KR101843165B1 - Perfume composition for expressing the fragrance of pinus pumila plantation in seoraksan-mountain - Google Patents

Abstract

The present invention relates to a perfume composition recreating the spatial fragrance of the pine tree community of Soraksan mountain. Based on the intrinsic components of the pine tree community of Soraksan, the optimum solvent is selected and the flavor component is added to reproduce the spatial orientation of the Soraksan pine cones And a perfume composition having excellent palatability.

Description

TECHNICAL FIELD [0001] The present invention relates to a perfume composition that reproduces a spatial flavor of a pine tree community of Soraksan mountain. BACKGROUND ART [0002]

The present invention relates to a perfume composition recreating the spatial fragrance of the pine tree community of Soraksan mountain. Based on the intrinsic components of the pine tree community of Soraksan, the optimum solvent is selected and the flavor component is added to reproduce the spatial orientation of the Soraksan pine cones And a perfume composition having excellent palatability.

The desire to spend the time of healing in the nature leaving the everyday space to the modern people living busy life is getting bigger, but there are many modern people who do not even have enough time to leave the forest and leave for the forest. The present inventors have conceived the present invention to provide a method of easily healing time within a short time by providing a space-recreating perfume composition that appears to be in a real forest.

The present inventors have selected Korean pine cones of Soraksan as an area having Korean beauty and healing senses and perfume composition which gives an image of space and a distinctive feeling by inventing a perfume composition recreating this space perfume.

Pinus pumila (pall.) REGEL is also known as luninus, lunation, and blood clusters. It grows in high mountains. It is 4 ~ 5m in height and 15cm in diameter. It grows sideways on the top of the mountain, but grows straight on the plain. The bark is blackish brown, and the young branches are densely covered with soft hairs. There are five leaves, with three ridges and three or four rows of pores on both sides, with serrations on the edges. Leaf length is 3 ~ 6cm, butterfly is about 1mm.

Flowers bloom in June ~ July, and ten male flowers hang on the bottom of new branches and are elliptical and purplish red. Two to three female flowers run on the tips of new branches, egg-shaped and purple. The fruit is ripened in September of the following year by cones. Its color changes from green to yellowish-brown to oval. It is 3 ~ 4.5cm in length, 3cm in butterfly and consists of 20 pieces of fruit. Seeds are edible, dark brown egg-shaped, with a thin film on the top.

The snow pines are distributed in Northeast Asia. In Korea, Seoraksan National Park is the southern limit and the only native place. According to the National Park Management Corporation, the Pinus densiflora grows in the alpine area over 1500 meters above sea level of the Daechongbong ridge of Mt.

On the other hand, there are various methods for reproducing the spatial incense. For example, a solvent extraction method in which a plant in the space is collected by a commonly used method to make a fragrance ingredient into an absolute form, and a steam distillation method in which a fragrance ingredient is made into an essential oil. However, the above methods require high heat in the extraction process, or the process is complicated and takes a lot of time, which may be different from the original flavor. In addition, it does not meet the object of the present invention because it reproduces the fragrance of the plant rather than reproducing the perfume of the space itself.

In the present invention, the dynamic headspace method used for analyzing the spatial fragrance component does not require a solvent and does not require a pretreatment step, so that the fragrance component in the actual space can be directly analyzed.

The dynamic headspace method is a method of circulating air through a resin for a predetermined period of time by using a collection device equipped with a resin capable of adsorbing fragrance to an air pump, analyzing components adsorbed on the resin, The fragrance ingredients contained in a trace amount can be measured.

In addition to various fragrance and flavor components such as terpene, phenol, ketone, and ester, the analyzed aroma components include volatile organic chemical components generally present in the air and allergen components that can cause an allergic reaction. Ingredients such as limonene, hexyl cinnamic acid, linalool, benzyl alcohol, geraniol and the like are fragrance ingredients and can induce allergy. When these ingredients are incorporated into the perfume composition as they are, they may cause problems such as allergic reaction.

The present inventors analyzed the spatial components of the pine saplings collected from the Daechongpo pine forest of Seolaksan, which were collected through the dynamic headspace method. Based on the other components except for the atmospheric and allergenic components, Thereby completing the reproduction perfume composition.

Further, the present inventors have perfected the fragrance composition having a high degree of preference while reproducing the spatial flavor of the Sorak mountain pine tree community by adjusting the content of the fragrance ingredient and using a suitable solvent.

Accordingly, a problem to be solved by the present invention is to provide a fragrance composition recreating the spatial flavor of the Korean white pine cones.

Another object to be solved by the present invention is to provide a fragrance composition that reproduces the spatial flavor of the Sorak mountain pine cones which does not induce an allergic reaction by excluding the allergen components from the components collected by the dynamic head space method.

Another object to be solved by the present invention is to provide a fragrance composition which reproduces the spatial flavor of the Sorak mountain pine cones of Soraksan and has a high degree of preference by selecting a suitable solvent and adjusting the content of the fragrance ingredient.

Another object of the present invention is to provide a cosmetic composition comprising the perfume composition.

Another object of the present invention is to provide a perfume composition comprising the perfume composition.

Another object to be solved by the present invention is to provide a composition for external application for skin comprising the perfume composition.

In order to solve the above problems, the present invention provides a perfume composition recreating the spatial flavor of the Sorak mountain pine cones containing the fragrance component of the pine cones of Daechungbong, Seolak Mountain, as an effective ingredient.

The above-mentioned fragrance component excludes the allergen component of the space-oriented component of the pine tree community of Seolak Mountain. More specifically, the fragrance component includes alpha-pinene, beta-pinene, para- It is composed of terpinolene and thymol.

In addition, the composition of the present invention additionally contains citral dimethyl acetal, galaxolide, and allyl hexanoate to provide a spatial orientation of highly reproducible Seoraksan pine cones.

The present invention provides a fragrance composition which reproduces the spatial flavor of the Soraksan snow pine community which is improved by using isopropyl myristate as a solvent to improve the reproducibility of the fragrance and has a soft feeling.

In one embodiment of the present invention, the perfume composition of the present invention comprises 1 to 30.0 wt% alpha-pinene, 0.1 to 15.0 wt% beta-pinene, 2.0 to 50.0 wt% para-cymene, 0.1 to 18.0 wt% terpinolene, 0.01 to 5.0% by weight of thymol can be used to reproduce the spatial orientation of the pine cones of Sorak mountains. Outside this range, the fragrance similarity is lowered. Preferably contains from 15.0 to 25.0% by weight of alpha-pinene, from 5.0 to 10.0% by weight of beta-pinene, from 35.0 to 45.0% by weight of para-cymene, from 6.0 to 15.0% by weight of terpinolene and from 0.01 to 0.1% by weight of thymol, The spatial orientation of the snow pine tree community can be reproduced.

In one embodiment of the present invention, the perfume composition of the present invention further contains 0.001 to 3.0% by weight of citral dimethylacetal, 0.001 to 3.0% by weight of galactolide and 0.001 to 3.0% by weight of allyhexanoate, The spatial orientation of the snow pine tree community can be reproduced. Preferably 0.01 to 0.1% by weight of citral dimethylacetal, 0.01 to 0.1% by weight of galactolide and 0.001 to 0.1% by weight of allyl hexanoate.

In one embodiment of the present invention, the perfume composition of the present invention may contain 5.0 to 95.0% by weight of isopropyl myristate based on the total weight of the composition. Preferably 10.0-50.0 wt% isopropyl myristate based on the total weight of the composition.

In addition, the perfume composition mixed in the above-mentioned range is not limited thereto, and can be applied to general household products, cosmetic composition, perfume composition, composition for external application for skin and composition for oral cavity.

The perfume composition of the present invention can be used as a cosmetic composition for skin, lotion, essence, lotion, gel, nutritional cream, massage cream, hand cream, foot cream, foundation, makeup base, hair cream, hair tonic, hair conditioner, A bath liquid, a liquid cleanser, a soap or a shampoo.

The perfume composition of the present invention may be provided as a perfume composition, such as a perfume, a perfume, a deodorant, a diffuser or an aroma candle.

The perfume composition of the present invention can be provided as an external composition for skin such as ointment, lotion, soluble image, suspension, emulsion, cream, gel, spray, papermaking,

The perfume composition of the present invention may be provided as an oral composition such as a wax solution, a toothpaste, a dental floss, an oral spray, a mouthwash, a mouthwash for oral hygiene, and the like.

At this time, the compositions may further include colorants, fungicides, preservatives, antioxidants, moisturizers, thickeners, etc., which are generally acceptable for improving the physical properties. It is also possible to substitute some of the fragrance ingredients and the additional ingredients for oral use when they are provided in an oral composition.

The term "space aroma" as used in the present invention means a scent extracted from a specific area, and simply refers to a scent of the space other than a specific plant scent. In the present invention, a specific area means a snow pine community of Soraksan mountain.

The term "spatially-oriented component" means the component identified as a result of analyzing the components collected in the space. In the present invention, the spatial orientation of the pine tree community of Soraksan is collected by dynamic headspace method and analyzed by gas chromatography It means the spatial fragrance component of the pine tree community area of Seolak Mountain.

In the present invention, the analyzed spatial perfumed components are divided into fragrance components and other components, and spatial fragrance is reproduced using only fragrance components.

Other components include general atmospheric components and allergen components. In the present invention, the term "general atmospheric component" refers to volatile organic chemical components present in the atmosphere as well as specific regions analyzed for spatial incoherence. Specific "general atmospheric components" include benzaldehyde, acetophenone, octanoic acid, nonanoic acid, and decanoic acid. "Allergen ingredients" are known to have the potential to cause allergic reactions when they enter the body, and include limonene, α-isomethyl ionone, and benzyl alcohol.

The "fragrance component" is a component excluding the "general atmospheric component" and "allergen component" among the spatial fragrance components of the specific region analyzed. In the present invention, the fragrance components of the pine cones of Seoraksan are alpha-pinene, - cymene, terpinolene and thymol.

The perfume composition of the present invention has an effect of enhancing the reproducibility of the fragrance and improving the reproducibility of the spatial orientation of the pine tree community of Soraksan pine from the selection of a solvent which improves to have a soft feeling.

In addition, the perfume composition of the present invention has the effect of preventing the allergic reaction and maintaining spatial perfusion by removing allergen components from the spatially-oriented components collected by the dynamic headspace method.

In addition, the perfume composition of the present invention contains an additional component and has an effect of further improving the preference degree by adjusting the content of the perfume ingredient.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood, however, that the scope of the present invention is not limited by these examples.

Experimental Example  One. Space incense  Analysis of fragrance components

In the present invention, a dynamic headspace method was used to analyze the spatial component of the pine cones of Sorak mountain.

Mini - pump and TENAX filling tube were used for collecting the space - oriented components. The collection tool was installed in the space where the fragrance characteristic of the specific area was best, and the space fragrance was collected in the TENAX filling tube at a flow rate of 1 L / min for more than 3 hours. Gas chromatography was used to identify the spatial fragrance components in the collected air, and the conditions were as shown in Table 1 below.

GC Model Agilent 6890N Inlet Temp. 250 Split mode Splitless Cryo-focus Initial -90 Ramp1 90 / min to 180 DEG C Final 180 Column TC-WAX: 60 m-0.25 mm-0.25 m Oven temp. program Initial 40 (0 min) Ramp1 3 / min to 230 ° C Final 30 min Carrier gas flow Helium-1.0 ml / min MSD Model Agilent 5973N Transfer line 280 Quad 150 Ion source 230

As a result, the spatial fragrance components of the pine cones of Soraksan were analyzed as shown in Table 2 below.

Ingredients Content (% by weight) Alpha-pinene < / RTI > 1.408 Beta-pinene < / RTI > 0.740 Para-cymene < / RTI > 2.280 Terpinolene 0.704 Thymol 0.078 Other 94.790

In Table 2, the guitar includes volatile organic chemical components (that is, general atmospheric components) that are generally floating in the air and components that are likely to act as allergens (that is, allergen components). Only the fragrance ingredients were used except for the ingredients. The major fragrance components in the spruce community space of Soraksan except for the other components are α-pinene, β-pinene, p-cymene, terpinolene and thymol (thymol).

Table 3 shows the compositional names of the main general air and allergen components and the respective contents (% by weight with respect to total space-oriented components).

Ingredients Content (% by weight) Classification Toluene 16.510 General atmospheric composition Benzaldehyde < / RTI > 8.176 General atmospheric composition Acetophenone 7.443 General atmospheric composition Nonanoic acid 6.161 General atmospheric composition Decanoic acid 1.009 General atmospheric composition Benzoic acid 14.120 General atmospheric composition Lauric acid 11.582 General atmospheric composition Linalool 1.065 Allogenic component Limonene 1.556 Allogenic component

Experimental Example  2. According to the analysis result Example  Manufacturing and sensory evaluation

Based on the results of the analysis of Experimental Example 1, Examples 1 and 2 having the compositions shown in Table 4 were prepared except for the other ingredients such as allergen and the similarity between the flavor and the flavor of the natural pine spruce community was verified by sensory evaluation.

Dipropylene glycol (DPG) and isopropyl myristate were used as solvents in the preparation of the examples. Dipropylene glycol is used as a flavoring agent, a solvent and a viscosity reducing agent, and isopropyl myristate has good skin absorbency and is mainly used as a cosmetic or dermatological solvent. In addition, both of these solvents are generally used as a solvent (solvent) for dissolving various constituents in the production of a perfume composition.

Ingredients Content (% by weight) Example 1 Example 2 Alpha-pinen 1.50 1.50 Beta-pinen 0.70 0.70 Para-cymen 2.30 2.30 Terpinolene 0.70 0.70 Thymol 0.07 0.07 Dipropylene glycol 94.73 - Isopropyl myristate - 94.73 total 100.00 100.00

Sensory evaluation was carried out on perfume experts composed of irritants. The fragrance suitability of the items was evaluated as -10 (very weak - unsuitable), -5 (slightly weak - fit), 0 (very fit) High-fit), and +10 (high-to-poor) scores. In other words, the closer the score is to zero, the better the local space is.

The diffusiveness and intensity were compared to assess reproducibility with local spatial orientation. The diffusiveness refers to the ability of the fragrance to spread around, and the intensity refers to the intensity of the fragrance. Since it is a basic sensory evaluation item of the fragrance composition, it is an item suitable for evaluating the reproducibility specific to the spatial fragrance.

The sensory evaluation results of Examples 1 and 2 for the above items are shown in Table 5 below.

Evaluation items Local space Example 1 Example 2 Diffusiveness 0 -3.0 -2.0 Intensity 0 +2.0 +1.0

As a result of the sensory evaluation of the above Examples 1 and 2, it was confirmed that both of the examples were less than ± 5.0 points and were similar to the fragrance type in the local space. The composition of Example 1 was slightly more diffusive (-3.0), slightly higher (+2.0), and more diffusive (-2.0) and intensity (+2.0) 1.0) was evaluated as similar to the local space.

Therefore, based on the above sensory evaluation results, an additional ingredient for further enhancing the reproducibility with respect to the local space was searched, and the content of the entire constituent including the suitable solvent was adjusted to find an optimal combination flavor.

Experimental Example  3. Depending on the additional ingredient mixture Example  Manufacturing and sensory evaluation

In order to improve the reproducibility and preference of the fragrance, citral dimethyl acetal, galaxolide and / or allyl hexanoate, To prepare a new embodiment. As the solvent, isopropyl myristate evaluated as excellent in reproducibility in Table 5 was used.

Examples 3 to 7 having the compositions shown in the following Table 6 were prepared and the similarity between the flavor and the flavor of the natural pine spruce community of Soraksan was confirmed by sensory evaluation.

Ingredients Example 3 Example 4 Example 5 Example 6 Example 7 Alpha-pinen 1.50 1.50 1.50 1.50 1.50 Beta-pinen 0.70 0.70 0.70 0.70 0.70 Para-cymen 2.30 2.30 2.30 2.30 2.30 Terpinolene 0.70 0.70 0.70 0.70 0.70 Thymol 0.07 0.07 0.07 0.07 0.07 Citral Dimethylacetal 3.00 - - 1.50 1.00 Galaxy Ride - 3.00 - 1.50 1.00 Allyhexanoate - - 3.00 - 1.00 Isopropyl myristate 91.73 91.73 91.73 91.73 91.73 total 100.00 100.00 100.00 100.00 100.00

The sensory evaluation was carried out in the same manner as in Experimental Example 1, and the evaluation results are shown in Table 7 below.

Evaluation items Local space Example 3 Example 4 Example 5 Example 6 Example 7 Diffusibility 0 -2.0 -1.5 -1.5 -1.0 -0.5 burglar 0 +2.5 +2.5 +2.0 +1.0 +1.0

The sensory evaluation results of Examples 3 to 7 were compared with those of Examples 1 and 2, and it was found that citral dimethylacetal, galactaride and / or allyhexanoate were further mixed Examples 3 to 7 showed better diffusibility and intensity of fragrance was appropriate, and thus it was confirmed that the reproducibility was excellent.

Experimental Example  4. Changes in content Example  Manufacturing and sensory evaluation

The new combination fragrances of Examples 8 to 11 were prepared by varying the content in the fragrance components identified in Example 7. The specific composition is shown in Table 8 below.

Ingredients Example 7 Example 8 Example 9 Example 10 Example 11 Alpha-pinen 1.50 7.50 15.00 20.00 25.00 Beta-pinen 0.70 3.50 5.00 7.00 10.00 Para-cymen 2.30 11.50 25.00 40.00 45.00 Terpinolene 0.70 3.50 8.00 12.00 15.00 Thymol 0.07 0.70 0.01 0.05 0.10 Citral Dimethylacetal 1.00 0.50 0.10 0.05 0.001 Galaxy Ride 1.00 0.50 0.10 0.05 0.001 Allyhexanoate 1.00 0.50 0.10 0.05 0.001 Isopropyl myristate 91.73 71.80 46.69 20.80 4.90 Total (% by weight) 100.00 100.00 100.00 100.00 100.00

For the fragrance evaluation of Examples 7 to 11, evaluation was made by the five-point rating method as strength, closeness, diffusiveness and hedonics as shown in Table 9 below. The evaluation was carried out with perfume experts composed of a perfume maker. The evaluation results are shown in Table 10 below. If each item is more than 2.5 points, it is judged that there is excellence in the item.

Evaluation items score Strength: Is the strength of the fragrance appropriate? 1 2 3 4 5
(Complaint) (fitness) (satisfaction) Reproducibility: Has the spatial orientation been expressed well? Diffusivity: The spread of fragrance is good Preference: Does it feel like a pleasant scent

Subject burglar Reproducibility preference Diffusibility Average Example 7 2.50 2.50 2.50 2.50 2.50 Example 8 2.75 2.75 2.50 2.50 2.63 Example 9 3.25 3.25 3.50 3.50 3.38 Example 10 3.50 4.50 3.75 4.00 3.94 Example 11 3.00 3.00 3.25 4.00 3.31

As a result of the sensory evaluation, it was confirmed that Examples 7 to 11 had superiority to the respective items, and in particular, the perfume composition of Example 10 was found to be excellent in fragrance strength, reproducibility, preference and diffusibility.

Claims (9)

Wherein the composition comprises 1 to 30.0% by weight of alpha-pinene, 0.1 to 15.0% by weight of beta-pinene, 2.0 to 50.0% by weight of p-cymene, a perfume recreating the spatial flavor of a Pinus pumila community containing 0.1 to 18.0% by weight of terpinolene and 0.01 to 5.0% by weight of thymol and containing isopropyl myristate as a solvent, Composition.
The method according to claim 1,
Wherein the composition further comprises at least one selected from the group consisting of citral dimethyl acetal, galaxolide, and allyl hexanoate. Of the perfume composition.
delete 3. The method of claim 2,
The composition further comprises at least one selected from the group consisting of 0.001 to 3.0% by weight of citral dimethylacetal, 0.001 to 3.0% by weight of galactolide and 0.001 to 3.0% by weight of allyhexanoate based on the total weight of the composition Which is characterized in that the fragrance composition of the pine tree community of Soraksan mountain is reproduced.
delete The method according to claim 1,
Wherein the isopropyl myristate is contained in an amount of 5.0 to 95.0% by weight based on the total weight of the composition.
A cosmetic composition comprising the perfume composition according to any one of claims 1, 2 and 4.
A perfume composition comprising the perfume composition of any one of claims 1, 2 or 4.
A composition for external application for skin comprising the perfume composition according to any one of claims 1, 2 and 4.