KR20130091638A - Fe-BEA/Fe-MFI 혼합 제올라이트 촉매 및 이를 사용하여 가스 스트림 내의 NOx를 처리하는 방법 - Google Patents

Fe-BEA/Fe-MFI 혼합 제올라이트 촉매 및 이를 사용하여 가스 스트림 내의 NOx를 처리하는 방법 Download PDF

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KR20130091638A
KR20130091638A KR1020127029118A KR20127029118A KR20130091638A KR 20130091638 A KR20130091638 A KR 20130091638A KR 1020127029118 A KR1020127029118 A KR 1020127029118A KR 20127029118 A KR20127029118 A KR 20127029118A KR 20130091638 A KR20130091638 A KR 20130091638A
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Prior art keywords
zeolite
catalyst
exhaust gas
weight
structure type
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English (en)
Korean (ko)
Inventor
수산네 스티벨스
클라우디아 벤드트
토르슈텐 노이바우어
에디쓰 슈나이더
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바스프 에스이
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46Iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7215Zeolite Beta
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2062Ammonia
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/20Reductants
    • B01D2251/206Ammonium compounds
    • B01D2251/2067Urea
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/92Dimensions
    • B01D2255/9205Porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
KR1020127029118A 2010-04-08 2011-04-08 Fe-BEA/Fe-MFI 혼합 제올라이트 촉매 및 이를 사용하여 가스 스트림 내의 NOx를 처리하는 방법 Withdrawn KR20130091638A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10159369.7 2010-04-08
EP10159369 2010-04-08
PCT/IB2011/051526 WO2011125050A1 (en) 2010-04-08 2011-04-08 Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same

Publications (1)

Publication Number Publication Date
KR20130091638A true KR20130091638A (ko) 2013-08-19

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KR1020127029118A Withdrawn KR20130091638A (ko) 2010-04-08 2011-04-08 Fe-BEA/Fe-MFI 혼합 제올라이트 촉매 및 이를 사용하여 가스 스트림 내의 NOx를 처리하는 방법

Country Status (9)

Country Link
EP (1) EP2555867A4 (enExample)
JP (1) JP2013523442A (enExample)
KR (1) KR20130091638A (enExample)
CN (1) CN102958610A (enExample)
BR (1) BR112012025744A2 (enExample)
CA (1) CA2795522A1 (enExample)
MX (1) MX2012011540A (enExample)
WO (1) WO2011125050A1 (enExample)
ZA (1) ZA201208258B (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6294127B2 (ja) * 2014-03-31 2018-03-14 株式会社キャタラー Scr用触媒及び排ガス浄化触媒システム
DE102015204012A1 (de) * 2015-03-05 2016-09-08 Clariant International Ltd. SCR-Katalysator mit verbesserter Haftung
EP3694643A1 (de) * 2017-10-09 2020-08-19 Umicore AG & Co. KG Scr-aktiver katalysator
KR102747753B1 (ko) * 2018-04-11 2024-12-31 바스프 모바일 에미션스 카탈리스츠 엘엘씨 혼합 제올라이트 함유 scr 촉매
CN109289508B (zh) * 2018-10-24 2021-09-24 昆山工统环保科技有限公司 一种高疏水性沸石材料的制备方法
CN109592687B (zh) * 2018-12-03 2023-06-06 南京理工大学 利用tob制备多孔二氧化硅材料的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5676912A (en) * 1995-02-22 1997-10-14 Mobil Oil Corporation Process for exhaust gas NOx, CO, and hydrocarbon removal
BR0003765A (pt) * 1999-08-25 2001-04-03 Praxair Technology Inc Adsorvente, e, processos para separação de nitrogênio gasoso de uma mistura gasosa, e para separação de nitrogênio gasoso de oxigênio gasoso
DE10001539B4 (de) * 2000-01-14 2006-01-19 Uhde Gmbh Verfahren zur Beseitigung von NOx und N2O
JP4425797B2 (ja) * 2002-11-18 2010-03-03 株式会社アイシーティー 排ガス浄化用触媒の製造方法および排ガスの浄化方法
WO2004047960A1 (en) * 2002-11-25 2004-06-10 Yara International Asa Method for preparation and activation of multimetallic zeolite catalysts, a catalyst composition and application for n2o abatement
WO2006093802A2 (en) * 2005-02-28 2006-09-08 Catalytic Solutions, Inc. Catalyst and method for reducing nitrogen oxides in exhaust streams with hydrocarbons or alcohols
DE102006020158B4 (de) * 2006-05-02 2009-04-09 Argillon Gmbh Extrudierter Vollkatalysator sowie Verfahren zu seiner Herstellung
CN101134172B (zh) * 2006-08-31 2010-10-27 中国石油化工股份有限公司 一种烃类转化催化剂
CN101190866B (zh) * 2006-11-21 2011-08-17 中国石油化工股份有限公司 低乙苯副产物的芳烃烷基转移和脱烷基反应方法
JP5110954B2 (ja) * 2007-05-09 2012-12-26 エヌ・イーケムキャット株式会社 選択還元型触媒を用いた排気ガス浄化触媒装置並びに排気ガス浄化方法
DE102007057305A1 (de) * 2007-11-28 2009-06-04 Süd-Chemie AG Beschichtungszusammensetzung für Dieseloxidationskatalysatoren
JP2009262098A (ja) * 2008-04-28 2009-11-12 Ne Chemcat Corp 選択還元触媒を用いた排気ガス浄化方法

Also Published As

Publication number Publication date
CA2795522A1 (en) 2011-10-13
JP2013523442A (ja) 2013-06-17
MX2012011540A (es) 2012-11-16
EP2555867A1 (en) 2013-02-13
WO2011125050A1 (en) 2011-10-13
EP2555867A4 (en) 2014-12-10
ZA201208258B (en) 2014-01-29
BR112012025744A2 (pt) 2016-06-28
CN102958610A (zh) 2013-03-06

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Patent event date: 20121106

Patent event code: PA01051R01D

Comment text: International Patent Application

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