JP4589622B2 - Liquid softener composition - Google Patents
Liquid softener composition Download PDFInfo
- Publication number
- JP4589622B2 JP4589622B2 JP2003430030A JP2003430030A JP4589622B2 JP 4589622 B2 JP4589622 B2 JP 4589622B2 JP 2003430030 A JP2003430030 A JP 2003430030A JP 2003430030 A JP2003430030 A JP 2003430030A JP 4589622 B2 JP4589622 B2 JP 4589622B2
- Authority
- JP
- Japan
- Prior art keywords
- compound
- water
- composition
- component
- silicone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000000203 mixture Substances 0.000 title claims description 64
- 239000007788 liquid Substances 0.000 title claims description 28
- 150000001875 compounds Chemical class 0.000 claims description 69
- 229920001296 polysiloxane Polymers 0.000 claims description 62
- 125000002091 cationic group Chemical group 0.000 claims description 27
- 229920000642 polymer Polymers 0.000 claims description 20
- 230000001877 deodorizing effect Effects 0.000 claims description 19
- 239000004902 Softening Agent Substances 0.000 claims description 18
- 229920003169 water-soluble polymer Polymers 0.000 claims description 18
- -1 diphenyl compound Chemical class 0.000 claims description 17
- 230000000844 anti-bacterial effect Effects 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- 239000002781 deodorant agent Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 9
- 238000013329 compounding Methods 0.000 claims description 8
- 239000000284 extract Substances 0.000 claims description 8
- 241000196324 Embryophyta Species 0.000 claims description 6
- 244000208060 Lawsonia inermis Species 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- 239000000419 plant extract Substances 0.000 claims description 4
- 239000000758 substrate Substances 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- 229940006460 bromide ion Drugs 0.000 claims description 3
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical class C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims description 3
- UFQDKRWQSFLPQY-UHFFFAOYSA-N 4,5-dihydro-1h-imidazol-3-ium;chloride Chemical compound Cl.C1CN=CN1 UFQDKRWQSFLPQY-UHFFFAOYSA-N 0.000 claims description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 2
- 229920002873 Polyethylenimine Polymers 0.000 claims description 2
- 229920006322 acrylamide copolymer Polymers 0.000 claims description 2
- YSCOODQOCWOXNL-UHFFFAOYSA-N diethylamino 2-methylprop-2-enoate Chemical compound CCN(CC)OC(=O)C(C)=C YSCOODQOCWOXNL-UHFFFAOYSA-N 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229940092258 rosemary extract Drugs 0.000 claims description 2
- 235000020748 rosemary extract Nutrition 0.000 claims description 2
- 239000001233 rosmarinus officinalis l. extract Substances 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 1
- 235000010290 biphenyl Nutrition 0.000 claims 1
- 239000004305 biphenyl Substances 0.000 claims 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
- 239000002518 antifoaming agent Substances 0.000 description 18
- 239000000835 fiber Substances 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 239000000126 substance Substances 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 13
- 239000004753 textile Substances 0.000 description 13
- 239000000178 monomer Substances 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 10
- 239000002585 base Substances 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 10
- 239000000975 dye Substances 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000003599 detergent Substances 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
- 239000000194 fatty acid Substances 0.000 description 8
- 229930195729 fatty acid Natural products 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 5
- 235000006708 antioxidants Nutrition 0.000 description 5
- 238000004332 deodorization Methods 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 239000008399 tap water Substances 0.000 description 5
- 235000020679 tap water Nutrition 0.000 description 5
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 4
- 125000003277 amino group Chemical group 0.000 description 4
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 4
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 4
- 229920006317 cationic polymer Polymers 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 241000282320 Panthera leo Species 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 150000004996 alkyl benzenes Chemical class 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 230000003078 antioxidant effect Effects 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 235000015165 citric acid Nutrition 0.000 description 3
- 239000013530 defoamer Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 229920006136 organohydrogenpolysiloxane Polymers 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 229920000570 polyether Polymers 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000003021 water soluble solvent Substances 0.000 description 3
- QSZCGGBDNYTQHH-UHFFFAOYSA-N 2,3-dimethoxyphenol Chemical compound COC1=CC=CC(O)=C1OC QSZCGGBDNYTQHH-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- CFKMVGJGLGKFKI-UHFFFAOYSA-N 4-chloro-m-cresol Chemical compound CC1=CC(O)=CC=C1Cl CFKMVGJGLGKFKI-UHFFFAOYSA-N 0.000 description 2
- CNGYZEMWVAWWOB-VAWYXSNFSA-N 5-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-[(e)-2-[4-[[4-anilino-6-[bis(2-hydroxyethyl)amino]-1,3,5-triazin-2-yl]amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound N=1C(NC=2C=C(C(\C=C\C=3C(=CC(NC=4N=C(N=C(NC=5C=CC=CC=5)N=4)N(CCO)CCO)=CC=3)S(O)(=O)=O)=CC=2)S(O)(=O)=O)=NC(N(CCO)CCO)=NC=1NC1=CC=CC=C1 CNGYZEMWVAWWOB-VAWYXSNFSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000004255 Butylated hydroxyanisole Substances 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 244000178231 Rosmarinus officinalis Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 240000001949 Taraxacum officinale Species 0.000 description 2
- 235000005187 Taraxacum officinale ssp. officinale Nutrition 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000002947 alkylene group Chemical group 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229960000686 benzalkonium chloride Drugs 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 2
- 235000019282 butylated hydroxyanisole Nutrition 0.000 description 2
- CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
- 229940043253 butylated hydroxyanisole Drugs 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 2
- 229960004585 etidronic acid Drugs 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 235000010388 propyl gallate Nutrition 0.000 description 2
- 239000000473 propyl gallate Substances 0.000 description 2
- 229940075579 propyl gallate Drugs 0.000 description 2
- 235000002020 sage Nutrition 0.000 description 2
- 150000003333 secondary alcohols Chemical class 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 150000003611 tocopherol derivatives Chemical class 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QFLWZFQWSBQYPS-AWRAUJHKSA-N (3S)-3-[[(2S)-2-[[(2S)-2-[5-[(3aS,6aR)-2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl]pentanoylamino]-3-methylbutanoyl]amino]-3-(4-hydroxyphenyl)propanoyl]amino]-4-[1-bis(4-chlorophenoxy)phosphorylbutylamino]-4-oxobutanoic acid Chemical compound CCCC(NC(=O)[C@H](CC(O)=O)NC(=O)[C@H](Cc1ccc(O)cc1)NC(=O)[C@@H](NC(=O)CCCCC1SC[C@@H]2NC(=O)N[C@H]12)C(C)C)P(=O)(Oc1ccc(Cl)cc1)Oc1ccc(Cl)cc1 QFLWZFQWSBQYPS-AWRAUJHKSA-N 0.000 description 1
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XUJLWPFSUCHPQL-UHFFFAOYSA-N 11-methyldodecan-1-ol Chemical compound CC(C)CCCCCCCCCCO XUJLWPFSUCHPQL-UHFFFAOYSA-N 0.000 description 1
- VZYDKJOUEPFKMW-UHFFFAOYSA-N 2,3-dihydroxybenzenesulfonic acid Chemical compound OC1=CC=CC(S(O)(=O)=O)=C1O VZYDKJOUEPFKMW-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
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- NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 description 1
- TYBHZVUFOINFDV-UHFFFAOYSA-N 2-bromo-6-[(3-bromo-5-chloro-2-hydroxyphenyl)methyl]-4-chlorophenol Chemical compound OC1=C(Br)C=C(Cl)C=C1CC1=CC(Cl)=CC(Br)=C1O TYBHZVUFOINFDV-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
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- 241000894006 Bacteria Species 0.000 description 1
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- FLWNIHKQWYRCTD-UHFFFAOYSA-N C(CCC)OC(C)CO.C(COCCO)O Chemical compound C(CCC)OC(C)CO.C(COCCO)O FLWNIHKQWYRCTD-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 101150065749 Churc1 gene Proteins 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 239000004287 Dehydroacetic acid Substances 0.000 description 1
- MDNWOSOZYLHTCG-UHFFFAOYSA-N Dichlorophen Chemical compound OC1=CC=C(Cl)C=C1CC1=CC(Cl)=CC=C1O MDNWOSOZYLHTCG-UHFFFAOYSA-N 0.000 description 1
- RPWFJAMTCNSJKK-UHFFFAOYSA-N Dodecyl gallate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC(O)=C(O)C(O)=C1 RPWFJAMTCNSJKK-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- 244000004281 Eucalyptus maculata Species 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 235000008694 Humulus lupulus Nutrition 0.000 description 1
- 244000025221 Humulus lupulus Species 0.000 description 1
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Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
本発明は、衣料などの繊維製品に有用な液体柔軟剤組成物に関する。特に、本発明は、衣料などの繊維製品に優れた柔軟性、滑らかさを付与することが可能であり且つ防臭効果を有する液体柔軟剤組成物に関する。 The present invention relates to a liquid softener composition useful for textiles such as clothing. In particular, the present invention relates to a liquid softener composition capable of imparting excellent flexibility and smoothness to textiles such as clothing and having a deodorizing effect.
従来から、衣料などの洗濯後のすすぎ時に添加し、繊維製品に柔軟性を付与することを目的として、様々な４級アンモニウム塩を主成分として含む柔軟剤が用いられている。４級アンモニウム塩としては、ジ長鎖型の４級アンモニウム塩が一般に使用されている。しかしながら、ジ長鎖型の４級アンモニウム塩を主成分とする柔軟剤は、綿製品に対しては良好な柔軟性付与効果が得られるものの、ぬめり感が生じたり、条件によってはポリエステル等の化学繊維への柔軟効果は小さくなり、滑らかさを付与する効果も小さい。
シリコーン系化合物はジ長鎖型の４級アンモニウム塩と異なり繊維製品、特に化学繊維に対し特有の柔軟性、しなやかさ、滑らかさを付与することが知られている。しかし、シリコーンは水浴中での仕上処理では繊維への吸着性に乏しく、十分な効果を得るためには、高濃度浴中で処理しなければならない。このような欠点を改善すべく、本発明者らは、先に特開２０００−１５４４７６号公報（特許文献１参照）に記載のようにシリコーンを水浴中から効率的に繊維へ吸着させる手段として、少量のカチオン界面活性剤との組合せを用いた、オシャレ着用の仕上げ剤組成物を提案した。しかしながら、この仕上げ剤組成物は、オシャレ着用のノニオン系洗剤の後に使用すると優れた性能を発揮するが、通常の洗濯に使用されるアニオン系の洗剤の後に用いると、すすぎ浴中に残留するアニオン活性剤の影響を受けやすく、性能が低下するという問題があった。
Conventionally, softeners containing various quaternary ammonium salts as main components have been used for the purpose of adding flexibility during rinsing after washing such as clothing and imparting flexibility to textiles. As the quaternary ammonium salt, a di-long-chain quaternary ammonium salt is generally used. However, softeners based on di-long-chain quaternary ammonium salts can provide a good softness-improving effect on cotton products, but may give a slimy feeling or may be chemically The softening effect on the fiber is small, and the effect of imparting smoothness is also small.
Unlike di-long-chain quaternary ammonium salts, silicone-based compounds are known to impart unique flexibility, flexibility, and smoothness to fiber products, particularly chemical fibers. However, silicone has poor adsorptivity to fibers in a finishing treatment in a water bath, and must be treated in a high concentration bath in order to obtain a sufficient effect. In order to improve such drawbacks, the present inventors previously as a means for efficiently adsorbing silicone from a water bath to a fiber as described in JP-A No. 2000-154476 (see Patent Document 1), A fashionable finish composition using a combination with a small amount of a cationic surfactant was proposed. However, this finish composition exhibits excellent performance when used after a fashionable nonionic detergent, but when used after an anionic detergent used in normal laundry, the anion remaining in the rinse bath There is a problem that the performance is lowered due to the influence of the activator.
また、特開平１０−１８３４７２号公報（特許文献２参照）には、従来から衣類にハリを付与することを目的として使用されている水溶性高分子を主体とした、水不溶性・非硬化シリコーン等を含む衣料用仕上げ剤組成物が開示されている。さらに、特開２０００−１２９５７７号公報（特許文献３参照）及び特開２０００−１２９５７８号公報（特許文献４参照）には、従来から衣類にハリを付与することを目的として使用されている水溶性高分子を主体とし、シリコーン化合物および非イオン界面活性剤を含む繊維製品用処理剤組成物が開示されている。しかしながら、これらの組成物を用いて繊維製品を処理すると、剛性値を高めることになり、柔らかさを求める柔軟剤としては好ましくない。
さらに、特開２０００−２３９９７０号公報（特許文献５参照）には、従来から衣類にハリを付与することを目的として使用されている水溶性高分子を主体として、アミノ変性シリコーンを含む繊維製品処理剤が開示されている。しかし、この組成物を用いて繊維製品を処理すると、剛性値を高めるため柔軟剤として好ましくないだけでなく、保管条件等によっては、アミノ変性シリコーンにより繊維製品が黄変することがある。
洗濯した衣料を室内で乾燥する場合、特に梅雨時には、菌の増殖等に起因するといわれている、室内乾燥特有の悪臭が発生する。このような悪臭を抑制することは多いに望まれており、特開２００１−１９２９６７号公報（特許文献６参照）では、ジ長鎖型４級アンモニウム塩を主体とする柔軟化合物に抗菌化合物を併用した柔軟剤組成物が開示されている。しかし、ジ長鎖型４級アンモニウム塩を主体とする組成物を用いて繊維製品を処理すると、菌の増殖を抑制する効果は高いものの、風合い面ではぬめり感が生じたり、滑らかさを付与する効果が小さくなる。
JP-A-10-183472 (see Patent Document 2) discloses a water-insoluble / non-cured silicone mainly composed of a water-soluble polymer that has been used for the purpose of imparting elasticity to clothing. A garment finish composition is disclosed. Furthermore, Japanese Patent Application Laid-Open No. 2000-129579 (see Patent Document 3) and Japanese Patent Application Laid-Open No. 2000-129578 (see Patent Document 4) have been used for the purpose of imparting elasticity to clothes. Disclosed is a fiber product treating agent composition mainly comprising a polymer and containing a silicone compound and a nonionic surfactant. However, when textile products are processed using these compositions, the rigidity value is increased, which is not preferable as a softening agent for obtaining softness.
Furthermore, JP 2000-239970 A (see Patent Document 5) discloses a fiber product treatment containing an amino-modified silicone mainly composed of a water-soluble polymer that has been used for the purpose of imparting elasticity to clothing. Agents are disclosed. However, when a textile product is treated with this composition, it is not preferable as a softening agent to increase the rigidity value, and the textile product may be yellowed by amino-modified silicone depending on storage conditions.
When clothes that have been washed are dried indoors, particularly during the rainy season, a bad odor peculiar to indoor drying, which is said to be caused by bacterial growth or the like, occurs. It is often desired to suppress such malodors, and in Japanese Patent Application Laid-Open No. 2001-192967 (see Patent Document 6), an antibacterial compound is used in combination with a flexible compound mainly composed of a di-long-chain quaternary ammonium salt. A softener composition is disclosed. However, when a textile product is treated with a composition mainly composed of a di-long quaternary ammonium salt, the effect of suppressing the growth of bacteria is high, but a feeling of sliminess is produced on the texture surface or smoothness is imparted. The effect is reduced.
本発明は、衣料などの繊維製品に優れた柔軟性、滑らかさを付与することが可能であり且つ優れた防臭効果を有する液体柔軟剤組成物を提供することを目的とする。 An object of this invention is to provide the liquid softening agent composition which can provide the softness | flexibility and smoothness which were excellent in textiles, such as clothing, and has the outstanding deodorizing effect.
本発明は、シリコーン化合物とカチオン性を有する水溶性高分子化合物を特定の比率で併用し、さらに抗菌性化合物を用いることにより上記課題を効率的に解決できるとの知見のもとになされたものである。
即ち、本発明は、（Ａ）シリコーン化合物、（Ｂ）カチオン性を有する水溶性高分子化合物、及び（Ｃ）抗菌性化合物を含有し、（Ａ）：（Ｂ）（質量比）が９９：１〜５０：５０であることを特徴とする液体柔軟剤組成物を提供する。
The present invention has been made based on the knowledge that the above-mentioned problems can be efficiently solved by using a silicone compound and a water-soluble polymer compound having a cationic property in a specific ratio and further using an antibacterial compound. It is.
That is, the present invention contains (A) a silicone compound, (B) a water-soluble polymer compound having a cationic property, and (C) an antibacterial compound, and (A) :( B) (mass ratio) is 99: Provided is a liquid softener composition characterized by being 1-50: 50.
本発明によれば、シリコーン化合物とカチオン性を有する水溶性高分子化合物を特定の比率で併用し、さらに抗菌性化合物を用いることで、衣料などの繊維製品に優れた柔軟性、滑らかさを付与することができると共に、優れた防臭効果を付与することができる。 According to the present invention, a silicone compound and a cationic water-soluble polymer compound are used in a specific ratio, and an antibacterial compound is used to provide excellent flexibility and smoothness to textile products such as clothing. In addition, it is possible to provide an excellent deodorizing effect.
以下、本発明につき更に詳しく説明する。
本発明の（Ａ）成分は、シリコーン化合物である。このシリコーン化合物は、繊維製品に吸着した時に、柔軟性、滑らかさを付与することが可能であれば特に限定されない。一般的に繊維処理に使用されているシリコーン化合物としては、ジメチルシリコーン、ポリエーテル変性シリコーン、メチルフェニルシリコーン、アルキル変性シリコーン、高級脂肪酸変性シリコーン、メチルハイドロジェンシリコーン、フッ素変性シリコーン、エポキシ変性シリコーン、カルボキシ変性シリコーン、カルビノール変性シリコーン、及びアミノ変性シリコーンなどが挙げられ、これらの１種を単独で又は２種以上の混合物として使用することができる。
このシリコーン化合物の分子構造は、直鎖状であっても分岐や架橋していてもよい。また、変性シリコーン化合物は１種類の有機官能基により変性されていても構わないし、２種以上の有機官能基により変性されていてもよい。
シリコーン化合物はオイルとして使用でき、また任意の乳化剤によって分散された乳化物としても使用できる。特に、柔軟処理した繊維製品の黄変を防止するために、アミノ基を含有しないシリコーン化合物であることが好ましい。さらに、後述する（Ｂ）成分による（Ａ）成分のシリコーン化合物を繊維へ吸着させる効果を高め、柔軟性、滑らかさを高める点から、（Ａ）成分のシリコーン化合物は、非イオン性であることが好ましく、より好ましい例としては、ジメチルシリコーン、カルビノール変性シリコーン、エポキシ変性シリコーン、ポリエーテル変性シリコーンが挙げられる。
Hereinafter, the present invention will be described in more detail.
The component (A) of the present invention is a silicone compound. The silicone compound is not particularly limited as long as it can impart flexibility and smoothness when adsorbed on a textile product. Silicone compounds generally used for fiber treatment include dimethyl silicone, polyether modified silicone, methylphenyl silicone, alkyl modified silicone, higher fatty acid modified silicone, methyl hydrogen silicone, fluorine modified silicone, epoxy modified silicone, carboxy Examples thereof include modified silicone, carbinol-modified silicone, and amino-modified silicone, and one of these can be used alone or as a mixture of two or more.
The molecular structure of the silicone compound may be linear or branched or cross-linked. The modified silicone compound may be modified with one kind of organic functional group or may be modified with two or more kinds of organic functional groups.
The silicone compound can be used as an oil or as an emulsion dispersed by any emulsifier. In particular, a silicone compound containing no amino group is preferable in order to prevent yellowing of the fiber product subjected to softening treatment. Furthermore, the silicone compound of the component (A) is nonionic from the viewpoint of enhancing the effect of adsorbing the silicone compound of the component (A) on the fiber by the component (B) described later, and improving flexibility and smoothness. More preferable examples include dimethyl silicone, carbinol-modified silicone, epoxy-modified silicone, and polyether-modified silicone.
このなかでも特に好ましいシリコーン化合物として、柔軟性付与及び液体柔軟剤組成物を透明にし、商品価値を高めることができる等の観点から、ポリエーテル変性シリコーンを挙げることができる。本シリコーンは、ポリエーテル基を有しないジメチルシリコーンに比べ、キシミ感が少なく良好な柔軟性を有するとともに、透明な液体柔軟剤組成物を得るのに好適である。好ましいポリエーテル変性シリコーンとしては、アルキル（炭素数１〜３）シロキサンとポリオキシアルキレン（アルキレン基の炭素数２〜５が好ましい）の共重合体が挙げられる。このうち、ジメチルシロキサンとポリオキシアルキレン（ポリオキシエチレン、ポリオキシプロピレン、エチレンオキシドとプロピレンオキシドとのランダム又はブロック共重合体など）の共重合体が好ましい。このようなものとして、下記一般式（Ｉ）又は （ＩＩ）で表される化合物が挙げられる。 Among these, particularly preferable silicone compounds include polyether-modified silicones from the viewpoints of imparting flexibility and making the liquid softener composition transparent and increasing commercial value. The silicone is suitable for obtaining a transparent liquid softening agent composition with less flexibility and good flexibility as compared with dimethyl silicone having no polyether group. Preferred polyether-modified silicones include copolymers of alkyl (C1 to C3) siloxane and polyoxyalkylene (preferably having 2 to 5 carbon atoms of an alkylene group). Among these, a copolymer of dimethylsiloxane and polyoxyalkylene (polyoxyethylene, polyoxypropylene, random or block copolymer of ethylene oxide and propylene oxide, etc.) is preferable. Examples of such compounds include compounds represented by the following general formula (I) or (II).
（式中、Ｍ、Ｎ、ａ及びｂは平均重合度であり、Ｒは水素又はアルキル基を表す。）
ここで、Ｍは１０〜１００００、Ｎは１〜１０００、かつＭ＞Ｎであることが好ましく、ａは２〜１００、ｂは０〜５０が好ましい。Ｒとしては水素又は炭素数１〜４のアルキル基が好ましい。
一般式（Ｉ）で表されるポリエーテル変性シリコーンは、一般に、Ｓｉ−Ｈ基を有するオルガノハイドロジェンポリシロキサンと、例えばポリオキシアルキレンアリルエーテル等の、炭素−炭素二重結合を末端に有するポリオキシアルキレンアルキルエーテルとを付加反応させることにより製造することができる。
(In the formula, M, N, a and b are average polymerization degrees, and R represents hydrogen or an alkyl group.)
Here, M is preferably 10 to 10000, N is preferably 1 to 1000, and M> N, a is preferably 2 to 100, and b is preferably 0 to 50. R is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms.
The polyether-modified silicone represented by the general formula (I) is generally an organohydrogenpolysiloxane having a Si-H group and a polycarbon having a carbon-carbon double bond at the end, such as a polyoxyalkylene allyl ether. It can be produced by addition reaction with oxyalkylene alkyl ether.
（式中、Ａ、Ｂ、ｈ、及びｉは平均重合度であり、Ｒはアルキル基を表し、Ｒ’は水素又はアルキル基を表す。）
ここで、Ａは５〜１００００、Ｂは２〜１００００であることが好ましく、ｈは２〜１００、ｉは０〜５０が好ましい。Ｒとしては炭素数１〜５のアルキル基が好ましい。Ｒ’としては水素又は炭素数１〜４のアルキル基が好ましい。また、式（ＩＩ）で表わされるブロック共重合体の重量平均分子量は、柔軟性、滑らかさの観点から１５，０００〜１００，０００，０００であることが好ましい。
上記線状ポリシロキサン−ポリオキシアルキレンブロック共重合体は、反応性末端基を有するポリオキシアルキレン化合物と、該化合物の反応性末端基と反応する末端基を有するジヒドロカルビルシロキサンとを反応させることにより製造することができる。
(In the formula, A, B, h, and i are average polymerization degrees, R represents an alkyl group, and R ′ represents hydrogen or an alkyl group.)
Here, A is preferably 5 to 10,000, B is preferably 2 to 10,000, h is preferably 2 to 100, and i is preferably 0 to 50. R is preferably an alkyl group having 1 to 5 carbon atoms. R ′ is preferably hydrogen or an alkyl group having 1 to 4 carbon atoms. Moreover, it is preferable that the weight average molecular weight of the block copolymer represented by Formula (II) is 15,000-100,000,000 from a viewpoint of a softness | flexibility and smoothness.
The linear polysiloxane-polyoxyalkylene block copolymer is obtained by reacting a polyoxyalkylene compound having a reactive end group with a dihydrocarbylsiloxane having an end group that reacts with the reactive end group of the compound. Can be manufactured.
本発明で用いるポリエーテル変性シリコーンオイルの具体的な例としては、東レ・ダウ コーニング・シリコーン（株）製のＳＨ３７７２Ｍ、ＳＨ３７７５Ｍ、ＳＨ３７４８、ＳＨ３７４９、ＳＦ８４１０、ＳＨ８７００、ＢＹ２２−００８、ＳＦ８４２１、信越化学工業（株）製のＫＦ３５２Ａ、ＫＦ６００８、ＫＦ６１５Ａ、ＫＦ６０１６、ＫＦ６０１７、ＧＥ東芝シリコーン（株）製のＴＳＦ４４５０、ＴＳＦ４４５２、日本ユニカー（株）製のＳＩＬＷＥＴ Ｌ−７００１、ＳＩＬＷＥＴ Ｌ−７００２、ＳＩＬＷＥＴ Ｌ−７６０２、ＳＩＬＷＥＴ Ｌ−７６０４、ＳＩＬＷＥＴ ＦＺ−２１０４、ＳＩＬＷＥＴ ＦＺ−２１２０、ＳＩＬＷＥＴ ＦＺ−２１６１、ＳＩＬＷＥＴ ＦＺ−２１６２、ＳＩＬＷＥＴ ＦＺ−２１６４、ＳＩＬＷＥＴ ＦＺ−２１７１、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−０１、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−０２、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−０３、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−０５、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−０９、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−１１、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−１３、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−Ｆ１−００９−５４、ＡＢＮ ＳＩＬＷＥＴ ＦＺ−２２２２等が挙げられ、これらを１種単独で又は２種以上の混合物として用いることができる。
本発明で用いる（Ａ）成分のシリコーン化合物の配合量は特に限定されないが、柔軟性、滑らかさ及び組成物の粘度の点から、組成物の全質量をベースとして、３〜７０質量％が好ましく、さらに好ましくは５〜５０質量％、特に好ましくは６〜４０質量％である。これにより、柔軟性、滑らかさなどの効果を優秀なものとすることができ、かつ、粘度の上昇を抑えて使用性を良好なものとすることができる。
Specific examples of the polyether-modified silicone oil used in the present invention include SH3772M, SH3775M, SH3748, SH3749, SF8410, SH8700, BY22-008, SF8421, and Shin-Etsu Chemical (manufactured by Toray Dow Corning Silicone). KF352A, KF6008, KF615A, KF6016, KF6017, GE Toshiba Silicone Co., Ltd. TSF4450, TSF4452, Nippon Unicar Co., Ltd. SILWET L-7002, SILWET L-7602, SILWET L-7602, SILWET L -7604, SILWET FZ-2104, SILWET FZ-2120, SILWET FZ-2161, SILWET FZ-2162, SILWET FZ-2164, SILWET FZ-2171, ABN SILWET FZ-F1-009-01, ABN SILWET FZ-F1-009-02, ABN SILWET FZ-F1-009-03, ABN SILWET FZ-F1-009-05, ABN SILWET FZ-F1- 009-09, ABN SILWET FZ-F1-009-11, ABN SILWET FZ-F1-009-13, ABN SILWET FZ-F1-009-54, ABN SILWET FZ-2222, and the like. Or it can use as a mixture of 2 or more types.
The blending amount of the silicone compound of component (A) used in the present invention is not particularly limited, but is preferably 3 to 70% by mass based on the total mass of the composition from the viewpoint of flexibility, smoothness and viscosity of the composition. More preferably, it is 5 to 50% by mass, particularly preferably 6 to 40% by mass. Thereby, effects, such as a softness | flexibility and smoothness, can be made excellent, and the usability can be made favorable by suppressing the increase in viscosity.
本発明の（Ｂ）成分は、（Ａ）成分のシリコーン化合物を繊維へ吸着させる効果を有するものである。カチオン性を有する水溶性高分子化合物としては、水に溶解した時にカチオン性を有するものが使用し得るが、特にカチオン性を有する水溶性高分子化合物としては、アミノ基、アミン基、第４級アンモニウム基から選ばれる１種以上のカチオン性基を有する水溶性高分子化合物が好ましい。なお、本発明において、水溶性高分子とは、２５℃の水１００ｇに対し、水溶性高分子化合物１ｇを加えたときに、その液が濁らず透明であるものをいう。
（Ｂ）成分のカチオン性を有する水溶性高分子化合物は、カチオン化度が０．１％以上のものが好ましく、例えば０．１〜３５であるのがよく、特に２．５％以上が好ましく、例えば２．５〜１５であるのがよい。カチオン化度がこのような条件を満たすことにより、共存するシリコーン化合物を繊維へ吸着させる効果を優秀なものとすることができ、かつ、多量の配合が必要となって経済的でないケースを防止することができる。
ここで、カチオン化度とは、高分子化合物がカチオン性モノマーの重合体、カチオン性モノマーとノニオン性モノマーの共重合体、及びノニオン性重合体の一部をカチオン性基で変性又は置換したもの（カチオン化セルロースなど）の場合には下記式（１）により、また、高分子化合物がカチオン性モノマーとアニオン性モノマーの共重合体、及びカチオン性モノマーとアニオン性モノマーとノニオン性モノマーの共重合体の場合には、下記式（２）により算出される値と定義する。
The component (B) of the present invention has an effect of adsorbing the silicone compound of the component (A) to the fiber. As the water-soluble polymer compound having a cationic property, those having a cationic property when dissolved in water can be used. Particularly, the water-soluble polymer compound having a cationic property includes an amino group, an amine group, a quaternary compound. A water-soluble polymer compound having one or more cationic groups selected from ammonium groups is preferred. In the present invention, the water-soluble polymer means that when 1 g of the water-soluble polymer compound is added to 100 g of water at 25 ° C., the liquid is not turbid and transparent.
The water-soluble polymer compound having a cationic property as component (B) preferably has a cationization degree of 0.1% or more, for example, preferably 0.1 to 35, and particularly preferably 2.5% or more. For example, it is good that it is 2.5-15. When the degree of cationization satisfies these conditions, the effect of adsorbing the coexisting silicone compound on the fiber can be made excellent, and a large amount of compounding is required to prevent an economical case. be able to.
Here, the degree of cationization means that a polymer compound is a polymer of a cationic monomer, a copolymer of a cationic monomer and a nonionic monomer, and a part of a nonionic polymer modified or substituted with a cationic group. In the case of (cationized cellulose, etc.), the polymer compound is a copolymer of a cationic monomer and an anionic monomer, and a copolymer of a cationic monomer, an anionic monomer and a nonionic monomer. In the case of coalescence, it is defined as a value calculated by the following formula (2).
カチオン化度（％）＝Ｘ×Ｙ×１００ …式（１）
[Ｘ：高分子化合物のカチオン性基中のカチオン化された原子（窒素等）の原子量
Ｙ：高分子化合物１ｇ中に含まれるカチオン性基のモル数]
カチオン化度（％）＝Ｘ×（Ｙ−Ｚ）×１００ …式（２）
[Ｘ：高分子化合物のカチオン性基中のカチオン化された原子（窒素等）の原子量
Ｙ：高分子化合物１ｇ中に含まれるカチオン性基のモル数
Ｚ：高分子化合物１ｇ中に含まれるアニオン性基のモル数
（Ｚのアニオン性基とは、高分子鎖中のモノマー単位に含まれるカルボキシル基、スルホン酸基などが挙げられる。具体的には、アクリル酸中のカルボン酸などである。ただし、カチオン性基の対イオンは含まない。）］
Cation degree (%) = X × Y × 100 (1)
[X: atomic weight of a cationized atom (such as nitrogen) in the cationic group of the polymer compound Y: number of moles of the cationic group contained in 1 g of the polymer compound]
Degree of cationization (%) = X × (Y−Z) × 100 Formula (2)
[X: atomic weight of a cationized atom (such as nitrogen) in a cationic group of a polymer compound Y: number of moles of a cationic group contained in 1 g of the polymer compound Z: anion contained in 1 g of the polymer compound The number of moles of the functional group (an anionic group of Z includes, for example, a carboxyl group and a sulfonic acid group contained in the monomer unit in the polymer chain. Specific examples include a carboxylic acid in acrylic acid. However, the counter ion of the cationic group is not included.)]
カチオン化度の算出例として、下記式（ＩＩＩ）で表されるＭＥＲＱＵＡＴ２８０（ｃａｌｇｏｎ社製）の場合を示す。
Ｘ：１４（窒素原子の原子量）
Ｙ：４．９５×１０-3（カチオン性基の１ｇ中の重量：０．８ｇとカチオン性基の分子量より算出）
Ｚ：２．７８×１０-3（アニオン性基の１ｇ中の重量：０．２ｇとアニオン性基の分子量より算出）
式（２）より、
カチオン化度（％）＝
１４×（４．９５×１０-3−２．７８×１０-3）×１００＝３．０
である。
As an example of calculating the degree of cationization, a case of MERQUAT280 (made by calgon) represented by the following formula (III) is shown.
X: 14 (atomic weight of nitrogen atom)
Y: 4.95 × 10 −3 (weight per 1 g of the cationic group: calculated from 0.8 g and the molecular weight of the cationic group)
Z: 2.78 × 10 −3 (weight per 1 g of anionic group: calculated from 0.2 g and molecular weight of the anionic group)
From equation (2)
Cation degree (%) =
14 × (4.95 × 10 −3 −2.78 × 10 −3 ) × 100 = 3.0
It is.
（ＭＥＲＱＵＡＴ２８０）
塩化ジメチルジアリルアンモニウムとアクリル酸との質量比＝８０：２０
よって、上記記載のカチオン化度の算出法によれば、ノニオン性モノマーの重合体やアニオン性モノマーの重合体のカチオン化度は０となる。
(MERQUAT280)
Mass ratio of dimethyldiallylammonium chloride to acrylic acid = 80: 20
Therefore, according to the cationization degree calculation method described above, the cationization degree of the nonionic monomer polymer or the anionic monomer polymer is zero.
（Ｂ）成分の水溶性高分子は、ポリエチレングリコールを標準物質としてゲルパーメーションクロマトグラフィ法で測定される重量平均分子量が、１，０００〜５，０００，０００であることが好ましく、より好ましくは３，０００〜１，０００，０００であり、さらに好ましくは５，０００〜５００，０００である。これにより臭気を良好に防止することができ、かつ、粘度の上昇を抑えて使用性を優秀なものとすることが可能となる。
（Ｂ）成分の例としては、ＭＥＲＱＵＡＴ１００（Ｃａｌｇｏｎ社製）、アデカカチオエースＰＤ−５０（旭電化工業（株））、ダイドールＥＣ−００４、ダイドールＨＥＣ、ダイドールＥＣ（大同化成工業（株）製）等の塩化ジメチルジアリルアンモニウムの重合体、ＭＥＲＱＵＡＴ５５０ ＪＬ５（Ｃａｌｇｏｎ社製）等の塩化ジメチルジアリルアンモニウム・アクリルアミド共重合体、ＭＥＲＱＵＡＴ２８０（Ｃａｌｇｏｎ社製）等の塩化ジメチルジアリルアンモニウム・アクリル酸共重合体、レオガードＫＧＰ（ライオン（株）製）等のカチオン化セルロース、ＬＵＶＩＱＵＡＴ−ＦＣ９０５（Ｂ・Ａ・Ｓ・Ｆ社製）等の塩化イミダゾリニウム・ビニルピロリドン共重体、ＬＵＧＡＬＶＡＮ−Ｇ１５０００（Ｂ・Ａ・Ｓ・Ｆ社製）等のポリエチレンイミン、ポバールＣＭ３１８（（株）クラレ製）等のカチオン化ポリビニルアルコール、キトサン等のアミノ基を有する天然系の高分子誘導体、ジエチルアミノメタクリレート・エチレンオキシド等が付加された親水基を有するビニルモノマーとの共重合体等が挙げられるが、水に溶解時にカチオン性を有する高分子化合物であればよく、本例に限定されるものではない。
この中で、シリコーンの付与する柔軟性などの風合いを妨げない観点から、（Ｂ）成分単独で吸着した時に繊維に付与する剛性の小さいものが好ましい。
特に好ましい高分子としては、下記一般式(ＩＶ)に示すジメチルジアリルアンモニウム塩を重合して得られるカチオン性高分子である。この高分子の構造は、通常、下記一般式（Ｖ）又は下記一般式（ＶＩ）で表わされる。また、一般式（Ｖ）の構造単位と一般式（ＶＩ）の構造単位が共に含まれていてもよい。
The water-soluble polymer of component (B) preferably has a weight average molecular weight of 1,000 to 5,000,000, more preferably 3 as measured by gel permeation chromatography using polyethylene glycol as a standard substance. , 1,000 to 1,000,000, more preferably 5,000 to 500,000. As a result, it is possible to satisfactorily prevent odor and to suppress the increase in viscosity and to improve the usability.
Examples of the component (B) include MERQUAT100 (Calgon), Adeka thioace PD-50 (Asahi Denka Kogyo Co., Ltd.), Daidol EC-004, Daidoru HEC, Daido Kasei Kogyo Co., Ltd. Polymers of dimethyldiallylammonium chloride such as MERQUAT550 JL5 (manufactured by Calgon), dimethyldiallylammonium chloride / acrylamide copolymer such as MERQUAT280 (manufactured by Calgon), dimethyldiallylammonium chloride / acrylic acid copolymer such as MERQUAT280 (manufactured by Calgon), Leogard KGP Cationized cellulose such as Lion (manufactured by Lion Corporation), imidazolinium chloride / vinylpyrrolidone copolymer such as LUVIQUAT-FC905 (manufactured by B / A / S / F), LUGALVAN-G15000 (B / A / S / F) Etc.) A cationic polymer such as polyethyleneimine and poval CM318 (manufactured by Kuraray Co., Ltd.), a natural polymer derivative having an amino group such as chitosan, and a vinyl monomer having a hydrophilic group to which diethylaminomethacrylate / ethylene oxide is added. Although a copolymer etc. are mentioned, it should just be a high molecular compound which has cationic property when melt | dissolving in water, It is not limited to this example.
Among these, from the viewpoint of not hindering the texture such as flexibility imparted by the silicone, those having low rigidity imparted to the fiber when adsorbed by the component (B) alone are preferable.
A particularly preferable polymer is a cationic polymer obtained by polymerizing a dimethyldiallylammonium salt represented by the following general formula (IV). The structure of this polymer is usually represented by the following general formula (V) or the following general formula (VI). Moreover, both the structural unit of general formula (V) and the structural unit of general formula (VI) may be contained.
このような高分子の例としては、ＭＥＲＱＵＡＴ１００（Ｃａｌｇｏｎ社製）、アデカカチオエースＰＤ−５０（旭電化工業（株）製）、ダイドールＥＣ−００４、ダイドールＨＥＣ、ダイドールＥＣ（大同化成工業（株）製）等が挙げられる。
本発明の（Ｂ）成分としては、上記のカチオン性を有する水溶性高分子化合物を１種単独で用いてもよいし、混合物として用いることもできる。
（Ｂ）成分の配合量は特に限定されないが、繊維製品に剛性を付与しない範囲のものとするのが好ましく、例えば、組成物の全質量をベースとして、０．１〜３０質量％とするのがよく、さらに好ましくは０．５〜１０質量％とするのがよい。（Ｂ）成分の配合量をこのような範囲のものとすることにより、シリコーンの吸着促進効果が高めて、柔軟性、滑らかさなどの効果を十分なものとすることが可能となり、かつ、粘度の上昇を抑えて使用性の面で良好なものとすることができる。
Examples of such a polymer include MERQUAT100 (Calgon), Adekathioace PD-50 (Asahi Denka Kogyo Co., Ltd.), Daidole EC-004, Daidole HEC, Daido Kagaku Kogyo Co., Ltd. Manufactured) and the like.
As the component (B) of the present invention, the above water-soluble polymer compound having a cationic property may be used singly or as a mixture.
(B) Although the compounding quantity of a component is not specifically limited, It is preferable to set it as the thing of the range which does not provide rigidity to textiles, For example, it shall be 0.1-30 mass% on the basis of the total mass of a composition. More preferably, it is good to set it as 0.5-10 mass%. By making the blending amount of component (B) within such a range, the effect of promoting the adsorption of silicone can be enhanced, and the effects such as flexibility and smoothness can be made sufficient, and the viscosity can be increased. It is possible to improve the usability by suppressing the increase in the thickness.
本発明の液体柔軟剤組成物中において、（Ａ）成分：（Ｂ）成分の質量比は、９９：１〜５０：５０の範囲内である。好ましくは９５：５〜６０：４０、さらに好ましくは９０：１０〜７０：３０の範囲である。このような範囲内の比とすることにより、ポリエステル、綿等の衣類に対し柔軟性、滑らかさ等の風合いの優れた機能が得られる。尚、（Ｂ）成分の割合がこの範囲内にあることにより、シリコーンの繊維への吸着性を良好なものとすることができる。
また、本発明の液体柔軟剤組成物は、実際に繊維製品の柔軟仕上げを行う際の全使用水量に対し、（Ａ）成分の濃度が５ｐｐｍ〜５０００ｐｐｍとなるような量で使用するのが好ましく、さらに好ましくは１０ｐｐｍ〜３００ｐｐｍとなるような量で使用され、（Ｂ）成分の濃度は０．５ｐｐｍ〜１００ｐｐｍとなるような量で使用するのが好ましく、さらに好ましくは３ｐｐｍ〜３０ｐｐｍとなるような量で使用される。
In the liquid softening agent composition of the present invention, the mass ratio of component (A): component (B) is in the range of 99: 1 to 50:50. Preferably it is 95: 5-60: 40, More preferably, it is the range of 90: 10-70: 30. By setting the ratio within such a range, functions having excellent texture such as flexibility and smoothness can be obtained for clothing such as polyester and cotton. In addition, when the ratio of the component (B) is within this range, the adsorptivity of silicone to fibers can be improved.
In addition, the liquid softener composition of the present invention is preferably used in such an amount that the concentration of the component (A) is 5 ppm to 5000 ppm with respect to the total amount of water used when the textile product is actually subjected to soft finishing. More preferably, it is used in an amount so as to be 10 ppm to 300 ppm, and the concentration of the component (B) is preferably used so as to be 0.5 ppm to 100 ppm, and more preferably 3 ppm to 30 ppm. Used in quantity.
本発明の（Ｃ）成分の抗菌性化合物は、木綿金巾＃２００３に該化合物１重量％を均一に付着させた布を用いＪＩＳ Ｌ １９０２「繊維製品の抗菌性試験法」の方法で抗菌性試験を行い阻止帯が見られる化合物である。このような化合物としては「香粧品、医薬品防腐・殺菌剤の科学」（吉村孝一、滝川博文著、フレグランスジャーナル社、１９９０年４月１０日発行）の５０１頁〜５６４頁に記載されているものから選択することができる。
本発明の（Ｃ）成分としては、以下に例を示すが、これに限定されない。
トリクロサン類、ビス−（２−ピリジルチオ−１−オキシド）亜鉛、２，４，５，６−テトラクロロイソフタロニトリル、トリクロロカルバニリド、８−オキシキノリン、デヒドロ酢酸、安息香酸エステル類、クロロクレゾール類、クロロチモール、クロロフェン、ジクロロフェン、ブロモクロロフェン、ヘキサクロロフェン、及びジアルキル（Ｃ８〜Ｃ１２）ジメチルアンモニウム塩、アルキル（Ｃ８〜Ｃ１２）ジメチルベンジルアンモニウム塩、モノアルキル（Ｃ１２〜Ｃ２０）トリメチルアンモニウム塩、セチルピリジニウム塩等の４級アンモニウム化合物、塩化ベンザルコニウムなどが挙げられる。成分（Ｃ）は、好ましくは、トリクロサン類、ジアルキル（Ｃ８〜Ｃ１２）ジメチルアンモニウム塩及び塩化ベンザルコニウムからなる群より選ばれる。
The antibacterial compound of the component (C) of the present invention is an antibacterial test according to the method of JIS L 1902 “Testing the antibacterial properties of textiles” using a cloth in which 1% by weight of the compound is uniformly attached to a cotton lacquer # 2003. It is a compound that shows a blocking zone. Such compounds are described in pages 501 to 564 of “Science of Cosmetics, Pharmaceutical Preservatives and Bactericides” (by Koichi Yoshimura and Hirofumi Takikawa, issued by Fragrance Journal, April 10, 1990). You can choose from.
Examples of the component (C) of the present invention are shown below, but are not limited thereto.
Triclosans, bis- (2-pyridylthio-1-oxide) zinc, 2,4,5,6-tetrachloroisophthalonitrile, trichlorocarbanilide, 8-oxyquinoline, dehydroacetic acid, benzoates, chlorocresol , Chlorothymol, chlorophene, dichlorophen, bromochlorophene, hexachlorophene, and dialkyl (C8-C12) dimethylammonium salt, alkyl (C8-C12) dimethylbenzylammonium salt, monoalkyl (C12-C20) trimethylammonium salt And quaternary ammonium compounds such as cetylpyridinium salt and benzalkonium chloride. Component (C) is preferably selected from the group consisting of triclosans, dialkyl (C8-C12) dimethylammonium salts and benzalkonium chloride.
これらの中でも前記カチオン性高分子化合物によるシリコーン化合物を効率的に繊維上へ吸着させる観点から非イオン性の抗菌剤が好ましい。この中でも、防臭効果の点から特開平１１−１８９９７５号記載のハロゲノ−ｏ−ヒドロキシジフェニル化合物が最も好ましく、特にチバスペシャリティケミカルズ社製の商品名ＩＲＧＡＣＡＲＥ ＭＰ、ＴＩＮＯＳＡＮ ＨＰ１００などで販売されているトリクロロヒドロキシジフェニルエーテル、ジクロロヒドロキシジフェニルエーテル、モノクロロヒドロキシジフェニルエーテルが好ましい。
（Ｃ）成分の配合量は、組成物の全質量をベースとして、０．０１〜１０質量％とするのがよく、好ましくは０．０５〜５質量％、特に好ましくは０．１〜３質量％である。（Ｃ）成分の配合量をこのような範囲内のものとすることにより、防臭効果を充分なものとすることができ、かつ、効果が飽和に達した際の余分な添加を抑えて経済性を図ることが可能となる。
ここで、（Ｃ）成分は、（Ａ）成分：（Ｂ）成分の質量比が、上述した９０：１０〜７０：３０であり、かつ、（Ａ）成分がポリエーテル変性シリコーンである場合、トリクロサン類であるのが好ましい。
Among these, nonionic antibacterial agents are preferable from the viewpoint of efficiently adsorbing the silicone compound by the cationic polymer compound onto the fiber. Of these, halogeno-o-hydroxydiphenyl compounds described in JP-A No. 11-189975 are the most preferable from the viewpoint of deodorizing effect, and trichlorohydroxydiphenyl ethers sold under the trade names IRGACARE MP, TINASAN HP100, etc., manufactured by Ciba Specialty Chemicals. , Dichlorohydroxydiphenyl ether, and monochlorohydroxydiphenyl ether are preferred.
The amount of component (C) is preferably 0.01 to 10% by mass, preferably 0.05 to 5% by mass, particularly preferably 0.1 to 3% by mass, based on the total mass of the composition. %. By making the blending amount of the component (C) within such a range, the deodorizing effect can be made sufficient, and the excessive addition when the effect reaches saturation is economical. Can be achieved.
Here, (C) component, when the mass ratio of (A) component: (B) component is 90: 10-70: 30 mentioned above, and (A) component is polyether modified silicone, Triclosans are preferred.
本発明では、防臭効果を更に高める目的で、上記成分に加えて（Ｄ）成分の消臭基材を含有することが好ましい。消臭基材とは、悪臭物質の濃度を減じることができる物質、および悪臭物質の濃度は減じないものの悪臭強度を低減させたと感じさせる物質である。具体的には、ベタイン化合物などの化学的消臭法に属する消臭基材、シクロデキストリン、金属石けんなどの包摂系消臭基材、香料などの主に感覚的消臭法に属する消臭基材などが挙げられる。その中でも感覚的消臭機構と化学的消臭機構をいずれも有する植物抽出系の消臭基材が防臭効果の観点から好ましい。該消臭基材は、その抽出物が消臭作用を有するものであれば、上記植物の種類が特に制限されるものではなく、具体的には、ローズマリー、セージ、オウゴン、オレガノ、マジョラム、ブラックミント、メボウキ、タチジャコウ、タイム、メリッサ、ナギナタコウジュ、セボリーなどのシソ科植物、グローブ、ユーカリ等のフツモモ科植物、バラ科植物、ヒノキ科植物、レンギョウ等のモクセイ科植物、スオウ、モウセンゴケ、コブシ、ホオノキ、ダイオウ、ヘンナ、フキタンポポ、ホップ、ヤロウ等の植物からの抽出物が挙げられる。これらの中でも、本発明において特に好ましい消臭基材は、ローズマリー、セージ、ヘンナ、フキタンポポからの抽出物である。上記植物抽出物は、１種単独で又は２種以上を適宜組み合わせて使用することができる。
ここで、本発明においては、（Ａ）成分がポリエーテル変性シリコーンであり、かつ、（Ｃ）成分がトリクロサン類であり、さらに（Ａ）成分：（Ｂ）成分の質量比が９０：１０〜７０：３０である場合に、さらに消臭基材、例えばローズマリー抽出物及びヘンナ抽出物からなる群より選ばれる消臭基材を含むのが好ましい。
In the present invention, in order to further enhance the deodorizing effect, it is preferable to contain a deodorizing base material of component (D) in addition to the above components. The deodorant base material is a substance that can reduce the concentration of malodorous substances, and a substance that does not reduce the concentration of malodorous substances but that makes it feel that the malodor intensity is reduced. Specifically, deodorant base materials belonging to chemical deodorization methods such as betaine compounds, inclusion deodorization base materials such as cyclodextrins and metal soaps, and deodorant groups mainly belonging to sensory deodorization methods Materials. Among these, a plant extraction-type deodorizing base material having both a sensory deodorizing mechanism and a chemical deodorizing mechanism is preferred from the viewpoint of the deodorizing effect. The deodorant base material is not particularly limited as long as the extract has a deodorizing action, and specifically, rosemary, sage, ougon, oregano, marjoram, Black mint, burdock, ginger, thyme, melissa, naginata, savory, etc., glove, eucalyptus, etc. And extracts from plants such as honoki, daiou, henna, dandelion, hops, and yarrow. Among these, a particularly preferred deodorant base material in the present invention is an extract from rosemary, sage, henna, and dandelion. The said plant extract can be used individually by 1 type or in combination of 2 or more types.
Here, in the present invention, the component (A) is a polyether-modified silicone, the component (C) is a triclosan, and the mass ratio of the component (A) :( B) is 90:10 In the case of 70:30, it is preferable to further contain a deodorizing substrate, for example, a deodorizing substrate selected from the group consisting of a rosemary extract and a henna extract.
また、本発明において、これらの植物からの抽出方法は、特に限定されないが、例えば以下のような方法で得ることができる。
即ち、原料となる植物の全部又は根部、茎部、葉部、種子部、花部などをそのまま、あるいは粉状にして極性溶媒に浸漬し、室温から溶媒還流温度までの温度で０．５〜２４時間、好ましくは１〜１０時間浸漬する。必要に応じて加熱する上記極性溶媒としては、水、エタノール、プロピレングリコール、ジプロピレングリコール、ジオキサン、メタノール、アセトン、ジエチルエーテル、エチレンクロライド及びイソプロパノールなどの有機溶媒が挙げられるが、特に水を溶媒として抽出した消臭基剤が消臭効果において優れている。必要に応じて加熱後、すぐに又は数日間室温でさらに浸漬した後、濾過、遠心分離などの方法で抽出液を残査から分離する。得られた抽出液をそのまま消臭基剤として用いてもよいが、好ましくは蒸留等で溶媒を除去する方法である。
本発明の組成物において、上記植物から抽出した消臭基剤の配合量は、特に制限されるものではないが、通常、組成物の全質量をベースとして、０．０１〜１０質量％とするのがよく、好ましくは０．１〜５質量％、更に好ましくは０．５〜２質量％が好適である。
In the present invention, the extraction method from these plants is not particularly limited, and can be obtained by the following method, for example.
That is, all or the root part, stem part, leaf part, seed part, flower part, etc. of the plant as a raw material are immersed in a polar solvent as it is or in powder form, and the temperature from room temperature to the solvent reflux temperature is 0.5 to Soak for 24 hours, preferably 1 to 10 hours. Examples of the polar solvent to be heated as necessary include organic solvents such as water, ethanol, propylene glycol, dipropylene glycol, dioxane, methanol, acetone, diethyl ether, ethylene chloride, and isopropanol. The extracted deodorant base is excellent in the deodorizing effect. If necessary, immediately after heating or after further immersion at room temperature for several days, the extract is separated from the residue by filtration, centrifugation, or the like. Although the obtained extract may be used as it is as a deodorant base, it is preferably a method of removing the solvent by distillation or the like.
In the composition of the present invention, the amount of the deodorant base extracted from the plant is not particularly limited, but is usually 0.01 to 10% by mass based on the total mass of the composition. It is preferably 0.1 to 5% by mass, more preferably 0.5 to 2% by mass.
さらに、本発明には、液体柔軟剤組成物の保存安定性を確保するため、上記成分に加えて、ノニオン性界面活性剤と水溶性溶剤を含有することができる。
ノニオン性界面活性剤としては、例えば炭素数８〜２０のアルキル基又はアルケニル基を１つ以上有するポリオキシアルキレンアルキルエーテルが好ましく、特にオキシアルキレン基が平均２〜５０モル付加されたものが好ましい。さらに下記一般式（ＶＩＩ）で表されるノニオン性界面活性剤が好ましい。
Ｒ1−Ｔ−［（Ｒ2Ｏ）p−Ｈ］q （ＶＩＩ）
（式中、Ｒ1は、炭素数１０〜１８、好ましくは１２〜１８のアルキル基又はアルケニル基であり、Ｒ2は炭素数２又は３のアルキレン基であり、好ましくはエチレン基である。ｐは平均付加モル数であり、２〜５０、好ましくは５〜３０、特に好ましくは５〜２０の数を示す。Ｔは−Ｏ−、−Ｎ−、−ＮＨ−、−Ｎ（Ｃ2Ｈ4ＯＨ）−、−ＣＯＮ−、−ＣＯＮＨ−又はＣＯＮ（Ｃ2Ｈ4ＯＨ）−であり、Ｔが−Ｏ−、−ＮＨ−、−Ｎ（Ｃ2Ｈ4ＯＨ）−、−ＣＯＮＨ−、又は−ＣＯＮ（Ｃ2Ｈ4ＯＨ）−の場合は、ｑは１であり、Ｔが−Ｎ−又は−ＣＯＮ−の場合は、ｑは２である。）
Furthermore, in order to ensure the storage stability of the liquid softening agent composition, the present invention may contain a nonionic surfactant and a water-soluble solvent in addition to the above components.
As the nonionic surfactant, for example, a polyoxyalkylene alkyl ether having at least one alkyl group or alkenyl group having 8 to 20 carbon atoms is preferable, and an average of 2 to 50 mol of an oxyalkylene group is particularly preferable. Furthermore, the nonionic surfactant represented by the following general formula (VII) is preferable.
R 1 -T - [(R 2 O) p -H] q (VII)
(In the formula, R 1 is an alkyl or alkenyl group having 10 to 18 carbon atoms, preferably 12 to 18 carbon atoms, and R 2 is an alkylene group having 2 or 3 carbon atoms, preferably an ethylene group. Is the average number of moles added, and represents a number of 2 to 50, preferably 5 to 30, particularly preferably 5 to 20. T represents —O—, —N—, —NH—, —N (C 2 H 4 OH) -, - CON -, - CONH- , or CON (C 2 H 4 OH) - and is, T is -O -, - NH -, - N (C 2 H 4 OH) -, - CONH-, or In the case of —CON (C 2 H 4 OH) —, q is 1, and in the case where T is —N— or —CON—, q is 2.)
上記一般式（ＶＩＩ）の化合物の具体例として、下記一般式（ＶＩＩＩ）、（ＩＸ）で表される化合物を挙げることができる。
Ｒ1−Ｏ−（Ｃ2Ｈ4Ｏ）r−Ｈ （ＶＩＩＩ）
（式中、Ｒ1は前記と同じ意味であり、ｒは平均付加モル数であり、２〜５０、好ましくは５〜３０の数である。）
Ｒ1−Ｏ−（Ｃ2Ｈ4Ｏ）s（Ｃ3Ｈ6Ｏ）t−Ｈ （ＩＸ）
（式中、Ｒ1は前記と同じ意味であり、ｓ及びｔは平均付加モル数であり、ｓは２〜４０、好ましくは５〜３０の数であり、ｔは１〜２０、好ましくは１〜１０の数である。（Ｃ2Ｈ4Ｏ）と（Ｃ3Ｈ6Ｏ）はランダム又はブロック付加体であってもよい。）
ノニオン活性剤の配合量は、組成物の全質量をベースとして、０．１〜２０質量％とするのがよく、特に０．５〜１５質量％、更に１〜１０質量％が好ましい。このような配合量とすることにより、保存安定性の向上効果を十分なものとすることができ、かつ、効果が飽和に達した際の余分な添加を抑えて経済性を図ることが可能となり、さらに柔軟処理時の泡立ちの点からも好ましいものとすることができる。
Specific examples of the compound of the general formula (VII) include compounds represented by the following general formulas (VIII) and (IX).
R 1 —O— (C 2 H 4 O) r —H (VIII)
(In the formula, R 1 has the same meaning as described above, and r is the average number of added moles, which is 2 to 50, preferably 5 to 30.)
R 1 —O— (C 2 H 4 O) s (C 3 H 6 O) t —H (IX)
(Wherein R 1 has the same meaning as described above, s and t are average added mole numbers, s is a number of 2 to 40, preferably 5 to 30, and t is 1 to 20, preferably 1) The number is from 10. (C 2 H 4 O) and (C 3 H 6 O) may be random or block adducts.
The blending amount of the nonionic active agent is preferably 0.1 to 20% by mass, particularly 0.5 to 15% by mass, and more preferably 1 to 10% by mass, based on the total mass of the composition. By using such a blending amount, the effect of improving the storage stability can be made sufficient, and it becomes possible to achieve economics by suppressing excessive addition when the effect reaches saturation. Furthermore, it can be preferable from the viewpoint of foaming during the flexible treatment.
水溶性溶剤としては、エタノール、イソプロパノール、グリセリン、エチレングリコール、プロピレングリコール、ジエチレングリコール、ジプロピレングリコール、ヘキシレングリコール、ポリオキシエチレンフェニルエーテル、及び下記一般式（Ｘ）で表わされる水溶性溶剤から選ばれる溶媒成分を配合することが好ましい。
Ｒ3−Ｏ−（Ｃ2Ｈ4Ｏ）y−（Ｃ3Ｈ6Ｏ）z−Ｈ （Ｘ）
（式中、Ｒ3は、炭素数１〜８、好ましくは２〜６のアルキル基又はアルケニル基である。ｙ及びｚは平均付加モル数であり、ｙは２〜５０、好ましくは２〜３０、ｚは０〜５０、好ましくは０〜２０の数を示す。）
中でも好ましい例としては、エタノール、エチレングリコール、ブチルカルビトール、プロピレングリコール、ジエチレングリコールモノプロピレングリコールモノブチルエーテル[Ｃ4Ｈ9（Ｃ3Ｈ6Ｏ）（Ｃ2Ｈ4Ｏ）２Ｈ]等が挙げられる。
これらの（Ｆ）成分の配合量は、組成物の全質量をベースとして、０．１〜３０質量％とするのがよく、好ましくは２〜２０質量％、さらに好ましくは５〜１５質量％とすることができる。
The water-soluble solvent is selected from ethanol, isopropanol, glycerin, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, hexylene glycol, polyoxyethylene phenyl ether, and a water-soluble solvent represented by the following general formula (X). It is preferable to mix a solvent component.
R 3 —O— (C 2 H 4 O) y — (C 3 H 6 O) z —H (X)
(In the formula, R 3 is an alkyl or alkenyl group having 1 to 8 carbon atoms, preferably 2 to 6 carbon atoms. Y and z are average added mole numbers, and y is 2 to 50, preferably 2 to 30. Z represents a number of 0 to 50, preferably 0 to 20.)
Among them, preferred examples include ethanol, ethylene glycol, butyl carbitol, propylene glycol, diethylene glycol monopropylene glycol monobutyl ether [C 4 H 9 (C 3 H 6 O) (C 2 H 4 O) 2 H] and the like.
The blending amount of these components (F) should be 0.1 to 30% by mass, preferably 2 to 20% by mass, more preferably 5 to 15% by mass, based on the total mass of the composition. can do.
本発明では、組成物の芳香のために香料を添加することができる。使用される香料原料のリストは、様々な文献、例えば「Ｐｅｒｆｕｍｅ ａｎｄ Ｆｌａｖｏｒ Ｃｈｅｍｉｃａｌｓ 」，Ｖｏｌ．Ｉａｎｄ II，Ｓｔｅｆｆｅｎ Ａｒｃｔａｎｄｅｒ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９４）および「合成香料 化学と商品知識」、印藤元一著、化学工業日報社（１９９６）および「Ｐｅｒｆｕｍｅ ａｎｄ Ｆｌａｖｏｒ Ｍａｔｅｒｉａｌｓ ｏｆ Ｎａｔｕｒａｌ Ｏｒｉｇｉｎ 」，Ｓｔｅｆｆｅｎ Ａｒｃｔａｎｄｅｒ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９４ ）および「香りの百科」、日本香料協会編、朝倉書店（１９８９）および「Ｐｅｒｆｕｍｅｒｙ Ｍａｔｅｒｉａｌ Ｐｅｒｆｏｒｍａｎｃｅ Ｖ．３．３」，Ｂｏｅｌｅｎｓ Ａｒｏｍａ Ｃｈｅｍｉｃａｌ Ｉｎｆｏｒｍａｔｉｏｎ Ｓｅｒｖｉｃｅ（１９９６）および「Ｆｌｏｗｅｒ ｏｉｌｓ ａｎｄ Ｆｌｏｒａｌ Ｃｏｍｐｏｕｎｄｓ Ｉｎ Ｐｅｒｆｕｍｅｒｙ」，Ｄａｎｕｔｅ Ｌａｊａｕｊｉｓ Ａｎｏｎｉｓ，Ａｌｌｕｒｅｄ Ｐｕｂ．Ｃｏ．（１９９３）等で見られ、それぞれを引用することにより本明細書の開示の一部とされる。 In the present invention, a fragrance can be added for the fragrance of the composition. A list of perfume ingredients used can be found in various documents such as “Perfume and Flavor Chemicals”, Vol. Iand II, Steffen Arctander, Allured Pub. Co. (1994) and "Synthetic fragrance chemistry and commercial knowledge", Motoichi Into, Chemical Industry Daily (1996) and "Perfume and Flavor Materials of Natural Origin", Stephen Arctander, Allred Pub. Co. (1994) and "Encyclopedia of Scents", edited by the Japan Fragrance Association, Asakura Shoten (1989) and "Performer Material Performance V3.3", Boelens Aroma Chemical Information Service (1996) and "Flower Oils". , Danute Lajaujis Anonis, Allured Pub. Co. (1993), etc., each of which is incorporated herein by reference.
本発明では、組成物の着色のために染料を添加することができる。染料は特に限定されないが、添加の容易さから水溶性染料が好ましく、中でも酸性染料、直接染料から選ばれる水溶性染料の１種又は２種以上であることが好ましい。添加できる染料の具体例は、例えば染料便覧（有機合成化学協会編,昭和４５年７月２０日発行,丸善（株））、染料ノート第２２版（（株）色染社）、法定色素ハンドブック（日本化粧品工業連合会編、１９８８年１１月２８日発行、（株）薬事日報社）等に記載されており、それらを引用することにより本明細書の開示の一部とされる。染料の配合量は、組成物の全質量をベースとして、好ましくは０．０１〜５０ｐｐｍ、より好ましくは０．1〜３０ｐｐｍとすることができる。このような配合量とすることにより、液体柔軟剤組成物に着色された色が非常に薄くなるのを防止でき、着色効果を充分なものとすることができる一方で、液体柔軟剤組成物に着色された色が濃くなりすぎるのを防止できる。 In the present invention, a dye can be added for coloring the composition. The dye is not particularly limited, but is preferably a water-soluble dye from the viewpoint of ease of addition, and among these, one or more water-soluble dyes selected from acidic dyes and direct dyes are preferable. Specific examples of dyes that can be added include, for example, the Dye Handbook (edited by the Society of Synthetic Organic Chemistry, issued July 20, 1969, Maruzen Co., Ltd.), Dye Note 22nd Edition (Colored Co., Ltd.), Legal Dye Handbook (Japan Cosmetic Industry Federation edited, issued on November 28, 1988, Yakuho Nippo Co., Ltd.) and the like, which are incorporated herein by reference. The blending amount of the dye is preferably 0.01 to 50 ppm, more preferably 0.1 to 30 ppm, based on the total mass of the composition. By setting it as such a compounding quantity, it can prevent that the color colored by the liquid softening agent composition becomes very thin, and can make a coloring effect sufficient, On the other hand, in a liquid softening agent composition It is possible to prevent the colored color from becoming too dark.
本発明では、組成物の香気安定性や色調安定性向上のため、酸化防止剤を添加することができる。酸化防止剤としては、一般に知られている天然系酸化防止剤、合成系酸化防止剤ともに使用できる。具体的には、アスコルビン酸、アスコルビン酸パルミテート、没食子酸プロピルの混合物、ＢＨＴ（ブチル化ヒドロキシトルエン）、ＢＨＡ（ブチル化ヒドロキシアニソール）、没食子酸プロピル、及びクエン酸の混合物、ハイドロキノン、三級ブチルハイドロキノン、天然のトコフェロール系化合物、没食子酸の長鎖エステル（Ｃ8〜Ｃ22）、例えば没食子酸ドデシル、チバスペシャルティケミカル（株）から入手可能なイルガノックス系化合物、クエン酸及び／またはクエン酸イソプロピル、１−ヒドロキシエチリデン−１，１−ジホスホン酸（エチドロン酸）、４，５−ジヒドロキシ−ｍ−ベンゼンスルホン酸／ナトリウム塩、ジメトキシフェノール、カテコール、メトキシフェノール、カロチノイド、フラン類、アミノ酸類等が挙げられる。
この中で、液体柔軟剤組成物の外観や保存安定性の観点から、ＢＨＴ（ブチル化ヒドロキシトルエン）、メトキシフェノール、トコフェロール系化合物等が好ましい。
酸化防止剤の配合量は、０．０１〜１質量％の範囲で使用されることが好ましい。
In the present invention, an antioxidant can be added to improve the aroma stability and color tone stability of the composition. As the antioxidant, generally known natural antioxidants and synthetic antioxidants can be used. Specifically, a mixture of ascorbic acid, ascorbyl palmitate, propyl gallate, BHT (butylated hydroxytoluene), BHA (butylated hydroxyanisole), propyl gallate, and citric acid, hydroquinone, tertiary butylhydroquinone Natural tocopherol compounds, long-chain esters of gallic acid (C8 to C22) such as dodecyl gallate, irganox compounds available from Ciba Specialty Chemicals, citric acid and / or isopropyl citrate, 1- Hydroxyethylidene-1,1-diphosphonic acid (etidronic acid), 4,5-dihydroxy-m-benzenesulfonic acid / sodium salt, dimethoxyphenol, catechol, methoxyphenol, carotenoid, furans, amino acids, etc. That.
Among these, BHT (butylated hydroxytoluene), methoxyphenol, tocopherol compounds, and the like are preferable from the viewpoint of the appearance and storage stability of the liquid softening agent composition.
It is preferable that the compounding quantity of antioxidant is used in 0.01-1 mass%.
本発明では、消泡剤を配合することができる。消泡剤としては、例えばシリコーン系消泡剤、アルコール系消泡剤、エステル系消泡剤、鉱油系消泡剤、植物油系消泡剤、及び合成油系消泡剤等が挙げられるが、柔軟剤計量時の泡立ちを抑えて計量性を向上させる観点からシリコーン系の消泡剤が好ましい。シリコーン系消泡剤としては、オイル型消泡剤、コンパウンド型消泡剤、自己乳化型消泡剤、エマルション型消泡剤、粉末型消泡剤及び固形型消泡剤等が挙げられ、この中でも、自己乳化型消泡剤及びエマルション型消泡剤が好ましい。消泡剤の配合量は特に限定されないが、組成物の全質量をベースとして、０．１ｐｐｍ〜１質量％とすることができ、さらに好ましくは１ｐｐｍ〜０．０５質量％とすることができる。
本発明の液体柔軟剤組成物には、本発明の効果を妨げない範囲で、通常の家庭用仕上げ剤に使用されている添加剤などを使用することができる。そのような添加剤として、具体的には、カチオン性界面活性剤、ヘキサン酸とグリセリンまたはペンタエリスリトールとの部分エステル化物や、食塩、塩化アンモニウム、塩化カルシウム、塩化マグネシウム、塩化カリウム等の水溶性塩、流動パラフィン、高級アルコールなどの油剤、尿素、炭化水素、非イオン性セルロース誘導体、紫外線吸収剤、蛍光増白剤、後述するｐＨ調整剤等が挙げられる。なお、アニオン性界面活性剤、アニオン性高分子化合物は、配合する場合には、シリコーン化合物の吸着効果を考慮して、（Ｂ）成分のカチオン性高分子化合物の含有量よりも低い量で配合するのがよい。
In the present invention, an antifoaming agent can be blended. Examples of the antifoaming agent include silicone-based antifoaming agents, alcohol-based antifoaming agents, ester-based antifoaming agents, mineral oil-based antifoaming agents, vegetable oil-based antifoaming agents, and synthetic oil-based antifoaming agents. A silicone-based antifoaming agent is preferred from the viewpoint of improving foamability by suppressing foaming during measurement of the softening agent. Examples of silicone-based antifoaming agents include oil-type antifoaming agents, compound-type antifoaming agents, self-emulsifying antifoaming agents, emulsion-type antifoaming agents, powder-type antifoaming agents, and solid-type antifoaming agents. Of these, self-emulsifying antifoaming agents and emulsion antifoaming agents are preferred. Although the compounding quantity of an antifoamer is not specifically limited, Based on the total mass of a composition, it can be 0.1 ppm-1 mass%, More preferably, it can be 1 ppm-0.05 mass%.
In the liquid softening agent composition of the present invention, additives and the like used in ordinary household finishing agents can be used as long as the effects of the present invention are not hindered. Specific examples of such additives include cationic surfactants, partially esterified products of hexanoic acid and glycerin or pentaerythritol, and water-soluble salts such as sodium chloride, ammonium chloride, calcium chloride, magnesium chloride, and potassium chloride. And oils such as liquid paraffin and higher alcohol, urea, hydrocarbons, nonionic cellulose derivatives, ultraviolet absorbers, fluorescent brighteners, pH adjusters described later, and the like. In addition, an anionic surfactant and an anionic polymer compound are blended in an amount lower than the content of the cationic polymer compound of the component (B) in consideration of the adsorption effect of the silicone compound. It is good to do.
本発明の液体柔軟剤組成物のｐＨは特に限定されないが、２〜１０の範囲であることが好ましく、３〜７の範囲であることがより好ましい。必要に応じて、塩酸、硫酸、リン酸、アルキル硫酸、安息香酸、パラトルエンスルホン酸、クエン酸、リンゴ酸、コハク酸、乳酸、グリコール酸、ヒドロキシエタンジホスホン酸、フィチン酸、エチレンジアミン四酢酸、トリエタノールアミン、ジエタノールアミン、ジメチルアミン、Ｎ−メチルエタノールアミン、Ｎ−メチルジエタノールアミン等の短鎖アミン化合物、水酸化ナトリウム等のアルカリ金属水酸化物、アルカリ金属炭酸塩、アルカリ金属珪酸塩などのｐＨ調整剤を用いることができる。
本発明の液体柔軟剤組成物は、上記（Ａ）〜（Ｃ）成分及び場合により任意成分を含有し、通常、残部は水である。本発明の液体柔軟剤組成物の製造は、上記各成分を容器に充填し、これを十分に撹拌した後に水を添加して均一になるまで十分に撹拌することにより行うことができる。これらの成分の添加は、一緒に又は任意の順序で行うことができるが、例えば、（Ａ）成分及び（Ｃ）成分を添加・撹拌した後、水を添加して撹拌し、次いで、成分（Ｂ）を添加・撹拌することにより本発明の柔軟剤組成物を製造することができる。また、本発明の液体柔軟剤組成物は、適度な濃度に希釈して使用される。使用方法は特に限定されないが、衣料を通常の洗濯を行い、すすぎの段階ですすぎ水に本発明の組成物を溶解させて処理を行ったり、また、たらいのような容器を用い本発明の組成物を水に溶解させ、更に衣料を入れて浸漬処理する方法などが挙げられる。繊維製品の処理はいずれの方法で行ってもよいが、浴比（繊維製品に対する処理液の比率）は３〜１００倍、特に５〜５０倍であることが好ましい。
以下、実施例及び比較例を示し、本発明を具体的に説明するが、本発明はこれに限定されるものではない。なお、下記例で％は質量％を示す。
Although the pH of the liquid softening agent composition of this invention is not specifically limited, It is preferable that it is the range of 2-10, and it is more preferable that it is the range of 3-7. As necessary, hydrochloric acid, sulfuric acid, phosphoric acid, alkyl sulfuric acid, benzoic acid, paratoluenesulfonic acid, citric acid, malic acid, succinic acid, lactic acid, glycolic acid, hydroxyethanediphosphonic acid, phytic acid, ethylenediaminetetraacetic acid, PH adjustment of short chain amine compounds such as triethanolamine, diethanolamine, dimethylamine, N-methylethanolamine, N-methyldiethanolamine, alkali metal hydroxides such as sodium hydroxide, alkali metal carbonates, and alkali metal silicates An agent can be used.
The liquid softener composition of the present invention contains the above components (A) to (C) and optionally an optional component, and the balance is usually water. The liquid softening agent composition of the present invention can be produced by filling each of the above components in a container, sufficiently stirring the mixture, and then adding water to the mixture until it becomes uniform. These components can be added together or in any order. For example, after the components (A) and (C) are added and stirred, water is added and stirred, and then the components ( The softener composition of the present invention can be produced by adding and stirring B). In addition, the liquid softener composition of the present invention is used after being diluted to an appropriate concentration. The method of use is not particularly limited, but the laundry is usually washed, and the composition of the present invention is dissolved in the rinse water at the rinsing stage, and the composition of the present invention is used using a container such as a tub. Examples include a method in which an object is dissolved in water, and further, clothing is added to perform immersion treatment. The fiber product may be treated by any method, but the bath ratio (the ratio of the treatment liquid to the fiber product) is preferably 3 to 100 times, particularly preferably 5 to 50 times.
EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not limited to this. In the following examples,% indicates mass%.
以下の表１に記載の（Ａ）シリコーン化合物及び表３に記載の（Ｃ）抗菌性化合物、及び場合により表４に記載の消臭基材及び共通成分１〜４のいずれかを、５００ｍｌビーカーに充填し、これを撹拌羽を用いて十分に撹拌した。次に、撹拌しながら、イオン交換水を添加し、さらに撹拌しながら、表２に記載の（Ｂ）カチオン性を有する水溶性高分子化合物を添加し撹拌後、均一になるまで十分に撹拌して、４００ｇの液体柔軟剤組成物を調製した。尚、各成分の配合量は、表５に示す組成物に順じたものとした。
このようにして得た各液体柔軟剤組成物（実施例１〜１５及び比較例１〜３）について、以下に記載する〔風合い評価方法〕及び〔防臭効果評価法〕に従って、風合い及び防臭効果を評価した。結果を表５に記載する。
A 500 ml beaker containing (A) the silicone compound described in Table 1 below and (C) the antibacterial compound described in Table 3 and optionally the deodorizing substrate and the common components 1 to 4 described in Table 4. The mixture was fully stirred using a stirring blade. Next, with stirring, ion-exchanged water is added, and further with stirring, (B) the water-soluble polymer compound having a cationic property shown in Table 2 is added and stirred, and then sufficiently stirred until uniform. 400 g of a liquid softener composition was prepared. In addition, the compounding quantity of each component shall follow the composition shown in Table 5.
About each liquid softening agent composition (Examples 1-15 and Comparative Examples 1-3) obtained in this way, according to the [texture evaluation method] and the [deodorization effect evaluation method] described below, the texture and the deodorization effect were obtained. evaluated. The results are listed in Table 5.
オルガノハイドロジェンポリシロキサン
Organohydrogenpolysiloxane
ポリオキシアルキレン化合物
ＣＨ2＝ＣＨＣＨ2Ｏ−（Ｃ2Ｈ4Ｏ）10−ＣＨ3
Polyoxyalkylene compound CH 2 = CHCH 2 O- (C 2 H 4 O) 10 -CH 3
（共通成分１）
下記の成分は、〔 〕内に示した量（有姿での配合量）を添加した。
1-1 ケーソンＣＧ−ＩＣＰ（ローム＆ハース社製） 〔１００ｐｐｍ〕
1-2 ソフタノール５０〔C12-14第2級アルコールEO5付加物、日本触媒(株)製） 〔４％〕
1-3 ９５％合成未変性エタノール（日本合成アルコール(株)製） 〔１０％〕
(Common ingredient 1)
The following components were added in the amount shown in [] (the amount in solid form).
1-1 Caisson CG-ICP (Rohm & Haas) [100ppm]
1-2 Softanol 50 [C12-14 secondary alcohol EO5 adduct, manufactured by Nippon Shokubai Co., Ltd.] [4%]
1-3 95% synthetic unmodified ethanol (manufactured by Nippon Synthetic Alcohol Co., Ltd.) [10%]
（共通成分２）
下記の成分は、〔 〕内に示した量（有姿での配合量）を添加した。
2-1 プロテアーゼキセルＢＤＮ（アビシア(株)製） 〔５ｐｐｍ〕
2-2 アミゼット５Ｃ（ヤシ油脂肪酸モノエタノールアミドEO5付加物、川研ファインケミカル(株))〔４％〕
2-3 ９５％合成未変性エタノール（日本合成アルコール(株)製） 〔１０％〕
2-4 X-50-963（シリコーン系エマルション型消泡剤、信越化学工業(株)製）〔１５ｐｐｍ〕
2-5 C.I.Acid Yellow 3(B.A.S.F社製、キノリンイエローWS 〔３ｐｐｍ〕
(Common component 2)
The following components were added in the amount shown in [] (the amount in solid form).
2-1 Protease Xelel BDN (Avisia Co., Ltd.) [5ppm]
2-2 Amidette 5C (coconut oil fatty acid monoethanolamide EO5 adduct, Kawaken Fine Chemicals Co., Ltd.) [4%]
2-3 95% synthetic unmodified ethanol (manufactured by Nippon Synthetic Alcohol Co., Ltd.) [10%]
2-4 X-50-963 (Silicone emulsion defoamer, manufactured by Shin-Etsu Chemical Co., Ltd.) [15ppm]
2-5 CIAcid Yellow 3 (manufactured by BASF, quinoline yellow WS [3ppm]
（共通成分３）
下記の成分は、〔 〕内に示した量（有姿での配合量）を添加した。
3-1 Ｐｒｏｔｅｃｔ ＢＮ（ＢＡＳＦ（株）製）〔２０ｐｐｍ〕
3-2 Ｌｕｔｅｎｓｏｌ ＴＯ ５（イソトリデカノールEO5付加物、BASF(株)製）〔４％〕
3-3 ９５％合成未変性エタノール（日本合成アルコール(株)製）〔１０％〕
3-4 X-50-963（シリコーン系エマルション型消泡剤、信越化学工業(株)製）〔１５ｐｐｍ〕
3-5 C.I.Direct Red 225(日本化薬(株)製、カヤフェクトレッドB) 〔３ｐｐｍ〕
3-6 香料組成物Ａ （表６記載）〔０．３％〕
(Common component 3)
The following components were added in the amount shown in [] (the amount in solid form).
3-1 Protect BN (BASF Co., Ltd.) [20ppm]
3-2 Lutensol TO 5 (isotridecanol EO5 adduct, manufactured by BASF Corp.) [4%]
3-3 95% synthetic unmodified ethanol (manufactured by Nippon Synthetic Alcohol Co., Ltd.) [10%]
3-4 X-50-963 (Silicone emulsion defoamer, manufactured by Shin-Etsu Chemical Co., Ltd.) [15ppm]
3-5 CIDirect Red 225 (Nippon Kayaku Co., Ltd., Kayafect Red B) [3ppm]
3-6 Fragrance composition A (described in Table 6) [0.3%]
（共通成分４）
下記の成分は、〔 〕内に示した量（有姿での配合量）を添加した。
4-1 ケーソンＣＧ−ＩＣＰ〔２０ｐｐｍ〕
4-2 ソフタノール９０（C12-14第2級アルコールEO9付加物、日本触媒(株)製）〔３％〕
4-3 ９５％合成未変性エタノール（日本合成アルコール(株)製）〔１０％〕
4-4 X-50-963（シリコーン系エマルション型消泡剤、信越化学工業(株)製）〔１５ｐｐｍ〕
4-5 C.I.Acid Blue 9((株)洛東化学工業製、ラクトーブリリアントブル-FCF)〔３ｐｐｍ〕
4-6 香料組成物Ｂ（表６記載）〔０．３％〕
(Common component 4)
The following components were added in the amount shown in [] (the amount in solid form).
4-1 Caisson CG-ICP [20ppm]
4-2 Softanol 90 (C12-14 secondary alcohol EO9 adduct, manufactured by Nippon Shokubai Co., Ltd.) [3%]
4-3 95% synthetic unmodified ethanol (manufactured by Nippon Synthetic Alcohol Co., Ltd.) [10%]
4-4 X-50-963 (Silicone emulsion defoamer, manufactured by Shin-Etsu Chemical Co., Ltd.) [15ppm]
4-5 CIAcid Blue 9 (manufactured by Pingtung Chemical Co., Ltd., Lacto Brilliant Bull-FCF) [3ppm]
4-6 Fragrance composition B (described in Table 6) [0.3%]
〔風合い評価方法〕
(１)柔軟剤組成物による処理方法
（試験布の調整）市販の綿ニット（綿１００％）とポリエステルジャージ（ポリエステル１００％）を市販衣料用洗剤「トップ」（ライオン（株）製、成分：界面活性剤（アルファスルホ脂肪酸エステルナトリウム、脂肪酸ナトリウム、直鎖アルキルベンゼン系、ポリオキシエチレンアルキルエーテル）、水軟化剤、アルカリ剤、酵素、蛍光増白剤）により、家庭用二槽式洗濯機を用いて洗浄１５分（洗剤は標準量使用、浴比３０倍、４５℃水道水）→脱水５分の工程を２サイクル繰り返した後、流水すすぎ１５分→脱水５分の工程を５回繰り返し、自然乾燥したものを試験布とした。
（柔軟剤による処理）上記処理を行った、綿ニット１００ｇとポリエステルジャージ１００ｇを各々市販衣料用洗剤「トップ」（ライオン（株）製、成分：界面活性剤（アルファスルホ脂肪酸エステルナトリウム、脂肪酸ナトリウム、直鎖アルキルベンゼン系、ポリオキシエチレンアルキルエーテル）、水軟化剤、アルカリ剤、酵素、蛍光増白剤）で１５分洗浄し（洗剤は標準使用量、浴比３０倍、２５℃の水道水使用）、ためすすぎ２回目に、表に示す柔軟剤組成物を水量３リットルに対して１．５ｇ（ただし、実施例１１は０．５ｇ）加えて、衣料の柔軟処理（浴比３０倍、２５℃の水道水使用、３分）を行った。その後、２０℃、４０％ＲＨの条件で自然乾燥し、以下の評価を行った。
[Texture evaluation method]
(1) Treatment method with softener composition (Adjustment of test cloth) Commercial cotton knit (100% cotton) and polyester jersey (100% polyester) made from commercial clothing detergent "Top" (manufactured by Lion Corporation, ingredients: Using a two-tank washing machine for home use with surfactants ( sodium alphasulfo fatty acid ester, sodium fatty acid, linear alkylbenzene, polyoxyethylene alkyl ether), water softener, alkali agent, enzyme, fluorescent brightener) Wash for 15 minutes (use standard amount of detergent, bath ratio 30 times, tap water at 45 ° C) → Repeat dehydration 5 minutes 2 cycles, then rinse with running water 15 minutes → Dewater 5 minutes 5 times The dried one was used as a test cloth.
(Treatment with softener) 100 g of cotton knit and 100 g of polyester jersey subjected to the above treatment were each made into a commercial clothing detergent “Top” (manufactured by Lion Co., Ltd., ingredients: surfactant ( alphasulfo fatty acid ester sodium , fatty acid sodium, Linear alkyl benzene, polyoxyethylene alkyl ether), water softener, alkali agent, enzyme, fluorescent brightener)) for 15 minutes (detergent is 30% standard bath, tap water at 25 ° C) Therefore, in the second rinsing, 1.5 g of the softener composition shown in the table is added to 3 liters of water (however, 0.5 g in Example 11) to soften the clothing (bath ratio 30 times, 25 ° C. Using tap water for 3 minutes). Then, it air-dried on 20 degreeC and 40% RH conditions, and performed the following evaluation.
(２)風合い（滑らかさ、柔軟性）の評価は、柔軟剤を使用せずに処理した綿ニット、ポリエステルジャージを対照として専門パネラー１０人による官能一対比較を行い、以下に示す評価基準で評価を行った。
＋２：対照よりはっきり良好
＋１：対照よりやや良好
０ ：対照とほぼ同じ
−１：対照の方がやや良好
−２：対照の方がはっきり良好
その評点の平均をとり、１．５〜２．０点を◎、１．０以上〜１．４点を○、０．５〜０．９点を△、０．４点以下を×とした。
(2) The texture (smoothness and flexibility) was evaluated by comparing the sensory pair by 10 expert panelists using cotton knit and polyester jersey treated without using a softener as the control, and evaluated according to the evaluation criteria shown below. Went.
+2: Clearly better than the control +1: Slightly better than the control 0: Almost the same as the control -1: Slightly better than the control -2: Clearly better than the control 1.5 to 2.0 Points were marked with ◎, 1.0 to 1.4 points as ◯, 0.5 to 0.9 points as Δ, and 0.4 points or less as x.
〔防臭効果評価法〕
家庭で１年間以上使用したタオルを半裁し、市販衣料用洗剤「トップ」（ライオン（株）製、成分：界面活性剤（アルファスルホ脂肪酸エステルナトリウム、脂肪酸ナトリウム、直鎖アルキルベンゼン系、ポリオキシエチレンアルキルエーテル）、水軟化剤、アルカリ剤、酵素、蛍光増白剤）で５分洗浄し（洗剤は標準使用量、浴比３０倍、２５℃の水道水使用）、ためすすぎを３分間２回行なった。その際、半裁した一方のみためすすぎ２回目に、表に示す柔軟剤組成物を水量３０リットルに対して１０ｇ（ただし、実施例１１は５ｇ）加えて、衣料の柔軟処理（浴比３０倍、２５℃の水道水使用、３分）を行った。又、半裁したもう一方はためすすぎ２回目にも柔軟剤を使用せずに水道水のみで処理を行なった。その後、脱水し、湿度９０％、２５℃で１２時間放置した後のタオルの臭いを１０人のパネラーにより下記の基準で判定し、平均点を求めた。平均点が１．４〜２．０点を◎、０．７〜１．３点を○、０．１〜０．６点を△、０．０点以下を×として判定した。
＋２：対照（柔軟剤未処理）よりはっきり臭いが少ない
＋１：対照よりやや臭いが少ない
０ ：対照とほぼ同じ
−１：対照の方がやや臭いが少ない
−２：対照の方がはっきり臭いが少ない
[Odor control effect evaluation method]
A towel that has been used at home for more than one year is cut in half, and a commercial clothing detergent “Top” (manufactured by Lion Co., Ltd., ingredients: surfactant ( sodium alphasulfo fatty acid ester, sodium fatty acid, linear alkylbenzene, polyoxyethylene alkyl) Ether), water softener, alkali agent, enzyme, fluorescent whitening agent) for 5 minutes (detergent is 30 times the standard amount, bath ratio is used at 25 ° C) and rinsed twice for 3 minutes. It was. At that time, 10 g of the softener composition shown in the table was added to 30 liters of water (however, 5 g in Example 11) for the second rinsing because only one half was cut, and the softening treatment of the clothing (bath ratio 30 times, 25 ° C. tap water was used for 3 minutes). Also, the other half-finished was rinsed and treated with tap water only without using a softening agent. Thereafter, the towel was dehydrated and left to stand for 12 hours at a humidity of 90% and 25 ° C., and the towel was judged by the following panelists according to the following criteria to obtain an average score. An average score of 1.4 to 2.0 points was evaluated as ◎, 0.7 to 1.3 points as ◯, 0.1 to 0.6 points as Δ, and 0.0 or less points as ×.
+2: Slightly less odor than control (no softener treatment) +1: Slightly less odor than control 0: Almost the same as control -1: Slightly less odor in control -2: Slightly less odor in control
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| JP5328084B2 (en) * | 2005-08-05 | 2013-10-30 | ライオン株式会社 | Liquid softener composition |
| JP4712666B2 (en) * | 2005-10-14 | 2011-06-29 | 花王株式会社 | Textile treatment composition |
| JP4841275B2 (en) * | 2006-03-20 | 2011-12-21 | ライオン株式会社 | Finishing composition |
| KR101358540B1 (en) | 2006-08-07 | 2014-02-05 | 라이온 가부시키가이샤 | Liquid softener composition |
| JP2008169534A (en) * | 2006-12-11 | 2008-07-24 | Lion Corp | Liquid finishing agent composition for textile products |
| KR101013154B1 (en) * | 2008-06-13 | 2011-02-10 | 금강실리테크(주) | A fabric treatment for atopic dermatitis prevention |
| DE102008050360A1 (en) * | 2008-10-02 | 2010-04-08 | Süd-Chemie AG | Detergent additive based on clay minerals, as well as its use and process for its preparation |
| JP7515274B2 (en) * | 2020-03-09 | 2024-07-12 | ライオン株式会社 | Cleaning composition for textile products |
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