KR101843168B1 - Perfume composition for expressing the fragrance of dongbaekdongsan in jeju island - Google Patents

Abstract

The present invention relates to a perfume composition recreating the spatial flavor of a camellia garden of Jeju Island, and a suitable solvent is selected based on the intrinsic fragrance component of the camellia plant of Cheju Island, The present invention relates to a perfume composition having excellent palatability while reproducing fragrance.

Description

TECHNICAL FIELD [0001] The present invention relates to a perfume composition that reproduces the spatial flavor of a camellia garden of Jeju Island.

The present invention relates to a perfume composition recreating the spatial fragrance of the camellia garden of Jeju Island. The perfume composition reproduces the spatial fragrance of the camellia garden of Jeju Island. The optimal solvent is selected based on the intrinsic fragrance component of the camellia garden of Jeju Island, The present invention relates to a perfume composition having excellent palatability.

The desire to spend the time of healing in the nature leaving the everyday space to the modern people living busy life is getting bigger, but there are many modern people who do not even have enough time to leave the forest and leave for the forest. The present inventors have conceived the present invention to provide a method of easily healing time within a short time by providing a space-recreating perfume composition that appears to be in a real forest.

The present inventors have selected a camellia garden of Jeju Island as a region having a Korean beauty and healing emotion and have perfected a perfume composition which gives an image of space and a distinctive feeling by inventing a perfume composition recreating the spatial perfume of this region.

The mountain of Dongbaekdong is designated as No. 10 of Jeju Special Self-Governing Province. It is a large, evergreen broad-leaved forest in the east of Seonhwi-ri. It has a forest of more than 20,000-year-old camellia trees and is named Camellia, but grows with mature species such as japonica, japonica and trivia.

Camellia (Camelia japonica) is an evergreen tree of the wheel namumok theaceae bark is grayish white and compound eyes is a long oval board. Leaves are alternate, oval or long oval. There are wavy sawtooths on the edges of the leaves, shiny and hairless.

On the other hand, there are various methods for reproducing the spatial incense. For example, a solvent extraction method in which a plant in the space is collected by a commonly used method to make a fragrance ingredient into an absolute form, and a steam distillation method in which a fragrance ingredient is made into an essential oil. However, the above methods require high heat in the extraction process, or the process is complicated and takes a lot of time, which may be different from the original flavor. In addition, it does not meet the object of the present invention because it reproduces the fragrance of the plant rather than reproducing the perfume of the space itself.

In the present invention, the dynamic headspace method used for analyzing the spatial fragrance component does not require a solvent and does not require a pretreatment step, so that the fragrance component in the actual space can be directly analyzed.

The dynamic headspace method is a method of circulating air through a resin for a predetermined period of time by using a collection device equipped with a resin capable of adsorbing fragrance to an air pump, analyzing components adsorbed on the resin, The fragrance ingredients contained in a trace amount can be measured.

In addition to various fragrance and flavor components such as terpene, phenol, ketone, and ester, the analyzed aroma components include volatile organic chemical components generally present in the air and allergen components that can cause an allergic reaction. Ingredients such as limonene, hexyl cinnamic acid, linalool, benzyl alcohol, geraniol and the like are fragrance ingredients and can induce allergy. When these ingredients are incorporated into the perfume composition as they are, they may cause problems such as allergic reaction.

The present inventors analyzed the spatial components of the camellia of Cheju Island collected through the dynamic headspace method, and then, based on the other components except for the atmospheric and allergen components, the fragrance composition .

Further, the inventors of the present invention have perfected the fragrance composition having a high degree of preference while reproducing the spatial flavor of the camellia tongue of Cheju Island by adjusting the content of the fragrance ingredient and using a suitable solvent.

Accordingly, a problem to be solved by the present invention is to provide a fragrance composition recreating the spatial flavor of the camellias of Cheju Island.

Another object to be solved by the present invention is to provide a flavor composition recreating the spatial flavor of Cheongdo Dongbaekwangsan which does not induce an allergic reaction by excluding the allergen components among the components collected by the dynamic headspace method.

Another object to be solved by the present invention is to provide a fragrance composition which reproduces the spatial flavor of the camellia tongue of Cheju Island and has a high preference degree by selecting a suitable solvent and adjusting the content of the fragrance ingredient.

Another object of the present invention is to provide a cosmetic composition comprising the perfume composition.

Another object of the present invention is to provide a perfume composition comprising the perfume composition.

Another object to be solved by the present invention is to provide a composition for external application for skin comprising the perfume composition.

In order to solve the above problems, the present invention provides a perfume composition recreating the spatial flavor of Cheju Island camellia tincture containing the fragrance component of the camellia tincture of Cheju Island as an active ingredient.

The above-mentioned fragrance component excludes the allergen component of the spatially-oriented component of the camellia of Cheju Island. More specifically, the fragrance component includes alpha-pinene, eucalyptol, beta-pinene, p-cymene and anisic aldehyde.

In addition, the composition of the present invention provides a spatial orientation of the reproducible Cheju Island camellia plant by using isobornyl acetate as an additional component.

The present invention provides a perfume composition recreating the spatial flavor of Jeju Island camellia plant improved in perfume reproducibility using isopropyl myristate as a solvent and improved to have a soft feel.

In one embodiment of the invention, the perfume composition of the present invention comprises 0.1 to 10.0% by weight of alpha-pinene, 0.1 to 6.0% by weight of eucalyptol, 0.1 to 6.0% by weight of beta-pinene, 0.1 to 5.0% by weight and an anhydrous aldehyde of 0.1 to 5.0% by weight, so that the spatial flavor of the camellia garden of Jeju Island can be reproduced. Outside this range, the fragrance similarity may be lowered. More preferably, 0.5 to 1.5 wt% of alpha-pinene, 0.3 to 0.9 wt% of eucalyptol, 0.25 to 0.8 wt% of beta-pinene, 0.25 to 0.75 wt% of para-cimene and 0.25 to 0.75 wt% of aniline aldehyde ≪ / RTI >

In one embodiment of the present invention, the perfume composition of the present invention may contain 0.001 to 3.0% by weight of isobornyl acetate and 75.0 to 99.0% by weight of isopropyl myristate based on the total weight of the composition. Outside this range, the fragrance similarity may be lowered. More preferably 0.03 to 0.09% by weight of isobornyl acetate and 91.0 to 98.0% by weight of isopropyl myristate.

In addition, the perfume composition mixed in the above-mentioned range is not limited thereto, and can be applied to general household products, cosmetic composition, perfume composition, composition for external application for skin and composition for oral cavity.

The perfume composition of the present invention can be used as a cosmetic composition for skin, lotion, essence, lotion, gel, nutritional cream, massage cream, hand cream, foot cream, foundation, makeup base, hair cream, hair tonic, hair conditioner, A bath liquid, a liquid cleanser, a soap or a shampoo.

The perfume composition of the present invention may be provided as a perfume composition, such as a perfume, a perfume, a deodorant, a diffuser or an aroma candle.

The perfume composition of the present invention can be provided as an external composition for skin such as ointment, lotion, soluble image, suspension, emulsion, cream, gel, spray, papermaking,

The perfume composition of the present invention may be provided as an oral composition such as a wax solution, a toothpaste, a dental floss, an oral spray, a mouthwash, a mouthwash for oral hygiene, and the like.

At this time, the compositions may further include colorants, fungicides, preservatives, antioxidants, moisturizers, thickeners, etc., which are generally acceptable for improving the physical properties. It is also possible to substitute some of the fragrance ingredients and the additional ingredients for oral use when they are provided in an oral composition.

The term "space aroma" as used in the present invention means a scent extracted from a specific area, and simply refers to a scent of the space other than a specific plant scent. In the present invention, a specific area means a camellia garden of Jeju Island.

The term "spatially-oriented component" means a component identified as a result of analyzing the components captured in the space. In the present invention, the spatial incense of the camellia of Cheju Island is collected by dynamic headspace method and analyzed by gas chromatography Which means the spatial fragrance component of the Cheongju camellia garden space.

In the present invention, the analyzed spatial perfumed components are divided into fragrance components and other components, and spatial fragrance is reproduced using only fragrance components.

Other components include general atmospheric components and allergen components. In the present invention, the term "general atmospheric component" refers to volatile organic chemical components present in the atmosphere as well as specific regions analyzed for spatial incoherence. Specific "general atmospheric components" include toluene, xylene, benzoic acid, and phenol. "Allergen ingredients" are known to have the potential to cause allergic reactions when they enter the body, including limonene, linalool, and benzyl alcohol.

The "fragrance component" is a component other than the "general atmospheric component" and "allergen component" among the spatial fragrance components of the specific region analyzed. In the present invention, the fragrance component of the camellia peach of Cheju Island is alpha-pinene, eucalyptol, Pine, para-cymene and an aldehyde.

The perfume composition of the present invention has an effect of enhancing the reproducibility of the fragrance and enhancing the reproducibility of the spatial flavor of the camellia garden of Jeju Island by selecting a solvent which improves to have a soft feeling.

In addition, the perfume composition of the present invention has the effect of preventing the allergic reaction and maintaining spatial perfusion by removing allergen components from the spatially-oriented components collected by the dynamic headspace method.

Further, the perfume composition of the present invention has an effect of further improving the preference degree by adjusting the content of the perfume ingredient.

Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood, however, that the scope of the present invention is not limited by these examples.

Experimental Example  One. Space incense  Analysis of fragrance components

In the present invention, the dynamic headspace method was used to analyze the spatial component of the camellia of Cheju Island.

Mini - pump and TENAX filling tube were used for collecting the space - oriented components. The collection tool was installed in the space where the fragrance characteristic of the specific area was best, and the space fragrance was collected in the TENAX filling tube at a flow rate of 1 L / min for more than 3 hours. Gas chromatography was used to identify the spatial fragrance components in the collected air, and the conditions were as shown in Table 1 below.

GC Model Agilent 6890N Inlet Temp. 250 ℃ Split mode Splitless Cryo-focus Initial -90 ° C Ramp1 90 ° C / min to 180 ° C Final 180 DEG C Column TC-WAX: 60 m-0.25 mm-0.25 m Oven temp. program Initial 40 [deg.] C (0 min) Ramp1 3 ° C / min to 230 ° C Final 30 min Carrier gas flow Helium-1.0 ml / min MSD Model Agilent 5973N Transfer line 280 ℃ Quad 150 ℃ Ion source 230 ℃

As a result, the spatial fragrance components of the camellia of Cheju Island were analyzed as shown in Table 2 below.

Ingredients Content (% by weight) Alpha-pinene < / RTI > 1.253 Eucalyptol 0.116 Beta-pinene < / RTI > 0.483 Para-cymene < / RTI > 0.665 Anisic aldehyde 0.651 Other 96.832 total 100

In Table 2, the guitar contains volatile organic chemical components (that is, general atmospheric components) that are generally floating in the air, pollutants, and components that are likely to act as allergens (i.e., allergen components) Only the fragrance components were used except these other components. The main fragrance components in the Cheongju Dongbaek Dongsan space except for the other ingredients are alpha - pinene, eucalyptol, beta - pinene, para - cymene and anilide aldehyde.

Table 3 shows the compositional names and contents (% by weight with respect to total space components) of major atmospheric, pollutant and allergen components.

Ingredients Content (% by weight) Classification Benzaldehyde < / RTI > 15.807 General atmospheric composition Acetophenone 15.063 General atmospheric composition Nonanoic acid 7.574 General atmospheric composition Phenol 3.707 General atmospheric composition Toluene 14.701 General atmospheric composition d-limonene < / RTI > 2.606 Allogenic component Benzyl alcohol 0.197 Allogenic component

Experimental Example  2. According to the analysis result Example  Manufacturing and sensory evaluation

Based on the results of the analysis of Experimental Example 1, Examples 1 and 2 having the compositions shown in Table 4 were prepared, except for the other components such as allergen, and the similarity between the flavor and the aroma of the native Cheju Island was verified by sensory evaluation.

Dipropylene glycol (DPG) and isopropyl myristate were used as solvents in the preparation of the examples. Dipropylene glycol has a use as a flavoring agent, a solvent and a viscosity reducing agent, and isopropyl myristate has good skin absorbency and is mainly used as a cosmetic or dermatological solvent. In addition, both of these solvents are generally used as a solvent (solvent) for dissolving various constituents in the preparation of a perfume composition.

Ingredients Content (% by weight) Example 1 Example 2 Alpha-pinen 1.3 1.3 Eucalyptol 0.1 0.1 Beta-pinen 0.5 0.5 Para-cymen 0.7 0.7 No formaldehyde 0.7 0.7 Dipropylene glycol 96.7 - Isopropyl myristate - 96.7 total 100.0 100.0

Sensory evaluation was carried out on perfume experts composed of irritants. The fragrance suitability of the items was evaluated as -10 (very weak - unsuitable), -5 (slightly weak - fit), 0 (very fit) High-fit), and +10 (high-to-poor) scores. In other words, the closer the score is to zero, the better the local space is.

Mildness and intensity were compared to assess reproducibility in the local space. Softness means a comfortable fragrance type that is not irritating, and is an item suitable for evaluating the reproducibility specific to the space flavor. The strength means the strength of the fragrance and is used as a basic sensory evaluation item of the perfume composition.

The sensory evaluation results of Examples 1 and 2 for the above items are shown in Table 5 below.

Evaluation items Local space Example 1 Example 2 Mildness 0 -3.5 -3.0 Intensity 0 -4.5 -3.5

As a result of the sensory evaluation of the above Examples 1 and 2, it was confirmed that there was a difference depending on the solvent, but it was similar to the aroma type in the local space. However, as shown in Table 5, it was evaluated that the degree of softness (-3.5 and -3.0) was weak and the strengths (-4.5 and -3.5) were somewhat weaker than those of the local space.

Therefore, based on the above sensory evaluation results, an additional ingredient for further enhancing the reproducibility with respect to the local space was searched, and the content of the entire constituent including the suitable solvent was adjusted to find an optimal combination flavor.

Experimental Example  3. Depending on the additional ingredient mixture Example  Manufacturing and sensory evaluation

As a result of Experimental Example 2, one of the flavoring agents, isobornyl acetate, was added to enhance the softness of the fragrance.

Examples are shown in Table 6, in which isobornyl acetate was added as an additional ingredient to Examples 1 and 2, respectively. The similarity between these fragrances and the flavor of natural Cheju can be verified through sensory evaluation Respectively.

Ingredients Content (% by weight) Example 3 Example 4 Alpha-pinen 1.3 1.3 Eucalyptol 0.1 0.1 Beta-pinen 0.5 0.5 Para-cymen 0.7 0.7 No formaldehyde 0.7 0.7 Isobornyl acetate 0.1 0.1 Dipropylene glycol 96.6 - Isopropyl myristate - 96.6 total 100.0 100.0

The sensory evaluation was carried out in the same manner as in Experimental Example 2, and the evaluation results are shown in Table 7 below.

Evaluation items Local space Example 1 Example 2 Example 3 Example 4 Mildness 0 -3.5 -3.0 +0.5 +0.5 Intensity 0 -4.5 -3.5 -1.5 -0.5

Comparing the results of the sensory evaluations of Examples 3 and 4 with those of Examples 1 and 2, Examples 1 and 2 were evaluated as having a weaker fragrance intensity and a somewhat lower degree of softness in comparison with the local space flavor, In Examples 3 and 4 in which isobornyl acetate was added as an additional component, the degree of softness was improved, and the strength was also improved, thereby confirming that the reproducibility was further improved. In particular, the reproducibility of Example 4 using isopropyl myristate as a solvent and adding isobornyl acetate was found to be the most excellent.

Experimental Example  4. Changes in content Example  Manufacturing and sensory evaluation

As is clear from the results of Experimental Example 3, when the isobornyl acetate was used as an additional component, the perfume composition was excellent in reproducibility of the perfume composition. . In addition, isopropyl myristate was selected as a solvent.

The new combination fragrances of Examples 5 to 8 were prepared by varying the contents of the components added to the fragrance components analyzed in Experimental Example 1 plus the additional components identified in Experimental Example 2. The specific composition is shown in Table 8 below.

Ingredients Example 4 Example 5 Example 6 Example 7 Example 8 Alpha-pinen 1.3 1.5 1.86 0.53 0.97 Eucalyptol 0.1 0.5 1.0 0.8 0.6 Beta-pinen 0.5 1.21 0.24 0.86 0.55 Para-cymen 0.7 0.2 1.2 1.0 0.5 No formaldehyde 0.7 1.0 1.5 0.4 0.5 Isobornyl acetate 0.1 1.0 0.5 0.03 0.06 Isopropyl myristate 96.6 94.59 93.7 96.38 96.82 Total (% by weight) 100.0 100.0 100.0 100.0 100.0

For the fragrance evaluation of Examples 4 to 8, evaluation was made by a five-point rating method as strength, reproducibility (closeness), diffusiveness and hedonics as shown in Table 9 below. The evaluation was carried out with perfume experts composed of a perfume maker. The evaluation results are shown in Table 10 below. If each item is more than 2.5 points, it is judged that there is excellence in the item.

Evaluation items score Strength: Is the strength of the fragrance appropriate?
1 2 3 4 5
(Complaint) (fitness) (satisfaction) Reproducibility: Has the spatial orientation been expressed well? Diffusivity: The spread of fragrance is good Preference: Does it feel like a pleasant scent

Subject burglar Reproducibility preference Diffusibility Average Example 4 2.50 2.25 3.25 3.00 2.75 Example 5 2.25 2.50 3.50 3.00 2.81 Example 6 2.50 3.00 3.25 2.50 2.81 Example 7 3.25 3.25 3.50 3.25 3.31 Example 8 3.75 3.25 4.75 3.25 3.75

As a result of the sensory evaluation, it was confirmed that Examples 4 to 8 were superior to each other in the item, and in particular, the perfume composition of Example 8 was found to be excellent in fragrance strength, reproducibility, preference and diffusibility.

Claims (9)

0.1 to 10.0 wt.% Of alpha-pinene, 0.1 to 6.0 wt.% Of eucalyptol, 0.1 to 6.0 wt.% Of beta-pinene, 0.1 to 6.0 wt.% Of para-cymene (p the camellia japonica community comprising 0.1 to 5.0% by weight of anisic aldehyde and 0.1 to 5.0% by weight of anisic aldehyde and containing isopropyl myristate as a solvent, The perfume composition being reproduced.
The method according to claim 1,
Wherein the cosmetic composition further comprises isobornyl acetate as an additional ingredient. The fragrance composition recreates the spatial flavor of the camellia community of Cheju Island.
delete 3. The method of claim 2,
Wherein the isobornyl acetate is contained in an amount of 0.001 to 3.0% by weight based on the total weight of the composition.
delete The method according to claim 1,
Wherein the isopropyl myristate is contained in an amount of 75.0 to 99.0% by weight based on the total weight of the composition.
A cosmetic composition comprising the perfume composition according to any one of claims 1, 2 and 4.
A perfume composition comprising the perfume composition of any one of claims 1, 2 or 4.
A composition for external application for skin comprising the perfume composition according to any one of claims 1, 2 and 4.