KR20120124404A - 열가소성 매트릭스 중의 씨엔티-주입된 섬유 - Google Patents
열가소성 매트릭스 중의 씨엔티-주입된 섬유 Download PDFInfo
- Publication number
- KR20120124404A KR20120124404A KR1020127017728A KR20127017728A KR20120124404A KR 20120124404 A KR20120124404 A KR 20120124404A KR 1020127017728 A KR1020127017728 A KR 1020127017728A KR 20127017728 A KR20127017728 A KR 20127017728A KR 20120124404 A KR20120124404 A KR 20120124404A
- Authority
- KR
- South Korea
- Prior art keywords
- cnt
- cnts
- fiber material
- composite
- carbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 51
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 50
- 239000000835 fiber Substances 0.000 title description 141
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 399
- 239000002131 composite material Substances 0.000 claims abstract description 100
- 239000011159 matrix material Substances 0.000 claims abstract description 47
- 239000000463 material Substances 0.000 claims description 250
- 238000000034 method Methods 0.000 claims description 115
- 239000003365 glass fiber Substances 0.000 claims description 28
- 238000004519 manufacturing process Methods 0.000 claims description 21
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 13
- 229920002530 polyetherether ketone Polymers 0.000 claims description 13
- 239000008188 pellet Substances 0.000 claims description 12
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 11
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 11
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 claims description 11
- 230000000694 effects Effects 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 239000004417 polycarbonate Substances 0.000 claims description 5
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- 239000012815 thermoplastic material Substances 0.000 claims description 4
- 239000004697 Polyetherimide Substances 0.000 claims description 3
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000001746 injection moulding Methods 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 467
- 229910021393 carbon nanotube Inorganic materials 0.000 abstract description 392
- 239000002657 fibrous material Substances 0.000 abstract description 98
- 229920000049 Carbon (fiber) Polymers 0.000 description 240
- 239000004917 carbon fiber Substances 0.000 description 240
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 223
- 239000003054 catalyst Substances 0.000 description 119
- 238000000576 coating method Methods 0.000 description 76
- 230000004888 barrier function Effects 0.000 description 75
- 229910052799 carbon Inorganic materials 0.000 description 72
- 239000011248 coating agent Substances 0.000 description 70
- 230000008569 process Effects 0.000 description 70
- 230000015572 biosynthetic process Effects 0.000 description 44
- 238000004513 sizing Methods 0.000 description 41
- 238000003786 synthesis reaction Methods 0.000 description 41
- 239000007789 gas Substances 0.000 description 40
- 210000002381 plasma Anatomy 0.000 description 39
- 238000002347 injection Methods 0.000 description 23
- 239000007924 injection Substances 0.000 description 23
- 238000010924 continuous production Methods 0.000 description 22
- 238000005229 chemical vapour deposition Methods 0.000 description 19
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- 229910052751 metal Inorganic materials 0.000 description 15
- 239000002184 metal Substances 0.000 description 15
- 239000003795 chemical substances by application Substances 0.000 description 14
- 239000002048 multi walled nanotube Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 238000000151 deposition Methods 0.000 description 13
- 229910052723 transition metal Inorganic materials 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 230000008021 deposition Effects 0.000 description 12
- 230000001965 increasing effect Effects 0.000 description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 239000002105 nanoparticle Substances 0.000 description 12
- 238000010438 heat treatment Methods 0.000 description 11
- -1 polypropylene Polymers 0.000 description 11
- 238000010926 purge Methods 0.000 description 11
- 239000002109 single walled nanotube Substances 0.000 description 11
- 239000000758 substrate Substances 0.000 description 11
- 150000003624 transition metals Chemical class 0.000 description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 230000008859 change Effects 0.000 description 9
- 238000009826 distribution Methods 0.000 description 9
- 230000008901 benefit Effects 0.000 description 8
- 238000003618 dip coating Methods 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 7
- 230000005684 electric field Effects 0.000 description 7
- 238000002513 implantation Methods 0.000 description 7
- 239000002243 precursor Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000004071 soot Substances 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 230000002194 synthesizing effect Effects 0.000 description 7
- 229910021524 transition metal nanoparticle Inorganic materials 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 239000002079 double walled nanotube Substances 0.000 description 6
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 6
- 229910052734 helium Inorganic materials 0.000 description 6
- 239000001307 helium Substances 0.000 description 6
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 6
- 238000005470 impregnation Methods 0.000 description 6
- 239000011261 inert gas Substances 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 238000012986 modification Methods 0.000 description 6
- 239000002071 nanotube Substances 0.000 description 6
- 230000002787 reinforcement Effects 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 150000003839 salts Chemical group 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 229910052786 argon Inorganic materials 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000010790 dilution Methods 0.000 description 5
- 239000012895 dilution Substances 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 238000011068 loading method Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229920002239 polyacrylonitrile Polymers 0.000 description 5
- 230000009467 reduction Effects 0.000 description 5
- 238000006722 reduction reaction Methods 0.000 description 5
- 238000001878 scanning electron micrograph Methods 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000010453 quartz Substances 0.000 description 4
- 239000002356 single layer Substances 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- 238000009827 uniform distribution Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000003917 TEM image Methods 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 3
- 238000010531 catalytic reduction reaction Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 229910003472 fullerene Inorganic materials 0.000 description 3
- 238000007306 functionalization reaction Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 230000001404 mediated effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- 238000009832 plasma treatment Methods 0.000 description 3
- 229920001601 polyetherimide Polymers 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910001374 Invar Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000009730 filament winding Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000002964 rayon Substances 0.000 description 2
- 238000002310 reflectometry Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000011167 3D woven fabric Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 230000005483 Hooke's law Effects 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- YZCKVEUIGOORGS-IGMARMGPSA-N Protium Chemical compound [1H] YZCKVEUIGOORGS-IGMARMGPSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002730 additional effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003321 amplification Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000009734 composite fabrication Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 210000000887 face Anatomy 0.000 description 1
- 239000011554 ferrofluid Substances 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000011148 full scale manufacturing process Methods 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000000608 laser ablation Methods 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 229940031182 nanoparticles iron oxide Drugs 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000003199 nucleic acid amplification method Methods 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006393 polyether sulfone Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000009790 rate-determining step (RDS) Methods 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004046 wet winding Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 238000013316 zoning Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/42—Coatings containing inorganic materials
- C03C25/44—Carbon, e.g. graphite
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Conductive Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26779409P | 2009-12-08 | 2009-12-08 | |
| US61/267,794 | 2009-12-08 | ||
| PCT/US2010/059565 WO2011072071A1 (en) | 2009-12-08 | 2010-12-08 | Cnt-infused fibers in thermoplastic matrices |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20120124404A true KR20120124404A (ko) | 2012-11-13 |
Family
ID=44145902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020127017728A Withdrawn KR20120124404A (ko) | 2009-12-08 | 2010-12-08 | 열가소성 매트릭스 중의 씨엔티-주입된 섬유 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20110297892A1 (enExample) |
| EP (1) | EP2509918A4 (enExample) |
| JP (1) | JP2013513020A (enExample) |
| KR (1) | KR20120124404A (enExample) |
| CN (1) | CN102648155A (enExample) |
| AU (1) | AU2010328139B2 (enExample) |
| BR (1) | BR112012013904A2 (enExample) |
| CA (1) | CA2779709A1 (enExample) |
| WO (1) | WO2011072071A1 (enExample) |
| ZA (1) | ZA201203339B (enExample) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140112990A (ko) * | 2013-03-15 | 2014-09-24 | 제일모직주식회사 | 전자파 차폐특성이 우수한 열가소성 수지조성물 |
| KR20170015321A (ko) * | 2014-06-11 | 2017-02-08 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 마이크로파 복사를 이용한 3 차원 인쇄된 목적물을 처리하기 위한 방법 |
| KR20220117967A (ko) * | 2021-02-17 | 2022-08-25 | 주식회사 삼양사 | 전자파 차폐 성능이 향상된 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8941094B2 (en) * | 2010-09-02 | 2015-01-27 | Nantero Inc. | Methods for adjusting the conductivity range of a nanotube fabric layer |
| EP2398955B8 (en) * | 2009-02-17 | 2020-06-03 | Applied NanoStructured Solutions, LLC | Composites comprising carbon nanotubes on fiber |
| CN102461361A (zh) | 2009-04-24 | 2012-05-16 | 应用纳米结构方案公司 | 并入cnt的emi屏蔽复合材料和涂层 |
| US9111658B2 (en) | 2009-04-24 | 2015-08-18 | Applied Nanostructured Solutions, Llc | CNS-shielded wires |
| US8664573B2 (en) | 2009-04-27 | 2014-03-04 | Applied Nanostructured Solutions, Llc | CNT-based resistive heating for deicing composite structures |
| US20110089958A1 (en) * | 2009-10-19 | 2011-04-21 | Applied Nanostructured Solutions, Llc | Damage-sensing composite structures |
| US8601965B2 (en) | 2009-11-23 | 2013-12-10 | Applied Nanostructured Solutions, Llc | CNT-tailored composite sea-based structures |
| CA2780354A1 (en) | 2009-12-14 | 2011-11-17 | Applied Nanostructured Solutions, Llc | Flame-resistant composite materials and articles containing carbon nanotube-infused fiber materials |
| US9167736B2 (en) | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| US8999453B2 (en) | 2010-02-02 | 2015-04-07 | Applied Nanostructured Solutions, Llc | Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom |
| US8665581B2 (en) | 2010-03-02 | 2014-03-04 | Applied Nanostructured Solutions, Llc | Spiral wound electrical devices containing carbon nanotube-infused electrode materials and methods and apparatuses for production thereof |
| EP2543052B1 (en) | 2010-03-02 | 2019-11-27 | Applied NanoStructured Solutions, LLC | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US8780526B2 (en) | 2010-06-15 | 2014-07-15 | Applied Nanostructured Solutions, Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US9017854B2 (en) | 2010-08-30 | 2015-04-28 | Applied Nanostructured Solutions, Llc | Structural energy storage assemblies and methods for production thereof |
| CA2782976A1 (en) | 2010-09-23 | 2012-03-29 | Applied Nanostructured Solutions, Llc | Cnt-infused fiber as a self shielding wire for enhanced power transmission line |
| US9085464B2 (en) | 2012-03-07 | 2015-07-21 | Applied Nanostructured Solutions, Llc | Resistance measurement system and method of using the same |
| US10357765B2 (en) * | 2012-06-22 | 2019-07-23 | The University Of Tokyo | Carbon-containing metal catalyst particles for carbon nanotube synthesis and method of producing the same, catalyst carrier support, and method of producing carbon nanotubes |
| WO2014039509A2 (en) | 2012-09-04 | 2014-03-13 | Ocv Intellectual Capital, Llc | Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media |
| CN102924910B (zh) * | 2012-11-16 | 2014-04-30 | 华东理工大学 | 一种高性能玻璃纤维增强聚酰胺导电复合材料的制备方法 |
| EP3172146B1 (en) | 2014-07-22 | 2019-06-05 | Entegris, Inc. | Molded fluoropolymer breakseal with compliant material |
| KR20160026764A (ko) * | 2014-08-29 | 2016-03-09 | 삼성에스디아이 주식회사 | 전도성 열가소성 수지 조성물 |
| US9908978B2 (en) | 2015-04-08 | 2018-03-06 | Arevo Inc. | Method to manufacture polymer composite materials with nano-fillers for use in additive manufacturing to improve material properties |
| WO2016200662A1 (en) | 2015-06-09 | 2016-12-15 | 3M Innovative Properties Company | High frequency electromagnetic interference (emi) composites |
| US11117311B2 (en) | 2015-10-05 | 2021-09-14 | Arevo, Inc. | Amorphous polyaryletherketone and blends thereof for use in additive manufacturing |
| US11058039B2 (en) | 2015-12-29 | 2021-07-06 | 3M Innovative Properties Company | Composites for high frequency electromagnetic interference (EMI) applications |
| KR101777945B1 (ko) | 2016-02-04 | 2017-09-12 | 고려대학교 산학협력단 | 플라즈마 처리를 통한 표면이 개질된 탄소섬유를 구비한 탄소 섬유 강화 폴리머 복합재 및 그 제조 방법 |
| CN107541038A (zh) * | 2016-06-27 | 2018-01-05 | 汉达精密电子(昆山)有限公司 | 碳纤维阻燃聚碳酸酯复合材料及其产品 |
| CN107641305A (zh) * | 2016-07-21 | 2018-01-30 | 汉达精密电子(昆山)有限公司 | 纳米碳管改性的玻璃纤维聚碳酸酯复合材料及其产品 |
| CN107722586A (zh) * | 2016-08-11 | 2018-02-23 | 汉达精密电子(昆山)有限公司 | 碳纳米管增强聚碳酸酯/碳纤维复合材料及其成型品 |
| DE102017209357A1 (de) * | 2017-06-01 | 2018-12-06 | Albis Plastic Gmbh | Compound |
| EP3819424A4 (en) * | 2018-06-11 | 2022-05-11 | Nitta Corporation | COMPOSITE MATERIAL, PREPREG, CARBON FIBER REINFORCED MOLDED PRODUCT AND METHOD FOR PRODUCING THE COMPOSITE MATERIAL |
| JP7382460B1 (ja) | 2022-07-14 | 2023-11-16 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、cnt付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| JP7568165B2 (ja) * | 2022-09-08 | 2024-10-16 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| JP2025083624A (ja) * | 2023-11-21 | 2025-06-02 | 住友ゴム工業株式会社 | ラケット用ストリング |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002518280A (ja) * | 1998-06-19 | 2002-06-25 | ザ・リサーチ・ファウンデーション・オブ・ステイト・ユニバーシティ・オブ・ニューヨーク | 整列した自立炭素ナノチューブおよびその合成 |
| US6762237B2 (en) * | 2001-06-08 | 2004-07-13 | Eikos, Inc. | Nanocomposite dielectrics |
| CA2515895A1 (en) * | 2003-02-13 | 2004-08-26 | Stichting Dutch Polymer Institute | Reinforced polymer |
| EP2067741B1 (en) * | 2003-07-28 | 2017-09-06 | William Marsh Rice University | Polymer composites comprising silane-functionalized carbon nanotubes. |
| US20050062024A1 (en) * | 2003-08-06 | 2005-03-24 | Bessette Michael D. | Electrically conductive pressure sensitive adhesives, method of manufacture, and use thereof |
| US20070189953A1 (en) * | 2004-01-30 | 2007-08-16 | Centre National De La Recherche Scientifique (Cnrs) | Method for obtaining carbon nanotubes on supports and composites comprising same |
| CN105696139B (zh) * | 2004-11-09 | 2019-04-16 | 得克萨斯大学体系董事会 | 纳米纤维纱线、带和板的制造和应用 |
| JPWO2006082829A1 (ja) * | 2005-02-02 | 2008-08-07 | 大塚化学株式会社 | カーボンナノチューブ担持無機粒子 |
| US8148276B2 (en) * | 2005-11-28 | 2012-04-03 | University Of Hawaii | Three-dimensionally reinforced multifunctional nanocomposites |
| CN100591613C (zh) * | 2006-08-11 | 2010-02-24 | 清华大学 | 碳纳米管复合材料及其制造方法 |
| WO2008068042A2 (en) * | 2006-12-04 | 2008-06-12 | Universite Catholique De Louvain | Polymer composite material structures comprising carbon based conductive loads |
| CN101582302B (zh) * | 2008-05-14 | 2011-12-21 | 清华大学 | 碳纳米管/导电聚合物复合材料 |
| US20100032629A1 (en) * | 2008-08-07 | 2010-02-11 | Benoit Brule | Adhesive composition containing carbon nanotubes and a copolyamide |
| US20110123735A1 (en) * | 2009-11-23 | 2011-05-26 | Applied Nanostructured Solutions, Llc | Cnt-infused fibers in thermoset matrices |
-
2010
- 2010-12-08 BR BR112012013904A patent/BR112012013904A2/pt not_active IP Right Cessation
- 2010-12-08 AU AU2010328139A patent/AU2010328139B2/en not_active Ceased
- 2010-12-08 KR KR1020127017728A patent/KR20120124404A/ko not_active Withdrawn
- 2010-12-08 JP JP2012543264A patent/JP2013513020A/ja active Pending
- 2010-12-08 CN CN2010800557617A patent/CN102648155A/zh active Pending
- 2010-12-08 WO PCT/US2010/059565 patent/WO2011072071A1/en not_active Ceased
- 2010-12-08 CA CA2779709A patent/CA2779709A1/en not_active Abandoned
- 2010-12-08 US US12/963,589 patent/US20110297892A1/en not_active Abandoned
- 2010-12-08 EP EP10836652.7A patent/EP2509918A4/en not_active Withdrawn
-
2012
- 2012-05-07 ZA ZA2012/03339A patent/ZA201203339B/en unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140112990A (ko) * | 2013-03-15 | 2014-09-24 | 제일모직주식회사 | 전자파 차폐특성이 우수한 열가소성 수지조성물 |
| KR20170015321A (ko) * | 2014-06-11 | 2017-02-08 | 어플라이드 나노스트럭처드 솔루션스, 엘엘씨. | 마이크로파 복사를 이용한 3 차원 인쇄된 목적물을 처리하기 위한 방법 |
| KR20220117967A (ko) * | 2021-02-17 | 2022-08-25 | 주식회사 삼양사 | 전자파 차폐 성능이 향상된 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110297892A1 (en) | 2011-12-08 |
| AU2010328139B2 (en) | 2014-09-18 |
| BR112012013904A2 (pt) | 2016-04-26 |
| EP2509918A4 (en) | 2013-09-25 |
| AU2010328139A1 (en) | 2012-05-31 |
| ZA201203339B (en) | 2013-01-30 |
| CA2779709A1 (en) | 2011-06-16 |
| EP2509918A1 (en) | 2012-10-17 |
| CN102648155A (zh) | 2012-08-22 |
| WO2011072071A1 (en) | 2011-06-16 |
| JP2013513020A (ja) | 2013-04-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AU2010328139B2 (en) | CNT-infused fibers in thermoplastic matrices | |
| AU2010321535B2 (en) | CNT-infused fibers in thermoset matrices | |
| CN102648088B (zh) | Cnt并入的金属纤维材料及其方法 | |
| CN102639771B (zh) | 并入cnt的陶瓷纤维材料及其方法 | |
| CN102598875A (zh) | 碳-碳复合材料中的并入cnt的纤维 | |
| US20110171469A1 (en) | Cnt-infused aramid fiber materials and process therefor | |
| KR20130100045A (ko) | 전력 전송 라인 향상을 위한 자가 실드 와이어로서 cnt 주입된 섬유 | |
| KR20120117012A (ko) | 전력 전송 라인 향상을 위한 자가 실드 와이어로서 cnt 주입된 섬유 | |
| CN103889890A (zh) | 用于在可重复使用的基材上连续生产碳纳米结构的系统和方法 | |
| JP2013509504A5 (enExample) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
Patent event date: 20120706 Patent event code: PA01051R01D Comment text: International Patent Application |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |