KR20080103172A - Deodorant composition for textiles or fabric products - Google Patents

Abstract

A deodorant composite for clothes and a fiber product is provided to maximize the deodorization effect of a fiber and clothes, remove bacteria and mold and prevent bleaching or discoloration. A deodorant composite for clothes and a fiber product comprises: a chemistry deodorizing agent selected from a group consisting of betaine compound classes, organic acid or salts of the organic acid, amines, polyol and a mixture consisting of the betaine compound classes, organic acid or salts of the organic acid, amines and polyol; an inorganic chelate metal complex dispersing copper or the zinc metal in the organic acid solution; a natural extract selected from a group consisting of green tea extract and seaweed extract; and a cationic biocide. The betaine compound classes are selected from a group consisting of alkylbetaine, fatty acid amid propyl betaine, alkyl sulfobetaine and imidazolinium betain.

Description

DEODORANT COMPOSITION FOR TEXTILES OR FABRIC PRODUCTS

The present invention relates to a deodorant composition for apparel and textiles, more specifically, a) a chemical deodorant selected from the group consisting of betaine-based compounds, organic acids or salts, amines, polyols and mixtures thereof; And b) a deodorant composition for apparel and textile products containing an inorganic metal complex compound in which copper or zinc metal is dispersed in an organic acid solution.

Generally, not only clothing and textile products, but also for removing unpleasant odors in the air in the home, removing body odors such as sweat, removing unpleasant odors in the bathroom, removing food odors in the kitchen, and removing unpleasant odors in the living space such as the entrance. Masking products using fragrance products with strong volatile fragrances have long been used.

In everyday life, there are various odors such as unpleasant odors in the air, body odors such as sweat, smells of toilets, food odors in kitchens, smells of cigarettes, and molds such as shoe racks or warehouses.

These scents can cause odor and discomfort in curtains, sofas, carpets, beddings such as duvets and pillows, closets, and clothing that are exposed all over the house. This may grow. In addition, in order to prevent this can be used to wash frequently, frequent washing is cumbersome and difficult to wash if you can not be applied, there is a limit to the method of removing odor through washing.

The following methods have been proposed to eliminate the cause of odor in clothing or textile products.

1) Chemical Deodorization Method

It is a method that uses chemical reactions such as neutralizing, oxidizing, reducing, and hydrolysis of odor-causing substances, and removes odor-causing substances by applying specific components that are combined with odorous substances and induces conversion to other substances. .

2) physical deodorization method

It is a method of blocking the odor of an odor causing substance by adsorption or collection of an odor causing substance by using a porous adsorbent or a carrier, for example, activated carbon, porous silica, and cyclodextrin, which have an adsorption or capture capability.

3) biological deodorization method

As a method of removing odor generated during metabolic processes of odor causing bacteria, the cause of odor generation is removed by directly sterilizing odor causing bacteria.

4) Deodorization method by masking

Basically, it is not a concept of deodorization, but a method of giving a high intensity to give a scent that feels better than the intensity of odor that is sensationally sensitized, so that the odor is not felt relatively.

Odor causing substances that cause discomfort in clothing or textile products are four major odor sources, and include ammonia, trimethylamine, hydrogen sulfide, and methylmercaptane. In addition, there is a smell of tobacco in everyday life made of a combination of various components, the smell of food waste, the smell of sweat, the smell by metabolism such as bacteria or mold.

The best way to remove the odor is to remove the cause of the odor by washing. However, such a method causes inconvenience in daily life, and some products are not washable, and washing is not a professional deodorizing method, so the cause of odor is not removed even after washing or during drying. There is also a problem that the odor may persist due to contamination.

Therefore, in recent years, deodorization technology using cyclodextrin, a kind of cyclic polysaccharide, which is known to have good capture performance (US Pat. Nos. 6,146,621, 5,942,217, 5,939,060, 5,783,544, 5,714,137, and 5,668,097). , No. 5,593,670, No. 5,534,165) were introduced, deodorization technology using inorganic metal complex compounds and persimmon leaf extract (Korean Patent No. 10-0593037), deodorization technology containing nano silver (Korean Patent Publication No. 10-2005 -012295), deodorization technology by metal oxide (Japanese Patent Application No. 2004-371717) and the like have been introduced.

Cyclodextrins have some effect on the removal of odors, but the collected odorous substances remain in clothing or textile products, which may cause discomfort. In addition, the cyclodextrin's glucose monomers remain on the clothing or fiber surface. There is a drawback that can lead to breeding and stickiness may impair the safety of the fiber or cause discomfort.

Inorganic metal complexes and natural extracts have the ability to remove odors, but are relatively weak in their efficacy, making them difficult to use alone. Deodorizing products containing nano silver can remove bacteria while being harmless to human body, and it is applied by adding deodorizing power of natural extracts such as persimmon leaf, green tea, and seaweed, but the effect is also expected when using nano silver alone. Did not reach.

In addition, natural extracts, such as persimmon leaf extract, seaweed extract, including green tea extract known to have a deodorizing effect has a problem in temperature stability over time there is a limitation in its use.

Therefore, there is a need for a deodorant for clothing and textiles having substantial effects by further enhancing the deodorizing effect and antimicrobial efficacy and stability of natural extracts in such deodorizing products for clothing and textiles.

Accordingly, the present inventors have made efforts to develop a deodorant composition for clothing and textiles that maximizes the deodorizing effect of clothing and textiles, removes bacteria and mold, and does not cause discoloration or discoloration of fibers due to good stability. The present invention has been completed.

After all, an object of the present invention is to provide a deodorant composition that can maximize the deodorizing effect of clothing and fibers through the combined action of each component containing a chemical deodorant component, inorganic metal complex compound, green tea extract, seaweed extract and antibacterial agent.

The present invention to achieve the above object is a) a chemical deodorant selected from the group consisting of betaine-based compounds, organic acids or salts thereof, amines, polyols and mixtures thereof; And b) a deodorant composition for apparel and textile products containing an inorganic metal complex compound in which copper or zinc metal is dispersed in an organic acid solution.

The deodorant composition according to the present invention may further contain c) a natural extract selected from the group consisting of green tea extract and seaweed extract or d) a cationic fungicide.

In the present invention, the betaine-based compounds may be selected from the group consisting of alkyl betaine, fatty acid amide propyl betaine, alkyl sulfobetaine and imidazolinium betaine.

In addition, the organic acid of a) or b) is p-toluenesulfonic acid, acetic acid, trifluoroacetic acid, citric acid, maleic acid (maleic acid), succinic acid, oxalic acid, benzoic acid, tartaric acid, fumaric acid, manderic acid, propionic acid (propionic acid) ), Citric acid, lactic acid, glycolic acid, glycolic acid, gluconic acid, galacturonic acid, glutamic acid, glutaric acid, glucuronic acid, It can be selected from the group consisting of aspartic acid, ascorbic acid, carbonic acid, vanic acid and hydroiodic acid.

In addition, the amines may be selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, and polymers thereof, and the polyols are ethylene glycol, propylene glycol, 1,3- Butylene glycol, polyethylene glycol and polypropylene glycol.

In the present invention, the d) the cationic fungicide is cetylpyridinium chloride, benzoalkonium chloride, benzoethonium chloride, distearyl dimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, didecyl dimethyl ammonium chloride, stearyl trimethyl chloride Quaternary ammonium salts selected from the group consisting of ammonium, cetyltrimethyl ammonium chloride, lauryltrimethylammonium chloride and laurylpyridinium chloride and chlorhexidine hydrochloride, chlorhexidine acetate, chlorohexyl gluconate, alexandrite hydrochloride, alexandrite acetate and gluconate acrylate It can be characterized by using only one or two or more selected from the group consisting of biguanide fungicides selected from the group consisting of Dean.

The present invention also provides a method for deodorizing clothing and textile products comprising spraying an effective amount of the deodorant composition for clothing and textile products according to the composition on clothing and textile products.

The content of each component of the deodorant composition for clothes and textiles according to the present invention is 0.1 to 10 parts by weight of the chemical deodorant, 0.01 to 5 parts by weight of the inorganic metal complex compound in which copper or zinc metal is dispersed in an organic acid solution, and green tea It is preferable to contain 0.01 to 5 parts by weight of the natural extract selected from the group consisting of extracts and seaweed extracts, and 0.05 to 3 parts by weight of cationic fungicides.

The deodorant composition for clothing and textile products according to the present invention is an excipient for imparting weight when spraying fibers, a stabilizer for stabilization of green tea extract or seaweed extract, a pH adjuster for adjusting pH, a flavoring agent, a fragrance agent, and the like. The solvent etc. which are intended to melt | dissolve can be added and manufactured as needed.

Among the additional components, excipients are 0.5 to 5 parts by weight, stabilizers for the green tea extract or seaweed extract stabilizer 0.01 to 5 parts by weight, pH adjuster is 0.1 to 3 parts by weight, flavor is 0.01 to 3 parts by weight, It is preferable to add a fragrance agent to 0.01-3 weight part and a solvent in the range of 1-95 weight part, and to prepare a deodorizing composition.

According to an embodiment of the present invention, the fiber deodorant composition according to the present invention is 0.1 to 10 parts by weight of chemical deodorant components, 0.5 to 5 parts by weight of excipients, 0.01 to 5 parts by weight of inorganic metal complex compounds, natural 0.01-5 parts by weight of green tea extract or seaweed extract, 0.01-5 parts by weight of stabilizer, 0.1-3 parts by weight of pH adjuster, 0.05-3 parts by weight of antibacterial agent, 0.01-3 parts by weight of flavoring agent, 0.01-3 parts by weight of fragrance, It contains 1-95 weight part of solvents.

Deodorant composition for garments and textiles prepared according to the present invention is in the form of a transparent liquid state, there is an advantage of excellent stability of the composition.

A) The chemical deodorant contained in the deodorant composition for clothes and textiles according to the present invention may be selected from the group consisting of betaine-based compounds, organic acids or salts thereof, amines, polyols and mixtures thereof. The chemical deodorizing component is to induce the odor causing substances to be replaced with other substances by combining the odor causing substances with chemical odors such as neutralization, oxidation, reduction, and hydrolysis. Can be.

Examples of such chemical deodorants include betaine compounds selected from the group consisting of alkyl betaine, fatty acid amide propyl betaine, alkyl sulfobetaine and imidazolinium betaine, p-toluenesulfonic acid, acetic acid, trifluoroacetic acid, citric acid, Maleic acid, succinic acid, oxalic acid, benzoic acid, tartaric acid, fumaric acid, manderic acid, propionic acid, citric acid, lactic acid, glycolic acid, gluconic acid ), Galacturonic acid, glutamic acid, glutaric acid, glucuronic acid, glucuronic acid, aspartic acid, ascorbic acid, carbonic acid, vanic acid and hydroiodic acid. Can be selected from the group consisting of ethanolamine, diethanolamine, triethanolamine and polymers thereof Polyols selected from the group consisting of amines, ethylene glycol, propylene glycol, 1,3-butylene glycol, polyethylene glycol, and polypropylene glycol.

B) Deodorization mechanism in the fiber of the inorganic metal complex compound in which the main component of the deodorant composition according to the present invention is a copper or zinc metal dispersed in an organic acid solution is different from the conventional mainstream physical, chemical adsorption, or fragrance masking. It deodorizes various odorous substances by decomposing action, and it is excited by temperature rise and ultraviolet irradiation, and it has the characteristic of increasing decomposition reaction rate. Also, there is no saturation deterioration which is a drawback of adsorption deodorization effect and deodorization effect can be maintained in the long term. have.

In addition, the metal complex compound exhibits almost perfect deodorizing effect on sulfide compounds such as hydrogen sulfide and methylmecaptan, which are the main components of acidic odor, and also ammonia and trimethylamine, which are basic odors, as well as acetaldehyde, which are volatile odors. It can exhibit very good deodorant effect on odorous substances. In addition, by using the metal complex compound mixed with an organic acid, it is possible to maximize the effect by maintaining the pH stability.

The deodorant composition according to the present invention may contain green tea extract or seaweed extract extracted from wakame seaweed, seaweed, green seaweed, starfish, etc. as a natural deodorizing component.

D) Cationic fungicide in the deodorant composition according to the present invention is contained as an antimicrobial component for the removal and sterilization of bacteria and fungi. As such antimicrobial components, quaternary ammonium salts and biguanide-based fungicides are preferred as cationic fungicides. For example, cetylpyridinium chloride, benzoalkonium chloride, benzoethonium chloride, distearyl dimethyl ammonium chloride, stearyl dimethylbenzyl ammonium chloride, didecyl dimethyl ammonium chloride, stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, Cations such as quaternary ammonium salts such as lauryltrimethylammonium chloride and laurylpyridinium chloride, and biguanide fungicides such as chlorhexidine hydrochloride, chlorhexidine acetate, gluconate chlorhexidine, alexandrite hydrochloride, alexandrite acetate, and gluconate alexidine Sex fungicides are included here. These cationic fungicides can be mix | blended individually or in combination of 2 or more types.

In the present invention, an excipient for imparting weight when spraying fibers may use ethylene glycol, propylene glycol, 1,3-butylene glycol, polyethylene glycol, polypropylene glycol, glycerin, and the like.

In the present invention, the pH adjusting agent for adjusting the pH may be used an organic acid, an alkali, an organic acid salt, etc., the flavoring agent and the fragrance emulsifier may be variously selected in consideration of the selection of the fragrance and the emulsification state according to the fragrance.

In the present invention, as the solvent for dissolving the substance and the like contained in the deodorant composition, ethanol, purified water and the like may be used.

 Hereinafter, the contents of the present invention will be described in more detail with reference to Examples. However, these examples are described by way of example for understanding the contents of the present invention and should not be construed that the scope of the present invention is limited to these examples.

In order to evaluate the deodorant composition according to the present invention, Examples 1 to 5 and Comparative Examples 1 to 5 were configured to perform deodorizing power evaluation.

Example  1 to 5 and Comparative example  1-5: Composition of deodorant for clothing and textile

Table 1 shows the composition of the deodorant for clothing and textiles.

Examples and comparative examples of the deodorant for clothing and textiles (unit: weight%) division Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Metal Complexes (CuZn / Organic Acid) 0.1 0.1 0.1 0.1 0.3 - - - - - Betaine 0.3 0.3 0.3 0.5 0.5 - - - - - Organic acid salt 0.5 0.5 0.5 0.5 0.5 - - - - - Amine (Mono-, Di-, Triethanola) 0.3 0.3 0.3 0.3 0.3 - - - - - Nano silver - - - - - - - - 0.3 0.05 Cyclodextrin - - - - - 0.5 - - - - Metal Complexes (TiO ₂ / Cu, Zn) - - - - - - 5 8 8 8 Persimmon Leaf Extract - 0.3 - - - - - 0.5 0.5 2 Green Tea Extract - - 0.3 - - 0.1 - - - - Seaweed Extract - - - 0.3 - - - - - - Surfactants 0.5 0.5 0.5 0.5 0.5 0.5 0.01 0.01 2 2 Propylene glycol One One One One One One 0.05 0.05 - - Antibacterial agents 0.1 0.1 0.1 0.1 0.1 0.1 Quantity Quantity 0.25 0.25 additive 0.5 0.5 0.5 0.5 0.5 3 One 0.5 0.5 0.5 ethanol 5 5 5 5 5 5 3 5 15 15 Purified water Quantity Quantity Quantity Quantity Quantity Quantity Quantity Quantity Quantity Quantity Total 100 100 100 100 100 100 100 100 100 100

* Comparative Example 1 is a composition disclosed in U.S. Pat.Nos. 5,714,137, 5,668,097, 5,593,670, and 5,534,165. It is a composition according to Korea Patent Publication No. 10-2005-0120295. The preparation was made according to the methods and examples specified in the patent.

Experimental Example  One: Deodorant effect  evaluation

Ammonia, trimethylamine, and hydrogen sulfide, which are representative components of basic odors, are known to represent odors of everyday life using the deodorants for clothing and textiles prepared in Examples 1 to 5 and Comparative Examples 1 to 5 described above. The deodorizing effect by the detection tube method was evaluated for each malodor source using methylmercaptan, which is a representative component of acidic odor.

The detection tube method was used for the experiment, and the detection tube used was gas inhaler and detection tube of GASTEC Co., Ltd., No. 3 (ammonia), No. 4 (hydrogen sulfide), No. 180 (trimethylamine), No. 71 (methylmer). Captan) and the like.

The test method for deodorizing power evaluation is as follows.

1. Prepare 0.5 g of clean cotton cloth.

2. Spray 3 g of the deodorant for clothing and textiles according to Examples and Comparative Examples to each cotton cloth.

3. Place the cotton cloth into a 1 L Erlenmeyer flask.

4. Inject the gas to be evaluated into the tube through the rubber stopper of the flask and seal it again with a para film.

5. After a certain period of time (30 minutes), measure the gas concentration using a detector tube.

-The detector tube and gas concentration meter should be inhaled for 30 seconds during measurement, removed and left for 20 seconds.

6. Blank Test-Add only gas and observe the change in gas concentration over time.

7. Deodorization rate (%) = (concentration of blank gas-gas concentration of Examples and Comparative Examples) / concentration of blank gas x 100

8. Experiment 3 times or more for each sample to find the average value and substitute in the above formula.

The test results by the evaluation are shown in Table 2 below.

Evaluation result of deodorant of clothing and textile deodorant (deodorant effect:%, after 30 minutes) division Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Ammonia 97 96 97 95 96 80 96 94 39 51 Hydrogen sulfide 82 85 86 85 84 56 81 84 6 13 Trimethylamine 94 93 92 91 92 60 93 90 - - Methylmercaptane 84 82 84 90 91 43 89 77 6 40

As can be seen through Table 2, the deodorizing power of the deodorant composition according to the present invention was superior to the effect of removing the various odor causing substances compared to the existing deodorant composition.

Experimental Example  2: antimicrobial activity evaluation

The antimicrobial test was carried out according to K 0693 method, which is the KS test method, as a deodorant for clothes and textiles having a composite function prepared in Examples 1 to 5 and Comparative Examples 1 to 5 described above. The test results by the evaluation are shown in Table 3 below.

.

Evaluation of Antimicrobial Activity of Clothing and Textile Deodorant (Reduction Rate of Bacteria:%,) division Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Bacteria Esherichia coli 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 Staphylococcus aureus 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 Pseudomonsa aeruginosa 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 Yeast Candida albicans 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 99.99 Fungi Aspergillus niger 99.99 99.99 99.99 99.99 99.99 33.33 99.99 99.99 99.99 99.99

As can be seen through Table 3, the deodorant composition according to the present invention was also excellent antibacterial activity.

Experimental Example  3: stability evaluation

The deodorant composition for clothes and textiles having a composite function prepared in Examples 1 to 5 and Comparative Examples 1 to 5 was subjected to stability experiments for 3 months under severe conditions of 50 ° C. × 75% RH.

The deodorant composition for clothes and textiles having a composite function prepared in Examples 1 to 5 and Comparative Examples 1 to 5 is in a colorless transparent liquid state. In the stability evaluation method, the composition contained in the transparent container was visually observed for 3 months to observe whether the liquid phase of the composition changed, and the results are shown in Table 4 below.

Results of stability evaluation of clothing and textile deodorant (50 ℃ × 75%, after 3 months) division Example 1 Example 2 Example 3 Example 4 Example 5 Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 Liquid state of the composition Transparency Light yellow Transparency Transparency Transparency Transparency Light green Light green Sedimentation Sedimentation

* The stability evaluation method of each Example and a comparative example is by visual observation.

As a result of the stability test as described above, as shown in Table 4, the deodorant composition according to the present invention of Examples 1 to 5 is excellent in stability because the overall transparent state is continuously maintained, but the deodorant composition of Comparative Examples 1 to 5 is It was confirmed that the color of the composition changed or precipitation occurred. In case of discoloration or sedimentation with time as in the example of the comparative composition, the stability of the deodorant composition is maintained because it may deteriorate or spoil the surface of the fiber after time when sprayed on the textile product or clothing. It is important to remain.

As described in detail above, the deodorant composition for clothes and textile products according to the present invention maximizes the deodorizing effect of clothes and fibers, removes bacteria and mold, and is excellent in stability that does not cause discoloration or discoloration. Therefore, when the deodorant composition of the present invention is applied to the deodorization of clothing and textile products, not only the deodorizing power and the antibacterial effect against the odor causing bacteria for various odor components, but also remain in the clothing and textile products to denature the surface of the fiber or There is an advantage that does not hurt.

Claims (14)

a) chemical deodorant selected from the group consisting of betaine-based compounds, organic acids or salts thereof, amines, polyols and mixtures thereof; And b) Deodorant composition for apparel and textile products containing an inorganic metal complex compound in which copper or zinc metal is dispersed in an organic acid solution. The deodorant composition of claim 1, further comprising a natural extract selected from the group consisting of green tea extract and seaweed extract. The deodorant composition according to claim 1 or 2, further comprising d) a cationic fungicide. The deodorant composition according to claim 1, wherein the betaine-based compound is selected from the group consisting of alkyl betaine, fatty acid amide propyl betaine, alkyl sulfobetaine and imidazolinium betaine. The method of claim 1, wherein the organic acid of a) or b) is p-toluenesulfonic acid, acetic acid, trifluoroacetic acid, citric acid, maleic acid, succinic acid, oxalic acid, benzoic acid, tartaric acid, fumaric acid, manderic acid, propionic acid (propionic acid), citric acid, lactic acid, glycolic acid, gluconic acid, galconic acid, galacturonic acid, glutamic acid, glutaric acid, glucuronic acid acid), aspartic acid, ascorbic acid, carbonic acid, vanic acid, and hydroiodic acid. The deodorant composition according to claim 1, wherein the amines are selected from the group consisting of monoethanolamine, diethanolamine, triethanolamine, and polymers thereof. The deodorant composition according to claim 1, wherein the polyol is selected from the group consisting of ethylene glycol, propylene glycol, 1,3-butylene glycol, polyethylene glycol and polypropylene glycol. The method according to claim 3, wherein the cationic fungicide is cetylpyridinium chloride, benzoalkonium chloride, benzoethonium chloride, distearyl dimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, didecyl dimethyl ammonium chloride, stearyl trimethyl chloride Quaternary ammonium salts selected from the group consisting of ammonium, cetyltrimethyl ammonium chloride, lauryltrimethylammonium chloride and laurylpyridinium chloride and chlorhexidine hydrochloride, chlorhexidine acetate, chlorohexyl gluconate, alexandrite hydrochloride, alexandrite acetate and gluconate acrylate A deodorant composition for apparel and textile products, characterized in that it is used alone or two or more selected from the group consisting of biguanide fungicides selected from the group consisting of dean. According to claim 1, Apparel and textile products, characterized in that 0.1 to 10 parts by weight of the chemical deodorant, 0.01 to 5 parts by weight of the inorganic metal complex compound based on a total of 100 weight of the deodorant composition for clothing and textile products Deodorant composition. The deodorant composition according to claim 2, wherein the natural extract is included in an amount of 0.01 to 5 parts by weight based on 100 parts by weight of the total composition. The deodorant composition according to claim 3, wherein the cationic fungicide is contained in an amount of 0.05 to 3 parts by weight based on 100 parts by weight of the total composition. According to claim 1, Deodorant composition for clothing and textile products is 0.5 to 5 parts by weight of excipients, 0.01 to 5 parts by weight of stabilizers for the stabilization of green tea extract or seaweed extract, 0.1 to 3 parts by weight of pH regulator, 0.01% flavoring agent Deodorant composition for clothing and textile products, characterized in that it further comprises ~ 3 parts by weight or 0.01 to 3 parts by weight of emulsifier. The deodorant composition according to claim 1, wherein the deodorant composition for clothing and textiles comprises 0.1 to 10 parts by weight of chemical deodorant, 0.5 to 5 parts by weight of excipient, 0.01 to 5 parts by weight of inorganic metal complex, natural green tea extract or seaweed extract. 0.01 to 5 parts by weight, stabilizer 0.01 to 5 parts by weight, pH regulator 0.1 to 3 parts by weight, antibacterial agent 0.05 to 3 parts by weight, flavoring agent 0.01 to 3 parts by weight, fragrance agent 0.01 to 3 parts by weight, solvent 1 to 95 parts by weight Deodorant composition for clothing and textiles comprising a part. A method of deodorizing clothing and textile products comprising spraying an effective amount of the deodorant composition for clothing and textile products according to any one of claims 1 to 13 on clothing and textile products.