KR100834481B1 - Fiber treatment composition - Google Patents

Abstract

The present invention relates to a fiber treatment composition, and more particularly, to (a) a polysiloxane compound of cationic hydroxyalkyl ammonium salt of formula (1); And (b) relates to a fiber treatment composition comprising a 1,4-cyclohexanediol compound of formula (2) or (3).

[Formula 1]

Wherein R ¹ and R ² are each independently a hydroxy alkyl group or alkenyl group having 8 to 22 carbon atoms, A is an alkyl group or alkanol group having 1 to 4 carbon atoms, and Z is a divalent anion having 1 to 4 carbon atoms. Alkyl carboxyl group, n represents an integer of 10 to 2,000.)

[Formula 2]

[Formula 3]

(In Formulas 2 and 3, X is hydrogen or an alkyl group having 1 to 3 carbon atoms, and Y represents an OH group.)

The fiber treatment composition of the present invention is excellent in flexibility, antistatic, anti-wrinkling, ironing, deodorizing power and drying property.

Fibers, Treatments, Spray Compositions

Description

Fiber Treatment Composition {FIBER TREATMENT COMPOSITION}

[Industrial use]

The present invention relates to a fiber treatment composition, and more particularly to a fiber treatment composition excellent in flexibility, antistatic, anti-wrinkle, ironing, deodorizing power and drying.

[Prior art]

Various garments or duvets made of natural or chemical fibers may cause wrinkles when used for a long period of time, thereby degrading aesthetics and releasing bad odors. These various odors also act as a cause to increase the stress of modern people by stimulating the nose olfactory nerves. These odors get worse as the fibers are more likely to come into contact with moisture, such as during the rainy season.

Examples of the causes of wrinkles and odors generated in various fibers include hydrogen bonds formed on the fibers. Therefore, in recent years, research and development are being actively conducted to remove hydrogen bonds formed on fibers or to prevent hydrogen bonds from being formed on fibers to remove wrinkles and odors emitted from fibers.                         

U. S. Patent No. 6,001, 343 and U. S. Patent No. 5,798, 197 describe a detergent composition comprising a polyalkyl or polyhydroxy alkylaminesiloxane compound that inhibits wrinkling of the fibers and removes odors of the fibers. However, this detergent composition has a poor wrinkle prevention and wrinkle removal effect, can not soften the feel of the fiber, and also has a weak antistatic effect. have.

U.S. Pat.Nos. 5,534,165, 5,593,670, 5,668,097, 5,714,137, and 5,882,638 also include inorganic metal complexes, such as zinc, that chemically decompose odorous substances during masking incense, and cycle during drying. A odor deodorization method is described in which a deodorant compound is decomposed to collect odor substances to remove odors.

The odor deodorizing method can not effectively deodorize acidic irritating odors such as hydrogen sulfide and methyl mercaptone generated during various food odors such as kimchi, tobacco odor and food decay, and if the fiber is wet by moisture again after drying There is a problem that the odorous substances collected by the substitution action of the odorous substances and water trapped in the dextrin compound are released again as it is not completely removed.

In addition, if the antimicrobial agent and the preservative are not properly used together with the cyclodextrin compound composed of glucose, microorganisms may develop and multiply on the fiber, and mold may easily proliferate even if left on the surface of the fiber for a bad smell or discolor the fiber. There is this. In addition, the garment treated by the deodorizing method has a problem that the feeling is not good and flexible when worn.

The present invention has been made to solve the above problems, an object of the present invention is to provide a fiber treatment composition excellent in flexibility, antistatic, anti-wrinkling, ironing, deodorizing power and drying.

In order to achieve the above object, the present invention (a) a polysiloxane compound of the cationic hydroxyalkyl ammonium salt of formula (1); And (b) provides a fiber treatment composition comprising a 1,4-cyclohexanediol compound of formula (2).

[Formula 1]

Wherein R ¹ and R ² are each independently a hydroxy alkyl group or alkenyl group having 8 to 22 carbon atoms, A is an alkyl group or alkanol group having 1 to 4 carbon atoms, and Z is a divalent anion having 1 to 4 carbon atoms. Alkyl carboxyl group, n represents an integer of 10 to 2,000.)

[Formula 2]

[Formula 3]

(In Formulas 2 and 3, X is hydrogen or an alkyl group having 1 to 3 carbon atoms, and Y represents an OH group.)

Hereinafter, the present invention will be described in more detail.

The fiber treatment composition of the present invention comprises, as an essential component, a polysiloxane compound of a cationic hydroxyalkyl ammonium salt of formula (1) and a 1,4-cyclohexanediol compound of formula (2).

[Formula 1]

Wherein R ¹ and R ² is each independently a hydroxy alkyl group or alkenyl group having 8 to 22 carbon atoms, A is an alkyl group or alkanol group having 1 to 4 carbon atoms, Z is an alkylcarboxyl group having 1 to 4 carbon atoms as a divalent anion, and n is 10 To an integer of 2,000.)

[Formula 2]

[Formula 3]

(In Formulas 2 and 3, X is hydrogen or an alkyl group having 1 to 3 carbon atoms, and Y represents an OH group.)

The polysiloxane compound of the cationic hydroxyalkyl ammonium salt of Chemical Formula 1 included in the fiber treatment composition of the present invention has an average molecular weight of 2,000 to 100,000, and has a function of improving the flexibility of the fiber with anti-wrinkle function and preventing static electricity. do.

Preferred examples of the polysiloxane compound of the cationic hydroxyalkyl ammonium salt of the formula (1) include hydroxybutyl ammonium salt polysiloxane and the like.

The content of the polysiloxane compound of the cationic hydroxyalkyl ammonium salt of the formula (1) is preferably 0.01 to 15% by weight, more preferably 0.1 to 8% by weight based on the fiber treatment composition.

When the content of the polysiloxane compound of the cationic hydroxyalkyl ammonium salt of the general formula (1) is less than 0.01% by weight with respect to the fiber treatment composition, the effect of preventing the wrinkle of the fiber is insignificant, and when the content exceeds 15% by weight, the strength of the fiber is decreased. It is not preferable because there is a problem that the fiber is damaged due to dyeing accumulated in the fiber when repeated use.

In addition, the 1,4-cyclohexanediol compound of Formula 2 or 3 included as an essential component in the fiber treatment composition of the present invention serves to prevent the wrinkle of the fiber and to soften the feel of the fiber. This is because the 1,4-cyclohexanediol compound of Formula 2 or 3 is excellent in permeability and spreadability in the fiber.

Preferable examples of the 1,4-cyclohexanediol compound represented by Formula 2 or 3 include diiso cyclohexanediol and the like.

As such, when the 1,4-cyclohexanediol compound of Formula 2 or 3 is mixed with the polysiloxane compound of the cationic hydroxyalkyl ammonium salt of Formula 1, only the polysiloxane compound of the cationic hydroxyalkyl ammonium salt of Formula 1 Compared with the case of use, it can exhibit an excellent anti-wrinkle effect.

The content of the 1,4-cyclohexanediol compound of Formula 2 or 3 is preferably 0.01 to 10% by weight, more preferably 0.2 to 6% by weight based on the fiber treatment composition.

When the content of the 1,4-cyclohexanediol compound of Formula 2 or 3 is less than 0.01% by weight, the anti-wrinkling effect is insignificant, and when it exceeds 10% by weight, the drying time of the fiber after the fiber treatment composition of the present invention It is not preferable because there is a problem that the length of the fiber remains moist and the strength of the fiber is sharply lowered and the shape of the fiber is damaged during repeated use.

The fiber treatment composition of the present invention may further include a metal complex salt compound selected from the group consisting of a resinolate metal complex salt of formula (4) and a metal complex salt of titanium oxide of formula (5).

[Formula 4]

R ³ -COO-M ¹

(Wherein R ³ is a resinolate group and M ¹ represents Zn, Cu or Mg.)

[Formula 5]

TiO ₂ -M ²

(In the above formula, M ² represents Zn, Cu or Mg.)

The resinolate metal complex salt of formula (4) or the metal complex salt of titanium oxide of formula (5) serves to remove the odor of the fiber in addition to preventing the wrinkle of the fiber.

Preferred examples of the resinoleate metal complex salt of the formula (4) include resinolate zinc complex salt, resinolate copper complex salt or reynolate magnesium complex salt.

Further, preferred examples of the metal complex salt of titanium oxide of the formula (5) include titanium oxide zinc oxide, titanium oxide copper complex salt or titanium oxide magnesium complex salt.

Resinolate metal complex salt of formula (4) or metal complex salt of titanium oxide of formula (5) may be used, respectively, may be used in combination. If the two compounds are used in a mixture, they may be deteriorated with time, which may cause problems such as separation or precipitation of properties.

The content of the metal complex compound selected from the group consisting of the resinolate metal complex salt of Formula 4 and the metal complex salt of titanium oxide of Formula 5 is preferably 0.01 to 8% by weight, and 0.1 to 3% by weight based on the fiber treatment composition. % Is more preferred.

When the content of the metal complex compound selected from the group consisting of the resinolate metal complex salt of Formula 4 and the metal complex salt of titanium oxide of Formula 5 is less than 0.01% by weight relative to the fiber treatment composition, the effect of removing the odor of the fiber is effective. It is insignificant. In particular, the deodorizing effect is insignificant to the irritating odors such as hydrogen sulfide and mercaptone, which are acidic odors, and are not preferable. If the amount exceeds 8% by weight, the fiber may be dyed or discolored. It is not preferable because there is a problem that the touch is bad.                     

The fiber treatment composition of the present invention may further comprise a diisoalkyl adipate compound of the formula (6).

[Formula 6]

(CH ₂ ) _m -CHO-C- (CH ₂ ) ₄ -C-OCH- (CH ₂ ) _r

(Wherein m and r represent an integer of 1 to 10).

The diisoalkyl adipate compound of Formula 6 functions to shorten the drying time of the fiber after spraying the fiber treatment composition of the present invention and to reduce the damp texture of the fiber.

Preferred examples of the diisoalkyl adipate compound represented by Chemical Formula 6 include diisopropyl adipate and the like.

The content of the diisoalkyl adipate compound of Chemical Formula 6 is preferably 0.01 to 10% by weight, more preferably 0.1 to 5% by weight based on the fiber treatment composition.

If the content of the diisoalkyl adipate compound of Formula 6 is less than 0.01% by weight with respect to the fiber treatment composition, it is not preferable to shorten the drying time of the fiber, and if it exceeds 10% by weight, the wrinkle preventing effect is lowered. Not.

In addition, the fiber treatment composition of the present invention may further include other various components within the range that does not affect the sprayability, physical property stability and performance of the fiber treatment composition of the present invention in addition to the compounds of Formulas 1 to 6 described above. Can be.                     

That is, when spraying the fiber treatment composition of the present invention, the antibacterial agent to induce the cleanliness of the fiber, the fragrance to impart a fragrance to the fiber, the antistatic agent to prevent static electricity, the time-lapse physical safety of the fiber treatment composition, water Cationic surfactants having a molecular weight of 400 or less, lower alcohols or glycols to improve freezing stability, organic acids or inorganic salts, microorganisms to adjust viscosity or pH to improve solubility and stability at high or low temperatures. Preservatives, etc. for preventing contamination by this can be further added.

In addition, the fiber treatment composition of the present invention may be used as a laundry aid for washing clothes or the like, or may be directly sprayed on the clothes for drying after washing of clothes, etc. Can also be used.

In addition, depending on the purpose of use, it may be diluted with water and used at an appropriate concentration. In particular, when the fiber treatment composition of the present invention is used simultaneously with the fabric softener generally used in washing and rinsing, the wrinkles of clothing and the like can be significantly reduced.

As described above, the fiber treatment composition of the present invention is excellent in flexibility, antistatic property, anti-wrinkle property, ironing property, deodorizing power and drying property.

Hereinafter, preferred examples and comparative examples of the present invention are described. The following examples and comparative examples are described for the purpose of more clearly expressing the present invention, but the contents of the present invention are not limited to the following examples and comparative examples.

(Examples 1 to 5 and Comparative Examples 1 to 4)                     

Each component (unit: wt%) was mixed at the composition ratios shown in Table 1 to prepare a fiber treatment composition.

TABLE 1

Item Example Comparative example One 2 3 4 5 One 2 3 4 Hydroxybutyl ammonium salt polysiloxane 4.0 9.0 4.0 6.0 5.0 Diisocyclohexanediol 3.0 1.0 3.0 2.0 2.0 Resinolate Zinc Complex Salt 1.5 1.0 Titanium oxide zinc complex 1.5 1.0 Diisopropyl Adipate 2.0 5.0 3.0 4.0 3.0 Polyhydroxy alkylamine siloxane polymer 8.0 4.0 Polyalkylene oxide siloxane polymer 4.0 2.0 Methyl Substituted Cyclodextrins 1.0 4.0 Zinc chloride 1.0 2.0 Sulfonated modified polystyrene potassium 5.0 Propylene glycol 0.5 0.5 0.5 1.5 ethanol 0.5 0.5 1.0 0.5 0.5 4.0 3.0 5.0 0.5 Cyclodimethicone 0.2 0.5 0.5 1.0 1.0 Sorbitan Fatty Acid Ester (EO-20 mol) 0.1 0.1 0.1 0.2 0.2 1.0 Hydrogenated Castor Oil (EO-40 mol) 0.1 0.2 0.2 0.2 Other additives (viscosity regulators, pH regulators, fragrances, preservatives, fungicides, fungicides, fluorescent brighteners and antioxidants, etc.) thimbleful Purified water Balance

Based on Examples 1 to 5 and Comparative Examples 1 to 4 prepared above, sprayed at the same concentration on KS K-0905's standard white cotton cloth (manufactured by Korea Apparel Testing & Research Institute) at 25 ° C., 60% RH After leaving for 24 hours under constant temperature and humidity conditions of the test evaluation results are shown in Table 2 below.                     

TABLE 2

Test Items Test Methods Example Comparative example One 2 3 4 5 One 2 3 4 flexibility Flexible preference ◎ ◎ ◎ ◎ ◎ ○ ○ △ ◎ Drape Castle ◎ ○ ◎ ◎ ◎ △ ○ X ○ Antistatic Half-life ○ ◎ ◎ ◎ ◎ ○ ○ △ ○ Anti wrinkle Fusiform ◎ ◎ ◎ ◎ ◎ △ △ X △ Open angle ◎ ◎ ◎ ◎ ◎ △ ○ X △ Ironing Slip Test ○ ◎ ◎ ◎ ◎ ○ ○ X ◎ Fiber Deodorization (Detection Tube Method) Trimethylamine (80 ppM) - - ◎ ◎ ◎ ◎ - ◎ - Acetaldehyde (100 ppM) - - ◎ ◎ ◎ ○ - ◎ - Hydrosulfate (50 ppM) - - ○ ◎ ◎ X - △ - Dryness 50% weight reduction method ◎ ◎ ◎ ◎ ◎ △ X X X

Various symbols shown in Table 2 indicate the results of testing according to the standard test method of the KS standard (Korean standard test standard) and AATCC (American textile product test standard) shown in Table 3.

TABLE 3

Test Items                                          Scale ◎ ○ △ X flexibility Flexible preference 5-point scale Greater than 4.0 4.0 or less 3.0 or less Less than 2.0 Drape Castle Drape Factor Less than 0.3 0.35 or less 0.4 or less Greater than 0.4 Antistatic Half-life second Less than 5 20 or less 100 or less More than 100 Anti wrinkle Fusiform DP water supply judgment 1 or less 2 or less 3 or less More than 3 Open angle Angle More than 110 over 90 More than 70 Less than 70 Ironing Slip test Sliding angle 5 or less 15 or less 25 or less More than 25 Deodorizing power Trimethyl amine ppM Less than 1 below 10 40 or less More than 40 Acetaldehyde ppM Less than 1 below 10 50 or less More than 50 Hydrosulfate ppM Less than 1 below 10 25 or less More than 25 Dryness Drying time minute 5 or less 15 or less 30 or less More than 30

As shown in Tables 2 and 3, the fiber treatment compositions of Examples 1 to 5 are excellent in flexibility, antistatic, anti-wrinkling, ironing, deodorizing power and dryness.

The fiber treatment composition of the present invention is excellent in flexibility, antistatic, anti-wrinkling, ironing, deodorizing power and drying property.

Claims (7)

(a) a polysiloxane compound of cationic hydroxyalkyl ammonium salt of formula (1); And (b) 1,4-cyclohexanediol compound of formula (2) or (3) Fiber treatment composition comprising: [Formula 1]

Wherein R ¹ and R ² are each independently a hydroxy alkyl group or alkenyl group having 8 to 22 carbon atoms, A is an alkyl group or alkanol group having 1 to 4 carbon atoms, and Z is a divalent anion having 1 to 4 carbon atoms. Alkyl carboxyl group, n represents an integer of 10 to 2,000.) [Formula 2]

[Formula 3]

(In Formulas 2 and 3, X is hydrogen or an alkyl group having 1 to 3 carbon atoms, and Y represents an OH group.) The fiber treatment composition of claim 1, wherein the content of the polysiloxane compound of the cationic hydroxyalkyl ammonium salt of formula (a) is 0.01 to 15% by weight. The fiber treatment composition of claim 1, wherein the content of the 1,4-cyclohexanediol compound of Formula 2 or 3 of (b) is 0.1 to 10 wt%. The method according to any one of claims 1 to 3, further comprising 0.1 to 8% by weight of a metal complex compound selected from the group consisting of a resinolate metal complex salt of formula (4) and a metal complex salt of titanium oxide of formula (5). Fiber Treatment Composition [Formula 4] R ³ -COO-M ¹ (Wherein R ³ is a resinolate group and M ¹ represents Zn, Cu or Mg.) [Formula 5] TiO ₂ -M ² (Wherein, M ² represents Zn, Cu or Mg. The fiber treatment composition according to any one of claims 1 to 3, further comprising 0.01 to 10% by weight of a diisoalkyl adipate compound of formula (6): [Formula 6] (CH ₂ ) _m -CHO-C- (CH ₂ ) ₄ -C-OCH- (CH ₂ ) _r (Wherein m and r represent an integer of 1 to 10). The fiber treatment composition of claim 4, further comprising 0.01 to 10% by weight of a diisoalkyl adipate compound of the formula: [Formula 6] (CH ₂ ) _m -CHO-C- (CH ₂ ) ₄ -C-OCH- (CH ₂ ) _r (Wherein m and r represent an integer of 1 to 10). The fiber treatment composition of claim 1, wherein the fiber treatment composition is used as a laundry aid or spray.