WO2020095808A1 - Fabric pest repelling composition, and, clothes deodorization method and fabric pest repelling deodorization method using composition - Google Patents

Fabric pest repelling composition, and, clothes deodorization method and fabric pest repelling deodorization method using composition Download PDF

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Publication number
WO2020095808A1
WO2020095808A1 PCT/JP2019/042762 JP2019042762W WO2020095808A1 WO 2020095808 A1 WO2020095808 A1 WO 2020095808A1 JP 2019042762 W JP2019042762 W JP 2019042762W WO 2020095808 A1 WO2020095808 A1 WO 2020095808A1
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WO
WIPO (PCT)
Prior art keywords
clothing
pest repellent
component
repellent composition
deodorizing
Prior art date
Application number
PCT/JP2019/042762
Other languages
French (fr)
Japanese (ja)
Inventor
友裕 田丸
鹿島　誠一
中山　幸治
Original Assignee
大日本除蟲菊株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 大日本除蟲菊株式会社 filed Critical 大日本除蟲菊株式会社
Priority to JP2020556016A priority Critical patent/JP7124113B2/en
Publication of WO2020095808A1 publication Critical patent/WO2020095808A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01M—CATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M29/00—Scaring or repelling devices, e.g. bird-scaring apparatus
    • A01M29/12—Scaring or repelling devices, e.g. bird-scaring apparatus using odoriferous substances, e.g. aromas, pheromones or chemical agents
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/16—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof the nitrogen atom being part of a heterocyclic ring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids

Definitions

  • the present invention relates to a clothing pest repellent composition containing a pest repellent component and a fragrance component, and a clothing deodorizing method using the composition. Further, the present invention relates to a clothing pest repellent and deodorizing method for simultaneously performing pest repellent treatment and deodorant treatment on clothing.
  • the clothing pest control product of Patent Document 1 is one in which a fragrance component such as an acetic acid ester compound and an allyl ester compound is held in a water-absorbent polymer, and by maintaining volatility of the active ingredient for a long period of time, In the storage space such as the drawer, the closet, and the clothing storage box, the larva of the clothing pest can be killed, and an excellent feeding-inhibiting effect can be exhibited.
  • a fragrance component such as an acetic acid ester compound and an allyl ester compound
  • Clothes may have a daily odor such as sweat odor, aging odor, cigarette odor, etc. while wearing. Therefore, in the management of clothing, in addition to controlling the harmful insects of clothing, it is desired to eliminate the bad odor attached to the clothing. In addition, since outer garments are often used every day, living odors attached to clothes on the previous day may cause discomfort when worn the next day, and it is desirable to be able to continuously eliminate odors while going out. Be done.
  • the clothing pest control product of Patent Document 1 is expected to have a deodorant function by using a fragrance component as an active ingredient, but a compound serving as a fragrance component has been selected with a focus on the insect control function against clothing pests, and is peculiar to clothing. There is room for consideration regarding the deodorizing function for bad odors.
  • the present invention has been made in view of the above problems, and a clothing pest repellent composition capable of continuously deodorizing a bad odor that adheres to clothes while performing an insect repellent function, and a clothing deodorant using the composition.
  • the purpose is to provide a method.
  • Another object of the present invention is to provide a method for repelling and deodorizing clothing pests, which is capable of imparting a pest repellent effect and a continuous deodorant effect to clothing at the same time.
  • a clothing pest repellent composition comprising a pest repellent component and a fragrance component,
  • the fragrance component has a deodorizing function of deodorizing a bad odor attached to clothing,
  • the pest repellent component has a continuous function of maintaining the deodorizing function of the fragrance component.
  • the clothing pest repellent composition of the present composition while preparing various clothing pest repellent composition and repeat various tests, a specific pest repellent component sustains the deodorant function of the perfume component. It was completed by newly discovering that it has a function.
  • the perfume component has a deodorant function of deodorizing the bad odor attached to the clothing
  • the pest repellent component has a continuous function of maintaining the deodorant function of the perfume component.
  • the deodorant function of the fragrance component can be maintained for a long period of time to continuously eliminate the bad odor attached to clothes. Therefore, by treating the clothing pest repellent composition of the present invention on clothes before going out, the deodorizing function of the fragrance component is maintained during going out, and it is possible to prevent discomfort due to the bad odor attached to the clothes. You can
  • the pest repellent component is at least one selected from the group consisting of ethyl 3- (N-butylacetamido) propionate, icaridin, and N, N-diethyltoluamide
  • the fragrance component does not have an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure, has 6 to 18 carbon atoms, and has a molecular weight of 98 to 270. It is preferable that the compound has a carbon atom, a hydrogen atom, and an oxygen atom and does not have a sulfur atom, a nitrogen atom, and a halogen atom.
  • the clothing pest repellent composition of the present configuration by combining the specific pest repellent component and the fragrance component described above, the deodorant function of the fragrance component is maintained for a long period of time due to the synergistic effect of the pest repellent component and the fragrance component. Can be sustained.
  • the perfume ingredients are cis-3-hexenol, dihydromyrcenol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenylethyl alcohol, helional, lilial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicyt. It is preferably at least one selected from the group consisting of rate, methyl dihydrojasmonate, linalyl acetate, raspberry ketone, galaxolide, ethylene brushlate, and cyclopentadecanolide.
  • the clothing pest repellent composition of this constitution by containing the above-mentioned fragrance component, the synergistic effect of the pest repellant component and the fragrance component becomes large, and the sustainability of the deodorant function can be improved.
  • the content of the fragrance component is preferably 0.1 to 1.0 w / v%.
  • the content of the fragrance component is in an appropriate range, it is possible to mask the bad odor adhering to the clothing with the aroma and obtain sufficient deodorant properties.
  • the compounding ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is preferably 0.1 to 1.5 as a weight ratio.
  • the clothing pest repellent composition of this configuration since the blending ratio is in an appropriate range, while sufficiently exerting the insect repellent function against the clothing pests by the pest repellent component, the synergistic effect of the pest repellent component and the fragrance component is sufficient. Therefore, the deodorizing function of the fragrance component can be maintained for a long period of time.
  • the characteristic configuration of the clothing deodorizing method according to the present invention for solving the above-mentioned problems A method for deodorizing clothing using the clothing pest repellent composition according to any one of the above, It is to spray-treat the clothing pest repellent composition.
  • the clothing deodorizing method of the present configuration by spraying the clothing pest repellent composition according to any one of the above to the clothing, with the insect repellent function by the pest repellent component, with the pest repellent component and Due to the synergistic effect with the fragrance component, the deodorizing function of the fragrance component continues for a long time. Therefore, by performing the clothing deodorizing method of the present invention before going out, it is possible to prevent the deodorizing function of the fragrance component from continuing while going out and prevent unpleasant sensation from being caused by the bad odor attached to the clothing.
  • the characteristic configuration of the clothing pest repellent deodorant method according to the present invention for solving the above-mentioned problems, A method for deodorizing clothing pests by simultaneously performing pest repellent treatment and deodorant treatment on clothing, A spraying step of spraying a clothing pest repellent composition containing a pest repellent component and a fragrance component on the clothing to be treated, In order to maintain a sufficient pest repellent effect and deodorant effect in the clothing, a changing step of changing the position of spraying the clothing pest repellent composition on the clothing, To include.
  • the clothing to be treated is sprayed with a clothing pest repellent composition containing a pest repellent component and a fragrance component, and further, a sufficient pest repellent effect and deodorant effect in clothing.
  • a clothing pest repellent composition containing a pest repellent component and a fragrance component
  • a sufficient pest repellent effect and deodorant effect in clothing By changing the position at which the clothing pest repellent composition is sprayed on the clothing so as to last, it is possible to impart the pest repellent effect and the continuous deodorant effect to the clothing at the same time in a single treatment. it can.
  • the clothing treated by the method for deodorizing clothing pest repellent of the present invention by the synergistic effect of the pest repellent component and the perfume component, because the deodorant function by the perfume component lasts for a long time, for example, go out all day. Even in such a case, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
  • the clothing pest repellent composition of the present invention is a perfume repellent component having a deodorant function of deodorizing a bad odor attached to clothing, and a pest repellent component having a continuous function of continuing the deodorant function of the perfume component in addition to the pest repellent effect. Contains and.
  • Examples of the pest repellent component which is one of the main components of the clothing pest repellent composition of the present invention include ethyl 3- (N-butylacetamido) propionate (hereinafter referred to as “IR3535”), ikaridin, and N, N. -Diethyltoluamide (hereinafter referred to as “diet”) is used. These can be used alone, but may be used in the form of a mixture of two or more kinds. IR3535, squalidin, and diet have a volatile property and have a high repellent effect against clothing pests, especially mosquitoes or adult mosquitoes.
  • IR3535, squalidin, and diet were conventionally used as pest repellents
  • the present inventors use IR3535, squalidin, and diet to prepare various clothing pest repellent compositions.
  • IR3535, icaridin, and diet have a sustaining function of sustaining the deodorizing function of the specific perfume ingredient described later.
  • the clothing pest repellent composition of the present invention is attached to clothing by spraying treatment or the like to prevent pest repellent components from volatilizing from the clothing in use to prevent approach or contact of clothing pests, and to spawn clothing pests in clothing. While preventing, it is possible to maintain the deodorization of the bad odor attached to the clothes in use for a long period of time.
  • in use means a state in which the clothes are taken out of the storage space and stored again in the storage space. Including the state of being. In the garment being worn, volatilization of the pest repellent component is promoted by the body temperature of the user, so that the approach or contact of the clothing pest can be more effectively prevented. In addition, although there are occasions when clothes are taken off to control the temperature in the field etc., since IR3535, icaridin, and diet have volatility, even clothes that have been taken off during use and left standing outdoors, etc. It is possible to sufficiently prevent the pests from approaching or coming into contact with the clothes.
  • the clothes pest repellent composition of the present invention can be used for clothing without damaging the clothes and the odor of the pest repellent component.
  • the content of the pest repellent component in the clothing pest repellent composition is preferably 0.4 to 10.0 w / v%. In such a range, by applying the clothing pest repellent composition to the clothing by spraying treatment or the like, while exerting a repellent effect against the clothing pests, a synergistic effect with a specific fragrance component described later is exerted, and The durability of the odor function can be improved.
  • the content of the pest repellent component is less than 0.4 w / v%, the repellent effect against clothing pests and the sustainability of the deodorizing function due to the synergistic effect with the perfume component may be insufficient.
  • the content of the pest repellent component exceeds 10.0 w / v%, the pest repellent component is blended in an amount exceeding the amount required to obtain the repellent effect required for practical use, which is economically disadvantageous.
  • the fragrance component which is one of the main components of the clothing pest repellent composition of the present invention, a benzene ring, a benzoic acid ester structure, or does not have an electron conjugated part other than the electron conjugated part derived from a salicylic acid ester structure, carbon A compound having a number of 6 to 18, a molecular weight of 98 to 270, a carbon atom, a hydrogen atom, and an oxygen atom and no sulfur atom, nitrogen atom, or halogen atom is used.
  • Such a compound has an excellent deodorizing function of masking an offensive odor (sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor) attached to clothes with an aroma, and is a pest repellent component in the present invention.
  • the deodorizing function can be maintained for a long time by a synergistic effect with IR3535, icaridin, and diet used as.
  • IR3535, icaridin, and diet used as.
  • Cis-3-hexenol represented by the following formula (hereinafter referred to as “compound A”), the following formula (2):
  • Ethyl linalool represented by the following formula (hereinafter referred to as “compound C”), the following formula (4):
  • Linalool represented by the following formula (hereinafter referred to as “compound D”), the following formula (5):
  • Geraniol represented by the following formula (hereinafter referred to as “compound E”), the following formula (6):
  • Compound K Benzyl benzoate represented by the following (hereinafter referred to as "Compound K”), the following formula (12):
  • Cis-3-hexenyl salicylate represented by the following (hereinafter referred to as “compound M”), the following formula (14):
  • a raspberry ketone (hereinafter, referred to as “compound P”) represented by the following formula (17):
  • a galaxolide represented by the following (hereinafter referred to as "compound Q"), the following formula (18):
  • compound S cyclopentadecanolide
  • the above compounds A to S may be used alone or in combination of two or more.
  • the content of the fragrance component is preferably 0.1 to 1.0 w / v%. When the content of the fragrance component is in such a range, the bad odor attached to the clothes can be masked and sufficient deodorant properties can be obtained. When the content of the fragrance component is less than 0.1 w / v%, the deodorizing property may be insufficient. When the content of the fragrance component exceeds 1.0 w / v%, the fragrance of the fragrance component becomes excessive, which may cause discomfort to consumers who do not like the strong fragrance. The perfume component is added in excess of the amount obtained, which is economically disadvantageous.
  • the blending ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is preferably adjusted to 0.1 to 1.5 as a weight ratio. ..
  • the compounding ratio (a / b) is within such a range, the synergistic effect between the pest repellent component and the fragrance component becomes large, and the deodorizing function of the fragrance component continues for a long time.
  • the blending ratio (a / b) is less than 0.1 and when the blending ratio (a / b) is more than 1.5, the synergistic effect of the pest repellent component and the fragrance component cannot be sufficiently exhibited. There is a risk.
  • the clothing pest repellent composition of the present invention includes, in addition to the above components, a stabilizer for the pest repellent component, an antifungal agent for fungi and fungi, an antibacterial agent, a bactericide, an antistatic agent, an antifoaming agent, etc. Can also be blended appropriately.
  • a stabilizer for the pest repellent component an antifungal agent for fungi and fungi, an antibacterial agent, a bactericide, an antistatic agent, an antifoaming agent, etc.
  • IR3535 when IR3535 is used as the pest repellent component, triethanolamine can be used as the stabilizer.
  • triethanolamine can be used as the stabilizer.
  • the stability of IR353535 which is easily decomposed under acidic conditions, is improved, and the content of IR3535 is excessive even when the clothing pest repellent composition is stored for a long period of time. Can be prevented from decreasing.
  • the content of triethanolamine in the clothing pest repellent composition is preferably 0.05 to 0.2 w / v%. Within such a range, the stability of IR3535 can be sufficiently improved, so that the clothing pest repellent composition is excellent in long-term storage stability and easy to use. When the content of triethanolamine is less than 0.05 w / v% and when the content of triethanolamine exceeds 0.2 w / v%, the stability of IR3535 may not be sufficiently improved. is there. As a stabilizer, it is preferable to use menthol in combination with triethanolamine. The content of menthol in the clothing pest repellent composition is preferably 0.2 to 1.5 w / v%.
  • the stability of IR3535 can be further improved by the synergistic effect of triethanolamine and menthol.
  • the content of menthol is less than 0.2 w / v% or when the content of menthol exceeds 1.5 w / v%, the synergistic effect with triethanolamine may not be sufficiently exerted. ..
  • menthol was conventionally used as a fragrance, but when the present inventors prepared various clothing pest repellent compositions, when the content of menthol is in the above range, menthol adheres to clothing. It did not show the deodorizing function of deodorizing the bad odor.
  • Antifungal agents, antibacterial agents, and bactericidal agents include hinokitiol, 2-mercaptobenzothiazole, 2- (4-thiazolyl) benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, triphorin, 3 -Methyl-4-isopropylphenol, ortho-phenylphenol and the like can be mentioned.
  • the clothing pest repellent composition of the present invention is prepared by blending the above-mentioned components in an appropriate weight ratio, and further adding water and alcohol to adjust the concentration of each component to be appropriate.
  • alcohols lower alcohols having 2 to 3 carbon atoms are preferable, and ethanol is particularly preferable.
  • a preferred product form of the clothing pest repellent composition of the present invention is a spray product.
  • a clothing pest control spray product is constituted.
  • the spray container one provided with a trigger type sprayer is preferable.
  • the clothing pest repellent composition diffuses, and the amount of the clothing pest repellent composition attached to the clothes to be treated becomes substantially uniform. Further, it is possible to apply an accurate amount of the clothes pest repellent composition to the clothes to be treated according to the number of sprays.
  • the clothing deodorizing method of the present invention is a method of spraying the clothing pest repellent composition of the present invention onto clothing, and can be carried out, for example, by using the above-mentioned clothing pest control spray product. Specifically, the user holds the trigger of the spray product for controlling clothes pests and sprays the clothes pest repellent composition onto the clothes or hat. As a result, the clothing pest repellent composition adheres to the surface of clothing or the like. At this time, the clothing may be worn or not worn. In the clothing pest repellent composition of the present invention, since IR3535, icalidin, and diet, which are highly safe for the human body, are used as the pest repellent components, it is possible to perform spray treatment on clothes while wearing them.
  • the clothes are provided with an excellent insect-controlling function and a continuous deodorizing function. As a result, it is possible to effectively prevent the spawning of clothing pests on the clothes being worn and to eliminate the bad odor attached to the clothes.
  • the clothing pest repellent deodorant method of the present invention has a spraying step of spraying a clothing pest repellent composition containing a pest repellent component and a fragrance component on the target clothing, and has a sufficient pest repellent effect and deodorant effect in the clothing. And a changing step of changing the position of spraying the clothing pest repellent composition onto the clothing so as to continue.
  • the clothing pest repellent deodorant method of the present invention has the same basic steps (operations) as the above-mentioned clothing deodorant method, but is used so that the clothing pest repellent composition adheres to the entire clothing in the changing step. The person may spray the clothing pest control spray product while properly moving.
  • the method for deodorizing clothing pest repellent of the present invention it is possible to impart the pest repellent effect and the continuous deodorant effect to clothing at the same time by a single treatment.
  • the clothing treated by the method for deodorizing clothing pests according to the present invention has a synergistic effect of a pest repellent component and a perfume component, which will be described later, because the deodorant function of the perfume component lasts for a long period of time, for example, all day long. Even when going out, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
  • the clothing pest repellent composition according to the present invention by combining a specific perfume component with a pest repellent component, by the synergistic effect of the pest repellent component and the perfume component, to maintain the deodorant function by the perfume component for a long time.
  • You can The duration of the deodorant function varies depending on the combination of the pest repellent component and the fragrance component, the mixing ratio of both components, the use conditions of the clothing pest repellent composition, etc., but the deodorant function is maintained for about half a day to one day. It is fully possible. Therefore, if the spray treatment is carried out before going out according to the clothing deodorizing method of the present invention which is carried out by using this clothing pest repellent composition, for example, the deodorizing function by the fragrance component during going out for about 12 hours. It is possible to prevent the discomfort caused by the bad smell attached to the clothes.
  • a clothing pest repellent composition (Examples 1 to 54) having the characteristic constitution of the present invention was prepared, and a deodorant function confirmation test was conducted. Was carried out.
  • clothing pest repellent compositions (Comparative Examples 1 to 56) not having the characteristic constitution of the present invention were prepared, and the same deodorant function confirmation test was carried out.
  • “g” is shown as a unit of weight, but it is possible to scale up at any magnification. That is, the unit “g” can be read as “part by weight”.
  • Clothing pest repellent compositions were prepared according to the following formulation 1 using IR3535 as a pest repellent component.
  • compounds A to S were used as perfume ingredients.
  • a compounded fragrance obtained by mixing compounds B, H, L, N, and Q in equal amounts (hereinafter referred to as “prepared fragrance 1”) was used as a fragrance component.
  • a compounded fragrance hereinafter, referred to as “prepared fragrance 2” in which equal amounts of the compounds L, N, Q, ⁇ -damascon, and cachemelan were mixed was used as a fragrance component. did.
  • Prescription 1 0.5 g (0.5 w / v%) of fragrance component, 3.5 g (3.5 w / v%) of IR3535, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL.
  • the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.14 as a weight ratio.
  • Clothing pest repellent compositions (Examples 22 to 27) were prepared according to the following formulation 2 using IR3535 as a pest repellent component.
  • the compounds B, H, L, N, Q and the prepared perfume 1 were used as the perfume ingredients.
  • Prescription 2 0.5 g (0.5 w / v%) of fragrance component, 0.5 g (0.5 w / v%) of IR3535, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL.
  • the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 1.00 as a weight ratio.
  • Clothing pest repellent compositions (Examples 28 to 48) were prepared according to the following Formulation 3 using icalidin as a pest repellent component.
  • Compounds A to S, Formulated Perfume 1 and Formulated Perfume 2 were used as perfume ingredients.
  • Prescription 3 0.5 g (0.5 w / v%) of fragrance component, 3.5 g (3.5 w / v%) of icaridin, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL.
  • the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.14 as a weight ratio.
  • Clothing pest repellent compositions (Examples 49 to 54) were prepared according to the following formulation 4 using icalidin as a pest repellent component.
  • Compounds B, H, L, N and Q, and the prepared perfume 1 were used as perfume ingredients.
  • Prescription 4 0.5 g (0.5 w / v%) of fragrance component, 0.5 g (0.5 w / v%) of icaridin, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL.
  • the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 1.00 as a weight ratio.
  • Clothing pest repellent compositions (Comparative Examples 1 to 21) were prepared according to the following formulation 5 containing no pest repellent component.
  • Compounds A to S, Formulated Perfume 1 and Formulated Perfume 2 were used as perfume ingredients.
  • Prescription 5 0.5 g (0.5 w / v%) of fragrance component, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), 1.0 g (1.0 w / v%) of menthol, triethanol 0.05 g (0.05 w / v%) of amine (TEA), 40 g (40 w / v%) of purified water, and the balance (balance) of anhydrous ethanol were mixed to prepare a total amount of 100 mL.
  • IPMP isopropylmethylphenol
  • IPMP isopropylmethylphenol
  • 1.0 g 1.0 w / v%) of menthol
  • 40 g (40 w / v%) of purified water and the balance (balance) of anhydrous ethanol were mixed to prepare a total amount of 100 mL.
  • a clothing pest repellent composition (Comparative Example 22) was prepared according to the following formulation 6 using IR3535 as a pest repellent component.
  • the clothing pest repellent composition of Comparative Example 22 does not contain a fragrance component.
  • Prescription 6 IR3535 3.5 g (3.5 w / v%), isopropyl methyl phenol (IPMP) 0.1 g (0.1 w / v%), menthol 1.0 g (1.0 w / v%), triethanolamine 0.05 g (0.05 w / v%) of (TEA), 40 g (40 w / v%) of purified water, and the balance (balance) of anhydrous ethanol were mixed to prepare a total amount of 100 mL.
  • the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.00 as a weight ratio.
  • a clothing pest repellent composition (Comparative Example 23) was prepared according to the following formulation 7 using icalidin as a pest repellent component.
  • the clothing pest repellent composition of Comparative Example 23 does not contain a fragrance component.
  • Prescription 7 3.5 g (3.5 w / v%) of squalidin, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), 1.0 g (1.0 w / v%) of menthol, triethanolamine 0.05 g (0.05 w / v%) of (TEA), 40 g (40 w / v%) of purified water, and the balance (balance) of anhydrous ethanol were mixed to prepare a total amount of 100 mL.
  • the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.00 as a weight ratio.
  • Clothing pest repellent compositions (Comparative Examples 24-34) were prepared according to Formulation 1 using IR3535 as a pest repellent component.
  • IR3535 as a pest repellent component.
  • compounds having an electron conjugated part other than the electron conjugated part derived from the benzene ring, the benzoic acid ester structure, or the salicylic acid ester structure were used as the perfume ingredients.
  • the clothing pest repellent composition of Comparative Example 24 the following formula (20):
  • compound C2 ⁇ -ionone represented by (hereinafter, referred to as “compound C2”) was used as a perfume ingredient.
  • ⁇ -Damascone represented by (hereinafter referred to as “compound C3”) was used as a perfume ingredient.
  • Damasenone represented by the formula (hereinafter referred to as "compound C4") was used as a perfume ingredient.
  • Citral represented by (hereinafter, referred to as "compound C5") was used as a perfume ingredient.
  • the cinnamaldehyde represented by (hereinafter, referred to as "compound C6") was used as a perfume ingredient.
  • the calixol represented by (hereinafter referred to as "compound C7") was used as a perfume ingredient.
  • the cashew melanin (hereinafter, referred to as "compound C8") was used as a perfume ingredient.
  • Carvone represented by (hereinafter referred to as "compound C10") was used as a perfume ingredient.
  • a clothing pest repellent composition (Comparative Examples 35 to 45) was prepared according to Formulation 3 using icalidin as a pest repellent component.
  • compounds C1 to C11 having an electron conjugated portion other than the electron conjugated portion derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure were used as perfume ingredients.
  • a clothing pest repellent composition (Comparative Examples 46 to 56) was prepared according to Formulation 5 containing no pest repellent component.
  • compounds C1 to C11 having an electron conjugated portion other than the electron conjugated portion derived from the benzene ring, the benzoic acid ester structure, or the salicylic acid ester structure were used as the perfume ingredients.
  • Tables 1 and 2 show the formulations of the clothing pest repellent compositions of Examples 1 to 54 and Comparative Examples 1 to 56, and the perfume ingredients.
  • Deodorant function confirmation test A deodorant function confirmation test for sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor was conducted. For sweat odor, place a test cotton cloth (5 cm x 5 cm cotton cloth (gold width 3)) on a waist high petri dish (outer diameter 75 mm, height 60 mm), and spray an ethanol solution of isovaleric acid (Nacalai Tesque, Inc.) as a test malodor. A proper amount was sprayed in a vial.
  • a test cotton cloth was placed on a high waist dish and an appropriate amount of an ethanol solution of diacetyl (manufactured by Nacalai Tesque, Inc.) was sprayed as a test malodor in a spray vial.
  • a test cotton cloth was placed on a high waist petri dish, and an ethanol solution of 2-nonenal (manufactured by Tokyo Kasei Kogyo Co., Ltd.) was sprayed as an offensive odor in an appropriate amount with a spray vial.
  • tobacco odor cigarette smoke was exposed to a test cotton cloth in a closed small space, and then the test cotton cloth was placed on a waist high petri dish.
  • cooking odor beef tallow was burned in a small enclosed space to expose the smoke to a test cotton cloth, and then the test cotton cloth was placed on a waist-high petri dish.
  • Tables 3 and 4 show the results of the deodorant function confirmation test for sweat odor.
  • Tables 5 and 6 show the results of the deodorant function confirmation test for middle-fat odors.
  • Tables 7 and 8 show the results of the deodorant function confirmation test for aging odor.
  • Tables 9 and 10 show the results of the deodorant function confirmation test for tobacco odor.
  • Tables 11 and 12 show the results of the deodorant function confirmation test for cooking odors.
  • the clothing pest repellent compositions having the characteristic constitution of the present invention are Examples 1 to 27 containing IR3535 as a pest repellent component and Example 28 to containing Icaridine as a pest repellent component.
  • Any of No. 54 exhibited excellent deodorizing properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor even after 12 hours from the spray treatment of the test solution. From this, by spraying the clothing pest repellent composition having the characteristic constitution of the present invention onto clothes before going out, the deodorizing function by the fragrance component is maintained during going out for about 12 hours, It is considered that it is possible to prevent the discomfort caused by the bad odor attached to the clothes.
  • the clothing pest repellent compositions of Comparative Examples 1 to 21 containing no pest repellent component are Examples 1 to 27 containing IR3535 as a pest repellent component and Example 28 containing Icaridine as a pest repellent component.
  • the same fragrance component is contained, but for any of sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor, the test solution is extinguished for up to 3 hours after spray treatment. It showed only odor, and did not show sufficient deodorant after 12 hours from the spray treatment of the test solution.
  • the clothing pest repellent composition of Comparative Example 22 contains IR3535 as a pest repellent component as in Examples 1-27, and the clothing pest repellent composition of Comparative Example 23 is the same as Examples 28-54. Although icalidin is contained as a repellent component, Comparative Examples 22 and 23 do not contain a fragrance component. The clothing pest repellent compositions of Comparative Examples 22 and 23 did not show deodorant properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor. From this, it was confirmed that IR3535, which is a pest repellent component, and icaridin alone have no deodorant property.
  • IR3535 which is a pest repellent component
  • icaridin alone have no deodorizing property
  • they are mixed with a pest repellent component as compared with the clothing pest repellent compositions of Comparative Examples 1 to 21. It is considered that the deodorant function of the clothing pest repellent compositions of Examples 1 to 54 lasted for a long time because the pest repellent component has some synergistic effect with the specific fragrance component defined in the present invention.
  • the clothing pest repellent compositions (Examples 1 to 54) provided with the characteristic constitution of the present invention are obtained by combining a specific pest repellent component and a specific perfume component with the pest repellent component and the perfume component. It was confirmed that a synergistic effect was obtained and that the deodorizing function of the fragrance component was maintained for a long time.
  • the clothing pest repellent composition and the clothing deodorizing method of the present invention are used for deodorizing a bad odor adhering to clothing and can be used for deodorizing a textile product. Furthermore, the clothing pest repellent and deodorizing method of the present invention can be used for pest repelling and deodorizing textile products.

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Abstract

Provided is a fabric pest repelling composition achieving a pest proofing function while being capable of removing unpleasant odors attached to clothes in a sustained manner. In this fabric pest repelling composition containing a pest repelling component and an aroma component, the aroma component has a deodorization function of removing unpleasant odors that have attached to clothes, and the pest repelling component has a sustaining function that causes the deodorization function of the aroma component to be sustained. The pest repelling component is at least one component selected from the group consisting of 3-(N-butylacetamide)ethyl propionate, icaridin, and N,N-diethyltoluamide, and the aroma component is a compound having carbon atoms, hydrogen atoms, and oxygen atoms, having no sulfur atoms, no nitrogen atoms, and no halogen atoms, whereof the molecular weight is 98 to 270 and the number of carbons is 6 to 18, and having no electron conjugated moieties other than the electron conjugated moieties derived from a benzene ring, a benzoate ester structure, or a salicylate ester structure.

Description

衣料害虫忌避組成物、並びに、当該組成物を用いた衣料消臭方法及び衣料害虫忌避消臭方法Clothing pest repellent composition, and clothing deodorant method and clothing pest repellent deodorant method using the composition
　本発明は、害虫忌避成分と香料成分とを含有する衣料害虫忌避組成物、及び当該組成物を用いた衣料消臭方法に関する。さらに、本発明は、衣料に対して害虫忌避処理と消臭処理とを同時に行う衣料害虫忌避消臭方法に関する。 The present invention relates to a clothing pest repellent composition containing a pest repellent component and a fragrance component, and a clothing deodorizing method using the composition. Further, the present invention relates to a clothing pest repellent and deodorizing method for simultaneously performing pest repellent treatment and deodorant treatment on clothing.
　衣料害虫から繊維製品を保護するため、様々な衣料害虫防除製品が開発され、実用化されている。例えば、常温揮散性を有するピレスロイド系防虫成分に代えて、香料成分を有効成分とする衣料害虫防除製品が知られている（例えば、特許文献１を参照）。 Various clothing pest control products have been developed and put into practical use in order to protect textile products from clothing pests. For example, there is known a clothing pest control product containing a fragrance component as an active ingredient in place of the pyrethroid insect control component having room temperature volatility (for example, see Patent Document 1).
　特許文献１の衣料害虫防除製品は、酢酸エステル化合物、アリルエステル化合物等の香料成分を吸水性ポリマーに保持させたものであり、長期に亘って有効成分の揮散性を維持することで、タンス、引き出し、クローゼット、衣料収納箱等の収納空間で衣料害虫の幼虫を致死させ、優れた摂食阻害効果を発揮することができる。 The clothing pest control product of Patent Document 1 is one in which a fragrance component such as an acetic acid ester compound and an allyl ester compound is held in a water-absorbent polymer, and by maintaining volatility of the active ingredient for a long period of time, In the storage space such as the drawer, the closet, and the clothing storage box, the larva of the clothing pest can be killed, and an excellent feeding-inhibiting effect can be exhibited.
特開２０１５－１１７２３１号公報JP, 2005-117231, A
　衣類は、着用中に汗臭、加齢臭、タバコ臭等の生活臭が付着することがある。そのため、衣類の管理では、衣料害虫の防除に加えて、衣類に付着する悪臭を消臭することが望まれる。また、外衣等は、連日使用することが多いため、前日に衣類に付着した生活臭が、翌日着用した際に不快感をもたらす虞があり、外出中に悪臭を持続的に消臭できることが望まれる。 Clothes may have a daily odor such as sweat odor, aging odor, cigarette odor, etc. while wearing. Therefore, in the management of clothing, in addition to controlling the harmful insects of clothing, it is desired to eliminate the bad odor attached to the clothing. In addition, since outer garments are often used every day, living odors attached to clothes on the previous day may cause discomfort when worn the next day, and it is desirable to be able to continuously eliminate odors while going out. Be done.
　特許文献１の衣料害虫防除製品は、香料成分を有効成分としていることで消臭機能が期待されるが、衣料害虫に対する防虫機能を主眼として香料成分となる化合物が選択されており、衣類特有の悪臭に対する消臭機能については、検討の余地がある。 The clothing pest control product of Patent Document 1 is expected to have a deodorant function by using a fragrance component as an active ingredient, but a compound serving as a fragrance component has been selected with a focus on the insect control function against clothing pests, and is peculiar to clothing. There is room for consideration regarding the deodorizing function for bad odors.
　本発明は、上記問題点に鑑みてなされたものであり、防虫機能を果たすとともに衣類に付着する悪臭を持続的に消臭可能な衣料害虫忌避組成物、及び当該組成物を用いた衣料消臭方法を提供することを目的とする。さらに、本発明は、一回の処理で衣料に害虫忌避効果と持続的な消臭効果とを同時に付与可能な衣料害虫忌避消臭方法を提供することを目的とする。 The present invention has been made in view of the above problems, and a clothing pest repellent composition capable of continuously deodorizing a bad odor that adheres to clothes while performing an insect repellent function, and a clothing deodorant using the composition. The purpose is to provide a method. Another object of the present invention is to provide a method for repelling and deodorizing clothing pests, which is capable of imparting a pest repellent effect and a continuous deodorant effect to clothing at the same time.
　上記課題を解決するための本発明に係る衣料害虫忌避組成物の特徴構成は、
　害虫忌避成分と香料成分とを含有する衣料害虫忌避組成物であって、
　前記香料成分は、衣料に付着した悪臭を消臭する消臭機能を有し、
　前記害虫忌避成分は、前記香料成分の消臭機能を持続させる持続機能を有することにある。 Characteristic composition of the clothing pest repellent composition according to the present invention for solving the above problems,
A clothing pest repellent composition comprising a pest repellent component and a fragrance component,
The fragrance component has a deodorizing function of deodorizing a bad odor attached to clothing,
The pest repellent component has a continuous function of maintaining the deodorizing function of the fragrance component.
　本構成の衣料害虫忌避組成物は、本発明者らが、様々な衣料害虫忌避組成物を調製して種々試験を繰り返す中で、特定の害虫忌避成分が香料成分の消臭機能を持続させる持続機能を有することを新たに見出したことにより、完成するに至ったものである。本構成の衣料害虫忌避組成物によれば、香料成分が衣料に付着した悪臭を消臭する消臭機能を有し、害虫忌避成分が香料成分の消臭機能を持続させる持続機能を有することにより、害虫忌避成分が衣料害虫に対する防虫機能を果たすととともに、香料成分による消臭機能を長期に亘って持続させて衣類に付着する悪臭を持続的に消臭することができる。そのため、本発明の衣料害虫忌避組成物を外出前に衣類に処理しておくことで、外出中に香料成分による消臭機能が持続し、衣類に付着した悪臭により不快感が生じることを防ぐことができる。 The clothing pest repellent composition of the present composition, the present inventors, while preparing various clothing pest repellent composition and repeat various tests, a specific pest repellent component sustains the deodorant function of the perfume component. It was completed by newly discovering that it has a function. According to the clothing pest repellent composition of this configuration, the perfume component has a deodorant function of deodorizing the bad odor attached to the clothing, and the pest repellent component has a continuous function of maintaining the deodorant function of the perfume component. In addition to the pest repellent component having an insect repellent function against clothing pests, the deodorant function of the fragrance component can be maintained for a long period of time to continuously eliminate the bad odor attached to clothes. Therefore, by treating the clothing pest repellent composition of the present invention on clothes before going out, the deodorizing function of the fragrance component is maintained during going out, and it is possible to prevent discomfort due to the bad odor attached to the clothes. You can
　本発明に係る衣料害虫忌避組成物において、
　前記害虫忌避成分は、３－（Ｎ－ブチルアセトアミド）プロピオン酸エチル、イカリジン、及びＮ，Ｎ－ジエチルトルアミドからなる群から選択される少なくとも一つであり、
　前記香料成分は、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物であることが好ましい。 In the clothing pest repellent composition according to the present invention,
The pest repellent component is at least one selected from the group consisting of ethyl 3- (N-butylacetamido) propionate, icaridin, and N, N-diethyltoluamide,
The fragrance component does not have an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure, has 6 to 18 carbon atoms, and has a molecular weight of 98 to 270. It is preferable that the compound has a carbon atom, a hydrogen atom, and an oxygen atom and does not have a sulfur atom, a nitrogen atom, and a halogen atom.
　本構成の衣料害虫忌避組成物によれば、上記の特定の害虫忌避成分と香料成分とを組み合わせることによって、害虫忌避成分と香料成分との相乗効果により、香料成分による消臭機能を長期に亘って持続させることができる。 According to the clothing pest repellent composition of the present configuration, by combining the specific pest repellent component and the fragrance component described above, the deodorant function of the fragrance component is maintained for a long period of time due to the synergistic effect of the pest repellent component and the fragrance component. Can be sustained.
　本発明に係る衣料害虫忌避組成物において、
　前記香料成分は、シス－３－ヘキセノール、ジヒドロミルセノール、エチルリナロール、リナロール 、ゲラニオール、テトラヒドロゲラニオール、テルピネオール、フェニルエチルアルコール、ヘリオナール、リリアール、安息香酸ベンジル、サリチル酸ベンジル、シス－３－ヘキセニルサリチレート、ジヒドロジャスモン酸メチル、リナリルアセテート、ラズベリーケトン、ガラクソリド、エチレンブラシレート、及びシクロペンタデカノリドからなる群から選択される少なくとも一つであることが好ましい。 In the clothing pest repellent composition according to the present invention,
The perfume ingredients are cis-3-hexenol, dihydromyrcenol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenylethyl alcohol, helional, lilial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicyt. It is preferably at least one selected from the group consisting of rate, methyl dihydrojasmonate, linalyl acetate, raspberry ketone, galaxolide, ethylene brushlate, and cyclopentadecanolide.
　本構成の衣料害虫忌避組成物によれば、上記の香料成分を含有することにより、害虫忌避成分と香料成分との相乗効果が大きくなり、消臭機能の持続性を向上させることができる。 According to the clothing pest repellent composition of this constitution, by containing the above-mentioned fragrance component, the synergistic effect of the pest repellant component and the fragrance component becomes large, and the sustainability of the deodorant function can be improved.
　本発明に係る衣料害虫忌避組成物において、
　前記香料成分の含有量が０．１～１．０ｗ／ｖ％であることが好ましい。 In the clothing pest repellent composition according to the present invention,
The content of the fragrance component is preferably 0.1 to 1.0 w / v%.
　本構成の衣料害虫忌避組成物によれば、香料成分の含有量が適切な範囲にあるため、衣類に付着する悪臭を芳香によってマスクして、十分な消臭性を得ることができる。 According to the clothing pest repellent composition of this configuration, since the content of the fragrance component is in an appropriate range, it is possible to mask the bad odor adhering to the clothing with the aroma and obtain sufficient deodorant properties.
　本発明に係る衣料害虫忌避組成物において、
　前記香料成分（ａ）と前記害虫忌避成分（ｂ）との配合比（ａ／ｂ）が、重量比として、０．１～１．５であることが好ましい。 In the clothing pest repellent composition according to the present invention,
The compounding ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is preferably 0.1 to 1.5 as a weight ratio.
　本構成の衣料害虫忌避組成物によれば、配合比が適切な範囲にあるため、害虫忌避成分による衣料害虫に対する防虫機能を十分に発揮しつつ、害虫忌避成分と香料成分との相乗効果を十分に発揮することができ、香料成分による消臭機能を長期に亘って持続させることができる。 According to the clothing pest repellent composition of this configuration, since the blending ratio is in an appropriate range, while sufficiently exerting the insect repellent function against the clothing pests by the pest repellent component, the synergistic effect of the pest repellent component and the fragrance component is sufficient. Therefore, the deodorizing function of the fragrance component can be maintained for a long period of time.
　上記課題を解決するための本発明に係る衣料消臭方法の特徴構成は、
　前記の何れか一つに記載の衣料害虫忌避組成物を用いた衣料消臭方法であって、
　前記衣料害虫忌避組成物を衣料に噴霧処理することにある。 The characteristic configuration of the clothing deodorizing method according to the present invention for solving the above-mentioned problems,
A method for deodorizing clothing using the clothing pest repellent composition according to any one of the above,
It is to spray-treat the clothing pest repellent composition.
　本構成の衣料消臭方法によれば、前記の何れか一つに記載の衣料害虫忌避組成物を衣料に噴霧処理することで、害虫忌避成分による防虫機能が得られるととともに、害虫忌避成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続する。そのため、本発明の衣料消臭方法を外出前に実施することで、外出中に香料成分による消臭機能が持続し、衣類に付着した悪臭により不快感が生じることを防ぐことができる。 According to the clothing deodorizing method of the present configuration, by spraying the clothing pest repellent composition according to any one of the above to the clothing, with the insect repellent function by the pest repellent component, with the pest repellent component and Due to the synergistic effect with the fragrance component, the deodorizing function of the fragrance component continues for a long time. Therefore, by performing the clothing deodorizing method of the present invention before going out, it is possible to prevent the deodorizing function of the fragrance component from continuing while going out and prevent unpleasant sensation from being caused by the bad odor attached to the clothing.
　上記課題を解決するための本発明に係る衣料害虫忌避消臭方法の特徴構成は、
　衣料に対して害虫忌避処理と消臭処理とを同時に行う衣料害虫忌避消臭方法であって、
　処理対象の衣料に害虫忌避成分と香料成分とを含有する衣料害虫忌避組成物を噴霧する噴霧工程と、
　前記衣料において十分な害虫忌避効果及び消臭効果が持続するように、前記衣料に対して前記衣料害虫忌避組成物を噴霧する位置を変更する変更工程と、
を包含することにある。 The characteristic configuration of the clothing pest repellent deodorant method according to the present invention for solving the above-mentioned problems,
A method for deodorizing clothing pests by simultaneously performing pest repellent treatment and deodorant treatment on clothing,
A spraying step of spraying a clothing pest repellent composition containing a pest repellent component and a fragrance component on the clothing to be treated,
In order to maintain a sufficient pest repellent effect and deodorant effect in the clothing, a changing step of changing the position of spraying the clothing pest repellent composition on the clothing,
To include.
　本構成の衣料害虫忌避消臭方法によれば、処理対象の衣料に害虫忌避成分と香料成分とを含有する衣料害虫忌避組成物を噴霧し、さらに、衣料において十分な害虫忌避効果及び消臭効果が持続するように、当該衣料に対して衣料害虫忌避組成物を噴霧する位置を変更することで、一回の処理で衣料に害虫忌避効果と持続的な消臭効果とを同時に付与することができる。そして、本発明の衣料害虫忌避消臭方法によって処理された衣料は、害虫忌避成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続するため、例えば、一日中外出するような場合であっても、不快な害虫が寄り付かず、かつ臭いも気にならずに長時間快適に活動することができる。 According to the clothing pest repellent deodorizing method of the present configuration, the clothing to be treated is sprayed with a clothing pest repellent composition containing a pest repellent component and a fragrance component, and further, a sufficient pest repellent effect and deodorant effect in clothing. By changing the position at which the clothing pest repellent composition is sprayed on the clothing so as to last, it is possible to impart the pest repellent effect and the continuous deodorant effect to the clothing at the same time in a single treatment. it can. Then, the clothing treated by the method for deodorizing clothing pest repellent of the present invention, by the synergistic effect of the pest repellent component and the perfume component, because the deodorant function by the perfume component lasts for a long time, for example, go out all day. Even in such a case, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
　以下、本発明の衣料害虫忌避組成物、及び衣料消臭方法について説明する。ただし、本発明は、以下に説明する実施形態に記載される構成に限定されることを意図しない。 The clothing pest repellent composition of the present invention and the clothing deodorizing method will be described below. However, the present invention is not intended to be limited to the configurations described in the embodiments described below.
＜衣料害虫忌避組成物＞
　本発明の衣料害虫忌避組成物は、衣料に付着した悪臭を消臭する消臭機能を有する香料成分と、害虫忌避効果に加えて香料成分の消臭機能を持続させる持続機能を有する害虫忌避成分とを含有する。 <Clothing pest repellent composition>
The clothing pest repellent composition of the present invention is a perfume repellent component having a deodorant function of deodorizing a bad odor attached to clothing, and a pest repellent component having a continuous function of continuing the deodorant function of the perfume component in addition to the pest repellent effect. Contains and.
　本発明の衣料害虫忌避組成物の主成分の一つである害虫忌避成分としては、３－（Ｎ－ブチルアセトアミド）プロピオン酸エチル（以下、「ＩＲ３５３５」と表記する）、イカリジン、及びＮ，Ｎ－ジエチルトルアミド（以下、「ディート」と表記する）が使用される。これらは、単独で使用可能であるが、二種以上の混合物の形態で使用しても構わない。ＩＲ３５３５、イカリジン、及びディートは、揮散性を有し、衣料害虫、特にイガ、又はコイガの成虫に対して高い忌避効果を有する。このように、ＩＲ３５３５、イカリジン、及びディートは、従来は害虫忌避剤として使用されていたが、本発明者らが、ＩＲ３５３５、イカリジン、及びディートを使用して様々な衣料害虫忌避組成物を調製する中で、ＩＲ３５３５、イカリジン、及びディートが、後述する特定の香料成分の消臭機能を持続させる持続機能を有することを新たに見出した。本発明の衣料害虫忌避組成物は、噴霧処理等により衣類へ付着させることで、使用中の衣類から害虫忌避成分を揮散させて衣料害虫の接近又は接触を防止し、着衣における衣料害虫の産卵を予防しつつ、使用中の衣類に付着した悪臭の消臭を長期に亘って持続させることができる。ここで「使用中」とは、衣類を収納空間から取り出してから、再び収納空間に収納するまでの状態を意味し、着用されている状態のみならず、着用前後に収納空間外で静置されている状態をも含む。着用中の衣類では、使用者の体温によって害虫忌避成分の揮散が促進されるため、衣料害虫の接近又は接触をより効果的に防止することができる。また、野外等では温度調節のために衣類を脱ぐような場面もあるが、ＩＲ３５３５、イカリジン、及びディートが揮散性を有することから、使用中に脱いで野外等で静置された衣類においても、衣料害虫の接近又は接触を十分に防止することができる。また、ＩＲ３５３５、及びイカリジンは、繊維製品に対してシミや変色等の影響を生じにくく、さらに、ほとんど無臭であり、人体に対する安全性が高い。そのため、本発明の衣料害虫忌避組成物は、衣類へのダメージや、害虫忌避成分の臭いを気にすることなく、着衣に使用することができる。衣料害虫忌避組成物中の害虫忌避成分の含有量は、０．４～１０．０ｗ／ｖ％であることが好ましい。このような範囲であれば、衣料害虫忌避組成物を噴霧処理等により衣類に付着させることで、衣料害虫に対する忌避効果を発揮しつつ、後述する特定の香料成分との相乗効果を奏して、消臭機能の持続性を向上することができる。害虫忌避成分の含有量が０．４ｗ／ｖ％未満である場合、衣料害虫に対する忌避効果や、香料成分との相乗効果による消臭機能の持続性が不十分となる虞がある。害虫忌避成分の含有量が１０．０ｗ／ｖ％を超える場合、実用上必要な忌避効果が得られる量を超えて害虫忌避成分を配合することになり、経済的に不利である。 Examples of the pest repellent component which is one of the main components of the clothing pest repellent composition of the present invention include ethyl 3- (N-butylacetamido) propionate (hereinafter referred to as “IR3535”), ikaridin, and N, N. -Diethyltoluamide (hereinafter referred to as "diet") is used. These can be used alone, but may be used in the form of a mixture of two or more kinds. IR3535, squalidin, and diet have a volatile property and have a high repellent effect against clothing pests, especially mosquitoes or adult mosquitoes. Thus, although IR3535, squalidin, and diet were conventionally used as pest repellents, the present inventors use IR3535, squalidin, and diet to prepare various clothing pest repellent compositions. Among them, it was newly found that IR3535, icaridin, and diet have a sustaining function of sustaining the deodorizing function of the specific perfume ingredient described later. The clothing pest repellent composition of the present invention is attached to clothing by spraying treatment or the like to prevent pest repellent components from volatilizing from the clothing in use to prevent approach or contact of clothing pests, and to spawn clothing pests in clothing. While preventing, it is possible to maintain the deodorization of the bad odor attached to the clothes in use for a long period of time. Here, "in use" means a state in which the clothes are taken out of the storage space and stored again in the storage space. Including the state of being. In the garment being worn, volatilization of the pest repellent component is promoted by the body temperature of the user, so that the approach or contact of the clothing pest can be more effectively prevented. In addition, although there are occasions when clothes are taken off to control the temperature in the field etc., since IR3535, icaridin, and diet have volatility, even clothes that have been taken off during use and left standing outdoors, etc. It is possible to sufficiently prevent the pests from approaching or coming into contact with the clothes. In addition, IR3535 and squalidin are unlikely to cause stains, discoloration, and the like on textiles, are almost odorless, and are highly safe for the human body. Therefore, the clothes pest repellent composition of the present invention can be used for clothing without damaging the clothes and the odor of the pest repellent component. The content of the pest repellent component in the clothing pest repellent composition is preferably 0.4 to 10.0 w / v%. In such a range, by applying the clothing pest repellent composition to the clothing by spraying treatment or the like, while exerting a repellent effect against the clothing pests, a synergistic effect with a specific fragrance component described later is exerted, and The durability of the odor function can be improved. When the content of the pest repellent component is less than 0.4 w / v%, the repellent effect against clothing pests and the sustainability of the deodorizing function due to the synergistic effect with the perfume component may be insufficient. When the content of the pest repellent component exceeds 10.0 w / v%, the pest repellent component is blended in an amount exceeding the amount required to obtain the repellent effect required for practical use, which is economically disadvantageous.
　本発明の衣料害虫忌避組成物の主成分の一つである香料成分としては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物が使用される。このような化合物は、衣類に付着した悪臭（汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭）を芳香によってマスクする優れた消臭機能を有するとともに、本発明において害虫忌避成分として使用されるＩＲ３５３５、イカリジン、及びディートとの相乗効果により、その消臭機能を長時間に亘って持続させることができる。このような化合物としては、下記式（１）： The fragrance component which is one of the main components of the clothing pest repellent composition of the present invention, a benzene ring, a benzoic acid ester structure, or does not have an electron conjugated part other than the electron conjugated part derived from a salicylic acid ester structure, carbon A compound having a number of 6 to 18, a molecular weight of 98 to 270, a carbon atom, a hydrogen atom, and an oxygen atom and no sulfur atom, nitrogen atom, or halogen atom is used. Such a compound has an excellent deodorizing function of masking an offensive odor (sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor) attached to clothes with an aroma, and is a pest repellent component in the present invention. The deodorizing function can be maintained for a long time by a synergistic effect with IR3535, icaridin, and diet used as. As such a compound, the following formula (1):
Figure JPOXMLDOC01-appb-C000001
 で示されるシス－３－ヘキセノール（以下、「化合物Ａ」と称する。）、下記式（２）：
Figure JPOXMLDOC01-appb-C000001
 Cis-3-hexenol represented by the following formula (hereinafter referred to as “compound A”), the following formula (2):
Figure JPOXMLDOC01-appb-C000002
 で示されるジヒドロミルセノール（以下、「化合物Ｂ」と称する。）、下記式（３）：
Figure JPOXMLDOC01-appb-C000002
 Dihydromyrcenol represented by the following formula (hereinafter referred to as “compound B”), the following formula (3):
Figure JPOXMLDOC01-appb-C000003
 で示されるエチルリナロール（以下、「化合物Ｃ」と称する。）、下記式（４）：
Figure JPOXMLDOC01-appb-C000003
 Ethyl linalool represented by the following formula (hereinafter referred to as “compound C”), the following formula (4):
Figure JPOXMLDOC01-appb-C000004
 で示されるリナロール（以下、「化合物Ｄ」と称する。）、下記式（５）：
Figure JPOXMLDOC01-appb-C000004
 Linalool represented by the following formula (hereinafter referred to as “compound D”), the following formula (5):
Figure JPOXMLDOC01-appb-C000005
 で示されるゲラニオール（以下、「化合物Ｅ」と称する。）、下記式（６）：
Figure JPOXMLDOC01-appb-C000005
 Geraniol represented by the following formula (hereinafter referred to as “compound E”), the following formula (6):
Figure JPOXMLDOC01-appb-C000006
 で示されるテトラヒドロゲラニオール（以下、「化合物Ｆ」と称する。）、下記式（７）：
Figure JPOXMLDOC01-appb-C000006
 Tetrahydrogeraniol represented by (hereinafter referred to as “Compound F”), the following formula (7):
Figure JPOXMLDOC01-appb-C000007
 で示されるテルピネオール（以下、「化合物Ｇ」と称する。）、下記式（８）：
Figure JPOXMLDOC01-appb-C000007
 Terpineol represented by the following formula (hereinafter referred to as “compound G”), the following formula (8):
Figure JPOXMLDOC01-appb-C000008
 で示されるフェニルエチルアルコール（以下、「化合物Ｈ」と称する。）、下記式（９）：
Figure JPOXMLDOC01-appb-C000008
 Phenylethyl alcohol represented by (hereinafter, referred to as "Compound H"), the following formula (9):
Figure JPOXMLDOC01-appb-C000009
 で示されるヘリオナール（以下、「化合物Ｉ」と称する。）、下記式（１０）：
Figure JPOXMLDOC01-appb-C000009
 Helional represented by the following (hereinafter referred to as “Compound I”), the following formula (10):
Figure JPOXMLDOC01-appb-C000010
 で示されるリリアール（以下、「化合物Ｊ」と称する。）、下記式（１１）：
Figure JPOXMLDOC01-appb-C000010
 Lilyal represented by the following formula (hereinafter referred to as “compound J”), the following formula (11):
Figure JPOXMLDOC01-appb-C000011
 で示される安息香酸ベンジル（以下、「化合物Ｋ」と称する。）、下記式（１２）：
Figure JPOXMLDOC01-appb-C000011
 Benzyl benzoate represented by the following (hereinafter referred to as "Compound K"), the following formula (12):
Figure JPOXMLDOC01-appb-C000012
 で示されるサリチル酸ベンジル（以下、「化合物Ｌ」と称する。）、下記式（１３）：
Figure JPOXMLDOC01-appb-C000012
 Benzyl salicylate (hereinafter referred to as “compound L”) represented by the following formula (13):
Figure JPOXMLDOC01-appb-C000013
 で示されるシス－３－ヘキセニルサリチレート（以下、「化合物Ｍ」と称する。）、下記式（１４）：
Figure JPOXMLDOC01-appb-C000013
 Cis-3-hexenyl salicylate represented by the following (hereinafter referred to as “compound M”), the following formula (14):
Figure JPOXMLDOC01-appb-C000014
 で示されるジヒドロジャスモン酸メチル（以下、「化合物Ｎ」と称する。）、下記式（１５）：
Figure JPOXMLDOC01-appb-C000014
 Methyl dihydrojasmonate represented by (hereinafter referred to as “compound N”), the following formula (15):
Figure JPOXMLDOC01-appb-C000015
 で示されるリナリルアセテート（以下、「化合物Ｏ」と称する。）、下記式（１６）：
Figure JPOXMLDOC01-appb-C000015
 Linalyl acetate represented by the following formula (hereinafter referred to as “compound O”), the following formula (16):
Figure JPOXMLDOC01-appb-C000016
 で示されるラズベリーケトン（以下、「化合物Ｐ」と称する。）、下記式（１７）：
Figure JPOXMLDOC01-appb-C000016
 A raspberry ketone (hereinafter, referred to as “compound P”) represented by the following formula (17):
Figure JPOXMLDOC01-appb-C000017
 で示されるガラクソリド（以下、「化合物Ｑ」と称する。）、下記式（１８）：
Figure JPOXMLDOC01-appb-C000017
 A galaxolide represented by the following (hereinafter referred to as "compound Q"), the following formula (18):
Figure JPOXMLDOC01-appb-C000018
 で示されるエチレンブラシレート（以下、「化合物Ｒ」と称する。）、下記式（１９）：
Figure JPOXMLDOC01-appb-C000018
 An ethylene brushlate represented by (hereinafter referred to as “compound R”), the following formula (19):
Figure JPOXMLDOC01-appb-C000019
 で示されるシクロペンタデカノリド（以下、「化合物Ｓ」と称する。）等が挙げられる。
Figure JPOXMLDOC01-appb-C000019
 And cyclopentadecanolide (hereinafter referred to as "compound S").
　上記の化合物Ａ～Ｓは、単独で使用してもよいし、複数種を組み合わせて使用してもよい。香料成分の含有量は、０．１～１．０ｗ／ｖ％が好ましい。香料成分の含有量がこのような範囲であれば、衣類に付着する悪臭をマスクして、十分な消臭性を得ることができる。香料成分の含有量が０．１ｗ／ｖ％未満である場合、消臭性が不足する虞がある。香料成分の含有量が１．０ｗ／ｖ％を超える場合、香料成分の芳香が過剰となり、強い芳香を好まない消費者に不快感を与える虞があり、また、実用上必要な消臭性が得られる量を超えて香料成分を配合することになり、経済的にも不利である。 The above compounds A to S may be used alone or in combination of two or more. The content of the fragrance component is preferably 0.1 to 1.0 w / v%. When the content of the fragrance component is in such a range, the bad odor attached to the clothes can be masked and sufficient deodorant properties can be obtained. When the content of the fragrance component is less than 0.1 w / v%, the deodorizing property may be insufficient. When the content of the fragrance component exceeds 1.0 w / v%, the fragrance of the fragrance component becomes excessive, which may cause discomfort to consumers who do not like the strong fragrance. The perfume component is added in excess of the amount obtained, which is economically disadvantageous.
　本発明の衣料害虫忌避組成物において、香料成分（ａ）と害虫忌避成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．１～１．５に調整することが好ましい。配合比（ａ／ｂ）がこのような範囲であれば、害虫忌避成分と香料成分との相乗効果が大きくなり、香料成分による消臭機能が長期に亘って持続する。配合比（ａ／ｂ）が０．１未満である場合、及び配合比（ａ／ｂ）が１．５を超える場合、害虫忌避成分と香料成分との相乗効果を十分に発揮することができない虞がある。 In the clothing pest repellent composition of the present invention, the blending ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is preferably adjusted to 0.1 to 1.5 as a weight ratio. .. When the compounding ratio (a / b) is within such a range, the synergistic effect between the pest repellent component and the fragrance component becomes large, and the deodorizing function of the fragrance component continues for a long time. When the blending ratio (a / b) is less than 0.1 and when the blending ratio (a / b) is more than 1.5, the synergistic effect of the pest repellent component and the fragrance component cannot be sufficiently exhibited. There is a risk.
　本発明の衣料害虫忌避組成物は、上記成分に加え、害虫忌避成分の安定化剤、カビ類や菌類等を対象とした防カビ剤、抗菌剤、殺菌剤、帯電防止剤、消泡剤等を適宜配合することもできる。例えば、害虫忌避成分としてＩＲ３５３５を使用する場合、安定化剤としては、トリエタノールアミンを用いることができる。安定化剤としてトリエタノールアミンを含有することで、酸性条件下で分解し易いＩＲ３５３５の安定性を向上させ、長期間に亘って衣料害虫忌避組成物を保存した場合にもＩＲ３５３５の含有量が過度に減少することを防止することができる。衣料害虫忌避組成物中のトリエタノールアミンの含有量は、０．０５～０．２ｗ／ｖ％であることが好ましい。このような範囲であれば、ＩＲ３５３５の安定性を十分に向上させることができるため、衣料害虫忌避組成物は、長期保存性に優れた使い勝手のよいものとなる。トリエタノールアミンの含有量が０．０５ｗ／ｖ％未満である場合、及びトリエタノールアミンの含有量が０．２ｗ／ｖ％を超える場合、ＩＲ３５３５の安定性を十分に向上することができない虞がある。安定化剤として、トリエタノールアミンに加えてメントールを併用することが好ましい。衣料害虫忌避組成物中のメントールの含有量は、０．２～１．５ｗ／ｖ％であることが好ましい。このような範囲であれば、トリエタノールアミンとメントールとの相乗効果により、ＩＲ３５３５の安定性をより向上させることができる。メントールの含有量が０．２ｗ／ｖ％未満である場合、及びメントールの含有量が１．５ｗ／ｖ％を超える場合、トリエタノールアミンとの相乗効果を十分に発揮することができない虞がある。なお、メントールは、従来は香料として使用されていたが、本発明者らが、様々な衣料害虫忌避組成物を調製したところ、メントールの含有量が上記の範囲である場合、メントールは衣料に付着した悪臭を消臭する消臭機能を示さなかった。また、消臭機能を示す程度にメントールの含有量を上記の範囲より大きくした場合にも、ＩＲ３５３５、イカリジン、及びディートによって消臭機能が持続することがなかった。このため、本発明の香料成分としては、メントールを含まない。防カビ剤、抗菌剤、及び殺菌剤としては、ヒノキチオール、２－メルカプトベンゾチアゾール、２－（４－チアゾリル）ベンツイミダゾール、５－クロロ－２－メチル－４－イソチアゾリン－３－オン、トリホリン、３－メチル－４－イソプロピルフェノール、オルト－フェニルフェノール等が挙げられる。 The clothing pest repellent composition of the present invention includes, in addition to the above components, a stabilizer for the pest repellent component, an antifungal agent for fungi and fungi, an antibacterial agent, a bactericide, an antistatic agent, an antifoaming agent, etc. Can also be blended appropriately. For example, when IR3535 is used as the pest repellent component, triethanolamine can be used as the stabilizer. By containing triethanolamine as a stabilizer, the stability of IR3535, which is easily decomposed under acidic conditions, is improved, and the content of IR3535 is excessive even when the clothing pest repellent composition is stored for a long period of time. Can be prevented from decreasing. The content of triethanolamine in the clothing pest repellent composition is preferably 0.05 to 0.2 w / v%. Within such a range, the stability of IR3535 can be sufficiently improved, so that the clothing pest repellent composition is excellent in long-term storage stability and easy to use. When the content of triethanolamine is less than 0.05 w / v% and when the content of triethanolamine exceeds 0.2 w / v%, the stability of IR3535 may not be sufficiently improved. is there. As a stabilizer, it is preferable to use menthol in combination with triethanolamine. The content of menthol in the clothing pest repellent composition is preferably 0.2 to 1.5 w / v%. Within such a range, the stability of IR3535 can be further improved by the synergistic effect of triethanolamine and menthol. When the content of menthol is less than 0.2 w / v% or when the content of menthol exceeds 1.5 w / v%, the synergistic effect with triethanolamine may not be sufficiently exerted. .. Incidentally, menthol was conventionally used as a fragrance, but when the present inventors prepared various clothing pest repellent compositions, when the content of menthol is in the above range, menthol adheres to clothing. It did not show the deodorizing function of deodorizing the bad odor. Further, even when the content of menthol was made larger than the above range to the extent that the deodorant function was exhibited, IR3535, icalidin, and diet did not sustain the deodorant function. Therefore, menthol is not included as the flavor component of the present invention. Antifungal agents, antibacterial agents, and bactericidal agents include hinokitiol, 2-mercaptobenzothiazole, 2- (4-thiazolyl) benzimidazole, 5-chloro-2-methyl-4-isothiazolin-3-one, triphorin, 3 -Methyl-4-isopropylphenol, ortho-phenylphenol and the like can be mentioned.
　本発明の衣料害虫忌避組成物は、上掲の各成分を適切な重量比で配合し、さらに水、及びアルコール類を添加して各成分の濃度が適切となるように調整される。アルコール類としては、炭素数が２～３の低級アルコールが好ましく、エタノールが特に好適である。 The clothing pest repellent composition of the present invention is prepared by blending the above-mentioned components in an appropriate weight ratio, and further adding water and alcohol to adjust the concentration of each component to be appropriate. As alcohols, lower alcohols having 2 to 3 carbon atoms are preferable, and ethanol is particularly preferable.
＜衣料害虫防除用スプレー製品＞
　本発明の衣料害虫忌避組成物の好ましい製品形態は、スプレー製品である。例えば、スプレー容器に、本発明の衣料害虫忌避組成物と、必要に応じて噴射剤とを封入することで、衣料害虫防除用スプレー製品が構成される。スプレー容器としては、トリガー式スプレーヤーを備えるものが好ましい。これにより、スプレーしたときに衣料害虫忌避組成物が拡散し、処理対象の衣類への衣料害虫忌避組成物の付着量が略均一となる。また、スプレー回数に応じて処理対象の衣類に正確な量の衣料害虫忌避組成物を付与することができる。 <Spray products for controlling pests of clothing>
A preferred product form of the clothing pest repellent composition of the present invention is a spray product. For example, by enclosing the clothing pest repellent composition of the present invention and, if necessary, a propellant in a spray container, a clothing pest control spray product is constituted. As the spray container, one provided with a trigger type sprayer is preferable. Thereby, when sprayed, the clothing pest repellent composition diffuses, and the amount of the clothing pest repellent composition attached to the clothes to be treated becomes substantially uniform. Further, it is possible to apply an accurate amount of the clothes pest repellent composition to the clothes to be treated according to the number of sprays.
＜衣料消臭方法＞
　本発明の衣料消臭方法は、本発明の衣料害虫忌避組成物を衣料に噴霧処理するものであり、例えば、上述の衣料害虫防除用スプレー製品を用いて実施することができる。具体的には、使用者が衣料害虫防除用スプレー製品のトリガーを把持し、衣類や帽子に向けて衣料害虫忌避組成物を噴霧する。これにより、衣類等の表面に衣料害虫忌避組成物が付着する。このとき、衣類は着用した状態、及び未着用の状態の何れであってもよい。本発明の衣料害虫忌避組成物では、人体に対する安全性が高いＩＲ３５３５、イカリジン、及びディートを害虫忌避成分として用いるため、着用した状態で衣類に噴霧処理を実施することが可能である。衣料害虫忌避組成物の噴霧処理を実施すると、衣類には優れた防虫機能、及び持続的な消臭機能が付与される。その結果、着用中の衣類への衣料害虫の産卵を効果的に予防しつつ、衣類に付着した悪臭を消臭することができる。 <Clothing deodorizing method>
The clothing deodorizing method of the present invention is a method of spraying the clothing pest repellent composition of the present invention onto clothing, and can be carried out, for example, by using the above-mentioned clothing pest control spray product. Specifically, the user holds the trigger of the spray product for controlling clothes pests and sprays the clothes pest repellent composition onto the clothes or hat. As a result, the clothing pest repellent composition adheres to the surface of clothing or the like. At this time, the clothing may be worn or not worn. In the clothing pest repellent composition of the present invention, since IR3535, icalidin, and diet, which are highly safe for the human body, are used as the pest repellent components, it is possible to perform spray treatment on clothes while wearing them. When the spray treatment of the clothes pest repellent composition is carried out, the clothes are provided with an excellent insect-controlling function and a continuous deodorizing function. As a result, it is possible to effectively prevent the spawning of clothing pests on the clothes being worn and to eliminate the bad odor attached to the clothes.
＜衣料害虫忌避消臭方法＞
　本発明の衣料害虫忌避消臭方法は、処理対象の衣料に害虫忌避成分と香料成分とを含有する衣料害虫忌避組成物を噴霧する噴霧工程と、衣料において十分な害虫忌避効果及び消臭効果が持続するように、当該衣料に対して衣料害虫忌避組成物を噴霧する位置を変更する変更工程とを実行するものである。本発明の衣料害虫忌避消臭方法は、基本的な工程（操作）は上述の衣料消臭方法と同様であるが、変更工程において、衣料全体に衣料害虫忌避組成物が付着するように、使用者は衣料害虫防除用スプレー製品を適切に動かしながら噴霧すればよい。例えば、衣料のうち特に臭いが気になる箇所（例えば、脇下、首回り、脚周辺部など）については、念入りに噴霧処理を行うことで、衣料に効果的な害虫忌避効果と持続的な消臭効果とを同時に付与することができる。このように、本発明の衣料害虫忌避消臭方法を実施すれば、一回の処理で衣料に害虫忌避効果と持続的な消臭効果とを同時に付与することができる。そして、本発明の衣料害虫忌避消臭方法によって処理された衣料は、後述する害虫忌避成分と香料成分との相乗効果により、香料成分による消臭機能が長期に亘って持続するため、例えば、一日中外出するような場合であっても、不快な害虫が寄り付かず、かつ臭いも気にならずに長時間快適に活動することができる。 <Clothing pest repellent deodorizing method>
The clothing pest repellent deodorant method of the present invention has a spraying step of spraying a clothing pest repellent composition containing a pest repellent component and a fragrance component on the target clothing, and has a sufficient pest repellent effect and deodorant effect in the clothing. And a changing step of changing the position of spraying the clothing pest repellent composition onto the clothing so as to continue. The clothing pest repellent deodorant method of the present invention has the same basic steps (operations) as the above-mentioned clothing deodorant method, but is used so that the clothing pest repellent composition adheres to the entire clothing in the changing step. The person may spray the clothing pest control spray product while properly moving. For example, in areas of clothing where odors are particularly worrisome (such as underarms, neck, and leg areas), careful spraying can be used to ensure effective pest repellent and long-lasting effects on clothing. A deodorant effect can be imparted at the same time. Thus, by carrying out the method for deodorizing clothing pest repellent of the present invention, it is possible to impart the pest repellent effect and the continuous deodorant effect to clothing at the same time by a single treatment. Then, the clothing treated by the method for deodorizing clothing pests according to the present invention has a synergistic effect of a pest repellent component and a perfume component, which will be described later, because the deodorant function of the perfume component lasts for a long period of time, for example, all day long. Even when going out, unpleasant pests do not approach and the odor can be comfortably taken for a long time.
　本発明に係る衣料害虫忌避組成物は、害虫忌避成分に特定の香料成分を組み合わせることによって、害虫忌避成分と香料成分との相乗効果により、香料成分による消臭機能を長期に亘って持続させることができる。消臭機能の持続期間は、害虫忌避成分と香料成分との組み合わせ、両成分の配合割合、衣料害虫忌避組成物の使用条件等により異なるが、おおよそ半日ないし一日程度、消臭機能を持続させることは十分に可能である。このため、この衣料害虫忌避組成物を用いて実行される本発明の衣料消臭方法に従って、外出前に噴霧処理を実施すれば、例えば、１２時間程度の外出の間は香料成分による消臭機能が持続し、衣類に付着した悪臭により不快感が生じることを防ぐことができる。 The clothing pest repellent composition according to the present invention, by combining a specific perfume component with a pest repellent component, by the synergistic effect of the pest repellent component and the perfume component, to maintain the deodorant function by the perfume component for a long time. You can The duration of the deodorant function varies depending on the combination of the pest repellent component and the fragrance component, the mixing ratio of both components, the use conditions of the clothing pest repellent composition, etc., but the deodorant function is maintained for about half a day to one day. It is fully possible. Therefore, if the spray treatment is carried out before going out according to the clothing deodorizing method of the present invention which is carried out by using this clothing pest repellent composition, for example, the deodorizing function by the fragrance component during going out for about 12 hours. It is possible to prevent the discomfort caused by the bad smell attached to the clothes.
　本発明の衣料害虫忌避組成物について、消臭機能の持続性を確認するため、本発明の特徴構成を備えた衣料害虫忌避組成物（実施例１～５４）を準備し、消臭機能確認試験を実施した。また、比較のため、本発明の特徴構成を備えていない衣料害虫忌避組成物（比較例１～５６）を準備し、同様の消臭機能確認試験を実施した。なお、実施例１～５４、及び比較例１～５６では重量の単位として「ｇ」が示されているが、任意の倍率でスケールアップが可能である。すなわち、単位「ｇ」は、「重量部」と読み替えることができる。 Regarding the clothing pest repellent composition of the present invention, in order to confirm the durability of the deodorant function, a clothing pest repellent composition (Examples 1 to 54) having the characteristic constitution of the present invention was prepared, and a deodorant function confirmation test was conducted. Was carried out. For comparison, clothing pest repellent compositions (Comparative Examples 1 to 56) not having the characteristic constitution of the present invention were prepared, and the same deodorant function confirmation test was carried out. In addition, in Examples 1 to 54 and Comparative Examples 1 to 56, “g” is shown as a unit of weight, but it is possible to scale up at any magnification. That is, the unit “g” can be read as “part by weight”.
＜実施例１～２１＞
　害虫忌避成分としてＩＲ３５３５を使用する下記の処方１により、衣料害虫忌避組成物（実施例１～２１）を調製した。実施例１～１９の衣料害虫忌避組成物においては、化合物Ａ～Ｓを香料成分として使用した。実施例２０の衣料害虫忌避組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、及びＱを等量ずつ混合した調合香料（以下、「調合香料１」と称する。）を香料成分として使用した。実施例２１の衣料害虫忌避組成物においては、化合物Ｌ、Ｎ、Ｑ、β－ダマスコン、及びカシュメランを等量ずつ混合した調合香料（以下、「調合香料２」と称する。）を香料成分として使用した。 <Examples 1 to 21>
Clothing pest repellent compositions (Examples 1 to 21) were prepared according to the following formulation 1 using IR3535 as a pest repellent component. In the clothing pest repellent compositions of Examples 1 to 19, compounds A to S were used as perfume ingredients. In the clothing pest repellent composition of Example 20, a compounded fragrance obtained by mixing compounds B, H, L, N, and Q in equal amounts (hereinafter referred to as “prepared fragrance 1”) was used as a fragrance component. In the clothing pest repellent composition of Example 21, a compounded fragrance (hereinafter, referred to as “prepared fragrance 2”) in which equal amounts of the compounds L, N, Q, β-damascon, and cachemelan were mixed was used as a fragrance component. did.
　処方１：
　香料成分を０．５ｇ（０．５ｗ／ｖ％）、ＩＲ３５３５を３．５ｇ（３．５ｗ／ｖ％）、イソプロピルメチルフェノール（ＩＰＭＰ）を０．１ｇ（０．１ｗ／ｖ％）、メントールを１．０ｇ（１．０ｗ／ｖ％）、トリエタノールアミン（ＴＥＡ）を０．０５ｇ（０．０５ｗ／ｖ％）、精製水を４０ｇ（４０ｗ／ｖ％）、並びに、無水エタノールを残分（バランス）混合し、全量１００ｍＬに調製した。処方１において、香料成分（ａ）と害虫忌避成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．１４である。 Prescription 1:
0.5 g (0.5 w / v%) of fragrance component, 3.5 g (3.5 w / v%) of IR3535, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL. In Formulation 1, the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.14 as a weight ratio.
＜実施例２２～２７＞
　害虫忌避成分としてＩＲ３５３５を使用する下記の処方２により、衣料害虫忌避組成物（実施例２２～２７）を調製した。実施例２２～２７の衣料害虫忌避組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、Ｑ、及び調合香料１を香料成分として使用した。 <Examples 22 to 27>
Clothing pest repellent compositions (Examples 22 to 27) were prepared according to the following formulation 2 using IR3535 as a pest repellent component. In the clothing pest repellent compositions of Examples 22 to 27, the compounds B, H, L, N, Q and the prepared perfume 1 were used as the perfume ingredients.
　処方２：
　香料成分を０．５ｇ（０．５ｗ／ｖ％）、ＩＲ３５３５を０．５ｇ（０．５ｗ／ｖ％）、イソプロピルメチルフェノール（ＩＰＭＰ）を０．１ｇ（０．１ｗ／ｖ％）、メントールを１．０ｇ（１．０ｗ／ｖ％）、トリエタノールアミン（ＴＥＡ）を０．０５ｇ（０．０５ｗ／ｖ％）、精製水を４０ｇ（４０ｗ／ｖ％）、並びに、無水エタノールを残分（バランス）混合し、全量１００ｍＬに調製した。処方２において、香料成分（ａ）と害虫忌避成分（ｂ）との配合比（ａ／ｂ）は、重量比として、１．００である。 Prescription 2:
0.5 g (0.5 w / v%) of fragrance component, 0.5 g (0.5 w / v%) of IR3535, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL. In Formulation 2, the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 1.00 as a weight ratio.
＜実施例２８～４８＞
　害虫忌避成分としてイカリジンを使用する下記の処方３により、衣料害虫忌避組成物（実施例２８～４８）を調製した。実施例２８～４８の衣料害虫忌避組成物においては、化合物Ａ～Ｓ、調合香料１、及び調合香料２を香料成分として使用した。 <Examples 28 to 48>
Clothing pest repellent compositions (Examples 28 to 48) were prepared according to the following Formulation 3 using icalidin as a pest repellent component. In the clothing pest repellent compositions of Examples 28 to 48, Compounds A to S, Formulated Perfume 1 and Formulated Perfume 2 were used as perfume ingredients.
　処方３：
　香料成分を０．５ｇ（０．５ｗ／ｖ％）、イカリジンを３．５ｇ（３．５ｗ／ｖ％）、イソプロピルメチルフェノール（ＩＰＭＰ）を０．１ｇ（０．１ｗ／ｖ％）、メントールを１．０ｇ（１．０ｗ／ｖ％）、トリエタノールアミン（ＴＥＡ）を０．０５ｇ（０．０５ｗ／ｖ％）、精製水を４０ｇ（４０ｗ／ｖ％）、並びに、無水エタノールを残分（バランス）混合し、全量１００ｍＬに調製した。処方３において、香料成分（ａ）と害虫忌避成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．１４である。 Prescription 3:
0.5 g (0.5 w / v%) of fragrance component, 3.5 g (3.5 w / v%) of icaridin, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL. In Formulation 3, the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.14 as a weight ratio.
＜実施例４９～５４＞
　害虫忌避成分としてイカリジンを使用する下記の処方４により、衣料害虫忌避組成物（実施例４９～５４）を調製した。実施例４９～５４の衣料害虫忌避組成物においては、化合物Ｂ、Ｈ、Ｌ、Ｎ、Ｑ、及び調合香料１を香料成分として使用した。 <Examples 49 to 54>
Clothing pest repellent compositions (Examples 49 to 54) were prepared according to the following formulation 4 using icalidin as a pest repellent component. In the clothing pest repellent compositions of Examples 49 to 54, Compounds B, H, L, N and Q, and the prepared perfume 1 were used as perfume ingredients.
　処方４：
　香料成分を０．５ｇ（０．５ｗ／ｖ％）、イカリジンを０．５ｇ（０．５ｗ／ｖ％）、イソプロピルメチルフェノール（ＩＰＭＰ）を０．１ｇ（０．１ｗ／ｖ％）、メントールを１．０ｇ（１．０ｗ／ｖ％）、トリエタノールアミン（ＴＥＡ）を０．０５ｇ（０．０５ｗ／ｖ％）、精製水を４０ｇ（４０ｗ／ｖ％）、並びに、無水エタノールを残分（バランス）混合し、全量１００ｍＬに調製した。処方４において、香料成分（ａ）と害虫忌避成分（ｂ）との配合比（ａ／ｂ）は、重量比として、１．００である。 Prescription 4:
0.5 g (0.5 w / v%) of fragrance component, 0.5 g (0.5 w / v%) of icaridin, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), and menthol 1.0 g (1.0 w / v%), triethanolamine (TEA) 0.05 g (0.05 w / v%), purified water 40 g (40 w / v%), and anhydrous ethanol as the balance ( (Balance) and mixed to prepare a total volume of 100 mL. In Formulation 4, the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 1.00 as a weight ratio.
＜比較例１～２１＞
　害虫忌避成分を配合しない下記の処方５により、衣料害虫忌避組成物（比較例１～２１）を調製した。比較例１～２１の衣料害虫忌避組成物においては、化合物Ａ～Ｓ、調合香料１、及び調合香料２を香料成分として使用した。 <Comparative Examples 1 to 21>
Clothing pest repellent compositions (Comparative Examples 1 to 21) were prepared according to the following formulation 5 containing no pest repellent component. In the clothing pest repellent compositions of Comparative Examples 1 to 21, Compounds A to S, Formulated Perfume 1 and Formulated Perfume 2 were used as perfume ingredients.
　処方５：
　香料成分を０．５ｇ（０．５ｗ／ｖ％）、イソプロピルメチルフェノール（ＩＰＭＰ）を０．１ｇ（０．１ｗ／ｖ％）、メントールを１．０ｇ（１．０ｗ／ｖ％）、トリエタノールアミン（ＴＥＡ）を０．０５ｇ（０．０５ｗ／ｖ％）、精製水を４０ｇ（４０ｗ／ｖ％）、並びに、無水エタノールを残分（バランス）混合し、全量１００ｍＬに調製した。 Prescription 5:
0.5 g (0.5 w / v%) of fragrance component, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), 1.0 g (1.0 w / v%) of menthol, triethanol 0.05 g (0.05 w / v%) of amine (TEA), 40 g (40 w / v%) of purified water, and the balance (balance) of anhydrous ethanol were mixed to prepare a total amount of 100 mL.
＜比較例２２＞
　害虫忌避成分としてＩＲ３５３５を使用する下記の処方６により、衣料害虫忌避組成物（比較例２２）を調製した。比較例２２の衣料害虫忌避組成物においては、香料成分を配合していない。 <Comparative Example 22>
A clothing pest repellent composition (Comparative Example 22) was prepared according to the following formulation 6 using IR3535 as a pest repellent component. The clothing pest repellent composition of Comparative Example 22 does not contain a fragrance component.
　処方６：
　ＩＲ３５３５を３．５ｇ（３．５ｗ／ｖ％）、イソプロピルメチルフェノール（ＩＰＭＰ）を０．１ｇ（０．１ｗ／ｖ％）、メントールを１．０ｇ（１．０ｗ／ｖ％）、トリエタノールアミン（ＴＥＡ）を０．０５ｇ（０．０５ｗ／ｖ％）、精製水を４０ｇ（４０ｗ／ｖ％）、並びに、無水エタノールを残分（バランス）混合し、全量１００ｍＬに調製した。処方６において、香料成分（ａ）と害虫忌避成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．００である。 Prescription 6:
IR3535 3.5 g (3.5 w / v%), isopropyl methyl phenol (IPMP) 0.1 g (0.1 w / v%), menthol 1.0 g (1.0 w / v%), triethanolamine 0.05 g (0.05 w / v%) of (TEA), 40 g (40 w / v%) of purified water, and the balance (balance) of anhydrous ethanol were mixed to prepare a total amount of 100 mL. In Formulation 6, the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.00 as a weight ratio.
＜比較例２３＞
　害虫忌避成分としてイカリジンを使用する下記の処方７により、衣料害虫忌避組成物（比較例２３）を調製した。比較例２３の衣料害虫忌避組成物においては、香料成分を配合していない。 <Comparative Example 23>
A clothing pest repellent composition (Comparative Example 23) was prepared according to the following formulation 7 using icalidin as a pest repellent component. The clothing pest repellent composition of Comparative Example 23 does not contain a fragrance component.
　処方７：
　イカリジンを３．５ｇ（３．５ｗ／ｖ％）、イソプロピルメチルフェノール（ＩＰＭＰ）を０．１ｇ（０．１ｗ／ｖ％）、メントールを１．０ｇ（１．０ｗ／ｖ％）、トリエタノールアミン（ＴＥＡ）を０．０５ｇ（０．０５ｗ／ｖ％）、精製水を４０ｇ（４０ｗ／ｖ％）、並びに、無水エタノールを残分（バランス）混合し、全量１００ｍＬに調製した。処方７において、香料成分（ａ）と害虫忌避成分（ｂ）との配合比（ａ／ｂ）は、重量比として、０．００である。 Prescription 7:
3.5 g (3.5 w / v%) of squalidin, 0.1 g (0.1 w / v%) of isopropylmethylphenol (IPMP), 1.0 g (1.0 w / v%) of menthol, triethanolamine 0.05 g (0.05 w / v%) of (TEA), 40 g (40 w / v%) of purified water, and the balance (balance) of anhydrous ethanol were mixed to prepare a total amount of 100 mL. In the formulation 7, the mixing ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.00 as a weight ratio.
＜比較例２４～３４＞
　害虫忌避成分としてＩＲ３５３５を使用する処方１により、衣料害虫忌避組成物（比較例２４～３４）を調製した。比較例２４～３４の衣料害虫忌避組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物を香料成分として使用した。具体的には、比較例２４の衣料害虫忌避組成物においては、下記式（２０）： <Comparative Examples 24 to 34>
Clothing pest repellent compositions (Comparative Examples 24-34) were prepared according to Formulation 1 using IR3535 as a pest repellent component. In the clothing pest repellent compositions of Comparative Examples 24 to 34, compounds having an electron conjugated part other than the electron conjugated part derived from the benzene ring, the benzoic acid ester structure, or the salicylic acid ester structure were used as the perfume ingredients. Specifically, in the clothing pest repellent composition of Comparative Example 24, the following formula (20):
Figure JPOXMLDOC01-appb-C000020
 で示されるクマリン（以下、「化合物Ｃ１」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000020
 Coumarin (hereinafter, referred to as "compound C1") represented by the formula (1) was used as a perfume ingredient.
　比較例２５の衣料害虫忌避組成物においては、下記式（２１）： In the clothing pest repellent composition of Comparative Example 25, the following formula (21):
Figure JPOXMLDOC01-appb-C000021
 で示されるβ-ヨノン（以下、「化合物Ｃ２」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000021
 Β-ionone represented by (hereinafter, referred to as “compound C2”) was used as a perfume ingredient.
　比較例２６の衣料害虫忌避組成物においては、下記式（２２）： In the clothing pest repellent composition of Comparative Example 26, the following formula (22):
Figure JPOXMLDOC01-appb-C000022
 で示されるβ-ダマスコン（以下、「化合物Ｃ３」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000022
 Β-Damascone represented by (hereinafter referred to as “compound C3”) was used as a perfume ingredient.
　比較例２７の衣料害虫忌避組成物においては、下記式（２３）： In the clothing pest repellent composition of Comparative Example 27, the following formula (23):
Figure JPOXMLDOC01-appb-C000023
 で示されるダマセノン（以下、「化合物Ｃ４」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000023
 Damasenone represented by the formula (hereinafter referred to as "compound C4") was used as a perfume ingredient.
　比較例２８の衣料害虫忌避組成物においては、下記式（２４）： In the clothing pest repellent composition of Comparative Example 28, the following formula (24):
Figure JPOXMLDOC01-appb-C000024
 で示されるシトラール（以下、「化合物Ｃ５」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000024
 Citral represented by (hereinafter, referred to as "compound C5") was used as a perfume ingredient.
　比較例２９の衣料害虫忌避組成物においては、下記式（２５）： In the clothing pest repellent composition of Comparative Example 29, the following formula (25):
Figure JPOXMLDOC01-appb-C000025
 で示されるシンナムアルデヒド（以下、「化合物Ｃ６」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000025
 The cinnamaldehyde represented by (hereinafter, referred to as "compound C6") was used as a perfume ingredient.
　比較例３０の衣料害虫忌避組成物においては、下記式（２６）： In the clothing pest repellent composition of Comparative Example 30, the following formula (26):
Figure JPOXMLDOC01-appb-C000026
 で示されるカリクソール（以下、「化合物Ｃ７」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000026
 The calixol represented by (hereinafter referred to as "compound C7") was used as a perfume ingredient.
　比較例３１の衣料害虫忌避組成物においては、下記式（２７）： In the clothing pest repellent composition of Comparative Example 31, the following formula (27):
Figure JPOXMLDOC01-appb-C000027
 で示されるカシュメラン（以下、「化合物Ｃ８」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000027
 The cashew melanin (hereinafter, referred to as "compound C8") was used as a perfume ingredient.
　比較例３２の衣料害虫忌避組成物においては、下記式（２８）： In the clothing pest repellent composition of Comparative Example 32, the following formula (28):
Figure JPOXMLDOC01-appb-C000028
 で示されるマルトール（以下、「化合物Ｃ９」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000028
 Maltol represented by (hereinafter, referred to as "compound C9") was used as a perfume ingredient.
　比較例３３の衣料害虫忌避組成物においては、下記式（２９）： In the clothing pest repellent composition of Comparative Example 33, the following formula (29):
Figure JPOXMLDOC01-appb-C000029
 で示されるカルボン（以下、「化合物Ｃ１０」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000029
 Carvone represented by (hereinafter referred to as "compound C10") was used as a perfume ingredient.
　比較例３４の衣料害虫忌避組成物においては、下記式（３０）： In the clothing pest repellent composition of Comparative Example 34, the following formula (30):
Figure JPOXMLDOC01-appb-C000030
 で示されるファルネセン（以下、「化合物Ｃ１１」と称する。）を香料成分として使用した。
Figure JPOXMLDOC01-appb-C000030
 Farnesene represented by (hereinafter referred to as "compound C11") was used as a perfume ingredient.
＜比較例３５～４５＞
　害虫忌避成分としてイカリジンを使用する処方３により、衣料害虫忌避組成物（比較例３５～４５）を調製した。比較例３５～４５の衣料害虫忌避組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物Ｃ１～Ｃ１１を香料成分として使用した。 <Comparative Examples 35 to 45>
A clothing pest repellent composition (Comparative Examples 35 to 45) was prepared according to Formulation 3 using icalidin as a pest repellent component. In the clothing pest repellent compositions of Comparative Examples 35 to 45, compounds C1 to C11 having an electron conjugated portion other than the electron conjugated portion derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure were used as perfume ingredients.
＜比較例４６～５６＞
　害虫忌避成分を配合しない処方５により、衣料害虫忌避組成物（比較例４６～５６）を調製した。比較例４６～５６の衣料害虫忌避組成物においては、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物Ｃ１～Ｃ１１を香料成分として使用した。 <Comparative Examples 46 to 56>
A clothing pest repellent composition (Comparative Examples 46 to 56) was prepared according to Formulation 5 containing no pest repellent component. In the clothing pest repellent compositions of Comparative Examples 46 to 56, compounds C1 to C11 having an electron conjugated portion other than the electron conjugated portion derived from the benzene ring, the benzoic acid ester structure, or the salicylic acid ester structure were used as the perfume ingredients.
　実施例１～５４、及び比較例１～５６の衣料害虫忌避組成物の処方、及び香料成分を表１、２に示す。 Tables 1 and 2 show the formulations of the clothing pest repellent compositions of Examples 1 to 54 and Comparative Examples 1 to 56, and the perfume ingredients.
Figure JPOXMLDOC01-appb-T000031
Figure JPOXMLDOC01-appb-T000031
Figure JPOXMLDOC01-appb-T000032
Figure JPOXMLDOC01-appb-T000032
［消臭機能確認試験］
　汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭に対する消臭機能確認試験を実施した。汗臭については、腰高シャーレ（外径７５ｍｍ、高さ６０ｍｍ）に試験綿布（５ｃｍｘ５ｃｍ綿布（金巾３号））を置き、イソ吉草酸（ナカライテスク株式会社製）のエタノール溶液を供試悪臭としてスプレーバイアルにて適量噴霧した。ミドル脂臭については、腰高シャーレに試験綿布を置き、ジアセチル（ナカライテスク株式会社製）のエタノール溶液を供試悪臭としてスプレーバイアルにて適量噴霧した。加齢臭については、腰高シャーレに試験綿布を置き、２－ノネナール（東京化成工業株式会社製）のエタノール溶液を供試悪臭としてスプレーバイアルにて適量噴霧した。タバコ臭については、密閉小空間でタバコの煙を試験綿布に暴露処理し、その後、試験綿布を腰高シャーレに置いた。調理臭については、密閉小空間で牛脂を燃やしてその煙を試験綿布に暴露処理し、その後、試験綿布を腰高シャーレに置いた。 [Deodorant function confirmation test]
A deodorant function confirmation test for sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor was conducted. For sweat odor, place a test cotton cloth (5 cm x 5 cm cotton cloth (gold width 3)) on a waist high petri dish (outer diameter 75 mm, height 60 mm), and spray an ethanol solution of isovaleric acid (Nacalai Tesque, Inc.) as a test malodor. A proper amount was sprayed in a vial. Regarding middle-fat odor, a test cotton cloth was placed on a high waist dish and an appropriate amount of an ethanol solution of diacetyl (manufactured by Nacalai Tesque, Inc.) was sprayed as a test malodor in a spray vial. Regarding the aging odor, a test cotton cloth was placed on a high waist petri dish, and an ethanol solution of 2-nonenal (manufactured by Tokyo Kasei Kogyo Co., Ltd.) was sprayed as an offensive odor in an appropriate amount with a spray vial. For tobacco odor, cigarette smoke was exposed to a test cotton cloth in a closed small space, and then the test cotton cloth was placed on a waist high petri dish. Regarding cooking odor, beef tallow was burned in a small enclosed space to expose the smoke to a test cotton cloth, and then the test cotton cloth was placed on a waist-high petri dish.
　悪臭を付加させたそれぞれの試験綿布に対し、実施例１～５４、及び比較例１～５６の試験溶液をスプレーバイアルにて０．０３ｍＬ噴霧し、試験溶液噴霧直後、３時間後、及び１２時間後に、腰高シャーレ内の臭気を評価した。臭気の評価は以下の５段階臭気強度表示法で５人のテスターにより評価し、平均点を求めた。平均点０以上２未満を○、２以上３未満を△、３以上４以下を×とした。
　　０：香りを感じない
　　１：かすかに感じる
　　２：弱く感じる
　　３：明らかに感じる
　　４：強く感じる 0.03 mL of the test solution of Examples 1 to 54 and Comparative Examples 1 to 56 was sprayed onto each test cotton cloth to which a malodor was added by a spray vial, immediately after spraying the test solution, 3 hours, and 12 hours. Later, the odor inside the high waist dish was evaluated. The odor was evaluated by five testers according to the following five-level odor intensity display method, and the average score was obtained. An average score of 0 or more and less than 2 was evaluated as ◯, 2 or more and less than 3 was evaluated as Δ, and 3 or more and 4 or less was evaluated as x.
0: Do not feel scent 1: Feel slightly 2: Feel weak 3: Feel clearly 4: Feel strongly
　汗臭に対する消臭機能確認試験の結果を表３、４に示す。 Tables 3 and 4 show the results of the deodorant function confirmation test for sweat odor.
Figure JPOXMLDOC01-appb-T000033
Figure JPOXMLDOC01-appb-T000033
Figure JPOXMLDOC01-appb-T000034
Figure JPOXMLDOC01-appb-T000034
　ミドル脂臭に対する消臭機能確認試験の結果を表５、６に示す。 Tables 5 and 6 show the results of the deodorant function confirmation test for middle-fat odors.
Figure JPOXMLDOC01-appb-T000035
Figure JPOXMLDOC01-appb-T000035
Figure JPOXMLDOC01-appb-T000036
Figure JPOXMLDOC01-appb-T000036
　加齢臭に対する消臭機能確認試験の結果を表７、８に示す。 Tables 7 and 8 show the results of the deodorant function confirmation test for aging odor.
Figure JPOXMLDOC01-appb-T000037
Figure JPOXMLDOC01-appb-T000037
Figure JPOXMLDOC01-appb-T000038
Figure JPOXMLDOC01-appb-T000038
　タバコ臭に対する消臭機能確認試験の結果を表９、１０に示す。 Tables 9 and 10 show the results of the deodorant function confirmation test for tobacco odor.
Figure JPOXMLDOC01-appb-T000039
Figure JPOXMLDOC01-appb-T000039
Figure JPOXMLDOC01-appb-T000040
Figure JPOXMLDOC01-appb-T000040
　調理臭に対する消臭機能確認試験の結果を表１１、１２に示す。 Tables 11 and 12 show the results of the deodorant function confirmation test for cooking odors.
Figure JPOXMLDOC01-appb-T000041
Figure JPOXMLDOC01-appb-T000041
Figure JPOXMLDOC01-appb-T000042
Figure JPOXMLDOC01-appb-T000042
　消臭機能確認試験の結果、本発明の特徴構成を備えた衣料害虫忌避組成物は、害虫忌避成分としてＩＲ３５３５を含有する実施例１～２７、及び害虫忌避成分としてイカリジンを含有する実施例２８～５４の何れであっても、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭に対して、試験溶液の噴霧処理から１２時間後も優れた消臭性を示した。このことから、本発明の特徴構成を備えた衣料害虫忌避組成物を、外出前に衣類へ噴霧処理しておくことで、１２時間程度の外出の間は香料成分による消臭機能が持続し、衣類に付着した悪臭により不快感が生じることを防ぐことができると考えられる。 As a result of the deodorant function confirmation test, the clothing pest repellent compositions having the characteristic constitution of the present invention are Examples 1 to 27 containing IR3535 as a pest repellent component and Example 28 to containing Icaridine as a pest repellent component. Any of No. 54 exhibited excellent deodorizing properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor even after 12 hours from the spray treatment of the test solution. From this, by spraying the clothing pest repellent composition having the characteristic constitution of the present invention onto clothes before going out, the deodorizing function by the fragrance component is maintained during going out for about 12 hours, It is considered that it is possible to prevent the discomfort caused by the bad odor attached to the clothes.
　一方、害虫忌避成分を含有していない比較例１～２１の衣料害虫忌避組成物は、害虫忌避成分としてＩＲ３５３５を含有する実施例１～２７、及び害虫忌避成分としてイカリジンを含有する実施例２８～５４と、同一の香料成分を含有しているが、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても、試験溶液の噴霧処理から３時間後までの消臭性を示すに留まり、試験溶液の噴霧処理から１２時間後には十分な消臭性を示さなかった。 On the other hand, the clothing pest repellent compositions of Comparative Examples 1 to 21 containing no pest repellent component are Examples 1 to 27 containing IR3535 as a pest repellent component and Example 28 containing Icaridine as a pest repellent component. 54, the same fragrance component is contained, but for any of sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor, the test solution is extinguished for up to 3 hours after spray treatment. It showed only odor, and did not show sufficient deodorant after 12 hours from the spray treatment of the test solution.
　比較例２２の衣料害虫忌避組成物は、実施例１～２７と同様に害虫忌避成分としてＩＲ３５３５を含有しており、比較例２３の衣料害虫忌避組成物は、実施例２８～５４と同様に害虫忌避成分としてイカリジンを含有しているが、比較例２２及び２３は何れも香料成分を含有していない。このような比較例２２及び２３の衣料害虫忌避組成物は、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても消臭性を示さなかった。このことから、害虫忌避成分であるＩＲ３５３５、及びイカリジンは単独では消臭性を有していないことが確認された。害虫忌避成分であるＩＲ３５３５、及びイカリジンが単独では消臭性を有していないにもかかわらず、比較例１～２１の衣料害虫忌避組成物と比較して、これらに害虫忌避成分を配合しただけの実施例１～５４の衣料害虫忌避組成物において消臭機能が長時間持続したのは、害虫忌避成分が本発明において規定する特定の香料成分と何らかの相乗効果を奏するためと考えられる。 The clothing pest repellent composition of Comparative Example 22 contains IR3535 as a pest repellent component as in Examples 1-27, and the clothing pest repellent composition of Comparative Example 23 is the same as Examples 28-54. Although icalidin is contained as a repellent component, Comparative Examples 22 and 23 do not contain a fragrance component. The clothing pest repellent compositions of Comparative Examples 22 and 23 did not show deodorant properties against sweat odor, middle fat odor, aging odor, tobacco odor, and cooking odor. From this, it was confirmed that IR3535, which is a pest repellent component, and icaridin alone have no deodorant property. Despite the fact that IR3535, which is a pest repellent component, and icaridin alone have no deodorizing property, they are mixed with a pest repellent component as compared with the clothing pest repellent compositions of Comparative Examples 1 to 21. It is considered that the deodorant function of the clothing pest repellent compositions of Examples 1 to 54 lasted for a long time because the pest repellent component has some synergistic effect with the specific fragrance component defined in the present invention.
　また、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有する化合物を香料成分として使用した比較例２４～５６は、汗臭、ミドル脂臭、加齢臭、タバコ臭、及び調理臭の何れに対しても、試験溶液の噴霧処理から３時間後までの消臭性を示すに留まり、試験溶液の噴霧処理から１２時間後には十分な消臭性を示さなかった。害虫忌避成分としてＩＲ３５３５を含有する場合（比較例２４～３４）、及び害虫忌避成分としてイカリジンを含有する場合（比較例３５～４５）でも、消臭機能が長時間持続しなかったのは、本発明において規定する特定の香料成分を使用していないために、害虫忌避成分と香料成分との相乗効果が得られなかったためと考えられる。 Further, Comparative Examples 24 to 56 in which a compound having an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure was used as a perfume component, were sweat odor, middle fat odor, and aging. With respect to all odors, cigarette odors, and cooking odors, the deodorant property is shown only after 3 hours from the spray treatment of the test solution, and sufficient deodorant property is obtained 12 hours after the spray treatment of the test solution. Did not show. Even when containing IR3535 as a pest repellent component (Comparative Examples 24 to 34) and ikaridin as a pest repellent component (Comparative Examples 35 to 45), the deodorant function did not last for a long time. It is considered that the synergistic effect of the pest repellent component and the fragrance component was not obtained because the specific fragrance component specified in the invention was not used.
　以上の結果から、本発明の特徴構成を備えた衣料害虫忌避組成物（実施例１～５４）は、特定の害虫忌避成分と特定の香料成分との組み合わせにより、害虫忌避成分と香料成分との相乗効果が得られ、香料成分による消臭機能が長時間に亘って持続することが確認された。 From the above results, the clothing pest repellent compositions (Examples 1 to 54) provided with the characteristic constitution of the present invention are obtained by combining a specific pest repellent component and a specific perfume component with the pest repellent component and the perfume component. It was confirmed that a synergistic effect was obtained and that the deodorizing function of the fragrance component was maintained for a long time.
　本発明の衣料害虫忌避組成物、及び衣料消臭方法は、衣類に付着した悪臭を消臭するために使用されるものであり、繊維製品の消臭に利用可能である。さらに、本発明の衣料害虫忌避消臭方法は、繊維製品に対する害虫忌避及び消臭に利用可能である。 The clothing pest repellent composition and the clothing deodorizing method of the present invention are used for deodorizing a bad odor adhering to clothing and can be used for deodorizing a textile product. Furthermore, the clothing pest repellent and deodorizing method of the present invention can be used for pest repelling and deodorizing textile products.

Claims (7)

  1. 　害虫忌避成分と香料成分とを含有する衣料害虫忌避組成物であって、
    　前記香料成分は、衣料に付着した悪臭を消臭する消臭機能を有し、
    　前記害虫忌避成分は、前記香料成分の消臭機能を持続させる持続機能を有する衣料害虫忌避組成物。     A clothing pest repellent composition comprising a pest repellent component and a fragrance component,
    The fragrance component has a deodorizing function of deodorizing a bad odor attached to clothing,
    The said insect pest repellent component is a clothing pest repellent composition having a sustaining function of sustaining the deodorizing function of said flavor component.
  2. 　前記害虫忌避成分は、３－（Ｎ－ブチルアセトアミド）プロピオン酸エチル、イカリジン、及びＮ，Ｎ－ジエチルトルアミドからなる群から選択される少なくとも一つであり、
    　前記香料成分は、ベンゼン環、安息香酸エステル構造、又はサリチル酸エステル構造に由来する電子共役部以外の電子共役部を有さず、炭素数が６～１８であり、分子量が９８～２７０であり、炭素原子、水素原子、及び酸素原子を有し、硫黄原子、窒素原子、及びハロゲン原子を有さない化合物である請求項１に記載の衣料害虫忌避組成物。     The pest repellent component is at least one selected from the group consisting of ethyl 3- (N-butylacetamide) propionate, icaridin, and N, N-diethyltoluamide,
    The fragrance component does not have an electron conjugated part other than the electron conjugated part derived from a benzene ring, a benzoic acid ester structure, or a salicylic acid ester structure, has 6 to 18 carbon atoms, and has a molecular weight of 98 to 270. The clothing pest repellent composition according to claim 1, which is a compound having a carbon atom, a hydrogen atom, and an oxygen atom and not having a sulfur atom, a nitrogen atom, and a halogen atom.
  3. 　前記香料成分は、シス－３－ヘキセノール、ジヒドロミルセノール、エチルリナロール、リナロール 、ゲラニオール、テトラヒドロゲラニオール、テルピネオール、フェニルエチルアルコール、ヘリオナール、リリアール、安息香酸ベンジル、サリチル酸ベンジル、シス－３－ヘキセニルサリチレート、ジヒドロジャスモン酸メチル、リナリルアセテート、ラズベリーケトン、ガラクソリド、エチレンブラシレート、及びシクロペンタデカノリドからなる群から選択される少なくとも一つである請求項１又は２に記載の衣料害虫忌避組成物。 The fragrance component is cis-3-hexenol, dihydromyrcenol, ethyl linalool, linalool, geraniol, tetrahydrogeraniol, terpineol, phenylethyl alcohol, helional, lilial, benzyl benzoate, benzyl salicylate, cis-3-hexenyl salicyt. 3. The clothing pest repellent composition according to claim 1 or 2, which is at least one selected from the group consisting of phthalate, methyl dihydrojasmonate, linalyl acetate, raspberry ketone, galaxolide, ethylene brushlate, and cyclopentadecanolide.
  4. 　前記香料成分の含有量が０．１～１．０ｗ／ｖ％である請求項１～３の何れか一項に記載の衣料害虫忌避組成物。 The clothing pest repellent composition according to any one of claims 1 to 3, wherein the content of the fragrance component is 0.1 to 1.0 w / v%.
  5. 　前記香料成分（ａ）と前記害虫忌避成分（ｂ）との配合比（ａ／ｂ）が、重量比として、０．１～１．５である請求項１～４の何れか一項に記載の衣料害虫忌避組成物。 The blending ratio (a / b) of the fragrance component (a) and the pest repellent component (b) is 0.1 to 1.5 as a weight ratio. Clothing pest repellent composition.
  6. 　請求項１～５の何れか一項に記載の衣料害虫忌避組成物を用いた衣料消臭方法であって、
    　前記衣料害虫忌避組成物を衣料に噴霧処理する衣料消臭方法。     A method for deodorizing clothing using the clothing pest repellent composition according to any one of claims 1 to 5, comprising:
    A method for deodorizing clothing, which comprises spray-treating the clothing pest repellent composition onto clothing.
  7. 　衣料に対して害虫忌避処理と消臭処理とを同時に行う衣料害虫忌避消臭方法であって、
    　処理対象の衣料に害虫忌避成分と香料成分とを含有する衣料害虫忌避組成物を噴霧する噴霧工程と、
    　前記衣料において十分な害虫忌避効果及び消臭効果が持続するように、前記衣料に対して前記衣料害虫忌避組成物を噴霧する位置を変更する変更工程と、
    を包含する衣料害虫忌避消臭方法。     A method for deodorizing clothing pests by simultaneously performing pest repellent treatment and deodorant treatment on clothing,
    A spraying step of spraying a clothing pest repellent composition containing a pest repellent component and a fragrance component on the clothing to be treated,
    In order to maintain a sufficient pest repellent effect and deodorant effect in the clothing, a changing step of changing the position of spraying the clothing pest repellent composition on the clothing,
    A method for deodorizing and deterring clothing pests including.
PCT/JP2019/042762 2018-11-06 2019-10-31 Fabric pest repelling composition, and, clothes deodorization method and fabric pest repelling deodorization method using composition WO2020095808A1 (en)

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