KR20060064636A - 온도 저항성을 갖는 연신성 핫멜트 접착제 조성물 - Google Patents
온도 저항성을 갖는 연신성 핫멜트 접착제 조성물 Download PDFInfo
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- KR20060064636A KR20060064636A KR1020067003194A KR20067003194A KR20060064636A KR 20060064636 A KR20060064636 A KR 20060064636A KR 1020067003194 A KR1020067003194 A KR 1020067003194A KR 20067003194 A KR20067003194 A KR 20067003194A KR 20060064636 A KR20060064636 A KR 20060064636A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
- C09J123/12—Polypropene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2437/00—Clothing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2555/00—Personal care
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/10—Peculiar tacticity
- C08L2207/14—Amorphous or atactic polypropylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
Abstract
Description
동적 및 정적 박리 강도 | ||
접착제 조성물 | 동적 박리 강도(그램/2인치 폭) | 180° 정적 박리 강도(파손 시간) |
폴리프로필렌 배합물 | 1350 | ~3시간 |
H2525A | 1170 | ~30분 |
APAO RT 2730 | 790 | ~5분 |
조성물 1 | 2300 | 8시간 |
정적 박리 강도 | ||
접착제 조성물 | 첨가(gsm) | 180° 정적 박리 강도 (파손 시간) |
조성물 2 | 15 | 6 내지 8시간 |
조성물 2 | 30 | 20시간 |
H2525A | 30 | 2 내지 4시간 |
Claims (20)
- 약 20% 이하의 결정화도를 갖는 어택틱 중합체;약 40% 이상의 결정화도를 갖는 이소택틱 중합체; 및탄성 기재 중합체를 포함하는 접착제 조성물.
- 제1항에 있어서, 어택틱 중합체가 약 1,000 내지 약 300,000의 수평균 분자량을 갖고, 이소택틱 중합체가 약 3,000 내지 약 200,000의 수평균 분자량을 갖는 것인 접착제 조성물.
- 제1항 또는 제2항에 있어서, 어택틱 중합체가 어택틱 폴리프로필렌, 약 0.910 내지 약 0.935g/cm3 범위의 밀도를 갖는 저밀도 폴리에틸렌, 어택틱 폴리스티렌, 어택틱 폴리부텐, 비결정성 폴리올레핀 공중합체 및 이들의 조합으로 구성된 군에서 선택되는 것인 접착제 조성물.
- 제1항 내지 제3항 중 어느 한 항에 있어서, 이소택틱 중합체가 이소택틱 폴리프로필렌, 약 0.935 내지 약 0.980g/cm3 범위의 밀도를 갖는 고밀도 폴리에틸렌, 이소택틱 폴리스티렌, 이소택틱 폴리부텐 및 이들의 조합으로 구성된 군에서 선택되는 것인 접착제 조성물.
- 제1항 내지 제4항 중 어느 한 항에 있어서, 탄성 기재 중합체가 약 0중량% 내지 약 45중량%의 스티렌 함량을 포함하는 것인 접착제 조성물.
- 제1항 내지 제5항 중 어느 한 항에 있어서, 탄성 기재 중합체가 스티렌-이소프렌-스티렌(SIS) 다중 블록 공중합체, 스티렌-부타디엔-스티렌(SBS) 다중 블록 공중합체, 스티렌-에틸렌-부텐-스티렌(SEBS) 다중 블록 공중합체, 스티렌-에틸렌-프로필렌-스티렌(SEPS) 다중 블록 공중합체, 메탈로센 폴리에틸렌/옥탄/폴리프로필렌 및(또는) 부탄, 헥산, 폴리이소프렌, 폴리부타디엔 또는 에틸렌 비닐 아세테이트 공중합체, 및 이들의 조합으로 구성된 군의 하나 이상을 포함하는 것인 접착제 조성물.
- 제1항 내지 제6항 중 어느 한 항에 있어서, 탄성 기재 중합체가 약 10 내지 약 2000 그램/분의 용융 유동 속도, 약 20 내지 약 70의 쇼어 A 경도를 갖고, 약 1300% 이하까지 연신될 수도 있는 것인 접착제 조성물.
- 제1항 내지 제7항 중 어느 한 항에 있어서, 약 30중량% 내지 약 90중량% 어택틱 중합체를 포함하는 접착제 조성물.
- 제1항 내지 제8항 중 어느 한 항에 있어서, 약 5중량% 내지 약 30중량% 이소 택틱 중합체를 포함하는 접착제 조성물.
- 제1항 내지 제9항 중 어느 한 항에 있어서, 약 2중량% 내지 약 20중량% 탄성 기재 중합체를 포함하는 접착제 조성물.
- 제1항 내지 제10항 중 어느 한 항에 있어서, 점착제, 산화방지제, 가소제, 광유, 착색 안료, 충진제, 고 연화점 점착제, 약 80℃ 이하의 연화점 및 182℃에서 약 1000cps 이하의 점도를 갖는 저 연화점 첨가제, 중합체 상용화제 및 이들의 조합으로 구성된 군에서 선택된 첨가제 약 50중량% 이하를 더 포함하는, 접착제 조성물.
- 제1항 내지 제11항 중 어느 한 항에 있어서, 조성물이 약 450℉ 이하에서 통상적인 가온 용융 장치에 의해 가공될 수 있는 것인 접착제 조성물.
- 제1 및 제2 표면 층; 및제1 및 제2 표면 층의 각각의 적어도 일부 사이에서 제1항 내지 제12항 중 어느 한 항에 따른 접착제 조성물을 포함하는, 적층 구조체.
- 제13항에 있어서, 제1 및 제2 표면 층의 적어도 하나가 부직 재료, 스펀본드 웹, 멜트블로운 웹, 직물 재료, 후크 재료, 라미네이트, 네크드-본디드 라미네이 트, 필름, 탄성화 성분, 및 이들의 조합으로 구성된 군의 하나 이상을 포함하는 것인, 적층 구조체.
- 제13항 또는 제14항에 있어서, 제1 및 제2 표면 층이 단일 기판의 각 부분들인 적층 구조체.
- 제13항 내지 제15항 중 어느 한 항에 있어서, 적층 구조체가 100℉에서 약 2시간 이상, 또는 약 4시간 이상, 또는 약 8시간 이상의 정적-박리-파손 시간을 갖는 것인 적층 구조체.
- 제13항 내지 제16항 중 어느 한 항에 있어서, 약 1 이하, 또는 약 0.5 이하, 또는 약 0.2 이하의 상대적 부착 값을 갖는 것인 적층 구조체.
- 제13항 내지 제17항 중 어느 한 항에 따른 적층 구조체를 포함하는 가먼트.
- 제18항에 있어서, 가먼트가 개인 위생 가먼트, 의료용 가먼트, 산업 작업복 가먼트, 기저귀, 배변훈련용 팬츠, 수영복, 흡수성 언더팬츠, 성인 요실금 제품, 여성 위생 제품, 보호용 의료 가운, 수술용 의료 가운, 모자, 장갑, 드레이프, 얼굴 마스크, 실험실 코트 및 커버롤스로 구성된 군에서 선택되는 것인 적층 구조체.
- 약 20% 이하의 결정화도 및 약 1,000 내지 약 300,000의 수평균 분자량을 갖는 어택틱 중합체 약 30 내지 약 90중량%, 약 40% 이상의 결정화도 및 약 3,000 내지 약 200,000의 수평균 분자량을 갖는 이소택틱 중합체 약 5 내지 약 30중량%, 및 탄성 기재 중합체 약 2 내지 약 20중량%를 조합함으로써 접착제 조성물을 형성하고;제1 기판을 제공하고;제2 기판을 제공하고;제1 기판과 제2 기판 중 적어도 하나에 접착제 조성물을 도포하고;제1 기판과 제2 기판 사이에 배치된 적용된 접착제 조성물의 적어도 일부로, 제1 기판의 적어도 일부를 제2 기판의 적어도 일부에 결합시키는 단계를 포함하는, 제13항 내지 제19항 중 어느 한 항에 따른 적층 구조체의 제조 방법.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/655,717 | 2003-09-05 | ||
US10/655,717 US20050054779A1 (en) | 2003-09-05 | 2003-09-05 | Stretchable hot-melt adhesive composition with temperature resistance |
Publications (2)
Publication Number | Publication Date |
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KR20060064636A true KR20060064636A (ko) | 2006-06-13 |
KR101023378B1 KR101023378B1 (ko) | 2011-03-18 |
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KR1020067003194A KR101023378B1 (ko) | 2003-09-05 | 2004-04-14 | 온도 저항성을 갖는 연신성 핫멜트 접착제 조성물 |
Country Status (8)
Country | Link |
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US (2) | US20050054779A1 (ko) |
EP (1) | EP1660605B1 (ko) |
KR (1) | KR101023378B1 (ko) |
AU (1) | AU2004272493B2 (ko) |
BR (1) | BRPI0413685B1 (ko) |
DE (2) | DE602004021607D1 (ko) |
MX (1) | MXPA06001797A (ko) |
WO (1) | WO2005026281A1 (ko) |
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2003
- 2003-09-05 US US10/655,717 patent/US20050054779A1/en not_active Abandoned
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2004
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- 2004-06-30 US US10/880,994 patent/US20050054780A1/en not_active Abandoned
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AU2004272493A1 (en) | 2005-03-24 |
MXPA06001797A (es) | 2006-05-04 |
DE602004021607D1 (de) | 2009-07-30 |
US20050054780A1 (en) | 2005-03-10 |
EP1660605B1 (en) | 2009-06-17 |
BRPI0413685A (pt) | 2006-10-24 |
AU2004272493B2 (en) | 2009-07-30 |
EP1660605A1 (en) | 2006-05-31 |
DE602004018001D1 (de) | 2009-01-08 |
BRPI0413685B1 (pt) | 2015-03-31 |
KR101023378B1 (ko) | 2011-03-18 |
US20050054779A1 (en) | 2005-03-10 |
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