CA2795522A1 - Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same - Google Patents

Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same Download PDF

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Publication number
CA2795522A1
CA2795522A1 CA2795522A CA2795522A CA2795522A1 CA 2795522 A1 CA2795522 A1 CA 2795522A1 CA 2795522 A CA2795522 A CA 2795522A CA 2795522 A CA2795522 A CA 2795522A CA 2795522 A1 CA2795522 A1 CA 2795522A1
Authority
CA
Canada
Prior art keywords
catalyst
zeolites
exhaust gas
structure type
bea
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2795522A
Other languages
English (en)
French (fr)
Inventor
Susanne Stiebels
Claudia Wendt
Torsten Neubauer
Edith Schneider
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of CA2795522A1 publication Critical patent/CA2795522A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/54—Nitrogen compounds
    • B01D53/56—Nitrogen oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404—Removing only nitrogen compounds
    • B01D53/9409—Nitrogen oxides
    • B01D53/9413—Processes characterised by a specific catalyst
    • B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7215—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2062—Ammonia
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20738—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/50—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/90—Physical characteristics of catalysts
    • B01D2255/92—Dimensions
    • B01D2255/9205—Porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas After Treatment (AREA)
CA2795522A 2010-04-08 2011-04-08 Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same Abandoned CA2795522A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP10159369.7 2010-04-08
EP10159369 2010-04-08
PCT/IB2011/051526 WO2011125050A1 (en) 2010-04-08 2011-04-08 Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same

Publications (1)

Publication Number Publication Date
CA2795522A1 true CA2795522A1 (en) 2011-10-13

Family

ID=44762074

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2795522A Abandoned CA2795522A1 (en) 2010-04-08 2011-04-08 Fe-bea/fe-mfi mixed zeolite catalyst and process for treating nox in gas streams using the same

Country Status (9)

Country Link
EP (1) EP2555867A4 (enExample)
JP (1) JP2013523442A (enExample)
KR (1) KR20130091638A (enExample)
CN (1) CN102958610A (enExample)
BR (1) BR112012025744A2 (enExample)
CA (1) CA2795522A1 (enExample)
MX (1) MX2012011540A (enExample)
WO (1) WO2011125050A1 (enExample)
ZA (1) ZA201208258B (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6294127B2 (ja) * 2014-03-31 2018-03-14 株式会社キャタラー Ｓｃｒ用触媒及び排ガス浄化触媒システム
DE102015204012A1 (de) 2015-03-05 2016-09-08 Clariant International Ltd. SCR-Katalysator mit verbesserter Haftung
WO2019072527A1 (de) * 2017-10-09 2019-04-18 Umicore Ag & Co. Kg Scr-aktiver katalysator
JP7494123B2 (ja) * 2018-04-11 2024-06-03 ビーエーエスエフ コーポレーション 混合ゼオライト含有ｓｃｒ触媒
CN109289508B (zh) * 2018-10-24 2021-09-24 昆山工统环保科技有限公司 一种高疏水性沸石材料的制备方法
CN109592687B (zh) * 2018-12-03 2023-06-06 南京理工大学 利用tob制备多孔二氧化硅材料的方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5676912A (en) * 1995-02-22 1997-10-14 Mobil Oil Corporation Process for exhaust gas NOx, CO, and hydrocarbon removal
CA2316664A1 (en) * 1999-08-25 2001-02-25 Vadim Guliants Novel adsorbents for preferential nitrogen adsorption from other gases
DE10001539B4 (de) * 2000-01-14 2006-01-19 Uhde Gmbh Verfahren zur Beseitigung von NOx und N2O
US7393804B2 (en) * 2002-11-18 2008-07-01 Ict Co., Ltd. Exhaust gas purifying catalyst and process for purification of exhaust gas
US20060088469A1 (en) * 2002-11-25 2006-04-27 Yara International Asa Method for preparation and activation of multimetallic zeolite catalysts, a catalyst composition and application for n2o abatement
JP4686553B2 (ja) * 2005-02-28 2011-05-25 田中貴金属工業株式会社 炭化水素またはアルコールにより排気流中の窒素酸化物を還元するための触媒および方法
DE102006020158B4 (de) * 2006-05-02 2009-04-09 Argillon Gmbh Extrudierter Vollkatalysator sowie Verfahren zu seiner Herstellung
CN101134172B (zh) * 2006-08-31 2010-10-27 中国石油化工股份有限公司 一种烃类转化催化剂
CN101190866B (zh) * 2006-11-21 2011-08-17 中国石油化工股份有限公司 低乙苯副产物的芳烃烷基转移和脱烷基反应方法
JP5110954B2 (ja) * 2007-05-09 2012-12-26 エヌ・イーケムキャット株式会社 選択還元型触媒を用いた排気ガス浄化触媒装置並びに排気ガス浄化方法
DE102007057305A1 (de) * 2007-11-28 2009-06-04 Süd-Chemie AG Beschichtungszusammensetzung für Dieseloxidationskatalysatoren
JP2009262098A (ja) * 2008-04-28 2009-11-12 Ne Chemcat Corp 選択還元触媒を用いた排気ガス浄化方法

Also Published As

Publication number Publication date
CN102958610A (zh) 2013-03-06
ZA201208258B (en) 2014-01-29
EP2555867A4 (en) 2014-12-10
EP2555867A1 (en) 2013-02-13
MX2012011540A (es) 2012-11-16
WO2011125050A1 (en) 2011-10-13
KR20130091638A (ko) 2013-08-19
JP2013523442A (ja) 2013-06-17
BR112012025744A2 (pt) 2016-06-28

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Legal Events

Date Code Title Description
FZDE Discontinued

Effective date: 20170410