KR20130131320A - 경화성 수지 조성물 및 그것을 사용하여 제조된 다층 라미네이트 - Google Patents
경화성 수지 조성물 및 그것을 사용하여 제조된 다층 라미네이트 Download PDFInfo
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- KR20130131320A KR20130131320A KR1020137008523A KR20137008523A KR20130131320A KR 20130131320 A KR20130131320 A KR 20130131320A KR 1020137008523 A KR1020137008523 A KR 1020137008523A KR 20137008523 A KR20137008523 A KR 20137008523A KR 20130131320 A KR20130131320 A KR 20130131320A
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- South Korea
- Prior art keywords
- meth
- resin composition
- curable resin
- molecule
- acrylic
- Prior art date
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- 239000011342 resin composition Substances 0.000 title claims abstract description 83
- 239000010410 layer Substances 0.000 claims abstract description 76
- 239000011247 coating layer Substances 0.000 claims abstract description 72
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- 239000000758 substrate Substances 0.000 claims abstract description 52
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 39
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 39
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 33
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 32
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims abstract description 27
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 26
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 59
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 59
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- 229920000178 Acrylic resin Polymers 0.000 claims description 22
- 238000003847 radiation curing Methods 0.000 claims description 20
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- 238000002360 preparation method Methods 0.000 description 4
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- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
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- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 3
- 238000013007 heat curing Methods 0.000 description 3
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- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- MYWOJODOMFBVCB-UHFFFAOYSA-N 1,2,6-trimethylphenanthrene Chemical compound CC1=CC=C2C3=CC(C)=CC=C3C=CC2=C1C MYWOJODOMFBVCB-UHFFFAOYSA-N 0.000 description 2
- AZYRZNIYJDKRHO-UHFFFAOYSA-N 1,3-bis(2-isocyanatopropan-2-yl)benzene Chemical compound O=C=NC(C)(C)C1=CC=CC(C(C)(C)N=C=O)=C1 AZYRZNIYJDKRHO-UHFFFAOYSA-N 0.000 description 2
- FWWWRCRHNMOYQY-UHFFFAOYSA-N 1,5-diisocyanato-2,4-dimethylbenzene Chemical compound CC1=CC(C)=C(N=C=O)C=C1N=C=O FWWWRCRHNMOYQY-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 description 2
- LWRBVKNFOYUCNP-UHFFFAOYSA-N 2-methyl-1-(4-methylsulfanylphenyl)-2-morpholin-4-ylpropan-1-one Chemical compound C1=CC(SC)=CC=C1C(=O)C(C)(C)N1CCOCC1 LWRBVKNFOYUCNP-UHFFFAOYSA-N 0.000 description 2
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- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/81—Unsaturated isocyanates or isothiocyanates
- C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
- C08G18/8116—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group esters of acrylic or alkylacrylic acid having only one isocyanate or isothiocyanate group
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- C—CHEMISTRY; METALLURGY
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
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- C09D133/04—Homopolymers or copolymers of esters
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
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- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31507—Of polycarbonate
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31573—Next to addition polymer of ethylenically unsaturated monomer
Landscapes
- Chemical & Material Sciences (AREA)
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2010/047974 WO2012033483A1 (en) | 2010-09-07 | 2010-09-07 | Curable resin composition and multi-layer laminate manufactured using the same |
Publications (1)
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| KR20130131320A true KR20130131320A (ko) | 2013-12-03 |
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Family Applications (1)
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| US (1) | US20130164541A1 (enExample) |
| JP (1) | JP2013537857A (enExample) |
| KR (1) | KR20130131320A (enExample) |
| CN (1) | CN103080252A (enExample) |
| WO (1) | WO2012033483A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20180125538A (ko) * | 2016-04-19 | 2018-11-23 | 후지필름 가부시키가이샤 | 적층 필름 및 그 제조 방법, 편광판, 액정 패널, 액정 표시 장치와 터치 패널 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104144975B (zh) * | 2012-02-25 | 2017-09-22 | 三菱化学株式会社 | 涂布膜 |
| US9222130B2 (en) * | 2013-03-15 | 2015-12-29 | Keith Oxenrider | Method and apparatus for sequencing molecules |
| KR101640369B1 (ko) * | 2013-07-19 | 2016-07-22 | 배인수 | 터치스크린 패널용 커버 시트 제조방법, 이를 이용한 터치스크린 패널 제조방법 및 그에 따라 제조된 터치스크린 패널 |
| KR20150033468A (ko) * | 2013-09-24 | 2015-04-01 | 엘지이노텍 주식회사 | 터치 패널 |
| JP6390319B2 (ja) * | 2014-10-01 | 2018-09-19 | 三菱ケミカル株式会社 | 積層ポリエステルフィルム |
| JP2016037046A (ja) * | 2014-08-06 | 2016-03-22 | 三菱樹脂株式会社 | 積層ポリエステルフィルム |
| CN105492511B (zh) * | 2014-08-06 | 2022-05-24 | 三菱化学株式会社 | 涂布膜 |
| JP7069006B2 (ja) * | 2015-09-04 | 2022-05-17 | カーボン,インコーポレイテッド | 積層造形用シアネートエステル二重硬化樹脂 |
| CN105398156B (zh) * | 2015-11-05 | 2017-12-26 | 浙江瑞欣装饰材料有限公司 | 纳米耐火板及其制作工艺 |
| US11572466B2 (en) | 2017-05-22 | 2023-02-07 | Lg Hausys, Ltd. | Low-gloss cured product having excellent stain resistance, and manufacturing method therefor |
| CN108047782A (zh) * | 2017-12-13 | 2018-05-18 | 天津宝兴威科技股份有限公司 | 一种纳米银导电膜的保护涂层配方 |
| JP6981269B2 (ja) * | 2018-01-17 | 2021-12-15 | 凸版印刷株式会社 | 化粧シート、化粧材、化粧シートの製造方法 |
| JP7054348B2 (ja) * | 2018-01-30 | 2022-04-13 | リンテック株式会社 | 粘着シート、構成体およびその製造方法 |
| US12053945B2 (en) * | 2018-06-04 | 2024-08-06 | 3M Innovative Properties Company | Thermoformed abrasion-resistant multilayer optical film and method of making the same |
| KR20200133288A (ko) * | 2019-05-16 | 2020-11-27 | 삼성디스플레이 주식회사 | 고분자 수지, 이를 포함하는 윈도우 모듈, 및 이를 포함하는 표시 장치 |
| EP4110843A1 (en) * | 2020-02-28 | 2023-01-04 | Carbon, Inc. | One part moisture curable resins for additive manufacturing |
| JPWO2022118745A1 (enExample) * | 2020-12-04 | 2022-06-09 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4404616A1 (de) * | 1994-02-14 | 1995-08-17 | Bayer Ag | Verwendung von UV-härtbaren Beschichtungsmitteln zur Beschichtung von Polycarbonatformkörpern |
| CA2189836C (en) * | 1995-12-04 | 2004-05-25 | Angela S. Rosenberry | Coating composition and floor covering including the composition |
| DE19741781A1 (de) * | 1997-09-22 | 1999-03-25 | Basf Ag | Verfahren zur Herstellung strahlungshärtbarer, Urethangruppen enthaltender Prepolymere |
| EP0903363B1 (de) * | 1997-09-22 | 2005-09-28 | Basf Aktiengesellschaft | Verfahren zur Herstellung strahlungshärtbarer, Urethangruppen enthaltender Prepolymere |
| CN1235985C (zh) * | 1998-12-09 | 2006-01-11 | 日本化药株式会社 | 硬涂覆材料以及用该材料获得的膜 |
| DE50008781D1 (de) * | 1999-10-02 | 2004-12-30 | Du Pont | Verfahren zur herstellung von basislack/klarlack-zweischichtlackierungen und/oder transparenten versiegelungsschichten |
| JP4623538B2 (ja) * | 2000-06-13 | 2011-02-02 | 日本化薬株式会社 | 放射線硬化型樹脂組成物の硬化皮膜を有するフィルム |
| JP3676260B2 (ja) * | 2000-12-28 | 2005-07-27 | ナトコ株式会社 | 活性エネルギー線硬化性ウレタン(メタ)アクリレート及び活性エネルギー線硬化性組成物並びにそれらの用途 |
| JP2004010728A (ja) | 2002-06-05 | 2004-01-15 | Shinnakamura Kagaku Kogyo Kk | 紫外線硬化性組成物 |
| CN1933968A (zh) | 2005-04-14 | 2007-03-21 | 村田望 | 具有精细装饰图案的树脂片材及其生产方法 |
| WO2007046741A1 (en) * | 2005-10-18 | 2007-04-26 | Perstorp Specialty Chemicals Ab | Dual cure composition |
| US7722955B2 (en) * | 2006-04-13 | 2010-05-25 | 3M Innovative Properties Company | Flooring substrate having a coating of a curable composition |
| JP5048304B2 (ja) * | 2006-11-02 | 2012-10-17 | リケンテクノス株式会社 | ハードコートフィルムおよび反射防止フィルム |
| US8268907B2 (en) * | 2008-06-13 | 2012-09-18 | Essilor International (Compagnie Generale D'optique) | Photocurable acrylic coating compositions having good adhesion properties to a subsequent coating and corresponding coated substrates |
| JP5662005B2 (ja) * | 2009-02-19 | 2015-01-28 | スリーエム イノベイティブ プロパティズ カンパニー | 硬化性樹脂組成物及び当該組成物を用いて作製された多層構造体 |
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2010
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- 2010-09-07 US US13/820,819 patent/US20130164541A1/en not_active Abandoned
- 2010-09-07 CN CN2010800689423A patent/CN103080252A/zh active Pending
- 2010-09-07 WO PCT/US2010/047974 patent/WO2012033483A1/en not_active Ceased
- 2010-09-07 JP JP2013528172A patent/JP2013537857A/ja active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20180125538A (ko) * | 2016-04-19 | 2018-11-23 | 후지필름 가부시키가이샤 | 적층 필름 및 그 제조 방법, 편광판, 액정 패널, 액정 표시 장치와 터치 패널 |
| US10974482B2 (en) | 2016-04-19 | 2021-04-13 | Fujifilm Corporation | Laminated film, production method thereof, polarizing plate, liquid crystal panel, liquid crystal display, and touch panel |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2013537857A (ja) | 2013-10-07 |
| CN103080252A (zh) | 2013-05-01 |
| WO2012033483A1 (en) | 2012-03-15 |
| US20130164541A1 (en) | 2013-06-27 |
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