KR20080071915A - 소수성 농약 활성 화합물을 함유하는 액체 농약 조성물 - Google Patents
소수성 농약 활성 화합물을 함유하는 액체 농약 조성물 Download PDFInfo
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- KR20080071915A KR20080071915A KR1020080009371A KR20080009371A KR20080071915A KR 20080071915 A KR20080071915 A KR 20080071915A KR 1020080009371 A KR1020080009371 A KR 1020080009371A KR 20080009371 A KR20080009371 A KR 20080009371A KR 20080071915 A KR20080071915 A KR 20080071915A
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- South Korea
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- compound
- polyoxyethylene polyoxypropylene
- pesticide
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- water
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 93
- 239000007788 liquid Substances 0.000 title claims abstract description 55
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 25
- 239000012872 agrochemical composition Substances 0.000 title abstract 4
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 claims abstract description 40
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- CYSGHNMQYZDMIA-UHFFFAOYSA-N 1,3-Dimethyl-2-imidazolidinon Chemical compound CN1CCN(C)C1=O CYSGHNMQYZDMIA-UHFFFAOYSA-N 0.000 claims abstract description 21
- -1 alkyl phenol Chemical compound 0.000 claims abstract description 20
- 229920001400 block copolymer Polymers 0.000 claims abstract description 17
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 15
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 13
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 4
- 238000007865 diluting Methods 0.000 claims abstract description 4
- 239000004359 castor oil Substances 0.000 claims abstract description 3
- 235000019438 castor oil Nutrition 0.000 claims abstract description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 3
- 239000000575 pesticide Substances 0.000 claims description 97
- 239000000203 mixture Substances 0.000 claims description 54
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- 230000002363 herbicidal effect Effects 0.000 description 74
- 230000001954 sterilising effect Effects 0.000 description 51
- 238000004659 sterilization and disinfection Methods 0.000 description 51
- 239000004009 herbicide Substances 0.000 description 28
- 241000238631 Hexapoda Species 0.000 description 27
- 230000000844 anti-bacterial effect Effects 0.000 description 15
- IUSARDYWEPUTPN-OZBXUNDUSA-N (2r)-n-[(2s,3r)-4-[[(4s)-6-(2,2-dimethylpropyl)spiro[3,4-dihydropyrano[2,3-b]pyridine-2,1'-cyclobutane]-4-yl]amino]-3-hydroxy-1-[3-(1,3-thiazol-2-yl)phenyl]butan-2-yl]-2-methoxypropanamide Chemical compound C([C@H](NC(=O)[C@@H](C)OC)[C@H](O)CN[C@@H]1C2=CC(CC(C)(C)C)=CN=C2OC2(CCC2)C1)C(C=1)=CC=CC=1C1=NC=CS1 IUSARDYWEPUTPN-OZBXUNDUSA-N 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 8
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 229940125782 compound 2 Drugs 0.000 description 6
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- 239000002728 pyrethroid Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- ZLIBICFPKPWGIZ-UHFFFAOYSA-N pyrimethanil Chemical compound CC1=CC(C)=NC(NC=2C=CC=CC=2)=N1 ZLIBICFPKPWGIZ-UHFFFAOYSA-N 0.000 description 1
- NHDHVHZZCFYRSB-UHFFFAOYSA-N pyriproxyfen Chemical compound C=1C=CC=NC=1OC(C)COC(C=C1)=CC=C1OC1=CC=CC=C1 NHDHVHZZCFYRSB-UHFFFAOYSA-N 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
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- 229960004546 thiabendazole Drugs 0.000 description 1
- AHTPATJNIAFOLR-UHFFFAOYSA-N thifensulfuron-methyl Chemical group S1C=CC(S(=O)(=O)NC(=O)NC=2N=C(OC)N=C(C)N=2)=C1C(=O)OC AHTPATJNIAFOLR-UHFFFAOYSA-N 0.000 description 1
- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- BAZVSMNPJJMILC-UHFFFAOYSA-N triadimenol Chemical compound C1=NC=NN1C(C(O)C(C)(C)C)OC1=CC=C(Cl)C=C1 BAZVSMNPJJMILC-UHFFFAOYSA-N 0.000 description 1
- FFSJPOPLSWBGQY-UHFFFAOYSA-N triazol-4-one Chemical compound O=C1C=NN=N1 FFSJPOPLSWBGQY-UHFFFAOYSA-N 0.000 description 1
- YWBFPKPWMSWWEA-UHFFFAOYSA-O triazolopyrimidine Chemical compound BrC1=CC=CC(C=2N=C3N=CN[N+]3=C(NCC=3C=CN=CC=3)C=2)=C1 YWBFPKPWMSWWEA-UHFFFAOYSA-O 0.000 description 1
- DQJCHOQLCLEDLL-UHFFFAOYSA-N tricyclazole Chemical compound CC1=CC=CC2=C1N1C=NN=C1S2 DQJCHOQLCLEDLL-UHFFFAOYSA-N 0.000 description 1
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- XAIPTRIXGHTTNT-UHFFFAOYSA-N triflumuron Chemical compound C1=CC(OC(F)(F)F)=CC=C1NC(=O)NC(=O)C1=CC=CC=C1Cl XAIPTRIXGHTTNT-UHFFFAOYSA-N 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
소수성 농약 활성 화합물 0.5 내지 30 중량%, 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 등으로 이루어진 군에서 선택된 비이온성 계면활성제 1 내지 20 중량%, 음이온성 계면활성제 0 내지 10 중량%, γ-부티로락톤 6 내지 60 중량% 및 1,3-디메틸-2-이미다졸리디논 20 내지 75 중량%를 포함하는 물-희석 상태가 안정한 액체 농약 조성물; 및 상기 액체 농약 조성물을 10 내지 10,000 배 양의 물로 희석시켜 수득된 물-희석 용액이 제공된다.
Description
본 발명은 소수성 농약 활성 화합물을 함유하는 액체 농약 조성물에 관한 것이다.
소수성 농약 활성 화합물을 함유하는 액체 농약 제제의 대표적인 예는 에멀젼 및 유동액을 포함한다. 에멀젼 및 유동액이 분무되는 경우, 이들은 다량의 물로 희석되어 물-희석 용액으로서 사용된다. 상기 물-희석 용액에 있어서, 소수성 농약 활성 화합물은 미세 오일 방울 또는 고체 입자가 물에서 계면활성제의 작용에 의해 분산되는 것으로, 상기 상태가 열역학적으로 불안정 상태이기 때문에, 소수성 농약 활성 화합물을 함유하는 오일 방울이 시간에 따라 분리되고, 소수성 농약 활성 화합물이 고체인 경우, 고체 입자는 일부 경우 침전 및 침강된다.
JP 2003-128501 A 에는 소수성 농약 화합물인 퀴잘로포프(quizalofop)-p-에틸, 폴리옥시에틸렌스티릴 페닐 에테르, 도데실벤젠 술폰산염, 솔베소 (Solvesso) 200 및 1,3-디메틸-2-이미다졸리디논을 함유하는 액체 농약 제제가 기재되어 있지 만, 상기 액체 농약 제제는 물-희석 상태에서 반드시 안정한 것은 아니다.
발명의 개요
상기 상황 하에서, 본 발명자들은 물-희석 상태에서 안정한 소수성 농약 활성 화합물을 함유하는 액체 농약 제제를 수득하기 위해 연구하였다. 결국, 본 발명을 완성하였다.
즉, 본 발명은 하기를 제공한다:
(1) 하기를 포함하는 액체 농약 조성물:
하나 이상의 소수성 농약 활성 화합물 0.5 내지 30 중량%;
하기 군 (A) 에서 선택된 하나 이상의 비이온성 계면활성제 1 내지 20 중량%;
하나 이상의 음이온성 계면활성제 0 내지 10 중량%;
γ-부티로락톤 6 내지 60 중량%; 및
1,3-디메틸-2-이미다졸리디논 20 내지 75 중량%,
군 (A):
폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체,
폴리옥시에틸렌 폴리옥시프로필렌 알킬 에테르,
폴리옥시에틸렌 폴리옥시프로필렌 알킬 페놀,
폴리옥시에틸렌 폴리옥시프로필렌 폴리스티릴 페닐 에테르, 및
폴리옥시에틸렌 폴리옥시프로필렌 피마자유;
(2) 상기 (1) 에 있어서, 비이온성 계면활성제가 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체인 액체 농약 조성물;
(3) 상기 (1) 또는 (2) 에 있어서, 음이온성 계면활성제의 양이 1 내지 10 중량%의 범위인 액체 농약 조성물;
(4) 상기 (3) 에 있어서, 음이온성 계면활성제가 알킬벤젠술포네이트인 액체 농약 조성물; 및
(5) 상기 (1) 내지 (4) 중 어느 하나에 따른 액체 농약 조성물을 10 내지 10,000 배 양의 물로 희석시켜 수득되는 물-희석 용액.
본 발명의 액체 농약 조성물 (이하, 때때로, 본 액체 농약 조성물로 칭함) 은 물-희석 상태에서 안정하다.
바람직한 구현예의 상세한 설명
본 발명에 있어서, 소수성 농약 활성 화합물은, 물에서 불용성이거나 또는 거의 가용성이 아니고, 25 ℃에서 물이 사용되는 경우, 물에 대한 용해도가 통상적으로 0.5 g/L 이하, 바람직하게는 0.1 g/L 이하이고, 25 ℃에서 고체 또는 액체 중 임의의 형태를 가질 수 있는 농약 활성 화합물을 의미한다.
농약 활성 화합물의 예는 제초 활성 화합물, 살균 활성 화합물, 살충 (살비) 활성 화합물 및 식물 성장 조절 화합물을 포함하고, 예를 들어, 하기 화합물이 구 체적으로 예시될 수 있다.
제초 활성 화합물로서, 예는 하기를 포함한다:
디카르복시이미드계 제초 활성 화합물: 플루미클로락-펜틸 (Flumiclorac-pentyl) [제초 화합물 1], 플루미옥사진 (Flumioxazin) [제초 화합물 2], 시니돈-에틸 (Cinidon-ethyl) [제초 화합물 3] 등;
피리다지논계 제초 활성 화합물: 플루펜피르-에틸 (Flufenpyr-ethyl) [제초 화합물 4], 브롬피라존 (Brompyrazone) [제초 화합물 5] 등;
우라실계 제초 활성 화합물: 부타페나실 (Butafenacil) [제초 화합물 6], 브로마실 (Bromacil) [제초 화합물 7], 플루프로파실 (Flupropacil) [제초 화합물 8], 벤조펜디존 (Benzofendizone) [제초 화합물 9] 등;
트리아졸론계 제초 활성 화합물: 카르펜트라존-에틸 (Carfentrazone-ethyl) [제초 화합물 10], 술펜트라존 (Sulfentrazone) [제초 화합물 11] 등;
디페닐 에테르 제초 활성 화합물: 락토펜 (Lactofen) [제초 화합물 12], 비페녹스 (Bifenox) [제초 화합물 13], 클로르니트로페논 (Chlornitrophenone) [제초 화합물 14], 클로메톡시닐 (Chlomethoxynil) [제초 화합물 15] 등;
술포닐우레아계 제초 활성 화합물: 술포술푸론 (Sulfosulfuron) [제초 화합물 16], 이마조술푸론 (Imazosulfuron) [제초 화합물 17], 니코술푸론 (Nicosulfuron) [제초 화합물 18], 프리미술푸론-메틸 (Primisulfuron-methyl) [제초 화합물 19], 림술푸론 (Rimsulfuron) [제초 화합물 20], 할로술푸론-메틸 (Halosulfuron-methyl) [제초 화합물 21], 프로술푸론 (Prosulfuron) [제초 화합물 22], 티펜술푸론-메틸 (Thifensulfuron-methyl) [제초 화합물 23] 등;
페녹시프로피온산계 제초 활성 화합물: 클로아지포프 (Cloazifop) [제초 화합물 24], 디클로포프 (Diclofop) [제초 화합물 25], 플루아지포프 (Fluazifop) [제초 화합물 26] 등;
트리아졸로피리미딘계 제초 활성 화합물: 디클로술람 (Diclosulam) [제초 화합물 27], 클로란술람 (Cloransulam) [제초 화합물 28], 플루메트술람 (Flumetsulam) [제초 화합물 29], 페녹스술람 (Penoxsulam) [제초 화합물 30], 필록스술람 (Pyloxsulam) [제초 화합물 31], 메토술람 (Metosulam) [제초 화합물 32] 등;
아닐리드계 제초 활성 화합물: 피콜리나펜 (Picolinafen) [제초 화합물 33], 플루페나세트 (Flufenacet) [제초 화합물 34], 메페나세트 (Mefenacet) [제초 화합물 35] 등;
트리아진계 제초 활성 화합물: 아트라진 (Atrazin) [제초 화합물 36], 메트리부진 (Metribuzin) [제초 화합물 37] 등;
우레아계 제초 활성 화합물: 플루오메투론 (Fluometuron) [제초 화합물 38], 이소프로투론 (Isoproturon) [제초 화합물 39], 딤론 (Dymron) [제초 화합물 40] 등;
이미다졸린계 제초 활성 화합물: 이마자피르 (Imazapyr) [제초 화합물 41], 이마자퀸 (Imazaquin) [제초 화합물 42], 이마제타피르 (Imazethapyr) [제초 화합물 43] 등;
클로로아세트아미드계 제초 활성 화합물: 프레틸라클로르 (Pretilachlor) [제초 화합물 44], 부타클로르 (Butachlor) [제초 화합물 45] 등;
티올카르바메이트계 제초 활성 화합물: 벤티오카르브 (Benthiocarb) [제초 화합물 46], 에스프로카르브 (Esprocarb) [제초 화합물 47], 몰리네이트 (Molinate) [제초 화합물 48] 등;
아미드계 제초 활성 화합물: 브로모부티드 (bromobutide) [제초 화합물 49], 프로파닐 (Propanil) [제초 화합물 50], 카펜스트롤 (Cafenstrole) [제초 화합물 51] 등;
벤조일피라졸계 제초 활성 화합물: 피라족시펜 (Pyrazoxyfen) [제초 화합물 52], 벤조페나프 (Benzofenap) [제초 화합물 53] 등; 및
메틸 {2-클로로-4-플루오로-5-[5,6,7,8-테트라히드로-3-옥소-1H,3H-[1,3,4]티아디아졸로[3,4-a]피리다진-1-일리덴아미노]페닐티오}아세테이트 [제초 화합물 54], N-벤질-2-(α,α,α,4-테트라플루오로-m-톨릴옥시)부틸아미드 [제초 화합물 55], 및 2-(2,4-디클로로-5-프로프-2-이닐옥시페닐)-5,6,7,8-테트라히드로-1,2,4-트리아졸로[4,3-a]피리딘-3(2H)-온 [제초 화합물 56].
살균 활성 화합물로서, 예는 하기를 포함한다:
아졸계 살균 활성 화합물: 프로피코나졸 (Propiconazole) [살균 화합물 1], 트리아디메놀 (Triadimenol) [살균 화합물 2], 프로클로라즈 (Prochloraz) [살균 화합물 3], 펜코나졸 (Penconazole) [살균 화합물 4], 테부코나졸 (Tebuconazole) [살균 화합물 5], 플루실라졸 (Flusilazole) [살균 화합물 6], 디니코나졸 (Diniconazole) [살균 화합물 7], 브롬코나졸 (Bromconazole) [살균 화합물 8], 에폭시코나졸 (Epoxyconazole) [살균 화합물 9], 디페노코나졸 (Difenoconazole) [살 균 화합물 10], 시프로코나졸 (Cyproconazole) [살균 화합물 11], 메트코나졸 (Metconazole) [살균 화합물 12], 트리플루미졸 (Triflumizole) [살균 화합물 13], 테트라코나졸 (Tetraconazole) [살균 화합물 14], 미클로부타닐 (Myclobutanil) [살균 화합물 15], 펜부코나졸 (Fenbuconazole) [살균 화합물 16], 헥사코나졸 (Hexaconazole) [살균 화합물 17], 플루퀸코나졸 (Fluquinconazole) [살균 화합물 18], 트리티코나졸 (Trityconazole) [살균 화합물 19], 비테르타놀 (Bitertanol) [살균 화합물 20], 이마잘릴 (Imazalil) [살균 화합물 21], 플루트리아폴 (Flutriafol) [살균 화합물 22] 등;
모르폴린계 살균 활성 화합물: 펜프로피모르프 (Fenpropimorph) [살균 화합물 23], 트리데모르프 (Tridemorph) [살균 화합물 24], 펜프로피모르프 (Fenpropimorph) [살균 화합물 25], 디메토모르프 (Dimethomorph) [살균 화합물 26] 등;
벤즈이미다졸계 살균 활성 화합물: 카르벤다짐 (Carbendazim) [살균 화합물 27], 베노밀 (Benomyl) [살균 화합물 28], 티아벤다졸 (Tiabendazole) [살균 화합물 29], 티오파네이트-메틸 (Thiophanate-methyl) [살균 화합물 30] 등;
스트로빌루린계 (strobilurin-based) 살균 활성 화합물: 아족시스트로빈 (Azoxystrobin) [살균 화합물 31], 트리플록시스트로빈 (Trifloxystrobin) [살균 화합물 32], 피콕시스트로빈 (Picoxystrobin) [살균 화합물 33], 피라클로스트로빈 (Pyraclostrobin) [살균 화합물 34], 디목시스트로빈 (Dimoxystrobin) [살균 화합물 35], 플루옥사스트로빈 (Fluoxastrobin) [살균 화합물 36], 메토미노스트로빈 (Metominostrobin) [살균 화합물 37], 오리사스트로빈 (Orysastrobin) [살균 화합 물 38] 등;
디카르복시이미드계 살균 활성 화합물: 프로시미돈 (Procymidone) [살균 화합물 39], 이프로디온 (Iprodione) [살균 화합물 40], 빈클로졸린 (Vinclozolin) [살균 화합물 41] 등;
카르복시아미드계 살균 활성 화합물: 푸라메트피르 (Furametpyr) [살균 화합물 42], 메프로닐 (Mepronil) [살균 화합물 43], 플루톨라닐 (Flutolanil) [살균 화합물 44], 트리플루즈아미드 (Trifluzamide) [살균 화합물 45] 등;
아닐리노피리미딘계 살균 활성 화합물: 시프로디닐 (Cyprodinil) [살균 화합물 46], 피리메타닐 (Pyrimethanil) [살균 화합물 47], 메파니피림 (Mepanipyrim) [살균 화합물 48] 등;
페닐피롤계 살균 활성 화합물: 펜피클로닐 (Fenpiclonil) [살균 화합물 49], 플루디옥소닐 (Fludioxonil) [살균 화합물 50] 등;
카르바메이트계 살균 활성 화합물: 이프로발리카르브 (Iprovalicarb) [살균 화합물 51], 벤티아발리카르브 (Benthiavalicarb) [살균 화합물 52], 디에토펜카르브 (Diethofencarb) [살균 화합물 53] 등;
피리딘계 살균 활성 화합물: 보스칼리드 (Boscalid) [살균 화합물 54], 플루아지남 (Fluazinam) [살균 화합물 55] 등; 및
(Z)-2'-메틸아세토페논 4,6-디메틸피리미딘-2-일히드라존, 1-(메톡시카르보닐)-2-(1-메틸에틸)-4-(2,6-디클로로페닐)-5-아미노-1H-피라졸-3-온 [살균 화합물 56],
1-[(에틸티오)카르보닐]-2-(1-메틸에틸)-4-(2,6-디클로로페닐)-5-아미노-1H-피라졸 -3-온 [살균 화합물 57],
1-[(2-프로페닐티오)카르보닐]-2-(1-메틸에틸)-4-(2-메틸페닐)-5-아미노-1H-피라졸-3-온 [살균 화합물 58],
5-메틸-1,2,4-트리아졸로-[3,4-b][1,3]벤조티아졸 [살균 화합물 59], 및
1,2,5,6-테트라히드로피롤로[3,2,1-ij]퀴놀린-4-온, 3-알릴옥시-1,2-벤조티아졸 1,1-디옥시드 [살균 화합물 60].
살충 (살비) 활성 화합물로서, 예는 하기를 포함한다:
유기 인계 살충 활성 화합물: 페니트로티온 (Fenitrothion) [살충 화합물 1], 디아지논 (Diazinon) [살충 화합물 2], 클로르피리포스 (Chlorpyrifos) [살충 화합물 3] 등;
카르바메이트계 살충 활성 화합물: 벤푸라카르브 (Benfuracarb) [살충 화합물 4], 프로폭수르 (Propoxur) [살충 화합물 5], 카르보술판 (Carbosulfan) [살충 화합물 6], 카르바릴 (Carbaryl) [살충 화합물 7], 알디카르브 (Aldicarb) [살충 화합물 8], 페노티오카르브 (Fenothiocarb) [살충 화합물 9] 등;
피레트로이드계 살충 활성 화합물: 에토펜프록스 (Etofenprox) [살충 화합물 10], 펜발레레이트 (Fenvalerate) [살충 화합물 11], 에스펜발레레이트 (Esfenvalerate) [살충 화합물 12], 펜프로파트린 (Fenpropathrin) [살충 화합물 13], 시퍼메트린 (Cypermethrin) [살충 화합물 14], 퍼메트린 (Permethrin) [살충 화합물 15], 시할로트린 (Cyhalothrin) [살충 화합물 16], 델타메트린 (Deltamethrin) [살충 화합물 17], 시클로프로트린 (Cycloprothrin) [살충 화합물 18], 플루발리네이트 (Fluvalinate) [살충 화합물 19], 비펜트린 (Bifenthrin) [살충 화합물 20], 할펜프록스 (Halfenprox) [살충 화합물 21], 트랄로메트린 (Tralomethrin) [살충 화합물 22], 실라플루오펜 (Silafluofen) [살충 화합물 23], d-페노트린 (Phenothrin) [살충 화합물 24], 시페노트린 (Cyphenothrin) [살충 화합물 25], d-레스메트린 (Resmethrin) [살충 화합물 26], 아크리나트린 (Acrinathrin) [살충 화합물 27], 시플루트린 (Cyfluthrin) [살충 화합물 28], 테플루트린 (Tefluthrin) [살충 화합물 29], 트란스플루트린 (Transfluthrin) [살충 화합물 30], 테트라메트린 (Tetramethrin) [살충 화합물 31], 알레트린 (Allethrin) [살충 화합물 32], 프랄레트린 (Prallethrin) [살충 화합물 33], 엔펜트린 (Enpenthrin) [살충 화합물 34], 이미프로트린 (Imiprothrin) [살충 화합물 35], d-푸라메트린 (Furamethrin) [살충 화합물 36] 등;
니코티노이드계 살충 활성 화합물: 클로티아니딘 (Clothianidin) [살충 화합물 37], 이미다클로프리드 (Imidacloprid) [살충 화합물 38], 티아메톡시암 (Thiamethoxiam) [살충 화합물 39], 티아클로프리드 (Thiacloprid) [살충 화합물 40] 등;
벤조일페닐우레아계 살충 활성 화합물: 클로르플루아주론 (Chlorfluazuron) [살충 화합물 41], 테플루벤주론 (Teflubenzuron) [살충 화합물 42], 플루페녹수론 (Flufenoxuron) [살충 화합물 43], 비스트리플루론 (Bistrifluron) [살충 화합물 44], 부프로페진 (Buprofezin) [살충 화합물 45], 트리플루무론 (Triflumuron) [살충 화합물 46] 등;
피라졸계 살충 활성 화합물: 아세토프롤 (Acetoprole) [살충 화합물 47], 에티프롤 (Ethiprole) [살충 화합물 48], 피프로닐 (Fipronil) [살충 화합물 49], 피라클로포스 (Pyraclofos) [살충 화합물 50] 등;
유충 호르몬계 살충 활성 화합물: 피리프록시펜 (Pyriproxyfen) [살충 화합물 51], 페녹시카르브 (Fenoxycarb) [살충 화합물 52] 등; 및
(RS)-5-tert-부틸-2-[2-(2,6-디플루오로페닐)-4,5-디히드로-1,3-옥사졸-4-일]페네톨 [살충 화합물 53], 및
2,6-디클로로-4-(3,3-디클로로알릴옥시)페닐 3-[5-(트리플루오로메틸)-2-피리딜옥시]프로필 에테르 [살충 화합물 54].
식물 성장 조절 화합물로서, 예는 아졸계 식물 성장 조절 화합물: 유니코나졸 (Uniconazole)-P [식물 성장 조절 화합물 1], 파클로부트라졸 (Paclobutrazol) [식물 성장 조절 화합물 2] 등; 및 (RS)-4'-클로로-2'-(α-히드록시벤질)이소니코틴아닐리드 [식물 성장 조절 화합물 3] 을 포함한다.
상기 농약 활성 화합물은 공지된 공보, 예컨대 [The Pesticide Manual, 제 13 판, The British Crop Protection Council 출판, 1987] 에 기재된 화합물이다.
본 액체 농약 조성물은 1 종 이상의 소수성 농약 활성 화합물을 함유할 수 있고, 본 액체 농약 조성물에서, 소수성 농약 활성 화합물의 총량은 0.5 내지 30 중량%, 바람직하게는 0.5 내지 25 중량%의 범위이다.
본 액체 농약 조성물에서, 방향족 탄화수소 용매에 거의 가용성이 아닌 (구체적으로 25 ℃에서 자일렌에 대한 용해도가 10 g/L 이하인) 고체 소수성 농약 활 성 화합물의 경우에도, 실용 농도를 갖는 액체 농약 제제를 제조할 수 있다.
본 발명에서, 군 (A) 에서 선택된 비이온성 계면활성제 (이하, 본 비이온성 계면활성제로 칭함) 는 단독으로 또는 이의 조합물로 사용될 수 있고, 본 액체 농약 조성물에서, 본 비이온성 계면활성제의 총량은 1 내지 20 중량%, 바람직하게는 1 내지 15 중량%, 더욱 바람직하게는 1 내지 12 중량%의 범위이다.
본 비이온성 계면활성제에서, p:q 는 폴리옥시에틸렌 구조에서 유래된 부분 구조 (CH2CH2)p 및 폴리옥시프로필렌 구조에서 유래된 부분 구조 (CH(CH3)CH2O)q 에서 바람직하게는 1:0.5 내지 2.0 의 범위이다.
본 발명에서, 바람직하게는, 본 비이온성 계면활성제는 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체이다.
폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체로서, Teric PE 64 (Huntsman 사제) 와 같은 시판되는 계면활성제가 사용될 수 있다.
폴리옥시에틸렌 폴리옥시프로필렌 알킬 에테르로서, Antarox BO/327 (모두 Rhodia Nikka 사제) 와 같은 시판되는 계면활성제가 사용될 수 있다.
본 발명에서, 음이온성 계면활성제는, 예를 들어, 하기 군 (B) 에서 선택된 음이온성 계면활성제이고, 단독으로 또는 이의 조합물로 사용될 수 있다. 본 액체 농약 조성물에서, 본 음이온성 계면활성제의 총량은 0 내지 10 중량%, 바람직하게는 0 내지 8 중량%, 더욱더 바람직하게는 1 내지 7 중량%의 범위이다:
군 (B):
도데실벤젠술포네이트 등과 같은 아릴술포네이트,
폴리옥시에틸렌 디스티릴 페닐 에테르 설페이트 등과 같은 폴리옥시에틸렌 (폴리)아릴아릴 에테르 설페이트,
폴리옥시에틸렌 트리스티릴 페닐 에테르 인산 등과 같은 폴리옥시에틸렌 (폴리)아릴아릴 에테르 포스페이트,
폴리옥시에틸렌 알킬아릴포스페이트,
및 폴리옥시에틸렌 알킬포스페이트.
일반적으로, 술포네이트, 설페이트 및 포스페이트의 염의 예는 나트륨염, 칼륨염 및 암모늄염을 포함한다.
본 액체 농약 조성물에 함유된 γ-부티로락톤의 양은 6 내지 60 중량%, 바람직하게는 15 내지 60 중량%의 범위이다.
본 액체 농약 조성물에 함유된 1,3-디메틸-2-이미다졸리디논의 양은 20 내지 75 중량%, 바람직하게는 25 내지 50 중량%의 범위이다.
본 발명에서, γ-부티로락톤 및 1,3-디메틸-2-이미다졸리디논으로서, 시판되는 것을 사용할 수 있다.
본 액체 농약 조성물에서, γ-부티로락톤 및 1,3-디메틸-2-이미다졸리디논의 중량비는 바람직하게는 10:90 내지 50:50 의 범위이다. 또한, 1,3-디메틸-2-이미다졸리디논은 통상적으로 1 중량부의 소수성 농약 활성 화합물에 대해 1.5 중량부 이상이다.
액체 농약 조성물의 특정예는 다음과 같다:
하기를 포함하는 액체 농약 조성물:
소수성 농약 활성 화합물 0.5 내지 30 중량%,
폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 1 내지 20 중량%,
음이온성 계면활성제 0 내지 10 중량%,
γ-부티로락톤 6 내지 60 중량% 및
1,3-디메틸-2-이미다졸리디논 20 내지 75 중량%;
하기를 포함하는 액체 농약 조성물:
소수성 농약 활성 화합물 0.5 내지 30 중량%,
폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 1 내지 20 중량%,
음이온성 계면활성제 0 내지 10 중량%,
γ-부티로락톤 6 내지 60 중량% 및
1,3-디메틸-2-이미다졸리디논 20 내지 75 중량%
(여기서, γ-부티로락톤 및 1,3-디메틸-2-이미다졸리디논의 중량비가 10:90 내지 50:50 의 범위이고, 1,3-디메틸-2-이미다졸리디논이 1 중량부의 소수성 농약 활성 화합물에 대해 1.5 중량부 이상임);
하기를 포함하는 액체 농약 조성물:
소수성 농약 활성 화합물 0.5 내지 30 중량%,
군 (A) 에서 선택된 비이온성 계면활성제 1 내지 15 중량%,
음이온성 계면활성제 0 내지 8 중량%,
γ-부티로락톤 15 내지 60 중량% 및
1,3-디메틸-2-이미다졸리디논 25 내지 50 중량%; 및
하기를 포함하는 액체 농약 조성물:
소수성 농약 활성 화합물 0.5 내지 25 중량%,
폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 1 내지 15 중량%,
음이온성 계면활성제 0 내지 8 중량%,
γ-부티로락톤 15 내지 60 중량% 및
1,3-디메틸-2-이미다졸리디논 25 내지 50 중량%.
본 액체 농약 조성물은, 필요한 경우, 제제용의 하나 이상의 보조제, 예컨대 항산화제, 착색제, 방향제, 효력 강화제, 약물 유발 고통 완화제 등을 함유할 수 있다.
항산화제의 예는 3-/2-t-부틸-4-히드록시아니솔, 부틸화 히드록시톨루엔 등을 포함하고, 착색제의 예는 로다민 B (Rhodamine B), 옐로우 (Yellow) No.4, 블루 (Blue) No.1, 레드 (Red) No.2 등을 포함한다.
본 액체 농약 조성물에서, 제제 보조제의 총량은 0 내지 5 중량%의 범위이다.
본 액체 농약 조성물은, 예를 들어, 소수성 농약 활성 화합물, 본 비이온성 계면활성제 및, 필요한 경우, 음이온성 계면활성제 및 제제용 보조제를 γ-부티로락톤 및 1,3-디메틸-2-이미다졸리디논의 혼합 용매에 첨가하고, 필요한 경우 가열 (80 ℃ 이하) 하고, 균일한 용액이 될 때까지 혼합물을 교반하고, 필요한 경우 용액을 여과하여, 제조될 수 있다.
본 액체 농약 조성물은 실질적으로 하나의 연속상으로부터 형성된 균일한 액체이다.
본 액체 농약 조성물은 물로 희석시켜 사용된다. 본 액체 농약 조성물은 통상적으로 액체 농약 조성물에 대해 10 내지 10,000 배, 바람직하게는 20 내지 5,000 배 양의 물로 희석될 수 있다. 일반적으로, 사용되는 물은 경수 (칼슘 이온 및/또는 마그네슘 이온의 함량이 많은 물; 물 중 칼슘 이온 및 마그네슘 이온의 총량은 상응하는 탄산염의 ppm 에서의 경도로서 나타냄) 또는 연수 (칼슘 이온 및/또는 마그네슘 이온의 함량이 적은 물) 일 수 있거나, 확산제와 같은 보조제, 무기염 등이 임의로 첨가된 물일 수 있다.
10 내지 10,000 배 양의 물로 본 액체 농약 조성물을 희석시켜 수득된 물-희석 용액 (이하, 본 물-희석 용액으로 칭함) 에서, 소수성 농약 활성 화합물은 본 비이온성 계면활성제에 의해 물에서 가용화되거나, 소수성 농약 활성 화합물을 함유한 액체 방울은 입자 직경이 충분히 작아서, 이의 외관은 종래의 농약 에멀젼의 물-희석 용액의 외관과 매우 상이하다. 즉, 착색 성분을 함유하지 않은 본 물-희석 용액은 외관이 투명하거나 담청색으로 투명하다.
예를 들어, 100 배 양의 물로 액체 농약 조성물을 희석한 직후에 550 nm 파장의 투과광으로 측정된 흡광도는 통상적으로 0.001 내지 1 의 범위이지만, 동일한 조건 하에서 종래의 농약 에멀젼의 물-희석 용액의 흡광도는 2 초과이고, 이로부터 본 액체 농약 조성물은 종래의 농약 에멀젼과 구별될 수 있다. 흡광도를 분석하기 위해, 자외선 및 가시광선 분광계 (예컨대, Shimadzu Corporation 사제 Model UV-2500 PC 유형) 이 사용될 수 있다.
이하, 본 발명은 실시예, 시험예 등에 의해 더욱 상세히 설명되지만, 본 발명은 이러한 예에 제한되지 않는다.
실시예 1
20 ℃에서, 살균 화합물 58 (활성 성분으로서 5.00 g), 칼슘 도데실벤젠술포네이트 (4.00 g, Huntsman 사제), 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 (4.50 g, Stepan 사제) 및 1,3-디메틸-2-이미다졸리디논 (35.0 g) 을 100 ml의 메스 플라스크에서 칭량하고, γ-부티로락톤을 사용하여 총 부피를 100 ml로 조정하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 본 액체 농약 조성물 (이하, 본 용액 1 로 칭함) 을 수득하였다.
실시예 2
20 ℃에서, 살충 화합물 37 (활성 성분으로서 5.00 g), 칼슘 도데실벤젠술포네이트 (3.00 g, Huntsman 사제), 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 (3.00 g, Stepan 사제) 및 1,3-디메틸-2-이미다졸리디논 (35.0 g) 을 100 ml의 메스 플라스크에서 칭량하고, γ-부티로락톤을 사용하여 총 부피를 100 ml로 조정하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 본 액체 농약 조성물 (이하, 본 용액 2 로 칭함) 을 수득하였다.
실시예 3
20 ℃에서, 살충 화합물 37 (활성 성분으로서 5.00 g), 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 (3.00 g, Stepan 사제) 및 1,3-디메틸-2-이미다졸리디 논 (45.0 g) 을 100 ml의 메스 플라스크에서 칭량하고, γ-부티로락톤을 사용하여 총 부피를 100 ml로 조정하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 본 액체 농약 조성물 (이하, 본 용액 3 으로 칭함) 을 수득하였다.
실시예 4
20 ℃에서, 살충 화합물 37 (활성 성분으로서 5.00 g), 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 (3.00 g, Stepan 사제) 및 1,3-디메틸-2-이미다졸리디논 (55.0 g) 을 100 ml의 메스 플라스크에서 칭량하고, γ-부티로락톤을 사용하여 총 부피를 100 ml로 조정하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 본 액체 농약 조성물 (이하, 본 용액 4 로 칭함) 을 수득하였다.
실시예 5
20 ℃에서, 살충 화합물 37 (활성 성분으로서 5.00 g), 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 (3.00 g, Stepan 사제) 및 1,3-디메틸-2-이미다졸리디논 (65.0 g) 을 100 ml의 메스 플라스크에서 칭량하고, γ-부티로락톤을 사용하여 총 부피를 100 ml로 조정하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 본 액체 농약 조성물 (이하, 본 용액 5 로 칭함) 을 수득하였다.
실시예 6
20 ℃에서, 살충 화합물 37 (활성 성분으로서 5.00 g), 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 (3.00 g, Stepan 사제) 및 1,3-디메틸-2-이미다졸리디논 (75.0 g) 을 100 ml의 메스 플라스크에서 칭량하고, γ-부티로락톤을 사용하여 총 부피를 100 ml로 조정하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 본 액 체 농약 조성물 (이하, 본 용액 6 으로 칭함) 을 수득하였다.
시험예 1
스토퍼 (stopper) 를 갖는 100 ml의 메스 실린더에 99 ml의 CIPAC 표준 수 (standard water) D (342 ppm) 를 채우고, 잠시 동안 30 ℃로 항온 물중탕에서 온도를 유지하였다. 이어서, 1 ml의 본 용액 1 내지 6 각각을 상기 메스 실린더에 첨가하고, 상기 메스 실린더를 2 초 당 한 번의 비율로 10 번 뒤집고, 다시 30 분 동안 30 ℃로 항온 물중탕에서 온도를 유지하였다. 그 후, 각각의 메스 실린더 내의 희석 용액의 상태를 관찰하고, 모두 안정한 상태를 유지하고 외관이 투명함을 발견하였다.
실시예 7
20 ℃에서, 제초 화합물 2 (활성 성분으로서 5.00 g), 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체 (15.00 g, Stepan 사제), 1,3-디메틸-2-이미다졸리디논 (67.0 g) 및 γ-부티로락톤 (15.0 g) 을 칭량하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 본 액체 농약 조성물 (이하, 본 용액 7 로 칭함) 을 수득하였다.
비교예 1
20 ℃에서, 제초 화합물 2 (활성 성분으로서 3.00 g), 폴리옥시에틸렌 소르비탄 모노라우레이트 (15.00 g, Rhodia Nikka 사제), 1,3-디메틸-2-이미다졸리디논 (67.0 g) 및 γ-부티로락톤 (15.0 g) 을 칭량하고, 균일한 용액이 될 때까지 혼합물을 교반하여, 비교 용액 (이하, 비교 용액 1 로 칭함) 을 수득하였다.
시험예 2
스토퍼를 갖는 100 ml의 메스 실린더에 99 ml의 CIPAC 표준 수 D (342 ppm) 을 채우고, 잠시 동안 30 ℃로 항온 물중탕에서 온도를 유지하였다. 이어서, 1 ml의 본 용액 7 및 비교 용액 1 각각을 상기 메스 실린더에 첨가하고, 상기 메스 실린더를 2 초 당 한 번의 비율로 10 번 뒤집고, 다시 2 시간 동안 30 ℃로 항온 물중탕에서 온도를 유지하였다. 그 후, 각각의 메스 실린더 내의 희석 용액의 상태를 관찰하고, 본 용액 7 이 안정한 상태를 유지하고 외관이 담청색으로 투명함을 발견하였다. 반면, 비교 용액 1 에서, 메스 실린더의 바닥에 침전된 대량의 결정을 관찰하였다.
상기와 같이, 본 발명의 액체 농약 조성물은 물-희석 상태가 매우 안정하고, 농약 활성 화합물을 함유한 제제로서 유용하다.
Claims (5)
- 하기를 포함하는 액체 농약 조성물:하나 이상의 소수성 농약 활성 화합물 0.5 내지 30 중량%;하기 군 (A) 에서 선택된 하나 이상의 비이온성 계면활성제 1 내지 20 중량%;하나 이상의 음이온성 계면활성제 0 내지 10 중량%;γ-부티로락톤 6 내지 60 중량%; 및1,3-디메틸-2-이미다졸리디논 20 내지 75 중량%,군 (A):폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체,폴리옥시에틸렌 폴리옥시프로필렌 알킬 에테르,폴리옥시에틸렌 폴리옥시프로필렌 알킬 페놀,폴리옥시에틸렌 폴리옥시프로필렌 폴리스티릴 페닐 에테르 및폴리옥시에틸렌 폴리옥시프로필렌 피마자유.
- 제 1 항에 있어서, 비이온성 계면활성제가 폴리옥시에틸렌 폴리옥시프로필렌 블록 공중합체인 액체 농약 조성물.
- 제 1 항에 있어서, 음이온성 계면활성제의 양이 1 내지 10 중량%의 범위인 액체 농약 조성물.
- 제 3 항에 있어서, 음이온성 계면활성제가 알킬벤젠술포네이트인 액체 농약 조성물.
- 제 1 항에 따른 액체 농약 조성물을 10 내지 10,000 배 양의 물로 희석시켜 수득되는 물-희석 용액.
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| JP2007021176A JP5092429B2 (ja) | 2007-01-31 | 2007-01-31 | 疎水性農薬活性化合物を含有する農薬液剤 |
| JPJP-P-2007-00021176 | 2007-01-31 |
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| JP5092428B2 (ja) * | 2007-01-31 | 2012-12-05 | 住友化学株式会社 | 疎水性農薬活性化合物を含有する農薬液剤 |
| JP5256749B2 (ja) * | 2008-01-23 | 2013-08-07 | 住友化学株式会社 | 乳剤組成物 |
| JP2009173578A (ja) * | 2008-01-24 | 2009-08-06 | Sumitomo Chemical Co Ltd | 乳剤組成物 |
| JP5262131B2 (ja) * | 2008-01-24 | 2013-08-14 | 住友化学株式会社 | 乳剤組成物 |
| CN102027900B (zh) * | 2009-09-28 | 2013-09-18 | 南京华洲药业有限公司 | 一种增效剂及含有该增效剂的敌草快水剂 |
| EP2548437B1 (en) * | 2011-07-19 | 2016-06-15 | Arysta LifeScience Benelux sprl | Improved method for producing emulsifiable pesticide solutions |
| WO2013026470A1 (en) | 2011-08-22 | 2013-02-28 | Agriphar S.A. | Aqueous suspension concentrate comprising dodecylguanidine |
| GB201707930D0 (en) * | 2017-05-17 | 2017-06-28 | Syngenta Participations Ag | Formulation component |
| CN109813667A (zh) * | 2017-11-18 | 2019-05-28 | 镇江亿特生物科技发展有限公司 | 乙虫腈含量紫外分光光度检测方法 |
| KR102498717B1 (ko) * | 2019-12-23 | 2023-02-13 | 주식회사 엘지화학 | 제초제 조성물 |
| WO2022191636A1 (ko) * | 2021-03-11 | 2022-09-15 | 주식회사 엘지화학 | 제초제 조성물 |
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| CN1223544A (zh) * | 1996-06-28 | 1999-07-21 | 诺瓦提斯公司 | 农药组合物 |
| TW460508B (en) * | 1997-05-02 | 2001-10-21 | Rohm & Haas | Aqueous composition comprising a mixed surfactant/associative thickener, its use in a formulated composition, and method for enhancing thickening efficiency of aqueous composition |
| JP4861581B2 (ja) * | 2001-09-18 | 2012-01-25 | クミアイ化学工業株式会社 | 安全で貯蔵安定性のある溶液状農薬組成物 |
| JP2003128501A (ja) * | 2001-10-18 | 2003-05-08 | Nissan Chem Ind Ltd | 農薬乳剤組成物 |
| US20060257440A1 (en) | 2003-05-19 | 2006-11-16 | Makoto Asai | Insecticidal composition |
| ZA200509284B (en) * | 2003-05-19 | 2007-03-28 | Nippon Soda Co | Insecticidal composition |
| US20060180677A1 (en) | 2005-02-02 | 2006-08-17 | Mcmanic Greg M | Agricultural compositions which enhance performance of pesticides applied through drift reducing nozzles |
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- 2008-01-30 US US12/010,864 patent/US8574606B2/en not_active Expired - Fee Related
- 2008-01-30 GB GB0801707A patent/GB2446289B/en not_active Expired - Fee Related
- 2008-01-30 BR BRPI0800177-4A patent/BRPI0800177A/pt not_active IP Right Cessation
- 2008-01-30 AU AU2008200454A patent/AU2008200454A1/en not_active Abandoned
- 2008-01-31 ZA ZA200801039A patent/ZA200801039B/en unknown
- 2008-01-31 DE DE102008007014A patent/DE102008007014A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP5092429B2 (ja) | 2012-12-05 |
| ES2324269B1 (es) | 2010-05-21 |
| TWI394529B (zh) | 2013-05-01 |
| GB2446289A (en) | 2008-08-06 |
| CN101233846B (zh) | 2012-07-11 |
| MX2008001472A (es) | 2009-02-24 |
| US20080182755A1 (en) | 2008-07-31 |
| ZA200801039B (en) | 2008-12-31 |
| CA2618975A1 (en) | 2008-07-31 |
| AR065065A1 (es) | 2009-05-13 |
| US8574606B2 (en) | 2013-11-05 |
| TR200800351A2 (tr) | 2008-09-22 |
| TW200836627A (en) | 2008-09-16 |
| BRPI0800177A (pt) | 2008-09-16 |
| CN101233846A (zh) | 2008-08-06 |
| JP2008184458A (ja) | 2008-08-14 |
| GB0801707D0 (en) | 2008-03-05 |
| FR2911758B1 (fr) | 2011-05-06 |
| AU2008200454A1 (en) | 2008-08-14 |
| GB2446289B (en) | 2011-07-20 |
| ES2324269A1 (es) | 2009-08-03 |
| ITTO20080060A1 (it) | 2008-08-01 |
| DE102008007014A1 (de) | 2008-08-28 |
| FR2911758A1 (fr) | 2008-08-01 |
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