KR20090100651A - Method of preparing the dye-sensitized solar cell - Google Patents

Abstract

PURPOSE: A method of preparing the dye-sensitized solar cell is provided to increase the processing efficiency by increasing the efficiency of the glass frit sealing. CONSTITUTION: The glass frit is applied on the combining surface of the upper plate or the coupling plane which unites with the upper plate along the airtight line of the dye-sensitized solar cell. The light curing resin composition is applied on the location surrounding the combining surface of the upper plate or the coupling plane. A combination structure is made by attaching the upper plate and coupling plane. Light is projected to the light curing resin composition to cure. Laser is projected along the glass frit of the attached combination structure.

Description

Method for preparing dye-sensitized solar cell {Method of preparing the dye-sensitized solar cell}

The present invention relates to a method for manufacturing a dye-sensitized solar cell, and in particular, by applying a low melting glass frit composition and a photocurable resin composition, the laser can be fired at low temperature, thereby reducing damage to a device sensitive to heat, and free of photocurable resin. By sealing, the efficiency of glass frit sealing can be improved and process efficiency can be increased. Accordingly, the electrolyte of the solar cell which is exposed to the harsh external environment can be easily prevented from volatilizing from the airtight area, thereby extending the service life. The present invention relates to a method for manufacturing a dye-sensitized solar cell, which is resistant to external impact and damage, and provides an airtight having high strength to prolong the life of the dye-sensitized solar cell and increase durability.

Since the development of the dye-sensitized nanoparticle titanium oxide solar cell by the team of Michael Gratzel of the Swiss National Lausanne Institute of Advanced Technology (EPFL) in 1991, much work has been done in this area. Dye-sensitized solar cells have the potential to replace conventional amorphous silicon solar cells because their manufacturing cost is significantly lower than conventional silicon-based solar cells. Unlike silicon solar cells, dye-sensitized solar cells absorb visible light It is a photoelectrochemical solar cell mainly composed of a dye molecule capable of generating electron-hole pairs and a transition metal oxide that transfers generated electrons.

The unit cell structure of a general dye-sensitized solar cell is based on the upper and lower transparent substrates and the conductive transparent electrodes formed on the surfaces of the transparent substrates, respectively. The porous metal layer having the adsorbed transition metal is formed, and the catalyst thin film electrode is formed on the other conductive transparent electrode corresponding to the second electrode, and the transition metal oxide, for example, TiO ₂ , the porous electrode and the catalyst thin film electrode It has a structure in which electrolyte is filled in between.

Therefore, in order to stably maintain the electrolyte filled between the first electrode and the second electrode, a thermoplastic polymer film is placed between the first electrode and the second electrode, and a thermal compression process is performed to bond them to each other. An electrolyte is formed between the second electrode and the second electrode to maintain and maintain a predetermined space.

However, in the case of the thermoplastic polymer film, its structure is not dense, so it is easily deteriorated by high temperature, intense sunlight, heat cycling, etc., and the electrolyte is volatilized finely through heat cycling such as night / day or winter / summer. , And finally become a factor that makes the end of life, there is a problem that the polymer film is easily damaged by an external impact due to the limitation of mechanical strength, such a problem is to decrease the life of the solar cell The situation is a fatal problem for durability.

In order to solve the problems of the prior art as described above, the present invention can be applied to a low-melting glass frit composition and a photocurable resin composition can be fired at a low temperature of the laser to reduce the damage to the device weak to heat, as a photocurable resin Pre-sealing can increase the efficiency of glass frit sealing and increase the process efficiency, thereby prolonging the service life by preventing the electrolyte of the solar cell which is exposed to the harsh external environment from being easily volatilized from the airtight part. To provide a method for manufacturing a dye-sensitized solar cell which has the effect of extending the life and increasing the durability of the dye-sensitized solar cell by providing airtightness having high strength and resistance to external impact or damage. It is done.

The present invention for realizing the above object

In the manufacturing method of the dye-sensitized solar cell comprising the bonding of the upper plate and the bonding plate to combine with the upper plate,

Coating a glass frit along an airtight line of the dye-sensitized solar cell on a bonding surface of the upper plate or the bonding plate to be coupled to the upper plate;

Applying a photocurable resin composition to a position of surrounding the outer space of the upper plate or the bonding plate coupled to the upper plate and spaced apart from the hermetic line;

Bonding the top plate and the bonding plate to form a binder;

Irradiating and curing the bonded binder with light for curing the photocurable resin composition; And,

It provides a method for producing a dye-sensitized solar cell comprising the step of firing by irradiating a laser along the glass frit of the bonded binder.

In another aspect, the present invention provides a dye-sensitized solar cell prepared by the above production method.

According to the manufacturing method of the dye-sensitized solar cell of the present invention, by applying a low-melting glass frit composition and a photocurable resin composition, the laser can be fired at low temperature, thereby reducing damage to a device that is weak to heat, and presealing with a photocurable resin. It can increase the efficiency of glass frit sealing and increase the process efficiency. Accordingly, the electrolyte of the solar cell which is exposed to the harsh external environment can be prevented from easily volatilizing from the airtight area, and the durability life can be extended. By providing airtightness with resistance to damage or high strength and high strength, it is possible to extend the life of dye-sensitized solar cell and increase durability.

Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.

The present invention is a method of manufacturing a dye-sensitized solar cell in the manufacturing method of a dye-sensitized solar cell comprising the bonding of the upper plate and the bonding plate to the upper plate, the bonding of the upper plate or the bonding plate (lower plate) to combine with the upper plate Applying a glass frit to a surface along an airtight line of the dye-sensitized solar cell; Applying a photocurable resin composition to a position of surrounding the outer space of the upper plate or the bonding plate coupled to the upper plate and spaced apart from the hermetic line; Bonding the top plate and the bonding plate to form a binder; Irradiating and curing the bonded binder with light for curing the photocurable resin composition; And firing by irradiating a laser along the glass frit of the bonded assembly.

A general dye-sensitized solar cell includes a first electrode (corresponding to a lower plate-bonding plate of FIG. 1) and a second electrode disposed opposite to the first electrode (lower plate) having a porous film containing dye on one side thereof. 1) and an electrolyte filled between these electrodes. In the present invention, the first electrode and the second electrode are spaced apart from each other in order to stably store the electrolyte between the first electrode and the second electrode for a long time, and the space therebetween is sealed by a glass frit fired body. The electrolyte is filled in the airtight space thus formed, and the porous membrane corresponds to various known porous membranes to which dyes are combined (adsorbed), and specific examples thereof include transition metal oxide porous, for example, 10 to 15 nm in size. And a porous film obtained by applying TiO ₂ and firing the same. The transparent plate on which the porous membrane is formed is not necessarily limited to a flat plate, but may include a plate having a curved surface, and includes a material that transmits visible light or a wave having a predetermined wavelength beyond that, for example, a plate made of glass. Various light-transmitting plates known to be applied to the solar cell may be included therein, and preferably, those having conductivity may serve as electrodes. As a specific example for this, the floodlight plate may be a well-known floodlight glass, floodlight resin, PET, ITO or FTO, etc., and a conductive film selectively between the porous membrane and the plate in addition to the material in order to achieve conductivity. Or it may be configured to further include a coating layer (ITO, FTO or conductive polymer). The second electrode (top plate) arranged in opposing pairs on the opposite side of the first electrode may include a plate applied as a known solar cell second electrode, and does not necessarily limit a flat plate, but also has a curved surface. It may be included in this, and may be made of a material that transmits visible light or a wave of a certain wavelength band beyond it, for this purpose it may be made of a material such as known transparent glass, PET glass, ITO glass or FTO glass, preferably The conductive material may be further configured to further include a conductive film or coating layer (ITO, FTO or conductive polymer) in order to make the conductive material, increase the absorption efficiency of sunlight, catalysts such as platinum to activate the reaction The metal layer may be further included in the outermost surface of the first electrode side.

The dye-sensitized solar cell is made of a glass substrate, the upper plate, the lower plate or the bonding plate may also be made of a glass substrate as needed, as shown in Figure 1, the lower plate or bonding plate of other materials (shown in Figure 1) As described above, in the case of the structure of the upper plate and the lower plate only, the lower plate is a bonding plate, and in the case of a multilayer structure having more layers than this, the bonding plate may be bonded to the lower surface of the upper plate and additional plate (s) may be further bonded to the lower plate. It can be made).

The dye-sensitized solar cell may manufacture a plurality of dye-sensitized solar cells (2 × 2 in the case of FIG. 1) on one substrate as shown in FIG. 1, or only one cell on one substrate. It may be. Each cell is required to maintain hermeticity at its mating surface, so the glass frit composition is applied along an hermetic line that hermetically encloses the outer edge of the cell as shown in FIG. 1. The hermetic line may be configured in various shapes according to the shape of the device, and as shown in FIG. 1, the glass frit is applied to the mating surface along the hermetic line. The coupling surface may be the lower surface of the upper plate or may be the upper surface of the lower plate (or the bonding plate to couple with the upper plate). This finally serves to maintain the confidentiality of the coupling site. Application of the glass frit may be performed through various known methods, for example, the glass frit may be made of glass paste and printed and dried by a screen printing technique.

As the glass frit, a known glass frit may be used, and preferably P ₂ O ₅ 0-30 mol%; V ₂ O ₅ 0-50 mol%; ZnO 0-20 mol%; BaO 0-15 mol%; As ₂ O ₃ 0-20 mol%; Sb ₂ O ₃ 0-20 mol%; In ₂ O ₃ 0-5 mol%; Fe ₂ O ₃ 0-10 mol%; Al ₂ O ₃ 0-5 mol%; B ₂ O ₃ 0-20 mol%; Bi ₂ O ₃ 0-10 mol%; And glass frits containing TiO ₂ 0-10 mol%.

Preferably, the glass frit paste containing the glass frit is applied along an edge, and the glass frit paste composition may include a) the glass frit, b) an organic binder, and c) an organic solvent. Preferably, a) 60 to 90 parts by weight of the glass frit, b) 0.1 to 5 parts by weight of the organic binder, and c) 5 to 35 parts by weight of the organic solvent.

Preferably the glass frit is P ₂ O ₅ 10-25 mol%; V ₂ O ₅ 40-50 mol%; ZnO 10-20 mol%; BaO 1-15 mol%; Sb ₂ O ₃ 1-10 mol%; Fe ₂ O ₃ 1-10 mol%; Al ₂ O ₃ 0.1-5 mol%; B ₂ O ₃ 0.1-5 mol%; Bi ₂ O ₃ 1-10 mol%; And TiO ₂ 0.1-5 mol%, more preferably P ₂ O ₅ 15-20 mol%; V ₂ O ₅ 40-50 mol%; ZnO 10-20 mol%; BaO 5-10 mol%; Sb ₂ O ₃ 3-7 mol%; Fe ₂ O ₃ 5-10 mol%; Al ₂ O ₃ 0.1-5 mol%; B ₂ O ₃ 0.1-5 mol%; Bi ₂ O ₃ 1-5 mol%; And TiO ₂ 0.1-5 mol%.

 If the content of the glass frit component constituting the present invention is out of the above range, the glass frit may not be vitrified, the water resistance may drop significantly, or laser firing may not be performed.

Preferably, the glass frit has a glass transition temperature (T _g ) of 300 to 400 ° C., and a softening temperature (T _dsp ) of 300 to 400 ° C. Within the above range, it shows excellent plastic stability at low temperature.

In addition, the glass frit may have a particle size of 0.1 to 20 ㎛. When the temperature is within the above range, it is possible to process at low temperature, so that it is suitable for hermetic sealing of a device that is weak to heat, and can be processed with a laser to increase the sealing efficiency of an electric device.

In the glass frit paste composition, the a) glass frit is as described above, and b) the organic binder may be a commercially available organic binder. As specific examples of the organic binder, an ethyl cellulose series or an acrylic copolymer may be used. In addition, c) the organic solvent may be an organic solvent compatible with the organic binder used in the glass frit paste composition of the present invention, of course, if the organic binder is an ethyl cellulose-based butyl carbitol acetate (BCA) , Terpineol (TPN) and dibutyl phthalate (DBP) may be used alone or in combination of two or more thereof. Preferably, the organic binder is first mixed with 30 to 70 parts by weight of the organic solvent in 100 parts by weight of the organic solvent to be used to prepare a vehicle, and then the remaining amount of the organic solvent and glass frit are mixed with the prepared vehicle to form a glass frit paste composition. It is good to manufacture. In this case, the dispersibility of the glass frit paste composition can be further improved. More preferably, 30 to 70 parts by weight of the organic solvent in the preparation of the vehicle preferably contains 20 to 55 parts by weight of BCA, 3 to 10 parts by weight of TPN, and 1 to 5 parts by weight of DBP, and a solvent used when mixing with the glass frit. It is recommended to use BCA.

The glass frit paste composition may further include a filler for adjusting the coefficient of thermal expansion. Specific examples of the filler may use cordierite of 0.1 to 20 ㎛, the content is preferably 0.1 to 30 parts by weight.

In addition, the glass frit paste composition preferably has a viscosity of 500 to 50000 cps. More preferably, it is 2000 to 35000 cps. When having a viscosity within the above range it is possible to further improve the workability by enabling the application by the screen printing technique.

In the method of manufacturing a dye-sensitized solar cell of the present invention, a photocurable resin composition is then applied to a position of surrounding the outer space of the upper plate or a bonding plate coupled to the upper plate to be spaced apart from the hermetic line. This may further increase the sealing efficiency of the glass frit. The photocurable resin composition may be applied to the top plate with the glass frit in the same place as shown in FIG. 1, or may be applied to the top surface of the bottom plate, and preferably to be coated together on one side so as to be advantageous from the alignment side. desirable. That is, the lower plate (or the coupling plate), which is the first electrode, may include a porous membrane including an electrode and a dye as shown in FIG. 1 and may further include a connection line connecting unit cells as necessary. The top plate, which is the second electrode, is applied together on one side as shown in the glass frit and the photocurable resin composition. Here, it is preferable that the glass frit and the resin composition are not sealed to the entire hermetic line during the application, and a portion thereof is opened and prepared as an electrolyte injection hole so that the electrolyte can be filled in the space between the bonding surfaces of the assembly.

Application of the photocurable resin composition may also be performed through various known methods, and examples thereof may include screen printing or gravure printing.

As such a photocurable resin composition, a conventional photocurable resin composition may be used. Preferably, the photocurable resin composition used in the present invention comprises (a) 100 parts by weight of an epoxy resin, (b) 0.01 to 20 parts by weight of the photopolymerization initiator, (c) 0.01 to 10 parts by weight of the coupling agent, (d) 0.01 to 100 parts by weight of the inorganic filler, and (e) 0.05 to 10 parts by weight of the photoacid generator. .

Photocurable resin composition of the present invention has a viscosity (at 25 ℃) of 5,000 ~ 150,000cps, preferably 10,000 ~ 100,000cps can be screen printing process can shorten the process time, reduce the cost to enter the process It has the advantage of being able to.

When explaining the preferable specific component of the said photocurable resin composition, it is as follows.

The epoxy resin of a) is bisphenol A type epoxy resin, bisphenol F type epoxy resin, bisphenol AD type epoxy resin, naphthalene type epoxy resin, biphenyl type epoxy resin, glycidyl amine (glycidyl amine) type epoxy resin, naphthol novolac type epoxy resin, dicyclo pentadiene type epoxy resin, phenol novolac type epoxy resin, alicyclic epoxy resin, prepolymer of the above epoxy resin , Polyether-modified epoxy resins, silicone-modified epoxy resins, copolymers of the epoxy resins with other polymers, and the like, may be used alone or in combination of two or more thereof.

As the photopolymerization initiator of b), an aromatic diazonium salt, an aromatic sulfonium salt, an aromatic iodine aluminum salt, an aromatic sulfonium aluminum salt, a metallocene compound, an ironene compound, or the like may be used.

In particular, an aromatic sulfonium salt is preferable in terms of photocurability, and an aromatic sulfonium hexa fluoro phosphate compound and an aromatic sulfonium hexafluoro antimonate in terms of curability and adhesion. hexa fluoro antimonate) or a mixture thereof.

The photopolymerization initiator is preferably used in an amount of 0.01 to 20 parts by weight, more preferably 0.1 to 10 parts by weight, and most preferably 1 to 6 parts by weight based on 100 parts by weight of the epoxy resin. If the content exceeds 20 parts by weight, the remaining components may not act in the reaction of the composition, and the remaining components may act as a factor for lowering the physical properties of the photocurable resin composition.

The coupling agent of c) is an additive for improving adhesion (adhesive properties), and a silane coupling agent such as trimethoxy silyl benzoic acid, γ-glycidoxy propyl trimethoxysilane, and a silane coupling agent such as titanium ( Titan) coupling agents, silicone compounds, and the like may be used alone or in combination of two or more thereof.

The coupling agent is preferably used in an amount of 0.01 to 10 parts by weight, more preferably 0.1 to 5 parts by weight, and most preferably 0.1 to 2 parts by weight based on 100 parts by weight of the epoxy resin. When the content is more than 10 parts by weight does not participate in the reaction of the composition, the remaining components may act as a factor to lower the physical properties of the photocurable resin composition.

The inorganic filler of d) is silica (silica), talc (talc), magnesium oxide (MgO), mica (montmorillonite), alumina (alumina), graphite (graphite), beryllium (beryllium) A plate-like or spherical inorganic filler such as oxide, aluminum nitride, silicon carbide, mullite, or silicon may be used.

In particular, the inorganic filler is good to use a talc (talc) that is excellent in the barrier properties and light transmittance against moisture, and prevents shrinkage after photocuring.

In addition, the inorganic filler may be used by introducing a substituent to the inorganic filler in order to increase the dispersion properties and adhesion with the epoxy resin in the photocurable resin composition.

The inorganic filler is preferably used in 0.01 to 100 parts by weight, more preferably 0.1 to 80 parts by weight based on 100 parts by weight of the epoxy resin. When the content exceeds 100 parts by weight may interfere with the reaction of the photocurable resin composition may act as a factor to lower the physical properties. The inorganic filler may be more preferably used particles having an average particle diameter of 0.1 to 50 um.

The photoacid generator of e) is not limited as long as it generates a Lewis acid and Bronsted acid component by exposure and can generate an acid by light. For example, sulfuric acid compounds such as eutectic acid, onium salt compounds such as onium salt, and mixtures thereof may be used as the photoacid generator. Non-limiting examples of photoacid generators include phthalimidotrifluoromethane sulfonate, dinitrobenzyltosylate, n-decyl disulfone, naphthylimidotrifluoro Naphthylimido trifluoromethane sulfonate, diphenylurido salt hexafluorophosphate, diphenylurido salt hexafluoro arsenate, diphenylurido salt hexafluoro antimonate, diphenylparamethoxyphenylsulfonium triflate, diphenyl Paratoluenylsulfonium triflate, diphenylparaisobutylphenylsulfonium triflate, triphenylsulfonium hexafluoro arsenate, triphenylsulfonium hexafluoro antimonate, triphenylsulfonium triflate, dibutyl Naphthylsulfonium triflate and the like.

The photoacid generator is preferably included in 0.05 to 10 parts by weight based on 100 parts by weight of the epoxy resin. When the content exceeds 10 parts by weight, the photoacid generator absorbs a lot of far ultraviolet rays, and a large amount of acid may be generated to lower the physical properties of the photocurable resin composition.

In addition, the photocurable resin composition may optionally further include a spacer. The spacer applicable to the photocurable resin composition is not particularly limited as long as it can maintain the thickness of the panel after curing, and the thickness of the panel can be maintained at 5 to 50 um, preferably 5 to 25 um. It is good. The shape of the spacer is spherical, log, and the like, and the shape of the spacer is not particularly limited as long as the thickness of the panel can be kept constant. The content of the spacer is preferably included in 0.01 to 10 parts by weight based on 100 parts by weight of the epoxy resin.

In the photocurable resin composition of this invention which consists of such a component, it is preferable that the epoxy change rate of the hardened | cured material is 85% or more.

Next, the upper plate prepared as described above and a bonding plate bonded to the upper plate are bonded to prepare a binder. The binding plate corresponds to the lower plate in FIG. 1, and further bonding after the bonding is made with the combination is limited. Therefore, before and after the coating step of the glass frit or the resin composition, after completing all the necessary processing steps in the configuration of the cell should be carried out the bonding of the top plate and the bonding plate. The electrode forming and dye adsorption processes as shown in Figure 1 may be applied to this.

In addition, when the glass frit and the photocurable resin composition are applied along the airtight line, all of them may be applied to maintain the airtightness, and may be applied while leaving a connector connected to the inner space as necessary. In the case of the dye-sensitized solar cell of the present invention, it is necessary to fill the electrolyte so that the electrolyte inlet can be applied for this purpose.

Thus, the glass frit and the photocurable resin composition of the bonded binder are not yet cured, and then the cured by irradiating light to cure the photocurable resin composition to the bonded binder. As shown in FIG. 1, when the photocurable resin composition coated as shown in FIG. 1 is cured by UV, ultraviolet rays are cured by irradiation with ultraviolet rays as shown. Next, since it is necessary to cure the glass frit of the bonded assembly, a step of irradiating a laser along the applied glass frit and firing is performed. The glass frit may preferably use a low melting glass frit as described above, so that the irradiated laser may use a laser having a low output, thereby minimizing thermal damage to the device. . In this case, the resin composition layer, which is already cured and surrounds the glass frit, serves to block gas generation and contact with oxygen during firing of the glass frit, and supports the binder during firing of the glass frit, thus presealing ( Pre-sealing can increase the efficiency of glass frit sealing and increase the process efficiency.

Through this, the airtightness of the dye-sensitized solar cell is maintained by double frit by the glass frit and the resin composition, and then cut between the airtight line and the photocurable resin composition coating portion as shown in FIG. The part which hardened the photocurable resin composition can be isolate | separated. In particular, in the case of FIG. 1, since a plurality of cells are manufactured on a single substrate, dicing operations are performed to cut each of the cells into a plurality of cells. In addition, after the glass frit firing process or after the dicing operation, the electrolyte may be injected into the electrolyte inlet described above, and finally, the airtight operation may be performed by using a glass frit or the like to complete the airtightness.

The present invention described above is not limited to the above-described embodiment and the accompanying drawings, and various modifications and changes made by those skilled in the art without departing from the spirit and scope of the present invention described in the claims below. Changes are also included within the scope of the invention.

1 is a view schematically showing a method of manufacturing a dye-sensitized solar cell as one embodiment of a method of manufacturing a dye-sensitized solar cell of the present invention.

Claims (12)

In the manufacturing method of the dye-sensitized solar cell comprising the bonding of the upper plate and the bonding plate to combine with the upper plate, Coating a glass frit along an airtight line of the dye-sensitized solar cell on a bonding surface of the upper plate or the bonding plate to be coupled to the upper plate; Applying a photocurable resin composition to a position of surrounding the outer space of the upper plate or the bonding plate coupled to the upper plate and spaced apart from the hermetic line; Bonding the top plate and the bonding plate to form a binder; Irradiating and curing the bonded binder with light for curing the photocurable resin composition; And, The method of manufacturing a dye-sensitized solar cell comprising the step of firing by irradiating a laser along the glass frit of the bonded binder. The method of claim 1, And a step of separating between the airtight line and the photocurable resin composition coated part after the manufacturing method to separate the cured part of the photocurable resin composition. The method of claim 1, The glass frit is P ₂ O ₅ 0-30 mol%; V ₂ O ₅ 0-50 mol%; ZnO 0-20 mol%; BaO 0-15 mol%; As ₂ O ₃ 0-20 mol%; Sb ₂ O ₃ 0-20 mol%; In ₂ O ₃ 0-5 mol%; Fe ₂ O ₃ 0-10 mol%; Al ₂ O ₃ 0-5 mol%; B ₂ O ₃ 0-20 mol%; Bi ₂ O ₃ 0-10 mol%; And TiO ₂ 0-10 mol%. The method of claim 1, The application of the glass frit a) the glass frit; b) organic binders; And c) organic solvents Method for producing a dye-sensitized solar cell comprising applying a glass frit paste composition comprising a. The method of claim 4, wherein The glass frit paste a) 60 to 90 parts by weight of the glass frit; b) 0.1 to 5 parts by weight of the organic binder; And c) 5 to 35 parts by weight of organic solvent Method for producing a dye-sensitized solar cell comprising a. The method of claim 1, The photocurable resin composition a) 100 parts by weight of an epoxy resin; b) 0.01 to 20 parts by weight of the photopolymerization initiator; c) 0.01 to 10 parts by weight of a coupling agent; d) 0.01 to 100 parts by weight of an inorganic filler; And e) 0.05 to 10 parts by weight of photoacid generator Method for producing a dye-sensitized solar cell comprising a. The method of claim 6, The epoxy resin of a) is bisphenol A type epoxy resin, bisphenol F type epoxy resin, bisphenol AD type epoxy resin, naphthalene type epoxy resin, biphenyl type biphenyl epoxy resin, glycidyl amine ( glycidyl amine) type epoxy resin, naphthol novolak type epoxy resin, dicyclo pentadiene type epoxy resin, phenol novolac type epoxy resin, alicyclic epoxy resin, prepolymer of the above epoxy resin, Method of manufacturing a dye-sensitized solar cell, characterized in that at least one selected from the group consisting of polyether modified epoxy resin, silicone modified epoxy resin and a copolymer of the epoxy resin and another polymer (polymer). . The method of claim 6, The photopolymerization initiator of b) is any one selected from the group consisting of aromatic diazonium salts, aromatic sulfonium salts, aromatic iodide aluminum salts, aromatic sulfonium aluminum salts, metallocene compounds, and ironene-based compounds Method for producing a dye-sensitized solar cell, characterized in that one or more. The method of claim 6, Wherein the coupling agent of c) is a silane coupling agent, a titanium (Titan) coupling agent and a silicon (silicone) is a method for producing a dye-sensitized solar cell, characterized in that any one or more selected from the group consisting of. The method of claim 6, The inorganic filler of d) is silica (silica), talc (talc), magnesium oxide (MgO), mica (mont), montmorillonite, alumina (alumina), graphite (graphite), beryllium oxide (beryllium oxide) ), A method of manufacturing a dye-sensitized solar cell, characterized in that at least one selected from the group consisting of aluminum nitride, silicon carbide, mullite and silicon. The method of claim 6, The photoacid generator of e) is a manufacturing method of a dye-sensitized solar cell, characterized in that selected from the group consisting of a sulfide-based compound, onium salt-based compound and mixtures thereof. The dye-sensitized solar cell manufactured by the manufacturing method of the dye-sensitized solar cell of any one of Claims 1-11.

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