KR100580067B1 - Fabric treatment composition - Google Patents
Fabric treatment composition Download PDFInfo
- Publication number
- KR100580067B1 KR100580067B1 KR1020040060703A KR20040060703A KR100580067B1 KR 100580067 B1 KR100580067 B1 KR 100580067B1 KR 1020040060703 A KR1020040060703 A KR 1020040060703A KR 20040060703 A KR20040060703 A KR 20040060703A KR 100580067 B1 KR100580067 B1 KR 100580067B1
- Authority
- KR
- South Korea
- Prior art keywords
- group
- formula
- fiber treatment
- fiber
- present
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 47
- 239000004744 fabric Substances 0.000 title description 12
- 239000000835 fiber Substances 0.000 claims abstract description 47
- 229910052751 metal Inorganic materials 0.000 claims abstract description 20
- 239000002184 metal Substances 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 14
- -1 metal complex compound Chemical class 0.000 claims abstract description 12
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 11
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- 235000011511 Diospyros Nutrition 0.000 claims description 8
- 239000000284 extract Substances 0.000 claims description 8
- 229940015043 glyoxal Drugs 0.000 claims description 8
- 150000003839 salts Chemical group 0.000 claims description 7
- 244000236655 Diospyros kaki Species 0.000 claims description 6
- 150000001805 chlorine compounds Chemical group 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical group COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 6
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 6
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 5
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 2
- 150000004696 coordination complex Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052737 gold Inorganic materials 0.000 claims description 2
- 229910052697 platinum Inorganic materials 0.000 claims description 2
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 20
- 239000000126 substance Substances 0.000 abstract description 17
- 230000001877 deodorizing effect Effects 0.000 abstract description 11
- 241000894006 Bacteria Species 0.000 abstract description 5
- 230000000845 anti-microbial effect Effects 0.000 abstract description 5
- 239000004753 textile Substances 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 238000012360 testing method Methods 0.000 description 32
- 235000019645 odor Nutrition 0.000 description 27
- 238000011156 evaluation Methods 0.000 description 13
- 238000005406 washing Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 230000000844 anti-bacterial effect Effects 0.000 description 10
- 238000004332 deodorization Methods 0.000 description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- 239000000654 additive Substances 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 7
- 239000003599 detergent Substances 0.000 description 6
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 6
- 229920000858 Cyclodextrin Polymers 0.000 description 5
- 239000002781 deodorant agent Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 244000005700 microbiome Species 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 102100037693 Fertilization-influencing membrane protein Human genes 0.000 description 4
- 101001027580 Homo sapiens Fertilization-influencing membrane protein Chemical group 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000001143 conditioned effect Effects 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 4
- 238000004043 dyeing Methods 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 230000009975 flexible effect Effects 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 230000000873 masking effect Effects 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 244000055850 Diospyros virginiana Species 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000004599 antimicrobial Substances 0.000 description 2
- 239000001045 blue dye Substances 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 150000002484 inorganic compounds Chemical class 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 150000008442 polyphenolic compounds Chemical class 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 235000018553 tannin Nutrition 0.000 description 2
- 229920001864 tannin Polymers 0.000 description 2
- 239000001648 tannin Substances 0.000 description 2
- 241000233866 Fungi Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- BGACXIOTGQQMAT-UHFFFAOYSA-N acetaldehyde sulfane Chemical compound S.C(C)=O BGACXIOTGQQMAT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- UBUYAZUEYAXMBU-UHFFFAOYSA-N azane;n,n-dimethylmethanamine Chemical compound N.CN(C)C UBUYAZUEYAXMBU-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 210000004556 brain Anatomy 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229920002770 condensed tannin Polymers 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 229940097362 cyclodextrins Drugs 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 231100000676 disease causative agent Toxicity 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 150000002214 flavonoid derivatives Chemical class 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 210000005036 nerve Anatomy 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 210000004415 olfactory epithelial cell Anatomy 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- MBMQEIFVQACCCH-QBODLPLBSA-N zearalenone Chemical compound O=C1O[C@@H](C)CCCC(=O)CCC\C=C\C2=CC(O)=CC(O)=C21 MBMQEIFVQACCCH-QBODLPLBSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
- D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S57/00—Textiles: spinning, twisting, and twining
- Y10S57/901—Antistatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
본 발명은 섬유처리제 조성물에 관한 것으로서, 본 발명에 따른 섬유처리제 조성물은 조성물 총 중량을 기준으로 양이온성 계면활성제 1 ~ 20 중량%; 및 금속성분이 산화티탄에 담지된 콜로이드상의 무기계 금속 착화합물 0.01 ~ 20 중량%;를 포함하는 것을 특징으로 한다. 본 발명에 따른 섬유처리제 조성물은 각종 냄새 원인물질과 세균 등을 근본적으로 제거함으로써 탁월한 소취 및 항균효과를 나타낼 뿐만 아니라, 유연효과, 흡수성, 정전기 방지성, 일광견뢰도 등도 우수하며, 인체나 섬유에 안전하다.The present invention relates to a fiber treatment composition, the fiber treatment composition according to the present invention is based on the total weight of the composition 1 to 20% by weight of the cationic surfactant; And 0.01 to 20% by weight of the colloidal inorganic metal complex compound in which the metal component is supported on titanium oxide. The fiber treatment agent composition according to the present invention exhibits excellent deodorizing and antimicrobial effects by fundamentally removing various odor causing substances and bacteria, and also has excellent softening effect, absorbency, antistatic property, and light fastness, and is safe for human body or fiber. Do.
섬유처리제*산화티탄*금속*착화합물*양이온성 계면활성제Textile Treatment Agents * Titanium Oxide * Metals * Complexes * Cationic Surfactants
Description
본 발명은 섬유처리제 조성물에 관한 것이다.The present invention relates to a fiber treatment composition.
예로부터 세탁물은 한 낮의 일광과 바람에 의해 건조되어 왔으며, 특히 직사광선에 의한 일광에 의해 건조와 함께 세탁물에 대한 살균이 이루어져 왔다.Since ancient times, laundry has been dried by daylight and wind, and in particular, by direct sunlight, drying and sterilization of laundry have been performed.
그러나, 최근들어 장마나 겨울 등 기후조건 뿐만 아니라 맞벌이의 증가 등 사회현상으로 인한 낮동안의 외출로 인해 야간 세탁이 늘어나고 있으며, 또한 꽃가루, 배기가스 등의 환경오염 물질에 의한 세탁물의 오염, 세탁물을 외부에 노출시키기를 꺼려하는 심리 등의 이유로 세탁물을 실내에서 건조시키는 경우가 늘고 있는 추세이다.Recently, however, nighttime washing is increasing due to daytime outings due to social phenomena such as rainy season or winter, as well as increase in double income, and also contaminates laundry and pollutants due to pollutants and pollutants. There is a growing trend to dry laundry indoors for reasons such as reluctance to expose it to the outside.
이러한 이유로 세탁물을 야간이나 실내에서 건조시키는 경우 불쾌취가 쉽게 발생하는 문제점이 있다. 다시 말하면, 오염이 심한 빨래나 묵은 빨래는 세제로 세탁을 한 이후에도 오염물이 완전히 제거되지 않아, 의류에서 불쾌한 냄새가 남아있는 경우가 많으며, 또한 이러한 잔존하는 오염물과 의류나 인체에 기생하는 미생물의 증식에 의해 불쾌취가 발생하게 되는 것이다.For this reason, when the laundry is dried at night or indoors, there is a problem in that an unpleasant odor easily occurs. In other words, contaminated laundry or old laundry may not be completely removed even after washing with detergent, and an unpleasant odor may remain in clothing, and the remaining contaminants and the growth of microorganisms parasitic in clothing or the human body It is caused by the discomfort.
종래에는 이러한 불쾌취에 대한 특별한 조치가 없어, 별도의 조치 없이 그대 로 의류를 착용하거나, 또는 다시 세탁을 하는 등의 소극적인 대처가 이루어졌다.In the prior art, there is no special measure against such an unpleasant feeling, and passive measures such as wearing clothing or washing again are performed without any further action.
한편, 우리의 일상생활에 있어서 불쾌취의 감지는 후각기관에 도달하는 몇 종류의 화학적, 물리적 반응의 결과로서, 휘발성 물질이 후각의 상피세포에 흡수되어 변화가 생기며 그로 인한 전위적 자극이 발생하면 신경을 통하여 뇌에 전달됨으로써 이러한 불쾌취를 감지하게 되는 것이다. 이러한 불쾌취를 제거하거나 방지하기 위해서 다양한 방법들이 사용되어 왔는데, 예를들면, 화학적 제거방법, 물리화학적 제거방법, 생물화학적 제거방법 및 감각적 탈취방법 등을 들 수 있다.On the other hand, the detection of malaise in our daily lives is the result of several chemical and physical reactions that reach the olfactory organs, where volatiles are absorbed by the olfactory epithelial cells, resulting in changes and potential dislocation stimuli. The nerves are transmitted to the brain to detect this discomfort. Various methods have been used to remove or prevent such unpleasant odors, for example, chemical removal, physicochemical removal, biochemical removal and sensory deodorization.
상기 여러가지 방법들 중에서도, 종래에는 방향성 향료에 의해 마스킹시키는 방법, 즉 감각적 탈취방법이 주로 사용되어 왔다. 그러나 이러한 마스킹에 의존하는 것은 악취가 발생한 이후에는 오히려 그 원인물질과 향료 간에 일어나는 교호작용으로 더 심한 악취를 유발한다는 단점이 있다. 즉, 세탁 후 마무리제로서 시중에 시판되고 있는 대부분의 제품은 세탁물의 대전방지 효과, 유연효과 등의 부여에는 탁월한 효능을 발휘하지만, 주로 향료를 이용한 감각적 탈취에 의존하고 있어 세탁 과정 중 혹은 세탁 후 건조시에 발생하는 불쾌감을 주는 취기의 제거에는 한계를 나타내고 있는 것이다.Among the various methods described above, a method of masking with aromatic fragrance, that is, a sensory deodorizing method has been mainly used. However, relying on such masking has a disadvantage in that after the occurrence of the odor, a more odor is caused by the interaction between the causative agent and the fragrance. In other words, most products on the market as finishing agents after washing show excellent efficacy in imparting antistatic effect and softening effect of laundry, but mainly rely on sensory deodorization using fragrances. The removal of the unpleasant odor generated at the time of drying is showing a limit.
최근에는 의류의 세탁 과정 중이나 건조 시기에 발생하는 악취를 제거하기 위한 기술이 활발히 전개되고 있다. 예를들면, 미국특허공보 제5,942,217호에는 환상다당류인 사이클로 덱스트린(Cyclo dextrine)과 사이클로 덱스트린 상용성 계면활성제 (Cyclo dextrine compatible surfactant), 저분자량 폴리올(Polyol), 금속염 등을 함유한 세제와 함께 사용하는 세탁 보조 기술이 개시되어 있다. 이에 의하면 사이클로 덱스트린이 세탁 과정 혹은 건조시에 남아 있는 오염원의 악취 물질을 포집하여, 악취를 제거하는 방법임을 기술하고 있다. 이러한 소취 기술은 섬유에 대한 손상이 거의 없고 암모니아나 아민류 화합물과 같은 염기성 취기와 휘산성 취기 물질에 대해서 우수한 소취 효과를 나타내는 장점이 있으나, 세탁과정중에 습윤된 섬유가 사이클로 덱스트린에 포집된 악취 물질과 수분의 교환 현상에 의해 포집되었던 악취 물질이 그대로 방출되어 취기가 다시 느껴질 수 있다는 단점이 있다. 또한, 글루코스로 구성된 사이클로 덱스트린은 항균제와 방부제를 적절히 사용하지 않으면 섬유상에 미생물이 발생하여 번식될 수 있고, 섬유 표면에 장기간 남아 있을 경우에도 곰팡이가 쉽게 증식하게 되어 냄새가 나거나 섬유를 변색시키게 되는 원인이 되어 좋지 않게 된다.Recently, techniques for removing odors generated during the washing process or drying time of clothing are actively developed. For example, U. S. Patent No. 5,942, 217 uses cyclodextrins, cyclodextrine compatible surfactants, low molecular weight polyols, metal salts, and the like, together with cyclic polysaccharides. Laundry assistance technology is disclosed. According to this, cyclodextrin is a method of collecting odorous substances from pollutants remaining during washing or drying to remove odors. This deodorization technique has almost no damage to the fiber and has an excellent deodorizing effect on basic odor and volatile odorous substances such as ammonia and amine compounds, but the wetted fibers during the washing process and the odorous substance trapped in the cyclodextrin There is a drawback that the odorous substance collected by the exchange of moisture is released as it is and odor is felt again. In addition, cyclodextrin composed of glucose may cause microorganisms to grow on the fiber if antimicrobial agents and preservatives are not used properly, and mold may easily proliferate even if left on the surface of the fiber for a long time, causing odor or discoloration of the fiber. This becomes bad.
또한, 최근 항균 성분을 함유한 섬유처리제 조성물에 대한 개발이 이루어지고 있으나, 이러한 기술들은 주로 미생물의 증식억제를 통해서 불쾌취를 제거하고자 한 것으로서 세탁물의 묵은 오염이나 먼지, 불순물에 의해 발생하는 불쾌취, 오염, 먼지, 불순물, 미생물의 혼합 오염에 의한 불쾌취에는 효과가 미미하다는 문제점이 있다.In addition, the development of a fiber treatment agent composition containing an antimicrobial component has recently been made, but these techniques are mainly intended to remove unpleasant odor by inhibiting the growth of microorganisms. There is a problem that the effect is insignificant due to the unpleasant odor caused by pollution, dirt, impurities, mixed microorganisms.
한편, 대한민국 공개특허공보 제2001-47432호에는 우수한 소취 물질을 사용하고 있으나, 세탁 과정이 아닌 세탁 과정 이외의 경우에 의류 및 섬유제품에 분무하여 사용하는 기술로써 분무 타입에 맞춘 섬유탈취제 조성물을 제공하고 있어, 세탁 과정 중에는 사용할 수 없다는 문제점을 가지고 있다.On the other hand, the Republic of Korea Patent Publication No. 2001-47432 uses excellent deodorant, but in the case of a non-washing process other than the washing process used to spray on clothing and textile products to provide a fiber deodorant composition according to the spray type It has a problem that it cannot be used during the washing process.
따라서, 본 발명이 이루고자 하는 기술적 과제는 상기와 같은 문제점을 해결하고자 안출한 것으로서, 각종 냄새 원인물질과 세균 등을 근본적으로 제거함으로써 탁월한 소취 및 항균효과를 나타낼 뿐만 아니라, 유연효과, 흡수성, 정전기 방지성, 일광견뢰도 등도 우수하며, 인체나 섬유에 안전한 섬유처리제 조성물을 제공하는데 있다. Therefore, the technical problem to be achieved by the present invention is to solve the problems as described above, by fundamentally removing various odor causing substances and bacteria, as well as excellent deodorant and antibacterial effect, softness, absorbency, antistatic It is also excellent in sex, light fastness, and the like to provide a fiber treatment agent composition that is safe for human body or fiber.
상기와 같은 기술적 과제를 달성하기 위해, 본 발명은 조성물 총 중량을 기준으로 양이온성 계면활성제 1 ~ 20중량%; 및 금속성분이 산화티탄에 담지된 콜로이드상의 무기계 금속 착화합물 0.01 ~ 20중량%;를 포함하는 것을 특징으로 하는 섬유처리제 조성물을 제공한다.In order to achieve the above technical problem, the present invention is 1 to 20% by weight based on the total weight of the composition; And 0.01 to 20% by weight of a colloidal inorganic metal complex compound in which a metal component is supported on titanium oxide. It provides a fiber treatment composition.
이하, 본 발명을 상세히 설명하도록 한다.Hereinafter, the present invention will be described in detail.
본 발명에 따른 섬유처리제 조성물에는 유연성분으로서 양이온성 계면활성제가 포함된다. 이러한 양이온성 계면활성제는 보편적으로 섬유처리제 조성물에 사용될 수 있는 것이면 특별히 한정되는 것은 아니며, 예를 들면 하기 화학식 1로 표시되는 4급 암모늄 화합물, 하기 화학식 2로 표시되는 이미다졸린형 4급염, 하기 화학식 3으로 표시되는 에스테르형 4급 암모늄 화합물 등이 1종이상 사용될 수 있다. 상기 양이온성 계면활성제는 본 발명의 섬유처리제 조성물 총량을 기준으로 1 ~ 20 중량% 정도 포함되는 것이 바람직한데, 상기 양이온성 계면활성제를 1 중량% 미만으로 사용하는 경우, 유연효과나 정전기 방지효과 등이 미약하고, 20 중량% 초과하여 사용하는 경우에는 비경제적이며 피부 안정성에 문제가 발생할 수 있기 때 문이다.The fiber treatment composition according to the present invention contains a cationic surfactant as a flexible component. Such cationic surfactants are not particularly limited as long as they can be generally used in the fiber treatment composition, for example, quaternary ammonium compounds represented by the following general formula (1), imidazoline type quaternary salts represented by the following general formula (2), At least one ester type quaternary ammonium compound represented by the formula (3) may be used. The cationic surfactant is preferably included in an amount of about 1 to 20% by weight based on the total amount of the fiber treatment agent composition of the present invention. When the cationic surfactant is used in less than 1% by weight, the softening effect or the antistatic effect, etc. This is weak and, if used in excess of 20% by weight, is uneconomical and may cause problems with skin stability.
상기 화학식 1에서, R1 및 R2는 서로 독립적으로 -CH3, -CH2 CH3, -CH2OH, 및 -CH2CH2OH로 이루어진 군으로부터 선택된 어느 하나이고, R3 및 R 4는 서로 독립적으로 라우릴, 미리스틸, 팔미틸, 올레일 및 스테아릴 등으로 이루어진 군으로부터 선택된 어느 하나이고, X는 클로라이드 또는 메틸설페이트이다.In Formula 1, R 1 and R 2 are each independently selected from the group consisting of -CH 3 , -CH 2 CH 3 , -CH 2 OH, and -CH 2 CH 2 OH, R 3 and R 4 Is independently selected from the group consisting of lauryl, myristyl, palmityl, oleyl and stearyl and the like, and X is chloride or methylsulfate.
상기 화학식 2에서, R5 및 R6은 서로 독립적으로 라우릴, 미리스틸, 팔미틸, 올레일 및 스테아릴 등으로 이루어진 군으로부터 선택된 어느 하나이고, X는 클로라이드 또는 메틸설페이트이다.In Formula 2, R 5 and R 6 are independently selected from the group consisting of lauryl, myristyl, palmityl, oleyl and stearyl, and the like, and X is chloride or methyl sulfate.
상기 화학식 3에서, R7 및 R8은 서로 독립적으로 -CH3, -CH2 CH3, -CH2OH, 및 -CH2CH2OH로 이루어진 군으로부터 선택된 어느 하나이고, R9 및 R 10은 서로 독립적으로 라우릴, 미리스틸, 팔미틸, 올레일 및 스테아릴 등으로 이루어진 군으로부터 선택된 어느 하나이고, X는 클로라이드 또는 메틸설페이트이다.In Formula 3, R 7 and R 8 are each independently selected from the group consisting of -CH 3 , -CH 2 CH 3 , -CH 2 OH, and -CH 2 CH 2 OH, and R 9 and R 10 Is independently selected from the group consisting of lauryl, myristyl, palmityl, oleyl, stearyl and the like, and X is chloride or methylsulfate.
본 발명에 따른 섬유처리제 조성물에는 상기와 같은 양이온성 계면활성제가 유연성분으로서 포함되어 있어 세탁세제와는 별도로 마지막 헹굼시에 투입하여 사용하는 것이 바람직하다. 이것은 양이온성 계면활성제가 세탁세제 중의 음이온 계면활성제와 이온결합에 의해 검화되거나 거대 소수성 분자의 형태가 되어 물에 용해되기가 어려워짐으로 인해 세정력이 저하될 뿐만 아니라 의류에 흡착되는 양이온 계면활성제의 양이 줄어들어 유연효과도 현저하게 저하되기 때문이다. 이와 같은 문제점은 상기 양이온성 계면활성제를 수용성 고분자로 코팅시켜 세탁세제 내의 음이온 계면활성제와의 결합을 방지함으로써 해결할 수 있는데, 이러한 경우에는 본 발명에 따른 섬유처리제 조성물을 세제성분과 동시에 사용하는 것도 가능해질 수 있다.The fiber treatment composition according to the present invention includes the above cationic surfactant as a flexible component, and it is preferable to be used after the last rinse separately from the laundry detergent. This is because the amount of cationic surfactant adsorbed on the garment is not only deteriorated as the cationic surfactant becomes saponified by the ionic bond with the anionic surfactant in the laundry detergent or becomes a large hydrophobic molecule, which makes it difficult to dissolve in water. This is because the softening effect is also significantly reduced. This problem can be solved by coating the cationic surfactant with a water-soluble polymer to prevent binding to the anionic surfactant in the laundry detergent. In this case, the fiber treatment composition according to the present invention can also be used simultaneously with the detergent component. Can be done.
한편, 본 발명에 따른 섬유처리제 조성물에 함유되는 무기계 금속 착화합물은 금속성분이 산화티탄에 담지된 콜로이드상의 착화합물이다. 이러한 상기 무기계 금속 착화합물은 산화티탄과 금속성분의 작용으로 소취, 살균, 항균 효과 등을 나타낸다. 또한, 상기 무기계 금속 착화합물은 전술한 효과를 최적화 하기 위하여 평균 입자크기가 1 ~ 10㎚ 정도의 콜로이드상인 것이 바람직하다.On the other hand, the inorganic metal complex compound contained in the fiber treatment composition according to the present invention is a colloidal complex compound in which a metal component is supported on titanium oxide. Such inorganic metal complexes exhibit deodorization, sterilization, antibacterial effects and the like by the action of titanium oxide and metal components. In addition, the inorganic metal complex compound is preferably a colloidal phase having an average particle size of about 1 ~ 10nm in order to optimize the above-described effect.
본 발명에 따른 섬유처리제 조성물에는 상기 무기계 금속 착화합물이 조성물 총 중량을 기준으로 0.01 내지 20 중량% 함유되는 것이 바람직하다. 상기 함량이 0.01 중량% 미만인 경우에는 소취 및 항균효과가 미미하며, 20 중량% 초과인 경우에는 함량 증가에 따른 상승 효과가 거의 비슷하기 때문이다.In the fiber treatment agent composition according to the present invention, the inorganic metal complex compound is preferably contained in an amount of 0.01 to 20% by weight based on the total weight of the composition. If the content is less than 0.01% by weight, the deodorizing and antibacterial effects are insignificant, and if it is more than 20% by weight, the synergistic effect of increasing the content is almost the same.
상기 산화티탄은 잘 알려진 광촉매로서, 자외선과 같은 빛에 의해 강한 환원력과 산화력을 나타내며, 특히 유기오염물질 등의 분해력, 소취력, 살균력 및 항균력 등이 우수하다. 또한, 화장품의 원료로 쓰이기도 하는 등 인체에 무해하고 안전한 특성이 있다. 상기 산화티탄은 광촉매이기 때문에, 반응 전후에 있어서 자신은 변화하기 않으므로 장기간 효과가 지속되는 특징이 있다.The titanium oxide is a well-known photocatalyst, and exhibits strong reducing power and oxidizing power by light such as ultraviolet rays, and is particularly excellent in degrading power, deodorizing power, bactericidal power, and antibacterial activity of organic pollutants. In addition, it is also used as a raw material of cosmetics, and is harmless to the human body and has a safe characteristic. Since the titanium oxide is a photocatalyst, it does not change itself before and after the reaction, so the effect is long-lasting.
또한, 상기 산화티탄에 담지되어 있는 상기 금속성분은 소취효과나 항균효과가 우수한 것으로서 상기 산화티탄과 함께 본 발명의 목적범위 내에서 전술한 무기계 금속 착화합물의 효능을 나타낼 수 있는 것이면 어떠한 금속성분이어도 상관 없으며, 이러한 한도 내에서는 그 금속성분의 화합물 형태에도 특별한 제한은 없다. 이러한 금속성분의 예로서는 구리(Cu), 아연(Zn), 은(Ag), 금(Au), 백금(Pt) 등의 금속 또는 그 금속염이 1종 이상 사용될 수 있으며, 이에 한정되는 것은 아니다.Further, the metal component supported on the titanium oxide may be any metal component as long as it exhibits an excellent deodorizing effect or an antibacterial effect and can exhibit the effects of the above-described inorganic metal complex compound within the object of the present invention together with the titanium oxide. There is no particular limitation to the form of the compound of the metal component within such limits. Examples of the metal component may include one or more metals such as copper (Cu), zinc (Zn), silver (Ag), gold (Au), platinum (Pt), or metal salts thereof, but is not limited thereto.
이러한 무기계 금속 착화합물은 종래 주류였던 물리화학적 흡착이나 향 마스킹과는 달리, 광촉매 반응에 의한 분해작용에 의해 각종 냄새물질이나 세균, 곰팡이 등을 근원적으로 제거함으로써 소취, 살균하는 것이며, 온도상승이나 자외선 조사에 의해 여기되어 분해, 반응속도가 증가하는 특징을 가지고 있다. 또한, 종래의 흡착에 의한 탈취방법과는 달리 포화나 열화현상이 없으며, 장기적으로 효과가 지속될 수 있는 장점도 가지고 있다. 본 발명에 있어서 상기 무기계 금속 착화합물은 황화수소나 메틸머캅탄과 같은 황화 화합물은 물론, 염기성 취기인 암모니아나 트리메틸아민류 등과, 휘산성 취기인 아세트 알데히드류 등의 원인 물질에도 우수한 소취효과를 나타낸다.Unlike the physicochemical adsorption or fragrance masking, which is a mainstream type of conventional inorganic metal complex compound, it is deodorized and sterilized by fundamentally removing various odorous substances, bacteria, molds, etc. by decomposition by photocatalytic reaction. It is excited by the decomposition and has the characteristic of increasing the decomposition rate and reaction rate. In addition, unlike conventional deodorization method by adsorption, there is no saturation or deterioration phenomenon, and has the advantage that the effect can be maintained in the long term. In the present invention, the inorganic metal complex compound exhibits excellent deodorizing effect not only to sulfide compounds such as hydrogen sulfide and methyl mercaptan, but also to causative substances such as ammonia and trimethylamine, which are basic odors, and acetaldehyde, which is volatile odors.
본 발명에 따른 섬유처리제 조성물에는 소취효과와 항균효과를 더욱 향상시키기 위하여 이러한 효능을 갖는 성분이 더 포함될 수 있다. 예를 들면, 감잎추출물과 글리옥살이 각각 단독으로 혹은 이들을 병용한 혼합물의 형태로 더 포함될 수 있다. 상기 감잎추출물이나 글리옥살은 세탁 후 건조과정에서 상기 무기계 금속 착화합물이 의류 및 섬유에 남아있는 냄새 물질을 초기에 분해하고, 감잎추출물의 주성분인 폴리 페놀류나 탄닌류 화합물과 글리옥살 화합물이 각종 냄새 물질과 화학적으로 부가 또는 축합반응을 하여 비휘발성 물질로 변화시킴으로써 냄새를 억제할 수 있다.The fiber treatment agent composition according to the present invention may further include a component having such an effect in order to further improve the deodorizing effect and the antibacterial effect. For example, persimmon leaf extract and glyoxal may be further included alone or in the form of a mixture thereof. The persimmon leaf extract or glyoxal decomposes the odorous substances remaining in the clothes and fibers in the inorganic metal complex in the drying process after washing, and polyphenols, tannins and glyoxal compounds, which are the main components of the persimmon leaf extract, are various odorous substances. The odor can be suppressed by chemically adding or condensation with a non-volatile substance.
상기 감잎추출물은 후라보노이드 유도체인 탄닌성분과 폴리페놀류, 축합형 탄닌, 유기 고분자류 등의 복합작용에 의해 세탁후 의류에 남아있는 오염 및 암모니아, 트리메틸아민, 황화수소, 메틸머캅탄 등의 냄새 원인물질을 중화 및 부가, 치환, 환원 등의 화학적 탈취작용과 물리적인 포접이나 흡착, 흡수 작용 등으로 효과적으로 제거한다. 상기 감잎추출물은 천연 식물 추출물로서, 조성물 내에서의 효능을 고려하여 본 발명의 섬유처리제 조성물 총 중량을 기준으로 0.1 내지 10 중량% 정도 함유됨이 바람직하다.The persimmon leaf extract is responsible for the contamination of odor-causing substances such as ammonia, trimethylamine, hydrogen sulfide and methyl mercaptan after washing by the complex action of the tannin component, which is a flavonoid derivative, with polyphenols, condensed tannins and organic polymers. It is effectively removed by chemical deodorization such as neutralization and addition, substitution and reduction, and physical inclusion, adsorption and absorption. The persimmon leaf extract is a natural plant extract, in consideration of efficacy in the composition is preferably contained about 0.1 to 10% by weight based on the total weight of the fiber treatment agent composition of the present invention.
또한, 상기 글리옥살은 염기성 및 휘산성의 냄새물질을 제거하고, 특히 세균 및 곰팡이의 억제작용으로 우수한 항균효과를 가지는데, 이는 글리옥살의 말단에 반응성이 큰 알데히드기에 의해 각종 냄새성분이 중화, 부가, 축합 등의 화학적 반응으로 소취작용을 함으로써 냄새물질을 제거해 주는 것이다. 상기 글리옥살은 본 발명의 조성물 내에서의 효능을 고려하여 본 발명의 섬유처리제 조성물 총 중량을 기준으로 0.1 내지 10 중량% 정도 함유됨이 바람직하다.In addition, the glyoxal removes basic and volatilizing odorous substances, and has an excellent antibacterial effect, in particular, by inhibiting bacteria and fungi, which neutralizes and adds various odor components by an aldehyde group that is highly reactive at the terminal of glyoxal. Deodorant is removed by chemical reactions such as condensation and condensation. The glyoxal is preferably contained in an amount of about 0.1 to 10% by weight based on the total weight of the fiber treatment composition of the present invention in consideration of the efficacy in the composition of the present invention.
본 발명에 따른 섬유처리제 조성물에는 분산안정제가 더 포함될 수 있는데, 이러한 분산안정제는 섬유처리제 조성물에 통상적으로 사용될 수 있는 유기 또는 무기 화합물로서 특별한 제한은 없다. 예를들면, 유기 화합물로서는 탄소수 8 미만의 저급알콜 또는 글리콜류, 탄소수 11 이상의 고급알콜류 , 요소 등이 있고, 무기화합물로서는 염화마그네슘, 염화나트륨, 염화칼슘, 질산나트륨 등이 있는데, 이들은 단독 또는 2종이상의 혼합물로 포함될 수 있다. 바람직하게는, 에탄올, 이소프로필알콜, 에틸렌글리콜, 프로필렌글리콜, 헥실렌글리콜, 세틸알콜, 스테아릴알콜, 염화마그네슘, 염화나트륨, 염화칼슘, 질산나트륨 등을 단독으로 또는 2종이상 혼합하여 본 발명에 따른 섬유처리제 조성물에 포함될 수 있다.The fiber treating agent composition according to the present invention may further include a dispersion stabilizer, which is not particularly limited as an organic or inorganic compound that can be commonly used in the fiber treatment composition. Examples of the organic compound include lower alcohols or glycols having less than 8 carbon atoms, higher alcohols having 11 or more carbon atoms, urea, and the like, and inorganic compounds include magnesium chloride, sodium chloride, calcium chloride, sodium nitrate, and the like. It can be included as a mixture. Preferably, ethanol, isopropyl alcohol, ethylene glycol, propylene glycol, hexylene glycol, cetyl alcohol, stearyl alcohol, magnesium chloride, sodium chloride, calcium chloride, sodium nitrate or the like alone or in combination of two or more according to the present invention It may be included in the fiber treatment composition.
또한, 본 발명에 따른 섬유처리제 조성물에는 본 발명의 목적범위 내에서 소 량의 첨가제가 더 포함될 수 있다. 예를 들면, 소취후에 섬유에 기분좋은 향취를 부여하기 위하여 신선하고 은은한 향료가 더 첨가될 수 있으며, 이외에도 색소, 방부제, 산화방지제, 소포제 등이 더 포함될 수 있다.In addition, the fiber treatment agent composition according to the present invention may further include a small amount of additives within the scope of the present invention. For example, fresh and subtle fragrances may be added to give the fiber a pleasant odor after deodorization, and may further include pigments, preservatives, antioxidants, antifoaming agents, and the like.
한편, 본 발명에 따른 섬유처리제 조성물은 각종 면 등의 천연섬유류나 폴리에스테르와 같은 합성섬유에 대하여 일광에 노출되어도 섬유의 형태나 색상의 변색 및 퇴색, 염착등의 섬유 손상을 주지 않으므로 안전하게 의류나 섬유류에 사용할 수 있다.On the other hand, the fiber treatment agent composition according to the present invention does not damage the fibers such as discoloration, fading, dyeing of the form or color of the fiber even when exposed to sunlight to natural fibers such as various cotton or synthetic fibers such as polyester, It can be used for fibers.
이하, 본 발명을 구체적으로 설명하기 위해 실시예를 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상술하는 실시예들에 한정되는 것으로 해석되어져서는 안된다. 본 발명의 실시예들은 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되어지는 것이다.Hereinafter, the present invention will be described in detail with reference to Examples. However, embodiments according to the present invention can be modified in many different forms, the scope of the present invention should not be construed as limited to the embodiments described below. Embodiments of the present invention are provided to more completely explain the present invention to those skilled in the art.
실시예Example
본 실시예에서는 일본 촉매화성 공업사에서 제조한 것으로서, 구리가 산화티탄에 담지되고 평균 입자크기가 5㎚인 콜로이드상의 금속 착화합물을 사용하였다. 또한, 양이온성 계면활성제는 디메틸 디스테아릴 암모늄 클로라이드, 이미다졸린형 4급염로서 (주)오성화학에서 제조한 FIMP, 에스테르형 4급 암모늄 화합물로서 (주)오성화학에서 제조한 HISOFTER EQ-85 중 어느 하나를 사용하였다. 이러한 금속 착화합물과 양이온성 계면활성제를 사용하여 하기 표 1에 나타난 성분과 함량으로 섬 유처리제 조성물을 제조하였다. 또한, 하기 표 1에서 기타 첨가제는 향료, 색소, 방부제, 산화방지제, 소포제 등의 소량 첨가제를 표시한 것이다. 각 단위는 중량%를 나타낸다.In this example, a colloidal metal complex compound manufactured by Nippon Catalytic Industries, Inc., in which copper was supported on titanium oxide and having an average particle size of 5 nm was used. In addition, cationic surfactants are dimethyl distearyl ammonium chloride, imidazoline type quaternary salt, FIMP manufactured by Ohsung Chemical Co., Ltd. and HISOFTER EQ-85 manufactured by Ohsung Chemical Co., Ltd. as quaternary ammonium compound. Either of them was used. Using these metal complexes and cationic surfactants, a fiber treating agent composition was prepared using the ingredients and contents shown in Table 1 below. In addition, the other additives in the following Table 1 is a small amount of additives such as fragrances, pigments, preservatives, antioxidants, antifoaming agents. Each unit represents weight percent.
비교예Comparative example
하기 표 2에 나타난 성분과 함량으로 섬유처리제 조성물을 제조하였다. 양이온성 계면활성제는 디메틸 디스테아릴 암모늄 클로라이드(dimethyl distearyl ammonium chloride), 이미다졸린형 4급염으로서 (주)오성화학에서 제조한 FIMP, 에스테르형 4급 암모늄 화합물로서 (주)오성화학에서 제조한 HISOFTER EQ-85중 어느 하나를 사용하였다. 또한, 하기 표 2에서 기타 첨가제는 향료, 색소, 방부제, 산화방지제, 소포제 등의 소량 첨가제를 표시한 것이다. 각 단위는 중량%를 나타낸다. To the fiber composition was prepared in the ingredients and contents shown in Table 2. Cationic surfactants are dimethyl distearyl ammonium chloride, imidazoline type quaternary salts, FIMP manufactured by Ohsung Chemical Co., Ltd. and quaternary ammonium compounds produced by Ohsung Chemical Co., Ltd. One of the HISOFTER EQ-85s was used. In addition, the other additives in Table 2 shows a small amount of additives, such as perfumes, pigments, preservatives, antioxidants, antifoaming agents. Each unit represents weight percent.
전술한 실시예와 비교예에 따라 제조된 조성물에 대하여 다음과 같은 시험을 행하였다.The following test was done about the composition manufactured according to the above-mentioned Example and a comparative example.
시험예 1: 소취효과 시험(기기 평가)Test Example 1: Deodorization effect test (equipment evaluation)
일상생활에서 쉽게 접할 수 있는 불쾌취인 염기성 취기, 휘산성 취기, 산성 취기등에 대해 각 조성물로서 검지관법에 의한 소취 효과를 3회 이상 반복하여 평가하였다. 염기성 취기로는 대표적인 암모니아, 트리메틸아민, 휘산성 취기로는 아세트 알데히드, 산성취기로는 메틸 머캅탄 등에 대해 실험을 실시하였다. 본 실험에 사용된 검지관은 GASTEC 사제, no.71, 92, 180으로써 각각 메틸머캅탄, 아세트 알데히드, 아민류용의 지정 검지관을 사용하였다. Deodorizing effect by the detection tube method was repeatedly evaluated three times or more for each of the compositions for the basic odor, volatilized odor, and acid odor which are easily encountered in daily life. Representative ammonia, trimethylamine as the basic odor group, acetaldehyde as the volatile odor group, and methyl mercaptan as the acidic odor group were tested. The detection tubes used in this experiment were Nos. 71, 92, and 180 manufactured by GASTEC Corporation, and designated detection tubes for methylmercaptan, acetaldehyde, and amines were used, respectively.
시험예 2: 잔향 평가 시험 (소취 관능 평가)Test Example 2: Reverberation evaluation test (deodorant sensory evaluation)
시판 100%의 면타올을 일반 세탁세제를 표준사용량 사용하고 세탁기로 5회 반복세탁한 후 탈수한 것을 표 1 및 2의 본 발명의 조성물을 표준사용량( 6.7㎖/10ℓ세탁수)을 기준으로 용해한 각각의 헹굼물(욕비 1:30, 25℃)에 유연 처리한 다음 탈수하여 20℃, 65% RH조건에서 24시간 conditioning시킨 다음 숙련된 panelist의 관능 평가 시험에 의하여 향의 강도정도를 점수로써 최저 1점에서 5점까지 부여하게 하고 이것을 3회 이상 반복하여 그 평균값으로써 잔향 효과를 측정하였다. 잔향 평가 기준은 실시예 및 비교예의 제품에 대한 잔향 효과를 잔향 강도에 따른 점수로써 부여하고 하기 표 3과 같이 판정하였다.Commercially used 100% cotton towels were used as a standard laundry detergent and repeatedly washed five times with a washing machine, followed by dehydration. The compositions of the present invention shown in Tables 1 and 2 were dissolved based on the standard usage amount (6.7ml / 10L wash water). After rinsing in each rinse water (bath ratio 1:30, 25 ℃), dehydrated and conditioned for 24 hours at 20 ℃, 65% RH conditions by the panelist's sensory evaluation test of the intensity of the fragrance as a minimum 1 The point was given up to 5 points, and this was repeated three more times, and the reverberation effect was measured as the average value. Reverberation evaluation criteria were given as a score according to the reverberation intensity to the reverberation effect on the product of the Examples and Comparative Examples and was determined as shown in Table 3.
시험예 3 : 일광 견뢰도 시험Test Example 3 Daylight Fastness Test
섬유제품에 대한 안정성 실험을 위하여 '직물의 일광견뢰도 시험 방법(KS K 0700법)'에 따라 변퇴색 및 의류의 염착 현상 등의 손상 여부를 확인하였다. Zenone Arc Light에 50℃ 에서 7 시간 노출시킨 후 손상 여부를 확인하였다.In order to test the stability of textile products, the fabrics were checked for damages such as discoloration and dyeing of clothing according to the 'Daylight Fastness Test Method of Fabrics (KS K 0700 Method)'. After exposing it to Zenone Arc Light for 7 hours at 50 ° C, it was checked for damage.
시험예 4 : 항균력 시험Test Example 4: Antimicrobial Activity Test
KS 0693 - 1990 시험법에 의거 Staphylococcus aureus를 균주로 하여 106 마리를 면, PET에 대해 접종하고 이에 대한 직물의 항균도를 측정하였다. 항균 효과는 하기 표 4와 같이 판정하였다.According to the KS 0693-1990 test method, 10 6 animals were inoculated against cotton, PET with Staphylococcus aureus as a strain, and the antimicrobial activity of the fabric was measured. Antimicrobial effect was determined as Table 4 below.
시험예 5 : 유연 효과 시험Test Example 5 Flexible Effect Test
시판 100%의 면타올을 상기 시험예 2의 방법과 동일하게 유연 처리한 다음 탈수하여 20℃, 65% RH조건에서 24시간 conditioning시킨 다음 숙련된 panelist의 관능 평가 시험에 의하여 촉감정도를 유연 점수로써 최저 1점에서 5점까지 부여하게 하고 이것을 3회 이상 반복하여 그 평균값으로써 유연 효과를 측정하였다. 유연성 평가 기준은 비교예의 제품에 대한 유연 효과를 유연 점수로 부여하고 하기 표 5와 같이 판정하였다.Commercially available 100% cotton towels were flexibly treated in the same manner as in Test Example 2, dehydrated, and conditioned for 24 hours at 20 ° C. and 65% RH. A minimum of 1 point was given to 5 points, and this was repeated three or more times, and the softening effect was measured as the average value. Flexibility evaluation criteria gave a softening effect on the product of the comparative example by the softness score and determined as shown in Table 5.
시험예 6 : 흡수성 시험Test Example 6 Absorbency Test
표준 면포를 위사, 경사로 구분하여 2×15cm 크기로 절단한 후, 상기 시험예 2의 방법과 동일하게 유연 처리하고 20℃, 65% RH조건에서 24시간 conditioning시킨 다음 시료포를 클램프와 추를 이용하여 수직으로 매달아 놓은 다음 수용성의 청색 염료를 0.1%로 희석시킨 수용액 중에 시험포의 말단을 동시에 담구어 청색 염료의 상승 높이를 20분 후에 측정하고 이것을 3회 이상 반복하여 그 평균값으로 흡수 효과를 시험하였다. 흡수성은 하기 표 6과 같이 판정하였다.After cutting the standard cotton cloth into 2 × 15cm size by dividing the weft and inclined, it was flexibly treated in the same manner as in Test Example 2, and then conditioned at 20 ° C. and 65% RH for 24 hours. Suspended vertically, and then immersed the ends of the test cloth in an aqueous solution of 0.1% diluted water-soluble blue dye, and the rising height of the blue dye was measured after 20 minutes, and repeated three or more times to test the absorption effect at the average value. . Absorbency was determined as Table 6 below.
시험예 7 : 정전기 방지성 시험(마찰 대전압)Test Example 7: Antistatic test (friction large voltage)
KS K-0950의 염색 견뢰도 시험용 백 면포, 백 폴리에스테르포, 나일론포(한국의류시험연구원 제작)를 각각 4×6cm의 크기로 절단하고, 상기 시험예 2의 방법과 동일하게 유연 처리하고 20℃, 65% RH조건에서 24시간 conditioning시킨 다음 시료포를 일본 DAIEI KAGAKU사 제품인 Rotary Static Tester 기기를 이용하여 KS K-0555B 시험방법으로 60초 동안 600RPM으로 회전 마찰시켜 발생된 대전압을 측정하고 3회 이상 반복 실험하여 정전기 방지성을 측정하였다. 정전기 방지성을 하기 표 7과 같이 판정하였다.KS K-0950 dyeing fastness test white cotton cloth, white polyester cloth, nylon cloth (manufactured by Korea Apparel Testing & Research Institute) were cut into 4 × 6 cm size, and the same as the method of Test Example 2, the flexible treatment and 20 ℃ , After conditioning for 24 hours at 65% RH conditions, measure the large voltage generated by rotating friction at 600 RPM for 60 seconds using KS K-0555B test method using Rotary Static Tester device manufactured by DAIEI KAGAKU of Japan. Repeated experiments were carried out to measure the antistatic properties. Antistatic properties were determined as shown in Table 7 below.
시험예 8 : 정전기 방지성 시험(반감기)Test Example 8: Antistatic Test (Half Life)
KS K-0950의 염색 견뢰도 시험용 백 면포, 백 폴리에스테르포, 나일론포(한국의류시험연구원 제작)를 각각 4×6cm의 크기로 절단하고, 상기 시험예 2의 방법과 동일하게 유연 처리한 다음 20℃, 65% RH조건에서 24시간 conditioning시킨 것을 KS K-0555A 시험방법을 응용하여, 스위스 Rothschild사 제품인 Static Voltmeter 기기를 이용하여 초기 전압 150V를 인가한 후 전압이 반으로 떨어지는 시간으로써 정전압 누설속도를 측정하고, 3회 이상 반복하여 평가하였다. 평가결과는 하기 표 8과 같이 판정하였다.KS K-0950 dyeing fastness test white cotton cloth, white polyester cloth, nylon cloth (manufactured by Korea Apparel Testing & Research Institute) were cut into sizes of 4 × 6 cm, respectively, and flexibly treated in the same manner as in Test Example 2, and then 20 By applying the KS K-0555A test method, which was conditioned for 24 hours at 65% RH, the voltage leakage rate was reduced by applying the initial voltage of 150V using the Static Voltmeter device manufactured by Rothschild, Switzerland. It measured and evaluated repeatedly three or more times. Evaluation results were determined as shown in Table 8.
상기 각각의 시험예에 대한 결과를 하기 표 9와 10에 나타내었다.The results for each test example are shown in Tables 9 and 10 below.
상기 표 9 내지 10에서 살펴본 바와 같이, 본 발명의 섬유처리제 조성물인 실시예 1 내지 4는 비교예 1 내지 4의 조성물보다 소취효과와 항균효과가 탁월함은 물론, 유연효과, 흡수성, 정전기 방지성, 일광견뢰도 등이 우수한 결과를 나타내었다.As described in Tables 9 to 10, Examples 1 to 4, which are the fiber treatment agent compositions of the present invention, are superior to the compositions of Comparative Examples 1 to 4, and have excellent deodorizing and antibacterial effects, as well as softness, absorbency, and antistatic properties. The light fastness and the like showed excellent results.
이상에서 살펴본 바와 같이, 본 발명에 따른 섬유처리제 조성물은 각종 냄새 원인물질과 세균 등을 근본적으로 제거함으로써 탁월한 소취 및 항균효과를 나타낼 뿐만 아니라, 유연효과, 흡수성, 정전기 방지성, 일광견뢰도 등도 우수하며, 인체나 섬유에 안전하다. 따라서 본 발명에 따른 섬유처리제 조성물은 가정용 또는 산업용 섬유처리제 등에 널리 이용될 수 있다.As described above, the fiber treatment agent composition according to the present invention exhibits excellent deodorizing and antibacterial effects by fundamentally removing various odor causing substances and bacteria, and also has excellent softening effect, absorbency, antistatic property, and light fastness. It is safe to human body and fiber. Therefore, the fiber treatment agent composition according to the present invention can be widely used for household or industrial fiber treatment agent.
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