AU2010328139B2 - CNT-infused fibers in thermoplastic matrices - Google Patents
CNT-infused fibers in thermoplastic matrices Download PDFInfo
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- AU2010328139B2 AU2010328139B2 AU2010328139A AU2010328139A AU2010328139B2 AU 2010328139 B2 AU2010328139 B2 AU 2010328139B2 AU 2010328139 A AU2010328139 A AU 2010328139A AU 2010328139 A AU2010328139 A AU 2010328139A AU 2010328139 B2 AU2010328139 B2 AU 2010328139B2
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- cnt
- cnts
- fiber material
- composite
- infused
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B1/00—Nanostructures formed by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
- B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/16—Preparation
- C01B32/162—Preparation characterised by catalysts
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/42—Coatings containing inorganic materials
- C03C25/44—Carbon, e.g. graphite
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/10—Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
- C08K3/041—Carbon nanotubes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Crystallography & Structural Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- General Chemical & Material Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Conductive Materials (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US26779409P | 2009-12-08 | 2009-12-08 | |
| US61/267,794 | 2009-12-08 | ||
| PCT/US2010/059565 WO2011072071A1 (en) | 2009-12-08 | 2010-12-08 | Cnt-infused fibers in thermoplastic matrices |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2010328139A1 AU2010328139A1 (en) | 2012-05-31 |
| AU2010328139B2 true AU2010328139B2 (en) | 2014-09-18 |
Family
ID=44145902
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2010328139A Ceased AU2010328139B2 (en) | 2009-12-08 | 2010-12-08 | CNT-infused fibers in thermoplastic matrices |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20110297892A1 (enExample) |
| EP (1) | EP2509918A4 (enExample) |
| JP (1) | JP2013513020A (enExample) |
| KR (1) | KR20120124404A (enExample) |
| CN (1) | CN102648155A (enExample) |
| AU (1) | AU2010328139B2 (enExample) |
| BR (1) | BR112012013904A2 (enExample) |
| CA (1) | CA2779709A1 (enExample) |
| WO (1) | WO2011072071A1 (enExample) |
| ZA (1) | ZA201203339B (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8941094B2 (en) * | 2010-09-02 | 2015-01-27 | Nantero Inc. | Methods for adjusting the conductivity range of a nanotube fabric layer |
| EP2398955B8 (en) * | 2009-02-17 | 2020-06-03 | Applied NanoStructured Solutions, LLC | Composites comprising carbon nanotubes on fiber |
| CN102461361A (zh) | 2009-04-24 | 2012-05-16 | 应用纳米结构方案公司 | 并入cnt的emi屏蔽复合材料和涂层 |
| US9111658B2 (en) | 2009-04-24 | 2015-08-18 | Applied Nanostructured Solutions, Llc | CNS-shielded wires |
| US8664573B2 (en) | 2009-04-27 | 2014-03-04 | Applied Nanostructured Solutions, Llc | CNT-based resistive heating for deicing composite structures |
| US20110089958A1 (en) * | 2009-10-19 | 2011-04-21 | Applied Nanostructured Solutions, Llc | Damage-sensing composite structures |
| US8601965B2 (en) | 2009-11-23 | 2013-12-10 | Applied Nanostructured Solutions, Llc | CNT-tailored composite sea-based structures |
| CA2780354A1 (en) | 2009-12-14 | 2011-11-17 | Applied Nanostructured Solutions, Llc | Flame-resistant composite materials and articles containing carbon nanotube-infused fiber materials |
| US9167736B2 (en) | 2010-01-15 | 2015-10-20 | Applied Nanostructured Solutions, Llc | CNT-infused fiber as a self shielding wire for enhanced power transmission line |
| US8999453B2 (en) | 2010-02-02 | 2015-04-07 | Applied Nanostructured Solutions, Llc | Carbon nanotube-infused fiber materials containing parallel-aligned carbon nanotubes, methods for production thereof, and composite materials derived therefrom |
| US8665581B2 (en) | 2010-03-02 | 2014-03-04 | Applied Nanostructured Solutions, Llc | Spiral wound electrical devices containing carbon nanotube-infused electrode materials and methods and apparatuses for production thereof |
| EP2543052B1 (en) | 2010-03-02 | 2019-11-27 | Applied NanoStructured Solutions, LLC | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US8780526B2 (en) | 2010-06-15 | 2014-07-15 | Applied Nanostructured Solutions, Llc | Electrical devices containing carbon nanotube-infused fibers and methods for production thereof |
| US9017854B2 (en) | 2010-08-30 | 2015-04-28 | Applied Nanostructured Solutions, Llc | Structural energy storage assemblies and methods for production thereof |
| CA2782976A1 (en) | 2010-09-23 | 2012-03-29 | Applied Nanostructured Solutions, Llc | Cnt-infused fiber as a self shielding wire for enhanced power transmission line |
| US9085464B2 (en) | 2012-03-07 | 2015-07-21 | Applied Nanostructured Solutions, Llc | Resistance measurement system and method of using the same |
| US10357765B2 (en) * | 2012-06-22 | 2019-07-23 | The University Of Tokyo | Carbon-containing metal catalyst particles for carbon nanotube synthesis and method of producing the same, catalyst carrier support, and method of producing carbon nanotubes |
| WO2014039509A2 (en) | 2012-09-04 | 2014-03-13 | Ocv Intellectual Capital, Llc | Dispersion of carbon enhanced reinforcement fibers in aqueous or non-aqueous media |
| CN102924910B (zh) * | 2012-11-16 | 2014-04-30 | 华东理工大学 | 一种高性能玻璃纤维增强聚酰胺导电复合材料的制备方法 |
| KR101674242B1 (ko) * | 2013-03-15 | 2016-11-08 | 롯데첨단소재(주) | 전자파 차폐특성이 우수한 열가소성 수지조성물 |
| US9802373B2 (en) * | 2014-06-11 | 2017-10-31 | Applied Nanostructured Solutions, Llc | Methods for processing three-dimensional printed objects using microwave radiation |
| EP3172146B1 (en) | 2014-07-22 | 2019-06-05 | Entegris, Inc. | Molded fluoropolymer breakseal with compliant material |
| KR20160026764A (ko) * | 2014-08-29 | 2016-03-09 | 삼성에스디아이 주식회사 | 전도성 열가소성 수지 조성물 |
| US9908978B2 (en) | 2015-04-08 | 2018-03-06 | Arevo Inc. | Method to manufacture polymer composite materials with nano-fillers for use in additive manufacturing to improve material properties |
| WO2016200662A1 (en) | 2015-06-09 | 2016-12-15 | 3M Innovative Properties Company | High frequency electromagnetic interference (emi) composites |
| US11117311B2 (en) | 2015-10-05 | 2021-09-14 | Arevo, Inc. | Amorphous polyaryletherketone and blends thereof for use in additive manufacturing |
| US11058039B2 (en) | 2015-12-29 | 2021-07-06 | 3M Innovative Properties Company | Composites for high frequency electromagnetic interference (EMI) applications |
| KR101777945B1 (ko) | 2016-02-04 | 2017-09-12 | 고려대학교 산학협력단 | 플라즈마 처리를 통한 표면이 개질된 탄소섬유를 구비한 탄소 섬유 강화 폴리머 복합재 및 그 제조 방법 |
| CN107541038A (zh) * | 2016-06-27 | 2018-01-05 | 汉达精密电子(昆山)有限公司 | 碳纤维阻燃聚碳酸酯复合材料及其产品 |
| CN107641305A (zh) * | 2016-07-21 | 2018-01-30 | 汉达精密电子(昆山)有限公司 | 纳米碳管改性的玻璃纤维聚碳酸酯复合材料及其产品 |
| CN107722586A (zh) * | 2016-08-11 | 2018-02-23 | 汉达精密电子(昆山)有限公司 | 碳纳米管增强聚碳酸酯/碳纤维复合材料及其成型品 |
| DE102017209357A1 (de) * | 2017-06-01 | 2018-12-06 | Albis Plastic Gmbh | Compound |
| EP3819424A4 (en) * | 2018-06-11 | 2022-05-11 | Nitta Corporation | COMPOSITE MATERIAL, PREPREG, CARBON FIBER REINFORCED MOLDED PRODUCT AND METHOD FOR PRODUCING THE COMPOSITE MATERIAL |
| KR102519880B1 (ko) * | 2021-02-17 | 2023-04-12 | 주식회사 삼양사 | 전자파 차폐 성능이 향상된 폴리아미드 수지 조성물 및 이를 포함하는 성형품 |
| JP7382460B1 (ja) | 2022-07-14 | 2023-11-16 | ニッタ株式会社 | 射出成形体及びその製造方法、複合繊維の製造方法、ｃｎｔ付着炭素繊維及びその製造方法、並びに炭素繊維複合材の製造方法 |
| JP7568165B2 (ja) * | 2022-09-08 | 2024-10-16 | Dic株式会社 | 導電性樹脂組成物、マスターバッチ、成形体及びそれらの製造方法 |
| JP2025083624A (ja) * | 2023-11-21 | 2025-06-02 | 住友ゴム工業株式会社 | ラケット用ストリング |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070298669A1 (en) * | 2003-07-28 | 2007-12-27 | William Marsh Rice University | Sidewall Functionalization Of Carbon Nanotubes With Organosilanes For Polymer Composites |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002518280A (ja) * | 1998-06-19 | 2002-06-25 | ザ・リサーチ・ファウンデーション・オブ・ステイト・ユニバーシティ・オブ・ニューヨーク | 整列した自立炭素ナノチューブおよびその合成 |
| US6762237B2 (en) * | 2001-06-08 | 2004-07-13 | Eikos, Inc. | Nanocomposite dielectrics |
| CA2515895A1 (en) * | 2003-02-13 | 2004-08-26 | Stichting Dutch Polymer Institute | Reinforced polymer |
| US20050062024A1 (en) * | 2003-08-06 | 2005-03-24 | Bessette Michael D. | Electrically conductive pressure sensitive adhesives, method of manufacture, and use thereof |
| US20070189953A1 (en) * | 2004-01-30 | 2007-08-16 | Centre National De La Recherche Scientifique (Cnrs) | Method for obtaining carbon nanotubes on supports and composites comprising same |
| CN105696139B (zh) * | 2004-11-09 | 2019-04-16 | 得克萨斯大学体系董事会 | 纳米纤维纱线、带和板的制造和应用 |
| JPWO2006082829A1 (ja) * | 2005-02-02 | 2008-08-07 | 大塚化学株式会社 | カーボンナノチューブ担持無機粒子 |
| US8148276B2 (en) * | 2005-11-28 | 2012-04-03 | University Of Hawaii | Three-dimensionally reinforced multifunctional nanocomposites |
| CN100591613C (zh) * | 2006-08-11 | 2010-02-24 | 清华大学 | 碳纳米管复合材料及其制造方法 |
| WO2008068042A2 (en) * | 2006-12-04 | 2008-06-12 | Universite Catholique De Louvain | Polymer composite material structures comprising carbon based conductive loads |
| CN101582302B (zh) * | 2008-05-14 | 2011-12-21 | 清华大学 | 碳纳米管/导电聚合物复合材料 |
| US20100032629A1 (en) * | 2008-08-07 | 2010-02-11 | Benoit Brule | Adhesive composition containing carbon nanotubes and a copolyamide |
| US20110123735A1 (en) * | 2009-11-23 | 2011-05-26 | Applied Nanostructured Solutions, Llc | Cnt-infused fibers in thermoset matrices |
-
2010
- 2010-12-08 BR BR112012013904A patent/BR112012013904A2/pt not_active IP Right Cessation
- 2010-12-08 AU AU2010328139A patent/AU2010328139B2/en not_active Ceased
- 2010-12-08 KR KR1020127017728A patent/KR20120124404A/ko not_active Withdrawn
- 2010-12-08 JP JP2012543264A patent/JP2013513020A/ja active Pending
- 2010-12-08 CN CN2010800557617A patent/CN102648155A/zh active Pending
- 2010-12-08 WO PCT/US2010/059565 patent/WO2011072071A1/en not_active Ceased
- 2010-12-08 CA CA2779709A patent/CA2779709A1/en not_active Abandoned
- 2010-12-08 US US12/963,589 patent/US20110297892A1/en not_active Abandoned
- 2010-12-08 EP EP10836652.7A patent/EP2509918A4/en not_active Withdrawn
-
2012
- 2012-05-07 ZA ZA2012/03339A patent/ZA201203339B/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070298669A1 (en) * | 2003-07-28 | 2007-12-27 | William Marsh Rice University | Sidewall Functionalization Of Carbon Nanotubes With Organosilanes For Polymer Composites |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110297892A1 (en) | 2011-12-08 |
| BR112012013904A2 (pt) | 2016-04-26 |
| EP2509918A4 (en) | 2013-09-25 |
| AU2010328139A1 (en) | 2012-05-31 |
| KR20120124404A (ko) | 2012-11-13 |
| ZA201203339B (en) | 2013-01-30 |
| CA2779709A1 (en) | 2011-06-16 |
| EP2509918A1 (en) | 2012-10-17 |
| CN102648155A (zh) | 2012-08-22 |
| WO2011072071A1 (en) | 2011-06-16 |
| JP2013513020A (ja) | 2013-04-18 |
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