KR101843171B1 - Perfume composition for expressing the fragrance of joongsan-forest lodge in jirisan-mountain - Google Patents

Abstract

The present invention relates to a perfume composition recreating the spatial fragrance of the Jirisan Zhongshan Recreational Forest, wherein a suitable solvent is selected based on the intrinsic fragrance component of the Jirisan Zhongshan Recreational Forest and the optimum content is determined, The present invention relates to a perfume composition having excellent palatability.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a perfume composition recreating the spatial flavor of Jirisan Zhongshan Recreational Forest,

The present invention relates to a perfume composition recreating the spatial fragrance of the Jirisan Zhongshan Recreational Forest, wherein a suitable solvent is selected based on the intrinsic fragrance component of the Jirisan Zhongshan Recreational Forest and the optimum content is determined, The present invention relates to a perfume composition having excellent palatability.

The desire to spend the time of healing in the nature leaving the everyday space to the modern people living busy life is getting bigger, but there are many modern people who do not even have enough time to leave the forest and leave for the forest. The present inventors have conceived the present invention to provide a method of easily healing time within a short time by providing a space-recreating perfume composition that appears to be in a real forest.

The present inventors have selected Jirisan Zhongshan Recreational Forest as an area having a Korean beauty and healing sensation, and perfume composition which gives space image and distinctive feeling by perfume composition recreating this space perfection is completed.

Zhongshan Recreational Forest is a natural recreational forest located in Sichuan, Sancheong-gun, Gyeongsangnam-do. It is located at the Yeongyoung Junction of the Wall Sung Valley. It is the valley where almost all the water streams of Jirisan are gathered. It is the starting point of the Baekdudaegan main stream, centered on Chirisan National Park Cheonwangbong. Most of the surrounding clinics are primeval forests corresponding to the old age, and there are some pine trees and fallen pine trees as planted forests below 750m above sea level, and the remaining are native deciduous forests. You can see beautiful autumn leaves and winter snow scenes due to the distinctive four seasons and high temperature difference. Due to the high altitude difference, various species, the mixture of conifer and broad-leaved trees, aquatic oak trees, and old trees such as cedar trees maintain beautiful scenery in each season and have a landscape that changes with the valley from time to time.

There are many ways to reproduce spatial incoherence. For example, a solvent extraction method in which a plant in the space is collected by a commonly used method to make a fragrance ingredient into an absolute form, and a steam distillation method in which a fragrance ingredient is made into an essential oil. However, the above methods require high heat in the extraction process, or the process is complicated and takes a lot of time, which may be different from the original flavor. In addition, it does not meet the object of the present invention because it reproduces the fragrance of the plant rather than reproducing the perfume of the space itself.

In the present invention, the dynamic headspace method used for analyzing the spatial fragrance component does not require a solvent and does not require a pretreatment step, so that the fragrance component in the actual space can be directly analyzed.

The dynamic headspace method is a method of circulating air through a resin for a predetermined period of time by using a collection device equipped with a resin capable of adsorbing fragrance to an air pump, analyzing components adsorbed on the resin, The fragrance ingredients contained in a trace amount can be measured.

In addition to various fragrance and flavor components such as terpene, phenol, ketone, and ester, the analyzed aroma components include volatile organic chemical components generally present in the air and allergen components that can cause an allergic reaction. Ingredients such as limonene, hexyl cinnamic acid, linalool, benzyl alcohol, geraniol and the like are fragrance ingredients and can induce allergy. When these ingredients are incorporated into the perfume composition as they are, they may cause problems such as allergic reaction.

The present inventors have analyzed the spatial flavor components of the Jirisan Zhongshan Recreational Forest collected through the dynamic headspace method, and then, based on the other aromatic components except the atmospheric and allergen components, the perfume composition of the Jirisan Zhongshan Recreational Forest .

Further, the inventors of the present invention have perfected the fragrance composition having a high degree of preference while reproducing the spatial flavor of the Jirisan Zhongshan Recreational Forest by adjusting the content of the fragrance component and using a solvent suitable therefor.

Therefore, a problem to be solved by the present invention is to provide a fragrance composition recreating the spatial flavor of Jirisan Zhongshan Recreational Forest.

Another object to be solved by the present invention is to provide a perfume composition recreating the spatial flavor of the Jirisan Zhongshan Recreational Forest which does not induce an allergic reaction by excluding the allergen components from the components collected by the dynamic headspace method.

Another object to be solved by the present invention is to provide a fragrance composition which reproduces the spatial flavor of the Jirisan Zhongshan Recreational Forest and has an excellent taste by selecting a suitable solvent and adjusting the content of the fragrance ingredient.

Another object of the present invention is to provide a cosmetic composition comprising the perfume composition.

Another object of the present invention is to provide a perfume composition comprising the perfume composition.

Another object to be solved by the present invention is to provide a composition for external application for skin comprising the perfume composition.

In order to solve the above problems, the present invention provides a perfume composition recreating the spatial flavor of Jirisan Zhongshan Recreational Forest containing the fragrance component of the Jirisan Zhongshan Recreational Forest as an active ingredient.

The above-mentioned fragrance component excludes the allergen component of the spatial aroma component of the Jirisan mountain recreation forest. More specifically, the fragrance component includes alpha-pinene, camphene, beta-pinene, 1- menthol, benzyl acetate and anisic aldehyde.

The present invention provides a perfume composition recreating the spatial flavor of Jirisan Zhongshan Recreational Forest, which is improved in reproducibility of fragrance by using isopropyl myristate as a solvent and has a soft feeling.

In one embodiment of the present invention, the perfume composition of the present invention comprises 1.0 to 20.0% by weight of alpha-pinene, 1.0 to 15.0% by weight of camphine, 1.0 to 30.0% by weight of beta-pinene, 10.0% by weight, benzyl acetate 0.1-8.0% by weight and an aniline aldehyde 0.1-10.0% by weight, so that the spatial orientation of the Jirisan Zhongsan Recreational Forest can be reproduced. Outside this range, the fragrance similarity is lowered. Preferably, the composition comprises 5.0 to 15.0% by weight of alpha-pinene, 5.0 to 15.0% by weight of camphine, 10.0 to 30.0% by weight of beta-pinene, 3.0 to 7.0% by weight of 1-menthol, 2.0 to 6.0% by weight of benzyl acetate, To 8.0% by weight, so that the spatial orientation of the Jirisan mountain recreational forest can be reproduced.

In one embodiment of the present invention, the perfume composition of the present invention may contain 30.0 to 95.0% by weight of isopropyl myristate based on the total weight of the composition. Outside this range, the fragrance similarity is lowered. Preferably, it contains 30.0 to 65.0% by weight of isopropyl myristate.

In addition, the perfume composition mixed in the above-mentioned range is not limited thereto, and can be applied to general household products, cosmetic composition, perfume composition, composition for external application for skin and composition for oral cavity.

The perfume composition of the present invention can be used as a cosmetic composition for skin, lotion, essence, lotion, gel, nutritional cream, massage cream, hand cream, foot cream, foundation, makeup base, hair cream, hair tonic, hair conditioner, A bath liquid, a liquid cleanser, a soap or a shampoo.

The perfume composition of the present invention may be provided as a perfume composition, such as a perfume, a perfume, a deodorant, a diffuser or an aroma candle.

The perfume composition of the present invention can be provided as an external composition for skin such as ointment, lotion, soluble image, suspension, emulsion, cream, gel, spray, papermaking,

The perfume composition of the present invention may be provided as an oral composition such as a wax solution, a toothpaste, a dental floss, an oral spray, a mouthwash, a mouthwash for oral hygiene, and the like.

At this time, the compositions may further include colorants, fungicides, preservatives, antioxidants, moisturizers, thickeners, etc., which are generally acceptable for improving the physical properties. It is also possible to substitute some of the fragrance ingredients and the additional ingredients for oral use when they are provided in an oral composition.

The term "space aroma" as used in the present invention means a scent extracted from a specific area, and simply refers to a scent of the space other than a specific plant scent. In the present invention, a specific area means the Jirisan Zhongshan Recreational Forest.

In the present invention, the spatial orientation of the Jirisan Zhongshan Recreational Forest is collected through the dynamic headspace method, and analyzed by gas chromatography. Which is the spatial component of the Jirisan Zhongshan Recreational Forest space.

In the present invention, the analyzed spatial perfumed components are divided into fragrance components and other components, and spatial fragrance is reproduced using only fragrance components.

Other components include general atmospheric components and allergen components. In the present invention, the term "general atmospheric component" refers to volatile organic chemical components present in the atmosphere as well as specific regions analyzed for spatial incoherence. Specific "general atmospheric components" include toluene, xylene, benzoic acid, and phenol. "Allergen ingredients" are known to have the potential to cause allergic reactions when they enter the body, including limonene, linalool, and benzyl alcohol.

The "fragrance component" is a component excluding the "general atmospheric component" and the "allogenic component" among the spatial fragrance components of the specific region analyzed. In the present invention, the fragrance components of the Jirisan mountain recreation forest are alpha-pinene, camphene, l-menthol, benzyl acetate, and an aldehyde aldehyde.

The perfume composition of the present invention has an effect of enhancing the reproducibility of the fragrance and enhancing the spatial reproducibility of the Jirisan Zhongshan Recreational Forest by selecting a solvent that improves to have a soft feeling.

In addition, the perfume composition of the present invention has the effect of preventing the allergic reaction and maintaining spatial perfusion by removing allergen components from the spatially-oriented components collected by the dynamic headspace method.

Further, the perfume composition of the present invention has an effect of further improving the preference degree by adjusting the content of the perfume ingredient.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood, however, that the scope of the present invention is not limited by these examples.

Experimental Example  One. Space incense  Analysis of fragrance components

In the present invention, a dynamic headspace method was used to analyze spatial components of the Jirisan mountain recreation forest.

Mini - pump and TENAX filling tube were used for collecting the space - oriented components. The collection tool was installed in the space where the fragrance characteristic of the specific area was best, and the space fragrance was collected in the TENAX filling tube at a flow rate of 1 L / min for more than 3 hours. Gas chromatography was used to identify the spatial fragrance components in the collected air, and the conditions were as shown in Table 1 below.

GC Model Agilent 6890N Inlet Temp. 250 ℃ Split mode Splitless Cryo-focus Initial -90 ° C Ramp1 90 ° C / min to 180 ° C Final 180 DEG C Column TC-WAX: 60 m-0.25 mm-0.25 m Oven temp. program Initial 40 [deg.] C (0 min) Ramp1 3 ° C / min to 230 ° C Final 30 min Carrier gas flow Helium-1.0 ml / min MSD Model Agilent 5973N Transfer line 280 ℃ Quad 150 ℃ Ion source 230 ℃

As a result of analysis, spatial orientations of Jirisan Zhongsan Recreational Forest were analyzed as shown in Table 2 below.

Ingredients Content (% by weight) Alpha-pinene < / RTI > 1.374 Camphene 1.750 Beta-pinene < / RTI > 2.163 l-menthol < / RTI > 0.604 Benzyl acetate < RTI ID = 0.0 > 0.234 Anisic aldehyde 0.705 Other 93.170 total 100

In Table 2, the guitar includes volatile organic chemical components (that is, general atmospheric components) that are generally floating in the air and components that are likely to act as allergens (that is, allergen components). Only the fragrance ingredients were used except for the ingredients. The major fragrance ingredients of Jirisan Zhongshan Recreational Forest, except for other ingredients, are alpha - pinene, camphene, beta - pinene, l - menthol, benzyl acetate and aniline aldehyde.

Table 3 shows the compositional names of the main general air and allergen components and the respective contents (% by weight with respect to total space-oriented components).

Ingredients Content (% by weight) Classification Toluene 9.582 General atmospheric composition Ethyl benzene 1.840 General atmospheric composition Xylene 3.290 General atmospheric composition Octanal 7.733 General atmospheric composition Nonanal 8.435 General atmospheric composition Acetic acid 1.474 General atmospheric composition Benzaldehyde < / RTI > 4.760 General atmospheric composition Limonene 2.057 Allogenic component

Experimental Example  2. According to the analysis result Example  Manufacturing and sensory evaluation

Based on the results of the analysis of Experimental Example 1, Examples 1 and 2 having the compositions shown in Table 4 below, except for the allergen component and other ingredients, were prepared and the similarity between the flavor and the aroma of natural Jiri Mountain Resort was verified through sensory evaluation.

Dipropylene glycol (DPG) and isopropyl myristate were used as solvents in the preparation of the examples. Dipropylene glycol is used as a flavoring agent, a solvent and a viscosity reducing agent, and isopropyl myristate has good skin absorbency and is mainly used as a cosmetic or dermatological solvent. In addition, both of these solvents are generally used as a solvent (solvent) for dissolving various constituents in the production of a perfume composition.

Ingredients Content (% by weight) Example 1 Example 2 Alpha-pinen 1.5 1.5 Kampen 2.0 2.0 Beta-pinen 2.0 2.0 l-menthol 0.5 0.5 Benzyl acetate 0.2 0.2 No formaldehyde 1.0 1.0 Dipropylene glycol 92.8 - Isopropyl myristate - 92.8 total 100.0 100.0

Sensory evaluation was carried out on perfume experts composed of irritants. The fragrance suitability was evaluated as -10 (very weak - unsuitable), -5 (slightly weak - fit), O (very fit), +5 High-fit), and +10 (high-to-poor) scores. In other words, the closer the score is to zero, the better the local space is.

We compared the diffusiveness and intensity to assess the reproducibility of the local space. Diffusivity is an ability to spread around the fragrance and is an item suitable for evaluating the reproducibility peculiar to the space. The strength means intensity of the fragrance and is used as a basic sensory evaluation item of the perfume composition.

The sensory evaluation results of Examples 1 and 2 for the above items are shown in Table 5 below.

Evaluation items Local space Example 1 Example 2 Diffusiveness 0 -2.0 -0.5 Intensity 0 +4.5 +2.0

As a result of the sensory evaluation of the above Examples 1 and 2, it was confirmed that both of the examples were less than ± 5.0 points and were similar to the fragrance type in the local space. The composition of Example 1 was slightly less diffusive (-2.0) and higher (+4.5) than the local space, while the composition of Example 2 was more diffusive (-0.5) and less intense (-2.0 ) Were evaluated as similar to the local space.

Therefore, based on the sensory evaluation results, the present inventors sought to find an optimal combination fragrance by adjusting the content of all constituents including solvents in order to increase the diffusibility and reduce the strength and reproduce the spatial flavor.

Experimental Example  3. Depending on the content change Example  Manufacturing and sensory evaluation

As can be seen from the results in Table 5, since the reproducibility of the perfume composition prepared using isopropyl myristate as a solvent was excellent, the perfume composition was prepared using the solvent in the following Examples.

The new combination fragrances of Examples 3 to 6 were prepared by varying the content in the fragrance components analyzed in Experimental Example 1. [ The specific composition is shown in Table 6 below.

Ingredients Example 2 Example 3 Example 4 Example 5 Example 6 Alpha-pinen 1.5 3.0 5.0 7.0 10.0 Kampen 2.0 4.0 8.0 10.0 9.0 Beta-pinen 2.0 5.0 15.0 20.0 20.0 l-menthol 0.5 2.0 5.0 5.0 5.0 Benzyl acetate 0.2 1.0 2.0 4.0 4.0 No formaldehyde 1.0 2.0 4.0 6.0 6.0 Isopropyl myristate 92.8 83.0 61.0 48.0 46.0 Total (% by weight) 100.0 100.0 100.0 100.0 100.0

For the perfume evaluation of Examples 2 to 6, evaluation was made by a five-point rating method as strength, reproducibility, diffusiveness and hedonics as shown in Table 9 below. The evaluation was carried out on perfume experts composed of a perfume maker. The evaluation results are shown in Table 8 below. If each item is more than 2.5 points, it is judged that there is excellence in the item.

Evaluation items score Strength: Is the strength of the fragrance appropriate?
1 2 3 4 5
(Complaint) (fitness) (satisfaction) Reproducibility: Has the spatial orientation been expressed well? Diffusivity: The spread of fragrance is good Preference: Does it feel like a pleasant scent

Subject burglar Reproducibility preference Diffusibility Average Example 2 2.75 3.00 2.50 3.75 3.00 Example 3 3.50 3.75 3.25 3.50 3.50 Example 4 3.75 3.25 2.75 4.00 3.44 Example 5 4.50 4.00 3.75 4.25 4.13 Example 6 4.50 4.25 4.25 4.25 4.31

As a result of the sensory evaluation, it was confirmed that Examples 2 to 6 have excellence in the respective items, and in particular, the perfume composition of Example 6 was found to have excellent perfume intensity, reproducibility, preference and diffusibility.

Claims (7)

A composition comprising 1.0 to 20.0% by weight of alpha-pinene, 1.0 to 15.0% by weight of camphene, 1.0 to 30.0% by weight of beta-pinene, 1-menthol ) 0.1 to 10.0% by weight, benzyl acetate 0.1 to 8.0% by weight, and anisicaldehyde 0.1 to 10.0% by weight.
delete The method according to claim 1,
Wherein the composition comprises isopropyl myristate as a solvent. The fragrance composition recreates the spatial flavor of the oak habitat of Jirisan Zhongshan Recreational Forest.
The method of claim 3,
Wherein the isopropyl myristate is contained in an amount of 30.0 to 95.0% by weight based on the total weight of the composition.
A cosmetic composition comprising the perfume composition of any one of claims 1 to 3.
A perfume composition comprising the perfume composition of any one of claims 1 to 3.
A composition for external application for skin comprising the perfume composition of claim 1 or 3.