition recreating the spatial flavor of the citrus planting field of Jeju Island containing the fragrance ingredient of the citrus cultivation field of Jeju Island as an active ingredient.

The above-mentioned fragrance component is the one excluding the allergen component of the spatial flavor component of the citrus planting field of Jeju Island, more specifically, octanal, l-menthol, phenethyl alcohol and benzophenone .

The composition of the present invention also provides a spatial orientation of the highly reproducible Jeju Island citrus plant using anisic aldehyde as an additional ingredient.

The present invention provides a perfume composition recreating the spatial flavor of a citrus planting field of Jeju Island which is improved in reproducibility of fragrance using isopropyl myristate as a solvent and improved in a soft feeling.

In one embodiment of the present invention, the perfume composition of the present invention comprises 0.01 to 3.0% by weight octadol, 2.0 to 20.0% by weight of 1-menthol, 1.0 to 15.0% by weight of phenethyl alcohol, 20.0% by weight, it is possible to reproduce the spatial orientation of the citrus cultivation field in Jeju Island. Outside this range, the fragrance similarity may be lowered. More preferably, it may contain 0.3 to 1.0% by weight of octanal, 3.0 to 8.0% by weight of 1-menthol, 1.0 to 3.0% by weight of phenethyl alcohol and 1.0 to 2.5% by weight of benzophenone.

In one embodiment of the invention, the perfume composition of the present invention may contain from 0.001 to 5.0% by weight of aniline aldehyde and from 65.0 to 95.0% by weight of isopropyl myristate based on the total weight of the composition. Outside this range, the fragrance similarity may be lowered. More preferably, it may contain 0.5-1.2% by weight of aniline aldehyde and 80.0-92.0% by weight of isopropyl myristate.

In addition, the perfume composition mixed in the above-mentioned range is not limited thereto, and can be applied to general household products, cosmetic composition, perfume composition, composition for external application for skin and composition for oral cavity.

The perfume composition of the present invention can be used as a cosmetic composition for skin, lotion, essence, lotion, gel, nutritional cream, massage cream, hand cream, foot cream, foundation, makeup base, hair cream, hair tonic, hair conditioner, A bath liquid, a liquid cleanser, a soap or a shampoo.

The perfume composition of the present invention may be provided as a perfume composition, such as a perfume, a perfume, a deodorant, a diffuser or an aroma candle.

The perfume composition of the present invention can be provided as an external composition for skin such as ointment, lotion, soluble image, suspension, emulsion, cream, gel, spray, papermaking,

The perfume composition of the present invention may be provided as an oral composition such as a wax solution, a toothpaste, a dental floss, an oral spray, a mouthwash, a mouthwash for oral hygiene, and the like.

At this time, the compositions may further include colorants, fungicides, preservatives, antioxidants, moisturizers, thickeners, etc., which are generally acceptable for improving the physical properties. It is also possible to substitute some of the fragrance ingredients and the additional ingredients for oral use when they are provided in an oral composition.

The term "space aroma" as used in the present invention means a scent extracted from a specific area, and simply refers to a scent of the space other than a specific plant scent. In the present invention, a specific region means citrus cultivation area of Jeju Island.

In the present invention, the spatial flavor of the citrus cultivation area of Jeju Island is collected through dynamic headspace method and analyzed by gas chromatography to confirm Which is a part of the citrus cultivation area of Jeju Island.

In the present invention, the analyzed spatial perfumed components are divided into fragrance components and other components, and spatial fragrance is reproduced using only fragrance components.

Other components include general atmospheric components and allergen components. In the present invention, the term "general atmospheric component" refers to volatile organic chemical components present in the atmosphere as well as specific regions analyzed for spatial incoherence. Specific "general atmospheric components" include toluene, xylene, benzoic acid, and phenol. "Allergen ingredients" are known to have the potential to cause allergic reactions when they enter the body, including limonene, linalool, and benzyl alcohol.

"Fragrance component" is a component other than the "general atmospheric component" and "allergen component" among the spatial fragrance components of the specific region analyzed. In the present invention, the fragrance component of the citrus fruit growing field of Jeju Island is octanal, , And benzophenone.

The perfume composition of the present invention enhances the reproducibility of the fragrance and improves the reproducibility of spatial orientation of the citrus cultivation area of Jeju Island by selecting a solvent which improves to have a soft feeling.

In addition, the perfume composition of the present invention has the effect of preventing the allergic reaction and maintaining spatial perfusion by removing allergen components from the spatially-oriented components collected by the dynamic headspace method.

Further, the perfume composition of the present invention has an effect of further improving the preference degree by adjusting the content of the perfume ingredient.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood, however, that the scope of the present invention is not limited by these examples.

EXPERIMENTAL EXAMPLE 1 Analysis of Spice Odor Scent Components

In the present invention, a dynamic headspace method was used to analyze the spatial composition of the citrus field in Jeju Island.

Mini - pump and TENAX filling tube were used for collecting the space - oriented components. The collection tool was installed in the space where the fragrance characteristic of the specific area was best, and the space fragrance was collected in the TENAX filling tube at a flow rate of 1 L / min for more than 3 hours. Gas chromatography was used to identify the spatial fragrance components in the collected air, and the conditions were as shown in Table 1 below.

GC Model Agilent 6890N Inlet Temp. 250 ℃ Split mode Splitless Cryo-focus Initial -90 ° C Ramp1 90 ° C / min to 180 ° C Final 180 DEG C Column TC-WAX: 60 m-0.25 mm-0.25 m Oven temp. program Initial 40 [deg.] C (0 min) Ramp1 3 ° C / min to 230 ° C Final 30 min Carrier gas flow Helium-1.0 ml / min MSD Model Agilent 5973N Transfer line 280 ℃ Quad 150 ℃ Ion source 230 ℃

As a result, the spatial flavor components of the citrus cultivation area of Jeju Island were analyzed as shown in Table 2 below.

Ingredients Content (% by weight) Octanal 1.837 l-menthol (l-menthol) 7.889 Phenethyl alcohol 2.585 Benzophenone 17.521 Other 70.168 total 100

In Table 2, the guitar includes a volatile organic chemical component (that is, a general atmospheric component) that generally floats in the air, and a component that may act as allergen. When producing a spatially reproducible perfume composition, Respectively. The main fragrance components of citrus cultivation area in Jeju Island excluding the other components are octanal, l-menthol, phenethyl alcohol and benzophenone.

Table 3 shows the compositional names of the main general air and allergen components and the respective contents (% by weight with respect to total space-oriented components).

Ingredients Content (% by weight) Classification Benzaldehyde < / RTI > 6.636 General atmospheric composition Acetophenone 6.410 General atmospheric composition Octanoic acid 2.683 General atmospheric composition Nonanoic acid 5.607 General atmospheric composition Decanoic acid 1.954 General atmospheric composition Limonene 3.726 Allogenic component Alpha-isomethylionone
(? -isomethyl ionone) 1.065 Allogenic component Benzyl alcohol 1.556 Allogenic component

Experimental Example 2. Preparation and Sensory Evaluation of Examples According to the Results of Analysis

Based on the analysis results of Experimental Example 1, Example 1 having the composition shown in the following Table 4 was prepared except for the other ingredients such as allergen and the similarity between the flavor and the flavor of citrus cultivation area in the native Jeju Island was verified through sensory evaluation.

Dipropylene glycol (DPG) and isopropyl myristate were used as solvents in the preparation of the examples. Dipropylene glycol has a use as a flavoring agent, a solvent and a viscosity reducing agent, and isopropyl myristate has good skin absorbency and is mainly used as a cosmetic or dermatological solvent. In addition, both of these solvents are generally used as a solvent (solvent) for dissolving various constituents in the preparation of a perfume composition.

Ingredients Content (% by weight) Example 1 Example 2 Octane 1.8 1.8 l-menthol 7.9 7.9 Phenethyl alcohol 2.6 2.6 Benzophenone 17.5 17.5 Dipropylene glycol 70.2 - Isopropyl myristate - 70.2 total 100.0

Sensory evaluation was carried out on perfume experts composed of irritants. The fragrance suitability was evaluated as -10 (very weak - unsuitable), -5 (slightly weak - fit), O (very fit), +5 High-fit), and +10 (high-to-poor) scores. In other words, the closer the score is to zero, the better the local space is.

The diffusiveness and mildness were compared to evaluate the reproducibility with the local space. The diffusiveness refers to the ability of the fragrance to spread around, and the mildness refers to a comfortable fragrance type that is not irritating and is suitable for evaluating the reproducibility specific to the space.

In addition, the intensity means the intensity of the fragrance and is used as a basic sensory evaluation item of the perfume composition.

The sensory evaluation results of Examples 1 and 2 for the above items are shown in Table 5 below.

Evaluation items Local space Example 1 Example 2 Diffusiveness 0 -3.0 -3.0 Mildness 0 -3.0 -2.5 Intensity 0 +5.0 +2.5

The sensory evaluation results of Examples 1 and 2 were confirmed to be similar to the fragrance type in the local space. However, as shown in Table 5, the degree of diffusivity (-3.0) and softness (-3.0 and -2.5) And the strengths (+5.0 and +2.5) were evaluated to be slightly higher.

Therefore, based on the above sensory evaluation results, an additional ingredient for further enhancing the reproducibility with respect to the local space was searched, and the content of the entire constituent including the suitable solvent was adjusted to find an optimal combination flavor.

EXPERIMENTAL EXAMPLE 3 Preparation and Sensory Evaluation of Examples According to Additional Component Mixing

As a result of Experimental Example 2, anisic aldehyde, one of the flavoring agents, was added to enhance the softness of the fragrance.

As shown in the composition of Table 6 below, examples were also prepared in which an anodic aldehyde was included as an additional component in Examples 1 and 2, respectively, and the similarity of these flavorings to the natural flavor of the citrus farmland was verified through sensory evaluation .

Ingredients Content (% by weight) Example 3 Example 4 Octane 1.8 1.8 l-menthol 7.9 7.9 Phenethyl alcohol 2.6 2.6 Benzophenone 17.5 17.5 No formaldehyde 2.0 2.0 Dipropylene glycol 68.2 - Isopropyl myristate - 68.2 total 100.0 100.0

The sensory evaluation was carried out in the same manner as in Experimental Example 2, and the evaluation results are shown in Table 7 below.

Evaluation items Local space Example 1 Example 2 Example 3 Example 4 Diffusiveness 0 -3.0 -3.0 -1.5 -0.5 Mildness 0 -3.0 -2.5 -1.0 +0.5 Intensity 0 +5.0 +2.5 +1.5 +1.0

Comparing the results of the sensory evaluation of Examples 3 and 4 with those of Examples 1 and 2, it was found that Examples 1 and 2 were evaluated that the fragrance intensity was higher than that in the local space and the degree of softness and diffusivity was somewhat lower In Examples 3 and 4 in which anilinoid aldehyde was added as an additional component, softness and diffusibility were improved, and strength was also lowered, and reproducibility was further improved. In particular, the reproducibility of Example 4 using isopropyl myristate as the solvent and the addition of aniline aldehyde was the best.

Experimental Example 4. Preparation and Sensory Evaluation of Examples according to Content Changes

As is apparent from the results of Experimental Example 3, when an aniline aldehyde was used as an additional component, the perfume composition was prepared by combining the fragrance components added with the component in the following Examples because the reproducibility of the perfume composition was excellent. In addition, isopropyl myristate was selected as a solvent.

The new combination fragrances of Examples 5 to 8 were prepared by varying the contents of the components added to the fragrance components analyzed in Experimental Example 1 plus the additional components identified in Experimental Example 2. The specific composition is shown in Table 8 below.

Ingredients Example 4 Example 5 Example 6 Example 7 Example 8 Octane 1.8 1.5 1.2 0.9 0.6 l-menthol 7.9 7.3 6.7 6.1 5.5 Phenethyl alcohol 2.6 3.0 2.0 1.5 2.2 Benzophenone 17.5 13.5 9.5 5.5 1.5 No formaldehyde 2.0 0.4 1.8 1.5 0.9 Isopropyl myristate 68.2 74.3 78.8 84.5 89.3 Total (% by weight) 100.0 100.0 100.0 100.0 100.0

For the fragrance evaluation of Examples 4 to 8, evaluation was made by a five-point rating method as strength, reproducibility (closeness), diffusiveness and hedonics as shown in Table 9 below. The evaluation was carried out with perfume experts composed of a perfume maker. The evaluation results are shown in Table 10 below. If each item is more than 2.5 points, it is judged that there is excellence in the item.

Evaluation items score Strength: Is the strength of the fragrance appropriate?
1 2 3 4 5
(Complaint) (fitness) (satisfaction) Reproducibility: Has the spatial orientation been expressed well? Diffusivity: The spread of fragrance is good Preference: Does it feel like a pleasant scent

Subject burglar Reproducibility preference Diffusibility Average Example 4 2.50 2.50 2.75 2.50 2.56 Example 5 2.50 3.00 3.25 2.50 2.81 Example 6 2.50 3.25 3.00 2.50 2.81 Example 7 3.00 3.25 3.75 3.00 3.25 Example 8 3.75 3.50 4.25 3.00 3.63

As a result of the sensory evaluation, it was confirmed that Examples 4 to 8 were superior to each other in the item, and in particular, the perfume composition of Example 8 was found to be excellent in fragrance strength, reproducibility, preference and diffusibility.

Claims (9)

A perfume composition recreating the spatial flavor of a citrus plantation field in Jeju Island including octanal, l-menthol, phenethyl alcohol and benzophenone.
The method according to claim 1,
Wherein the composition further comprises an anisic aldehyde as an additional ingredient. The fragrance composition recreates the spatial flavor of a citrus cultivation field in Jeju Island.
The method according to claim 1,
Wherein the composition comprises 0.01 to 3.0% by weight octanal, 2.0 to 20.0% by weight of 1-menthol, 1.0 to 15.0% by weight of phenethyl alcohol and 0.5 to 20.0% by weight of benzophenone based on the total weight of the composition. A fragrance composition recreating the spatial flavor of a plantation field.
3. The method of claim 2,
Wherein the anionic aldehyde is contained in an amount of 0.001-5.0 wt% with respect to the total weight of the composition.
5. The method according to any one of claims 1 to 4,
Wherein said composition comprises isopropyl myristate as a solvent. ≪ Desc / Clms Page number 25 >
6. The method of claim 5,
Wherein the isopropyl myristate is contained in an amount of 65.0 to 95.0% by weight based on the total weight of the composition.
A cosmetic composition comprising the perfume composition according to any one of claims 1 to 4.
A perfume composition comprising the perfume composition of any one of claims 1 to 4.
A composition for external application for skin comprising the perfume composition according to any one of claims 1 to 4.