KR20170032376A - 고 염소 함량 저 감쇠 광섬유 - Google Patents
고 염소 함량 저 감쇠 광섬유 Download PDFInfo
- Publication number
- KR20170032376A KR20170032376A KR1020177003852A KR20177003852A KR20170032376A KR 20170032376 A KR20170032376 A KR 20170032376A KR 1020177003852 A KR1020177003852 A KR 1020177003852A KR 20177003852 A KR20177003852 A KR 20177003852A KR 20170032376 A KR20170032376 A KR 20170032376A
- Authority
- KR
- South Korea
- Prior art keywords
- chlorine
- preform
- core
- fluorine
- microns
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000460 chlorine Substances 0.000 title claims description 136
- 229910052801 chlorine Inorganic materials 0.000 title claims description 108
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title claims description 105
- 239000013307 optical fiber Substances 0.000 title claims description 64
- 238000005253 cladding Methods 0.000 claims abstract description 116
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 109
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 44
- 239000000835 fiber Substances 0.000 claims description 97
- 229910052731 fluorine Inorganic materials 0.000 claims description 77
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 76
- 239000011737 fluorine Substances 0.000 claims description 76
- 238000000034 method Methods 0.000 claims description 70
- 239000004071 soot Substances 0.000 claims description 61
- 239000011521 glass Substances 0.000 claims description 36
- 229910003902 SiCl 4 Inorganic materials 0.000 claims description 27
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 20
- 238000005245 sintering Methods 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 12
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 238000000151 deposition Methods 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000005229 chemical vapour deposition Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims 4
- 235000010446 mineral oil Nutrition 0.000 claims 4
- 150000001875 compounds Chemical class 0.000 claims 3
- 239000006185 dispersion Substances 0.000 description 27
- 239000002019 doping agent Substances 0.000 description 22
- 230000003287 optical effect Effects 0.000 description 19
- 238000007711 solidification Methods 0.000 description 16
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- 238000012360 testing method Methods 0.000 description 12
- 239000001307 helium Substances 0.000 description 10
- 229910052734 helium Inorganic materials 0.000 description 10
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 10
- 229910005793 GeO 2 Inorganic materials 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
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- 239000006200 vaporizer Substances 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium dioxide Chemical compound O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000012681 fiber drawing Methods 0.000 description 3
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- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- DTTPWCNKTMQMTE-TYNNPWLESA-N [(1R,2S,3S,4S,5R,6S,8R,12S,13S,16R,19S,20R,21S)-14-ethyl-2-hydroxy-4,6,19-trimethoxy-16-methyl-9,11-dioxa-14-azaheptacyclo[10.7.2.12,5.01,13.03,8.08,12.016,20]docosan-21-yl] acetate Chemical compound CCN1C[C@]2(C)CC[C@H](OC)[C@]34[C@@H]2[C@H](OC(C)=O)[C@@]2(OCO[C@@]22C[C@H](OC)[C@H]5C[C@]3(O)[C@@H]2[C@H]5OC)[C@@H]14 DTTPWCNKTMQMTE-TYNNPWLESA-N 0.000 description 2
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- DTTPWCNKTMQMTE-UHFFFAOYSA-N delphelatine Natural products O1COC2(C3C4OC)CC(OC)C4CC3(O)C34C(OC)CCC5(C)CN(CC)C4C21C(OC(C)=O)C53 DTTPWCNKTMQMTE-UHFFFAOYSA-N 0.000 description 2
- WNIGHBYIOLQQSJ-UHFFFAOYSA-N deltaline Natural products CCN1CC2(COC)CCC(O)C34C2C(OC(=O)C)C5(OCOC56CC(OC)C7CC3(O)C6C7O)C14 WNIGHBYIOLQQSJ-UHFFFAOYSA-N 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 230000000994 depressogenic effect Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
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- UAOUIVVJBYDFKD-XKCDOFEDSA-N (1R,9R,10S,11R,12R,15S,18S,21R)-10,11,21-trihydroxy-8,8-dimethyl-14-methylidene-4-(prop-2-enylamino)-20-oxa-5-thia-3-azahexacyclo[9.7.2.112,15.01,9.02,6.012,18]henicosa-2(6),3-dien-13-one Chemical compound C([C@@H]1[C@@H](O)[C@@]23C(C1=C)=O)C[C@H]2[C@]12C(N=C(NCC=C)S4)=C4CC(C)(C)[C@H]1[C@H](O)[C@]3(O)OC2 UAOUIVVJBYDFKD-XKCDOFEDSA-N 0.000 description 1
- 239000010963 304 stainless steel Substances 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
- 229910020163 SiOCl Inorganic materials 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000003491 array Methods 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
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- 238000013016 damping Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 238000007496 glass forming Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- -1 i.e. Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 230000003595 spectral effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Images
Classifications
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- G02B6/02009—Large effective area or mode field radius, e.g. to reduce nonlinear effects in single mode fibres
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- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
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- C03B37/012—Manufacture of preforms for drawing fibres or filaments
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- C03B37/018—Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
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- C03B37/018—Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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- C03B2207/30—For glass precursor of non-standard type, e.g. solid SiH3F
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- C03B37/01205—Manufacture of preforms for drawing fibres or filaments starting from tubes, rods, fibres or filaments
- C03B37/01211—Manufacture of preforms for drawing fibres or filaments starting from tubes, rods, fibres or filaments by inserting one or more rods or tubes into a tube
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- C03B37/014—Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD]
- C03B37/018—Manufacture of preforms for drawing fibres or filaments made entirely or partially by chemical means, e.g. vapour phase deposition of bulk porous glass either by outside vapour deposition [OVD], or by outside vapour phase oxidation [OVPO] or by vapour axial deposition [VAD] by glass deposition on a glass substrate, e.g. by inside-, modified-, plasma-, or plasma modified- chemical vapour deposition [ICVD, MCVD, PCVD, PMCVD], i.e. by thin layer coating on the inside or outside of a glass tube or on a glass rod
- C03B37/01807—Reactant delivery systems, e.g. reactant deposition burners
- C03B37/01838—Reactant delivery systems, e.g. reactant deposition burners for delivering and depositing additional reactants as liquids or solutions, e.g. for solution doping of the deposited glass
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- C—CHEMISTRY; METALLURGY
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- C03C2201/00—Glass compositions
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2201/00—Glass compositions
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- C03C2201/12—Doped silica-based glasses containing boron or halide containing fluorine
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
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-
2015
- 2015-06-30 US US14/755,469 patent/US9618692B2/en active Active
- 2015-07-10 WO PCT/US2015/039854 patent/WO2016007806A1/en not_active Ceased
- 2015-07-10 CN CN201580048706.8A patent/CN107076921B/zh active Active
- 2015-07-10 EP EP15742456.5A patent/EP3166899B1/en active Active
- 2015-07-10 KR KR1020177003852A patent/KR20170032376A/ko not_active Withdrawn
- 2015-07-10 JP JP2017501188A patent/JP6632600B2/ja active Active
- 2015-07-10 RU RU2017104234A patent/RU2706849C2/ru active
- 2015-07-10 BR BR112017000501A patent/BR112017000501A2/pt not_active Application Discontinuation
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2017
- 2017-02-28 US US15/444,687 patent/US10429579B2/en active Active
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2019
- 2019-08-19 US US16/543,967 patent/US11237321B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2017104234A (ru) | 2018-08-10 |
| US9618692B2 (en) | 2017-04-11 |
| RU2706849C2 (ru) | 2019-11-21 |
| JP2017526601A (ja) | 2017-09-14 |
| US11237321B2 (en) | 2022-02-01 |
| CN107076921B (zh) | 2019-09-03 |
| US20160011365A1 (en) | 2016-01-14 |
| US10429579B2 (en) | 2019-10-01 |
| WO2016007806A1 (en) | 2016-01-14 |
| BR112017000501A2 (pt) | 2017-11-07 |
| EP3166899B1 (en) | 2020-09-30 |
| JP6632600B2 (ja) | 2020-01-22 |
| EP3166899A1 (en) | 2017-05-17 |
| CN107076921A (zh) | 2017-08-18 |
| US20190369325A1 (en) | 2019-12-05 |
| RU2017104234A3 (enExample) | 2018-12-17 |
| US20170168231A1 (en) | 2017-06-15 |
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