KR100509862B1 - Composition of spray for refreshing clothing - Google Patents

Abstract

The present invention relates to a spray composition for garment refresher, comprising 0.001 to 10% by weight of a polysiloxane compound of hydroxyalkyl ammonium salt, based on the total weight of the composition; 0 to 3% by weight of 1,4-cyclohexanediol compound; 0.001 to 5% by weight of a compound selected from the group consisting of resinolate metal complex salts, hollow silica metal complex salt compounds and mixtures thereof; And 0.001 to 5% by weight of diisoalkyl adipate compound. Spray composition for clothing refresher according to the present invention can achieve the effect of removing wrinkles, deodorizing, fast drying and the like of the fiber, and improves the fiber fit.

Description

Spray composition for clothing refresher {COMPOSITION OF SPRAY FOR REFRESHING CLOTHING}

The present invention relates to a spray composition for a garment refresher, and more particularly, to a spray composition for a garment refresher, which can achieve effects such as wrinkle removal, deodorization, and quick drying property of fibers, and can improve fiber fit.

It is apparent that the technology for reducing wrinkles and deodorizing odors in textiles has been actively studied. In particular, US Pat. Nos. 6,001,343 and 5,798,197 also disclose technical problems related to the suppression of crease generation and odor removal of fibers, and for this purpose, a polyalkyl or polyhydroxy alkylaminesiloxane compound used as an anti-wrinkle component is proposed. have. However, the anti-wrinkling component proposed in the US patent data is not very remarkable as the wrinkle removal effect and wrinkle generation suppression effect, as well as the anti-wrinkling component of the polyalkyl or polyhydroxy alkylamine siloxane compound treated fibers There is a problem that the touch is not flexible and stiff, so the wear is not good, and there is no antistatic effect. In addition, when spraying the composition containing the anti-wrinkle component to the fiber, the drying of the sprayed component takes a considerable time, and the disadvantage that the fiber is moistened after spraying has been proposed, there is a problem in commercialization. .

In addition to the above-described U.S. patents, U.S. Pat.Nos. 5552165, 5593670, 5658097, 5714137, 5882638, and the like, and the techniques for deodorizing the odors permeating into the fibers, which are commonly referred to as a While inorganic metal complexes such as zinc chemically decompose malodorous substances and describe how cyclodextrin compounds decompose decomposed malodorous substances while moisture is dried, odorous substances are mainly described. This conventional fiber deodorization technology has almost no damage to fibers, and has the advantage of showing an excellent deodorizing effect against basic odors such as ammonia and trimethylamines, and neutral volatilized odors such as tobacco odors. However, the deodorizing effect is not sufficient for acidic irritating odors such as hydrogen sulfide and methylmecaptan resulting from the smell of kimchi and the decay of food. Also, if the fibers are wetted by moisture after drying, they are trapped in the cyclodextrin compound. There is a problem in that the malodorous substance is released again as it is by the substitution action of the malodorous substance and water is still odor. On the other hand, the cyclodextrin compound composed of glucose units can be multiplied by the generation of microorganisms on the fiber when the antimicrobial agent and the preservative are not used properly, and even if it remains on the surface of the fiber for a long time, the mold easily proliferates, causing odor or It may cause discoloration, and in particular, the texture of the fiber becomes rough and inflexible while wearing, such as clothing, which is emerging as a problem in commercialization.

The technology for controlling wrinkles generated in the conventional fibers, suppressing the occurrence of wrinkles again, and effectively removing the odors permeated in the fibers has been studied with particular attention in the related clothing and textile industries. It is apparent that the present invention has been devised based on the technical background.

The technical problem to be achieved by the present invention is to provide a spray composition for clothing refresher that can achieve the effects of wrinkle removal, deodorization, fast drying and the like of the fiber, and can improve the fit of the fiber.

The present invention to achieve the above technical problem, based on the total weight of the composition, 0.001 to 10% by weight of a polysiloxane compound of the hydroxyalkyl ammonium salt represented by the formula (1); 0 to 3% by weight of 1,4-cyclohexanediol compound represented by Formula 2 or 3; 0.001 to 5% by weight of a compound selected from the group consisting of a resinolate metal complex salt represented by Formula 4, a hollow silica metal complex salt compound represented by Formula 5, and a mixture thereof; And 0.001 to 5% by weight of a diisoalkyl adipate compound represented by the following Chemical Formula 6; provides a spray composition for a garment refresher.

In Formula 1, R is a hydroxy alkyl group or alkenyl group having 8 to 22 carbon atoms, A is an alkyl group or alkanol group having 1 to 4 carbon atoms, Z is an alkylcarboxy group having 1 to 4 carbon atoms as a divalent anion, X Is an integer of 10 to 2,000 or less.

In Formulas 2 and 3, X is an H group or an alkyl group having 1 to 3 carbon atoms, and Y is an OH group.

R-COO-M

In the general formula (4), R is a resinolate group, M is a divalent trivalent metal, and examples thereof include Zn, Al, Cu, Mg, and the like.

(SiO ₂ -M) n

In the above formula (5), M is a divalent trivalent metal, for example Zn, Al, Cu, Mg and the like, n is an integer of 1,000 to 100,000.

(CH ₂ ) m-CHO-C- (CH ₂ ) ₄ -C-OCH- (CH ₂ ) m

In Chemical Formula 6, m is an integer of 1 to 10.

Hereinafter, the spray composition for garment refresher according to the present invention will be described in detail.

In the spray composition for garment refresher according to the present invention, the polysiloxane compound of the hydroxyalkyl ammonium salt represented by the formula (1) simultaneously imparts anti-wrinkling function, flexibility and antistatic effect to the garment. The polysiloxane compound of such cationic hydroxyalkyl ammonium salt preferably has a molecular weight of 2,000 to 100,000, the content is 0.001 to 10% by weight, preferably 0.1% to 5% by weight based on the total weight of the composition. If the compound content of Formula 1 is less than 0.001% by weight, it is difficult to expect the anti-wrinkle effect expected in the present invention, and the ironing property may be poor, and when the content is more than 10% by weight, the strength and the salt of the fiber may be reduced. It can cause a problem of wearing.

In addition, in order to further improve the anti-wrinkle effect and the soft touch of the spray composition for clothing refresher according to the present invention, the 1,4-cyclohexanediol compound represented by the formula (2) or (3) may be optionally added. Such 1,4-cyclohexanediol compound improves the penetration and spreading properties so that the function of the compound of formula (1) is better exhibited.

In addition, the spray composition for clothing refresher according to the present invention comprises at least one of the resinolate metal complex salt of Formula 4 or the hollow silica metal complex salt of Formula 5 as a main component of the fiber deodorizing function, the content is 0.001 to 5% by weight %, More preferably 0.1 to 3% by weight. When the content of the resinolate metal complex salt and / or hollow silica metal complex salt compound is less than 0.001% by weight based on the total weight of the spray composition, the fiber deodorization effect is poor. The problem that the deodorizing effect is sharply reduced may occur, which is undesirable. In addition, when the content exceeds 5% by weight, it may cause dyeing or staining of the fiber, and in particular, the texture of the fiber may be poor, which is not preferable.

In addition, the spray composition for a clothing refresher according to the present invention comprises 0.001 to 5% by weight, preferably 0.1 to 2% by weight of the diisoalkyl adipate compound of the formula (6), which compound comprises the composition of the present invention After spraying, the drying time of the garment fibers is shortened and the damp feel is reduced to improve the feel of the fibers. Therefore, the spray composition for the garment refresher according to the present invention is particularly suitable for the purpose of the garment refresher (Whirlpool, Electrolux, etc.) for home use usually for the purpose of drying the fibers. When the content of the compound of Chemical Formula 6 is less than 0.001% by weight relative to the total weight of the spray composition, it is not preferable to shorten the drying time of the fiber, and thus it is not preferable because the moistness lasts a long time, and when the content exceeds 5% by weight. It is also undesirable because it sharply lowers the wrinkle effect.

On the other hand, the spray composition for clothes refresher provided in the present invention may further include other additional ingredients for the purpose of improving the stability of the final product. In other words, anti-static ingredients, fiber color protection ingredients, anti-contamination prevention ingredients, stability of the product over time, containing a small amount of fragrance and antimicrobial ingredients for the purpose of leaving a clean and good odor in the fiber when spraying And a small amount of a nonionic and a cationic surfactant having a molecular weight of 400 or less for the purpose of water solubility and high temperature and low temperature stability, or a small amount of lower alcohols or glycols for the purpose of improving freezing stability, and a small amount as a viscosity adjusting agent and a pH adjusting agent. As organic acids or inorganic salts, other preservatives which prevent microbial contamination, metal ion encapsulants, antifoaming components and the like are preferable. The inclusion of such additional components, etc. will correspond to the obvious matters in the art related to the present invention.

Hereinafter, the present invention will be described in detail with reference to embodiments. Embodiments according to the present invention may be modified in various forms, and the scope of the present invention is limited to the embodiments described below. It should not be interpreted as. Embodiments of the present invention are provided to more completely explain the present invention to those skilled in the art.

Examples 1 to 6 and Comparative Examples 1 to 3

Each of the components at the composition ratio as shown in Table 1 was mixed to prepare a spray composition for a garment refresher of the present invention, respectively, based on the net material based on Examples 1 to 6 and Comparative Examples 1 to 3 of each composition Each fiber material was treated with the same use concentration and spraying time (5 minutes), followed by conditioning for 1 hour under constant temperature and humidity conditions at 25 ° C. and 60% RH, and the test evaluation results are shown in Table 2 below. Evaluation criteria for the test evaluation shown in Table 2 is shown in Table 3 below. In accordance with the evaluation criteria of the following Table 3, the test was evaluated according to the standard test method of KS standard (Korean Standard Test Standard) and AATCC (American Textile Products Test Standard).

division                   Composition Example Comparative example One 2 3 4 5 6 One 2 3 Components of the Invention Hydroxybutylammonium salt polysiloxane 2.0 2.5 1.5 3.0 1.0 0.5 - - - Diisocyclohexanediol 0.5 - 1.0 - 1.5 1.8 - - - Resinolate Zinc Complex Salt 1.0 1.5 1.0 1.0 2.0 0.1 - - - Hollow Silica Metal Complex Salt 0.5 - 1.5 1.0 - 1.5 - - - Diisopropyl Adipate 1.0 1.0 1.0 1.5 1.0 1.5 - - - Components other than the present invention Polyhydroxy alkylamine siloxane polymer - - - - - - 4.0 - 2.0 Polyalkylene oxide siloxane polymer - - - - - - - - 2.0 Methyl Substituted Cyclodextrins - - - - - - 2.0 3.5 - Zinc chloride - - - - - - 1.0 1.0 - Sulfonated modified polystyrene potassium salt - - - - - - - - 3.0 Propylene glycol 0.2 0.2 0.2 - 0.1 0.1 0.5 0.5 1.0 ethanol 3.0 3.0 3.0 3.0 3.0 3.0 3.0 5.0 0.5 Cyclo methicone 0.2 0.2 0.2 0.2 0.2 0.5 0.5 1.0 1.0 Solbitan fatty acid ester (EO-20 mol) 0.1 - 0.1 0.1 - - 0.2 0.2 0.5 Hydrogenated Castor Oil (EO-40mol) - 0.1 - 0.2 0.2 - - - 0.2 Other additives Very small amounts (viscosity regulators, pH regulators, fragrances, preservatives, fungicides, fungicides, antioxidants, etc.) Purified water Up to 100% by weight

Test Items    Composition Test Method Example Comparative example One 2 3 4 5 6 One 2 3 flexibility Flexible preference ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ ◎ Drape Castle ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ ◎ Antistatic Half-life ◎ ◎ ◎ ◎ ◎ ◎ ◎ ○ ○ Anti wrinkle Fusiform ◎ ◎ ◎ ◎ ◎ ○ ○ △ ○ Open angle ◎ ◎ ◎ ◎ ◎ ○ ◎ ○ ○ Ironing Slip test ◎ ◎ ◎ ◎ ◎ ◎ ○ △ ○ Fiber Deodorization (Detection Tube Method) Trimethylamine (80 ppm) ◎ ◎ ◎ ◎ ◎ ◎ ○ ◎ △ Acetaldehyde (100 ppm) ◎ ◎ ◎ ◎ ◎ ○ ○ ◎ △ Hydrosulfate (50 ppm) ◎ ◎ ◎ ◎ ◎ ○ ○ ○ X Dryness 50% weight reduction method ◎ ◎ ◎ ◎ ◎ ◎ △ X X

Test Items Scale ◎ ○ △ X Flexible preference 5-point scale Greater than 4.0 4.0 or less 3.0 or less Less than 2.0 Drape Castle Drape coefficient Less than 0.3 0.35 or less 0.4 or less Greater than 0.4 Half-life sec Less than 5 20 or less 100 or less More than 100 Fusiform DP water supply judgment 1 or less 2 or less 3 or less More than 3 Open angle Angle More than 110 over 90 More than 70 Less than 70 Ironing Sliding Angle 5 or less 15 or less 25 or less More than 25 Deodorizing power Trimethylamine ppm Less than 1 below 10 40 or less More than 40 Acetaldehyde ppm Less than 1 below 10 50 or less More than 50 Hydrosulfate ppm Less than 1 below 10 25 or less More than 25 Drying time min below 10 20 or less 30 or less More than 30

Looking at the test evaluation results shown in Table 2, it can be seen that in the case of Examples 1 to 6 according to the present invention showed excellent results in almost all evaluation items, on the contrary, Comparative Examples 1 to 3 is an evaluation scale It can be seen that the evaluation results of the intermediate or less, it can be objectively confirmed the technical effect of the present invention. Looking specifically, as shown in Table 2, in the case of Examples 1 to 6 according to the present invention exhibits excellent effects as a spray composition for clothing refreshers, such as wrinkle prevention and fiber deodorization, shortening the drying time, as well as fiber It can be seen that the flexibility and antistatic properties are excellent and the ironing property is further improved. In addition, it can be seen that the drying time of the fiber after spraying is markedly different from the comparative examples.

An optimal embodiment according to the present invention described above has been disclosed. Although specific terms have been used herein, they are used only for the purpose of describing the present invention in detail to those skilled in the art and are not intended to limit the scope of the present invention as defined in the claims or the claims.

The spray composition for a garment refresher according to the present invention can be used by simply spraying on a fiber by using a garment refresher which is conventionally used for clothes or textile products which are worn after drying or being worn or stored and managed after washing. By the functional action of the compound contained in the composition, it not only removes the wrinkles of the fibers and deodorizes the bad smell of the fibers, but also quick drying time and easy ironing as well as soften the texture of the fibers and suppress the generation of static electricity It has the advantage of improving the fit.

Claims (1)

Based on the total weight of the composition, 0.1 to 10% by weight of a polysiloxane compound of hydroxyalkyl ammonium salt represented by Formula 1; 0 to 3% by weight of 1,4-cyclohexanediol compound represented by Formula 2 or 3; 0.1 to 5% by weight of a compound selected from the group consisting of a resinolate metal complex salt represented by Formula 4, a hollow silica metal complex salt compound represented by Formula 5, and a mixture thereof; And 0.1 to 5% by weight of a diisoalkyl adipate compound represented by the following formula (6); Spray composition for a clothing refresher comprising a. <Formula 1> In Formula 1, R is a hydroxy alkyl group or alkenyl group having 8 to 22 carbon atoms, A is an alkyl group or alkanol group having 1 to 4 carbon atoms, Z is an alkylcarboxy group having 1 to 4 carbon atoms as a divalent anion, X Is an integer of 10 to 2,000 or less; <Formula 2> <Formula 3> In Chemical Formulas 2 and 3, X is an H group or an alkyl group having 1 to 3 carbon atoms, and Y is an OH group; <Formula 4> R-COO-M In formula (4), R is a resinoleate group, M is a divalent trivalent metal; <Formula 5> (SiO ₂ -M) n In Formula 5, M is a bivalent to trivalent metal, n is an integer of 1,000 to 100,000; <Formula 6> (CH ₂ ) m-CHO-C- (CH ₂ ) ₄ -C-OCH- (CH ₂ ) m In Chemical Formula 6, m is an integer of 1 to 10.