KR20120053018A

KR20120053018A - 캡슐화된 페놀계 항산화제

캡슐화된 페놀계 항산화제 Download PDF

Info

Publication number: KR20120053018A
Authority: KR; South Korea
Prior art keywords: alkyl; polymer; aqueous dispersion; coo; substituted
Prior art date: 2009-07-29
Legal status : Ceased

Application number

KR1020127005201A

Other languages

English (en)

Korean (ko)

Inventor

프란크 올리버 하인리히 피룽

클레멘스 아우슈라

크리스토프 하슬러

Original Assignee

바스프 에스이

Priority date

2009-07-29

Filing date

2010-07-27

Publication date

2012-05-24

2010-07-27 Application filed by 바스프 에스이 filed Critical 바스프 에스이

2012-05-24 Publication of KR20120053018A publication Critical patent/KR20120053018A/ko

Status Ceased legal-status Critical Current

Links

239000002530 phenolic antioxidant Substances 0.000 title claims abstract description 50
229920000642 polymer Polymers 0.000 claims abstract description 94
239000006185 dispersion Substances 0.000 claims abstract description 64
239000000203 mixture Substances 0.000 claims abstract description 53
239000000843 powder Substances 0.000 claims abstract description 37
239000002245 particle Substances 0.000 claims abstract description 26
239000011368 organic material Substances 0.000 claims abstract description 16
239000003381 stabilizer Substances 0.000 claims abstract description 11
238000004519 manufacturing process Methods 0.000 claims abstract description 5
125000000217 alkyl group Chemical group 0.000 claims description 95
-1 alkyl methacrylate Chemical compound 0.000 claims description 77
239000000178 monomer Substances 0.000 claims description 60
238000000576 coating method Methods 0.000 claims description 41
239000011248 coating agent Substances 0.000 claims description 27
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 23
125000004423 acyloxy group Chemical group 0.000 claims description 23
125000002947 alkylene group Chemical group 0.000 claims description 23
239000007787 solid Substances 0.000 claims description 22
150000001875 compounds Chemical class 0.000 claims description 21
239000000463 material Substances 0.000 claims description 21
238000006116 polymerization reaction Methods 0.000 claims description 21
125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 20
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 19
239000011230 binding agent Substances 0.000 claims description 17
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 17
125000004432 carbon atom Chemical group C* 0.000 claims description 16
230000015556 catabolic process Effects 0.000 claims description 15
238000006731 degradation reaction Methods 0.000 claims description 15
230000003647 oxidation Effects 0.000 claims description 15
238000007254 oxidation reaction Methods 0.000 claims description 15
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 14
125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 14
150000001412 amines Chemical class 0.000 claims description 13
150000001252 acrylic acid derivatives Chemical class 0.000 claims description 12
125000003545 alkoxy group Chemical group 0.000 claims description 12
229910052739 hydrogen Inorganic materials 0.000 claims description 12
239000000654 additive Substances 0.000 claims description 11
230000015572 biosynthetic process Effects 0.000 claims description 11
239000003795 chemical substances by application Substances 0.000 claims description 11
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 10
229910052799 carbon Inorganic materials 0.000 claims description 10
125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 8
239000001257 hydrogen Substances 0.000 claims description 8
150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 8
239000002736 nonionic surfactant Substances 0.000 claims description 8
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
125000003282 alkyl amino group Chemical group 0.000 claims description 7
239000003945 anionic surfactant Substances 0.000 claims description 7
229910052751 metal Inorganic materials 0.000 claims description 7
239000002184 metal Substances 0.000 claims description 7
150000001298 alcohols Chemical class 0.000 claims description 6
239000003093 cationic surfactant Substances 0.000 claims description 6
239000008199 coating composition Substances 0.000 claims description 6
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 6
238000010526 radical polymerization reaction Methods 0.000 claims description 6
229910052783 alkali metal Inorganic materials 0.000 claims description 5
150000001340 alkali metals Chemical class 0.000 claims description 5
229910052784 alkaline earth metal Inorganic materials 0.000 claims description 5
150000001342 alkaline earth metals Chemical class 0.000 claims description 5
125000004414 alkyl thio group Chemical group 0.000 claims description 5
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
239000003054 catalyst Substances 0.000 claims description 5
125000002091 cationic group Chemical group 0.000 claims description 5
239000003139 biocide Substances 0.000 claims description 4
239000003995 emulsifying agent Substances 0.000 claims description 4
150000002978 peroxides Chemical class 0.000 claims description 4
239000000049 pigment Substances 0.000 claims description 4
HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 claims description 4
125000006850 spacer group Chemical group 0.000 claims description 4
239000000080 wetting agent Substances 0.000 claims description 4
238000001704 evaporation Methods 0.000 claims description 3
239000000945 filler Substances 0.000 claims description 3
239000008394 flocculating agent Substances 0.000 claims description 3
125000005113 hydroxyalkoxy group Chemical group 0.000 claims description 3
125000002768 hydroxyalkyl group Chemical group 0.000 claims description 3
230000000379 polymerizing effect Effects 0.000 claims description 3
239000006254 rheological additive Substances 0.000 claims description 3
239000013008 thixotropic agent Substances 0.000 claims description 3
239000001993 wax Substances 0.000 claims description 3
ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical compound C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 claims description 2
239000004604 Blowing Agent Substances 0.000 claims description 2
239000006096 absorbing agent Substances 0.000 claims description 2
239000002318 adhesion promoter Substances 0.000 claims description 2
125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
239000002216 antistatic agent Substances 0.000 claims description 2
125000000753 cycloalkyl group Chemical group 0.000 claims description 2
239000002270 dispersing agent Substances 0.000 claims description 2
239000003063 flame retardant Substances 0.000 claims description 2
JYGFTBXVXVMTGB-UHFFFAOYSA-N indolin-2-one Chemical compound C1=CC=C2NC(=O)CC2=C1 JYGFTBXVXVMTGB-UHFFFAOYSA-N 0.000 claims description 2
239000000314 lubricant Substances 0.000 claims description 2
239000006224 matting agent Substances 0.000 claims description 2
239000006078 metal deactivator Substances 0.000 claims description 2
229910044991 metal oxide Inorganic materials 0.000 claims description 2
150000004706 metal oxides Chemical class 0.000 claims description 2
239000002667 nucleating agent Substances 0.000 claims description 2
230000003287 optical effect Effects 0.000 claims description 2
150000002903 organophosphorus compounds Chemical class 0.000 claims description 2
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical compound OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 2
239000004014 plasticizer Substances 0.000 claims description 2
238000000518 rheometry Methods 0.000 claims description 2
CWGBFIRHYJNILV-UHFFFAOYSA-N (1,4-diphenyl-1,2,4-triazol-4-ium-3-yl)-phenylazanide Chemical compound C=1C=CC=CC=1[N-]C1=NN(C=2C=CC=CC=2)C=[N+]1C1=CC=CC=C1 CWGBFIRHYJNILV-UHFFFAOYSA-N 0.000 claims 1
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
239000002671 adjuvant Substances 0.000 claims 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
POCUPXSSKQAQRY-UHFFFAOYSA-N hydroxylamine;hydrate Chemical compound O.ON POCUPXSSKQAQRY-UHFFFAOYSA-N 0.000 claims 1
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims 1
230000002265 prevention Effects 0.000 claims 1
230000008719 thickening Effects 0.000 claims 1
239000004094 surface-active agent Substances 0.000 abstract description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 52
239000000839 emulsion Substances 0.000 description 27
239000003963 antioxidant agent Substances 0.000 description 21
238000002296 dynamic light scattering Methods 0.000 description 17
229920000728 polyester Polymers 0.000 description 17
239000000243 solution Substances 0.000 description 16
238000000034 method Methods 0.000 description 15
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 14
239000002253 acid Substances 0.000 description 13
239000000047 product Substances 0.000 description 13
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
239000003999 initiator Substances 0.000 description 12
HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 12
239000002023 wood Substances 0.000 description 12
229920000647 polyepoxide Polymers 0.000 description 11
239000003822 epoxy resin Substances 0.000 description 10
229920005989 resin Polymers 0.000 description 10
239000011347 resin Substances 0.000 description 10
JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 9
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
229920000180 alkyd Polymers 0.000 description 9
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 9
239000003973 paint Substances 0.000 description 9
239000004971 Cross linker Substances 0.000 description 8
239000008367 deionised water Substances 0.000 description 8
229910021641 deionized water Inorganic materials 0.000 description 8
239000010408 film Substances 0.000 description 8
LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 8
239000000976 ink Substances 0.000 description 8
239000005056 polyisocyanate Substances 0.000 description 8
229920001228 polyisocyanate Polymers 0.000 description 8
150000003254 radicals Chemical class 0.000 description 8
150000003839 salts Chemical class 0.000 description 8
239000011149 active material Substances 0.000 description 7
239000000853 adhesive Substances 0.000 description 7
230000001070 adhesive effect Effects 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
238000009472 formulation Methods 0.000 description 7
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 7
239000004922 lacquer Substances 0.000 description 7
239000012071 phase Substances 0.000 description 7
229920000058 polyacrylate Polymers 0.000 description 7
239000000126 substance Substances 0.000 description 7
WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
229920000877 Melamine resin Polymers 0.000 description 6
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 6
150000008064 anhydrides Chemical class 0.000 description 6
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
238000004132 cross linking Methods 0.000 description 6
239000003431 cross linking reagent Substances 0.000 description 6
150000002148 esters Chemical class 0.000 description 6
239000012948 isocyanate Substances 0.000 description 6
150000002513 isocyanates Chemical class 0.000 description 6
238000002360 preparation method Methods 0.000 description 6
239000002904 solvent Substances 0.000 description 6
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 6
239000004593 Epoxy Substances 0.000 description 5
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 5
238000013019 agitation Methods 0.000 description 5
230000000694 effects Effects 0.000 description 5
238000005516 engineering process Methods 0.000 description 5
SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 5
239000011541 reaction mixture Substances 0.000 description 5
238000005245 sintering Methods 0.000 description 5
159000000000 sodium salts Chemical class 0.000 description 5
238000003786 synthesis reaction Methods 0.000 description 5
125000001973 tert-pentyl group Chemical group [H]C([H])([H])C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 5
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 4
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
0 CC(C)(C1)N(*)C(C)(C)CC1OC(C)=O Chemical compound CC(C)(C1)N(*)C(C)(C)CC1OC(C)=O 0.000 description 4
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
150000007513 acids Chemical class 0.000 description 4
238000013459 approach Methods 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
229920001577 copolymer Polymers 0.000 description 4
150000001991 dicarboxylic acids Chemical class 0.000 description 4
238000004090 dissolution Methods 0.000 description 4
239000000975 dye Substances 0.000 description 4
238000002290 gas chromatography-mass spectrometry Methods 0.000 description 4
239000012456 homogeneous solution Substances 0.000 description 4
125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
229920003023 plastic Polymers 0.000 description 4
239000004033 plastic Substances 0.000 description 4
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 4
CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
238000000527 sonication Methods 0.000 description 4
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 4
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 3
QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 3
VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 3
OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 3
RDFQSFOGKVZWKF-UHFFFAOYSA-N 3-hydroxy-2,2-dimethylpropanoic acid Chemical compound OCC(C)(C)C(O)=O RDFQSFOGKVZWKF-UHFFFAOYSA-N 0.000 description 3
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 3
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 3
BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 3
125000001931 aliphatic group Chemical group 0.000 description 3
125000004429 atom Chemical group 0.000 description 3
239000002981 blocking agent Substances 0.000 description 3
150000001721 carbon Chemical group 0.000 description 3
UOCJDOLVGGIYIQ-PBFPGSCMSA-N cefatrizine Chemical group S([C@@H]1[C@@H](C(N1C=1C(O)=O)=O)NC(=O)[C@H](N)C=2C=CC(O)=CC=2)CC=1CSC=1C=NNN=1 UOCJDOLVGGIYIQ-PBFPGSCMSA-N 0.000 description 3
229920006037 cross link polymer Polymers 0.000 description 3
MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
150000002009 diols Chemical class 0.000 description 3
150000002576 ketones Chemical class 0.000 description 3
125000005647 linker group Chemical group 0.000 description 3
239000007788 liquid Substances 0.000 description 3
FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
239000011120 plywood Substances 0.000 description 3
229920001225 polyester resin Polymers 0.000 description 3
239000003505 polymerization initiator Substances 0.000 description 3
229920005862 polyol Polymers 0.000 description 3
239000004814 polyurethane Substances 0.000 description 3
229920002635 polyurethane Polymers 0.000 description 3
229920002451 polyvinyl alcohol Polymers 0.000 description 3
230000008569 process Effects 0.000 description 3
235000020354 squash Nutrition 0.000 description 3
229920003048 styrene butadiene rubber Polymers 0.000 description 3
239000000758 substrate Substances 0.000 description 3
229920001169 thermoplastic Polymers 0.000 description 3
229940117958 vinyl acetate Drugs 0.000 description 3
229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical compound CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 2
LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
GOLORTLGFDVFDW-UHFFFAOYSA-N 3-(1h-benzimidazol-2-yl)-7-(diethylamino)chromen-2-one Chemical compound C1=CC=C2NC(C3=CC4=CC=C(C=C4OC3=O)N(CC)CC)=NC2=C1 GOLORTLGFDVFDW-UHFFFAOYSA-N 0.000 description 2
OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 2
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 2
KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
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