KR20050060112A - Paint composition which contains nephrite jade and process for preparing thereof - Google Patents

Abstract

An object of the present invention is to provide a paint containing the purgatory powder and a manufacturing method thereof.

The present invention adds 1 to 30% by weight of nephrite powder having a particle size of 100 to 1000 mesh based on the total weight of waste raw materials mainly based on inorganic materials such as bio-ceramic, thereby increasing far-infrared emissivity useful for the human body. In addition, antibacterial and deodorant, and to reduce the generation of toxic gases in the fire.

Description

Paint Composition Which Contains Nephrite Jade And Process For Preparing Thereof}

The present invention relates to a paint composition containing nephrite jade powder and a method for manufacturing the same. Particularly, the present invention relates to a hollow fiber brown rice fiber having a very thin fibrous granules of cationic feldspar series. The fine jade powder having a micro structure is added to a paint raw material mainly composed of inorganic material such as ceramics to increase the far-infrared emissivity useful for the human body and to have non-toxic, non-flammable, antibacterial and deodorizing properties. The present invention relates to a powder containing powder and a method of manufacturing the same.

In general, it is well known that a variety of paints, that is, paint varieties, have been developed to be used for painting interior and exterior of a house or building.

However, conventional paints are the mainstream only developed for the purpose of clean and beautiful decoration.

Therefore, in recent years, a lot of functional paints containing a functional material in the paint raw material has been developed, but this paint also does not have a significant effect compared to the paints.

Accordingly, an object of the present invention is to eliminate the above-mentioned shortcomings, and to add a fine purifying powder to the paint material mainly based on minerals, to provide the far-infrared radiation property useful to the human body, and to provide the antibacterial and deodorizing properties. To provide a paint and a method of manufacturing the same.

In order to achieve the above object, the paint containing the nephrite powder of the present invention may have 1 to 30% by weight of the nephrite powder having a particle size of 100 to 1000 mesh based on the total weight of the paint raw material mainly composed of inorganic materials such as bio ceramics. It is characterized by the addition.

In addition, the manufacturing method of the paint containing the purgatory powder of the present invention for achieving the above object is 1 to 30% by weight of the purgatory powder having a particle size of 100 to 1000 mesh during the preparation of the waste ste composition mainly composed of inorganic bio-ceramic It is characterized by the addition.

The nephrite powder is characterized in that it is defined as butch δ ¹⁸ O as a diaphragm nephrite in the high quality surrogate rock.

In addition, the composition ratio of the purgatory powder used in the above is characterized in that it is made as follows.

Semi QuanTitative Analysis (%)

Silicon 34

Magnesium 10

Calcium 4.9

Iron 0.23

Aluminum 0.16

Copper 0.17

Cobalt 0.046

Manganese 0.14

Tin 0.024

Beryllium 0.00072

Is 0.0013

Titanium 0.0038

Nickel 0.0028

Chromium 0.0030

Miscellaneous 0

The nephrite used above is an inosilicates monolithic ore-stone mineral, which is divided into nephrite and serpentine superbasic nephrite in high-quality surrogate rock and their The quality is determined by its fine structure, that is, the degree of fineness of the hollowstone-positive stone sperm into fastenings and fibers, and it is known that the finer the fiber, the better the quality.

In addition, the particle size of the purgatory powder used in the present invention is selected in consideration of paint raw materials, etc., but generally 100-360 mesh is suitable. However, when the ductility of paint properties should be increased, it is more advantageous to use finer particles of about 360-1000 mesh. If the jade powder has a particle size larger than the above range, the surface roughness of the product becomes severe, which is not preferable, and finer particles than the above range are not preferable because of difficulty in grinding.

In addition, when the addition amount of the jadeite powder is less than 1% by weight, the effect of the addition of the jadeite powder cannot be expected, and it is not preferable. In addition to lowering the properties, in particular, the ductility of the product, there is a risk of weakening the product, and due to the high price of the nephrite powder, the price of the product increases, so about 30% by weight or less of the total weight of the resin raw material is appropriate.

Still another object of the present invention is to provide a maximal use of purgatory by using jade powder obtained from residues or debris purgatory derived from mining or jewelry processing. For this purpose, it is economically advantageous in terms of cost reduction.

Hereinafter, the preferred embodiment of the paint containing the purgatory powder and the manufacturing method thereof according to the present invention will be described in detail.

Example 1

50 wt% of bio-ceramic is added to 30 wt% of nephrite powder having a particle size of 100 mesh, and 10 wt% of binder is maintained at pH 10 to 12, and 10 wt% of water is added thereto, followed by a high speed mixing stirrer. The mixture was mixed at 2000 rpm for 35 minutes to obtain the product.

As a result of the test on the physical properties of the product, it was an aqueous solution of pH 10-12, specific gravity was 1.5 ± 0.1 and viscosity was 1500CPS ± 100.

Example 2

70% by weight of bio-ceramic is added to 1% by weight of nephrite powder having a particle size of 1000 mesh, and 19% by weight of a binder for maintaining a pH of 10 to 12 is added thereto while 10% by weight of water is added thereto. The mixture was mixed at 2000 rpm for 35 minutes to obtain the product.

As a result of the test on the physical properties of the product, it was in the form of an aqueous solution of pH 10-12, and the specific gravity was 1.5 ± 0.1 and the viscosity was 1500 CPS ± 100.

The binder used in the above embodiment is any one of geogel (trade name), casein, and acrylic resin emulsion.

The following experimental examples can indirectly confirm that the paint containing the purgatory powder has a useful effect on the human body.

Experimental Example 1

In order to find out how beneficial the paint containing the nephrite powder prepared by the above embodiment has a beneficial effect on the human body, it was conducted by the Daejeon University Oriental Medicine Hospital, the experimental method is to paint the paint containing the nephrite powder of the present invention In one room and a room painted with ordinary paint, adult males and females over 45 years of age were used for about 12 hours, and then the changes in the human body were measured. The results are shown in the following Tables 1 to 3. It was like

<Test object: 45-year-old adult man> division Plain paint Paint containing the purgatory powder of the present invention Heart rate HR (SaO2) 81 BPM     76 BPM Blood pressure NIBP SYS 127 mmHg     128 mmHg MEAN (average) 107 mmHg     104 mmHg DIAS 80 mmHg     76 mmHg Oxygen Concentration (SaO2) 91%     93%  Pulse rate 81 BPM     76 BPM

<Test object: Adult man 55 years old> division Plain paint Paint containing the purgatory powder of the present invention Heart rate HR (SaO2)   81 BPM 85 BPM Blood pressure NIBP SYS    181mmHg  173 mmHg Average (MEAN)   142 mmHg  127 mmHg  Diastolic (DIAS)    111mmHg 110 mmHg Oxygen Concentration (SaO2)  95% 95% Pulse rate    83 BPM   85 BPM

<Inspection subject: 64 years old adult woman> division  Plain paint  Paint containing the purgatory powder of the present invention Heart rate HR (SaO2) 68 BPM  68 BPM Blood pressure NIBP SYS   185 mmHg   176 mmHg Average (MEAN)   117 mmHg   125 mmHg Diastolic (DIAS)   104 mmHg    105 mmHg Oxygen Concentration (SaO2)  74% 96% Pulse rate     68 BPM   68 BPM

As shown in Tables 1 to 3 above, as a result of using the paint containing the purgatory powder of the present invention, the oxygen concentration, that is, the amount of oxygen is generally increased as compared to the existing paint, thereby promoting the metabolism of the human body, and blood circulation It can be seen that there is an effect to smooth.

Experimental Example 2

As a result of clinical trials of the paint containing the purgatory powder according to the present invention applied to the bed or ondol room, sofa, chair, etc. used by the patients, it was found that approximately 88% of the trial subjects were effective.

◎ The selection criteria and selection method of the examinee

Twenty-five patients were selected as clinical trial subjects who were diagnosed or diagnosed with symptoms such as headache, insomnia, Hyun-hoon, anxiety, chest pain, and numbness of hands and feet.

◎ Observation Event and Inspection Method

After a certain period of time (approximately 10 days or more) in patients undergoing inpatient treatment for headache, insomnia, vertigo, anxiety, chest pain, and numbness of the hands and feet, the patient's condition and physical changes were observed.

◎ Evaluation criteria and evaluation methods

A. Evaluation Criteria: Based on the status at the time of first visit.

B. Evaluation method: The evaluation was performed in the same manner as in Table 4 below, and the results were as shown in Table 5 below.

 order         division  evaluation(%)    One   If the effect is small or no  Less than 70%    2   When it works  More than 70%    3   When there is a significant effect  80% or more    4  When the effect is close to cure  over 90

Effect Determination Disease No effect Effective  A significant effect Cure effect   system  Less than 70%  More than 70%  80% or more    over 90 headache. Hyun Hoon     2     3      5     One   11  Blows     0     2      One      One   4  Anxiety.     One     One      One      2   5  Hogtied     0     One      One      One   3  Indigestion     0     0      2      0   2     system   3 (12%)   7 (28%)   10 (40%)    5 (20%) 25 (100%)

As can be seen from the clinical trial results of Table 5, most of the clinical trial patients have symptoms such as relief of headache and dizziness, recovery of insomnia and anxiety, improvement of numbness of hands and feet, indigestion, etc. From these results, it can be seen that there is a medical effect of purgatory.

The following experimental examples were conducted on the efficacy of the purgatory powder contained in the paint of the present invention and the effects of the purgatory powder on the living body, and the results are shown in the following tables.

Lead Content Test  sample       Jade minutes  Sample property       White powder  Job number       United States F.D.A.Affiliated Research Institute Federal IW 091394-1   Way       Atomic absorption analysis   result       Not detected

<Heavy Metals (Pb, etc.)>         sample           Jade powder         Sample property           White         Job number       Federal IW 080894-4         Way        USP 23         result        Not detected

<Inorganic elution test>         sample          Jade powder          Sample property          White          Job number     Federal IW 080894-4          Way       As          result       As

100 g of the sample was extracted with 1 liter of water by autoclave treatment, and the extract liquid was analyzed.

     Analyte     Results (ppm)     Detection limit (ppm)      Arsenic (As) ND  0.05      Barium (Ba) ND 0.20      Cadmium (Cd) 0.005 0.007      Chlorine (Cl) ND One      Chrome (Cr) ND 0.01      Copper (Cu) ND 0.05      Fe ND 0.10      Pb ND 0.05      Manganese (Mn) ND 0.02      Mercury (Hg) ND 0.0005      Nitrate (NO3) ND 0.1      Selenium (Se) ND 0.05      Silver (Ag) ND 0.01      Sulfate (SO4) ND  One      Zinc (Zn) ND 0.01

(ND = concentration is below detection limit or not detected)

As shown in the above experimental results, the purgatory powder used in the present invention was indirectly proved to be safe even when used as a raw material of the paint because no harmful lead, heavy metals or other toxic components were detected.

Experimental Example 3

In this experiment, the effect of purgatory used in the present invention on the growth and development of silkworms was examined (see FIGS. 1 to 2D).

① Material and method

1. Disclosed silkworm breed: Baekokjam

2. Breeding time: November-December

3. Breeding method: constant temperature and humidity, heraldic mulberry leaf meat

4. Number of Disclosures: Control-150 Repeat

Treatment-130 Heads 2 Repeat

5. Treatment details: Control-Mulberry feed by distilled water spray

Treatment-Mulberry feed by spraying purgatory

Processing Period: From 2nd Stage Sleep

Breeding Results by Oxygen Treatment division repeat Treated Larvae 5th Infancy Total larvae Chrysalis percentage Work time Work time % Indices Control One 150 7 07 23 07 91.3 100 2 150 7 07 23 07 76.6 Average 150 7 07 23 07 84.0 Treatment group One 130 7 15 23 15 74.1 85 2 130 7 15 23 15 68.2 Average 130 7 15 23 15 71.2 division repeat High yield Cocoon weight Cocoon shell weight Cocoon shell percentage (kg / 10,000) Indices g Indices cg time % Indices Control One 17.9 100 2.08 100 43.0 100 20.7 100 2 15.0 1.96 39.0 19.9 Average 16.5 2.02 41.0 20.3 Treatment group One 16.2 93 2.14 106 44.0 109 20.6 102 2 14.6 2.14 45.0 21.0 Average 15.4 2.14 44.5 20.8

<Threading from cocoon with Oxygen Treatment> division Cocoon filament length (m) Cocoon filament weight (cg) Silk size (d) Specific cutting length (m) Specific Cutting Filament Weight (cg) Thread Pulling Ability (%) Control 1,222 33.7 2.48 3.47 23.4 69 Treatment group 1,283 36.3 2.55 1,005 28.5 78 division Percentage of unprocessed silk (%) Refinement (score) Adhesion (g / d) Elongation (%) Raw silk weight (kg) Control 19.68 95 3.80 3.47 2.75 Treatment group 16.96 96 3.93 1,005 2.61

Change in Larvae Weight due to Jade Treatment division Weight of larvae immediately away from the third slough Weight of larvae immediately away from the fourth slough 3rd day weight of 5 Mature caterpillars Control 0.46 1.85 20.80 47.4 Treatment group 0.47 1.94 23.03 52.2

<Reduction effect of blood glucose by jade solution> Silkworm extract Blood sugar Reduction effect of blood glucose Injection with maltose '(A) Injection into silkworm extract (B) Reduction amount (C = A-B) efficiency Water treatment mg / 100ml mg / ml mg / ml% 64.0 ± 1.87 27.7 ± 1.70 36.3 56.7 Treated with jade solution 69.6 ± 1.62 20.7 ± 1.62 48.9 70.3

': Injection of Silkworm Extract Previous

result

The weight of larvae was heavier than the control of distilled water in the age of messenger, especially 0.48 g / kg.

2. The rate of fire was 71.2%, which was 15% lower than that of control, and 15.4g of 10,000 head was 7% lower than control.

3. The total weight of the necrosis was 2.14 g, 6% heavier than the control, and 44.5 g, 9% heavier. The silk ratio was 2% higher than the control.

4. Purgatory feeding showed better overall performance than control. In particular, the length of silk thread was long, the amount of silk was high, and the rate of hatchery was much higher than that of the control by about 9%.

5. In the sands, the nephrophylls showed slightly thicker fine grains, and showed higher ratios of strength, elongation, and yield than those of the control.

6. There was no significant difference in silk surface structure between control and treatment.

7. The crystal structure of the nephrite nephrite had a pointed rod structure.

Experimental Example 4

In this experiment, we observed changes in the activity of mice drinking jade flour drinking water added with jade jade used in the present invention.

As shown in Figure 3, the mice in the positive control in the stabilization experiment, the central nerve starts to stabilize from 5 minutes after drinking Ubabito (Note: Chinese name) medicine, and gradually returns to normal after 30 minutes, Mice in the control group showed ups and downs in activity rates and declined overall. The activity rate of the drinking test group (mouse) of the drinking water of jade powder was similar to that of the normal control group, but the average value of the overall activity rate was higher than that of the normal control group, and the difference was more significant compared to the positive control group. .

Experimental Example 5

In this experimental example, infrared experiments were performed on purgatory powder (FIG. 4).

     sample       Jade minutes      Sample property       White      method of inspection     Perkin elmer 137      result         As

<IR spec in IR spectrum>

Form: Tetrahydrofran Liquefied Thin Film

It appeared to match the pattern of polycarbonate resin and radiated electromagnetic waves with a wavelength of 6-52μ.

Experimental Example 6

In this experimental example, the experiments were performed as shown in Table 15 and Table 16 below for the chemical and biological oxygen requirements for the purgatory powder samples used in the present invention.

sample Jade minutes Sample property White Way Standard method result Same as Table 17

division Water (control) Jade addition 5-day BOD 224 mg / l 223 mg / l COD 115 mg / l 110 mg / l

Experimental Example 7

In this test example, the experiment on the effect of the purgatory powder used in the present invention on the breeding and growth of the test sphere (rat) was performed as shown in Table 17.

Effect of Oxite and Agate on Delivery and Sperm Capacity in Rats Childbirth and sperm ability Treatment group ^* A B C Childbirth Number (n = 10) Total Childbirth Sexual number of offspring (♂ / ♀) Average childbirth per mother Weight at birth Childbirth at birth (pups, g) Weight after delivery at day of birth (g) Weight at slaughter (♂) (g) sperm weight (g) sperm concentration (10 ⁸ / ml) sperm vitality (%) 99657: 3911.8 ± 1.94.73 ± 1.1023.8 ± 1.4 ^a 43.45 ± 8.04294.0 ± 10.93.90 ± 0.21 ^a 6.32 ± 2.491.0 ± 4.2 99457: 3710.9 ± 1.45.79 ± 0.9525.1 ± 1.7 ^b 42.73 ± 8.76274.4 ± 8.63.57 ± 0.30 ^b 4.80 ± 1.392.0 ± 2.7 810 254: 4812.8 ± 2.15.35 ± 0.3525.5 ± 3.7 ^b 42.07 ± 10.71288.4 ± 26.73.99 ± 0.15 ^a 4.60 ± 1.988.0 ± 7.6

* A: Purgatory treatment group

B: Purgatory Corn Salary

C: control

p <0.05: Statistically significant at 95% level.

This study was carried out to investigate the effects on the reproduction and growth rate of rats treated with the paint prepared from Chuncheon Mountain Purgatory and used to precipitate the cornmeal. Thirty water samples were prepared, respectively. The test treatment was carried out with three treatment groups of nephrite paint (A), chalcedony (B) and control group (C). In all treatment groups, male rats were isolated for 9 days and then slaughtered for sperm concentration and vitality test.

<Test Results>

(1) The jadeite paint (A) and maize (B) treatment groups were superior to the control group (C).

② The delivery rate was 90% in the jade (A, B) treatment group and 80% in the control group (C), respectively.

③ Although the litter size was 6-8 more in the control group (C), the male number was higher in the jade treatment group (A, B).

④ The number of days after delivery was significantly shortened by jade treatment group, and sperm activity of sperm concentration was also excellent in jade treatment group (A).

Experimental Example 8

In this test example, the effect of purgatory powder used in the present invention on the freshness of pork was performed as shown in Table 18.

<Effect on freshness when storing pork in purgatory bowl> Temperature 0 4 Vessel Control purgatory Control purgatory Day 0 pHVBNTBAcolor (ΔE) 5.83 ± 0.04 3.50 ± 0.43 0.063 ± 0.013 53.70 ± 4.34 Day 4 Drip loss (%) pHVBNTBAColor (ΔE) 0.14 0.57 0.54 0.01 5.46 ± 0.04 5.42 ± 0.00 5.59 ± 0.01 5.69 ± 0.01 5.56 ± 0.20 4.29 ± 0.20 5.65 ± 0.39 5.42 ± 1.41 0.153 ± 0.00 0.104 ± 0.032 0.122 ± 0.006 0.099 ± 0.025 55.80 ± 0.01 49.30 ± 0.11 54.90 ± 0.08 56.50 ± 0.07 DAY7 Drip loss (%) pHVBNTBAColor (ΔE) 1.02 0.17 1.90 0.43 5.77 ± 0.03 5.84 ± 0.01 5.56 ± 0.01 5.65 ± 0.01 2.36 ± 0.00 2.32 ± 0.00 3.48 ± 0.45 2.59 ± 0.22 0.234 ± 0.013 0.203 ± 0.006 0.239 ± 0.006 0.203 ± 0.019 55.50 ± 0.47 52.60 ± 0.75 52.80 ± 0.06 52.90 ± 0.05 DAY14 Drip loss (%) pHVBNTBAColor (ΔE) 0.92 0.27 2.70 0.19 5.50 ± 0.01 5.67 ± 0.03 6.71 ± 0.00 5.91 ± 0.02 3.00 ± 0.39 3.98 ± 0.18 6.17 ± 0.87 3.85 ± 0.53 0.162 ± 0.013 0.176 ± 0.019 2.406 ± 0.191 0.811 ± 0.089 51.70 ± 0.10 53.80 ± 0.13 62.80 ± 0.00 56.70 ± 0.04 DAY21 Drip loss (%) pHVBNTBAColor (ΔE) 1.11 0.35 0.85 0.25 6.41 ± 0.01 6.07 ± 0.00 7.24 ± 0.00 6.69 ± 0.01 5.32 ± 0.36 7.35 ± 0.42 30.67 ± 3.31 15.08 ± 0.98 10.220 ± 0.230 6.852 ± 0.274 10.15 ± 0.198 2.298 ± 0.102 52.40 ± 0.06 59.20 ± 0.13 58.20 ± 0.13 66.30 ± 0.33

Drip Loss:%

VBN (protein variability): mg%

TBN (fatty acidity degree): mg Mal / kg of meat

Color

The test was carried out to measure the effect on freshness change over time when the pork is stored in the bowl (bowl) prepared with Chuncheon mountain purgatory used in the present invention. There were two types of test materials: purgatory and normal (control). The storage temperature was 0 ℃, 4 ℃, and the storage period was 0,4,7,14,21. The ham (Ham) of pork cut about 100g while storing the juice (Drip Loss), meat color (meat Color), pH, volatile basic nitrogen (VBN), fatty acid septic (TBA) was measured.

<Test Results>

① When the pork was stored in the purgatory bowl (jug), the juicy outflow rate was much lower than that of the general bowl, regardless of the storage temperature.

② As an important indicator of postmortem change of muscle, pH was higher at 4 ℃ than 0 ℃, but there was no clear difference according to storage container.

③ VBN, which shows protein deterioration, was slightly higher at Day 14 and Day 21 at 0 ° C, but was significantly lower at 4 ° C in purgatory.

④ TBA (價), which indicates fatty acid loss, was much lower in jade purge regardless of storage temperature.

Primary skin irritation test sample Jade minutes Sample property White powder Way As result As

Method: US Federal Register Vol. 43, no. 163

CTFA (The Cosmetic, Toiletry and Fragrance Association, Washington, D.C.) Technical Guidelines

Experimental procedure: Patch testing was performed on the skin of the white rabbit and the original skin. The hair was cut short at the back and sides. Two areas, about 10 cm away, were selected as patch locations. One area is made of 4 small epidermal incisions in the patch area to remove the skin (two of which are perpendicular to the other and are "tic-tac-toe"). The patch is attached using a thin rubber band and adhesive tape Samples are introduced in each part in an amount of 0.5 ml (g) under the patch The body of the animal is wrapped with a rubberized cloth for 24 hours of exposure. After the patch was removed, the reaction at each site was evaluated based on the scores described below (see Table 20).

Evaluation of Skin Response

Erythema and crust formation

No erythema-0

Very weak erythema (recognizable barely)-1

Properly Identified Erythema-2

Moderate to severe erythema-3

Severe erythema (beat red) to slight crust formation (deep damage)-4

Edema

No edema-0

Very mild edema (recognizable barely)-1

Slight edema (it is obvious that the edges of the area are prominent)-2

Moderate edema (approximately 1 mm up)-3

rabbit 24 hours 72 hours Original skin Worn skin Original skin Worn skin ER ED ER ED ER ED ER ED #One 0 0 0 0 0 0 0 0 #2 0 0 0 0 0 0 0 0 # 3 0 0 0 0 0 0 0 0 #4 0 0 0 0 0 0 0 0 # 5 0 0 0 0 0 0 0 0 # 6 0 0 0 0 0 0 0 0

Conclusions: This sample was determined to have no skin irritation. Therefore, it is indirectly proved that there is no large crowd even when used in contact with the skin.

<Acute oral toxicity [(0.5 g) / 100 g body weight] experiment> sample Purgatory powder Sample property White powder Way As result Same as Table 24 below

rat gender Initial weight (g) Dosage (ml) Lag weight (g) Toxicity One F 207 1.0 219 none 2 F 211 1.1 226 none 3 F 215 1.1 225 none 4 F 208 1.0 217 none 5 F 200 1.0 213 none 6 M 227 1.1 235 none 7 M 216 1.1 224 none 8 M 205 1.0 218 none 9 M 210 1.1 224 none 10 M 212 1.1 221 none

Preparation of Samples: A portion of the sample was placed in sterile distilled water and boiled for 10 minutes to extract, and the extract was administered by intubation in an amount of 0.5 g per 100 g of body weight.

CONCLUSIONS: The sample meets the criteria for no oral toxicity.

Experimental Example 9

This experiment example is a process and results of the experiment performed by the Inha University bioinformatics system engineering laboratory to investigate the various effects of the purgatory powder used in the present invention on the living body. In this experiment, 70% of the constituent elements of the human body are water, so it is determined that there is a lot of relationship between the change of water and the effect on the human body. Experiments on the effects were performed.

A. Hard water change

Experiment 1

100 ml of artificially-made hard water was transferred to each of the four flasks by 50 ml, and purgatory was placed on the bottom of two flasks for about 10 minutes.

To determine the change in hardness, a titration method using ethylene diamineacetic acid (hereinafter referred to as "EDTA" titer 2.9412) was used. 1 ml of a buffer solution of pH 10, EBT was used as an indicator.

The change in hardness was measured by the amount of EDTA until the moment when the color of the hard water was changed by EDTA. At this time, the color returned to its original state over time, but in this experiment, the measurement was made based on the changing moment.

<Result 1>

At 100ppm hard water, EDTA 1.70ml is required

It takes 1.25ml of EDTA after purgatory test, so the hardness of 100.00ppm is lowered to 73.53ppm. That is, the hardness of 100.00 ppm was softened 26.47%.

Experiment 2

200 ml of 100ppm hard water made in the same manner as in Experiment 1 was transferred to a beaker to immerse the purgatory.

After about 30 minutes, the water in the beaker was divided into three flasks to measure the change in hardness. In this experiment, the hardness was measured by adding EDTA until the color of hard water did not change any more after the color of hard water changed by EDTA.

<Result 2>

Each 100ppm hard water before purgatory experiment

89.62 ppm

91.19ppm

89.62 ppm

Average 90.14ppm, thus 9.9% hardness decrease

Experiment 3

This experiment was conducted with tap water. Tap water was placed in a container and transferred to six flasks, and purgatory was placed at the bottom of three flasks, and hardness was measured after about 5 minutes.

<Result 3>

* Tap water without purgatory

97.48 ppm

97.48 ppm

97.48 ppm

Average 97.48 ppm

* Tap water after purgatory experiment

 91.19ppm

 91.19ppm

 91.19ppm

 Average 91.19ppm therefore, hardness decrease of 6.5%

I. Effect of Purgatory on the Proliferation of Digital Plant Suspensions of Digitalis lanata

Effects of Purgatory on the Growth of Digitalis lanata Cells in Growth Medium

FIG. 5 is a graph showing changes in culture medium volume of cells grown in growth medium for 11 days, and FIG. 6 is a graph showing changes in cell volume, in proportion to the increase of cells growing over time. As the depletion of and the evaporation of the medium occur, the volume change of the whole culture reflects these factors. In particular, humidity and temperature in the atmosphere are closely related to the evaporation of the medium, and such factors also affect the cell growth rate.

As shown in the figure, the use of purgatory shows that the volume of the total culture solution is slightly decreased compared to the control group which is not used. This is because the use of purgatory rather than the control group has a faster cell growth rate against the evaporation of the medium or the depletion of nutrients, and thus, it is possible to offset the rapid decrease of the depleted medium to some extent. This phenomenon is observed in the case of continuous purgatory use from 4 to 11 days after inoculation of cells as shown in Figure 6, which measured the volume change of only the submerged cells, it is observed that the cell volume increases more than the control group not used. This fact can be estimated. Therefore, the use of nephrite showed a faster cell growth rate than the control without the nephrite. These results can be said to be the result of delaying the decrease of the total volume than the control by offsetting the decrease in the total culture volume due to nutrient depletion and medium evaporation. In addition, the result of comparing the volume of the increased cell alone is also observed to show a tendency to gradually increase the cell volume after 4 days, it is thought that can support this result.

Cell proliferation and dry weight are the most common measures of cell proliferation. In general, the growth curve of all cells is represented by the S-shaped curve, which can be classified into four stages. Lag phase, which is a period of adaptation to the medium, in which there is no cell proliferation and no mass growth, and an exponential curve showing a steep slope due to a mass increase at a rapid proliferation rate after this period. phase), the stationary phase, which has a maximum growth to some extent, and the Chinese food is slowed down and shows no mass increase, and the cell ruptures due to the depletion of nutrients, the release of toxic components, and the saturation of cell density. It can be divided into a dead phase where the total cell volume or mass decreases due to the tendency to die.

7 and 8 are the results of measuring the cell biomass and dry weight.

7 follows the growth curve of these four stages. In the case of using jade, after 7 days, the growth rate was slightly higher than that of the control without jade, and the growth stopped until 10 days, unlike the control showing the decrease in cell biomass. have. This is remarkable in that cell growth is continued even when the concentration of nutrient is almost depleted and the concentration in the medium becomes zero compared with the change in the concentration of glucose, a nutrient that acts as the main metabolic substrate in the medium. It is common to show a tendency to stop the growth and decrease the growth rate at the point of depletion of the influenced ingredients, like the control without purgatory, but the effect of purgatory on cell growth is different when purgatory is used. It is assumed that there is. This result is also shown in Figure 8 shows the cell growth proliferating at a higher rate than the control after 3 days, and from 9 days after, the same phenomenon as in FIG. As a result, cells grown near nephrite in the growth medium showed better effect on cell growth than the control group that did not. Digitalis lanata plant cells, which have a growth limit of about 10 days, are maintained in a stable state that does not cause necrosis of cells without exchanging with new medium even after 10 days when cultured with purgatory. Rather, it is expected that cell proliferation may be an advantageous method for optimizing cell growth and concentration in the production process for the production of useful substances.

② Effect of Purgatory on Changes in Medium pH

9 is a graph showing the pH change in the cell growth medium, Figure 10 is a graph showing the pH change of the production medium after the addition of purgatory powder.

Figure 9 is a measure of the change in the pH of the medium in the control medium with and without the purgatory in the growth medium. The control group shows a general tendency of pH in the medium applied to the plant cells, which gradually decreases over time and is maintained at a certain level. However, by using the purgatory, it showed a similar pattern to the control group until the 7th day and then increased gradually. This phenomenon is extreme in the result of FIG. 9 which shows the result in the production medium in which the purgatory powder was added directly to the culture medium. . The control group without added jade powder showed a consistent drop in pH, while the addition of jade powder showed a tendency to maintain the value to some extent. It is assumed that it acts as a cause.

③ Results of analysis of water quality for purgatory

FIG. 11 is a view showing the condition of the water analyzer containing the purgatory powder used in the present invention, and FIG. 12 is a view showing the analysis results of the water containing the purgatory powder used in the present invention.

The data from FIG. 11 and FIG. 12 is summarized in Table 23 to Table 26. Table 23 shows the analysis of each analysis item for Sample 1 after 48 hours of 20 g of nephrite mass in the solution. In Table 23, there is little change in each measurement item, and the effect of purgatory is hardly seen.

Table 24 shows the measured values for each analysis item in Sample 2 after 48 hours of placing 20 g of purgatory lumps outside the solution.

Table 26 also shows the measured values for each analysis item in Sample 4 after 48 hours of purifying powder outside the solution. There was no change for each analysis item in this experiment. However, in the case of Sample 3, the data measured for each analysis item of the sample 48 hours passed after 20 g of purgatory powder was added to the solution is shown in Table 25. This change is as follows.

Cr, Pb, Ni, and Co, which are harmful to the human body, changed significantly after 48 hours. Cr was removed in the absence of purgatory powder, that is, 45.30 mg before the reaction was removed to 0 after 48 hours in the purifying powder, and Pb was also completely removed from 13.76 mg to zero. Ni decreased from 51.8 mg to 1.733 mg and Co also decreased from 52.69 mg to 11.94 mg. Mg, one of the necessary elements in the human body, increased from 48.36mg to 55.74mg.

The hydrogen ion concentration of distilled water was acidic to pH 3.5, but after the reaction, it was neutral to pH6.8, and the conductivity rapidly decreased. The adsorption force is physically large, about 3-4 mmol.q (equivalent) per gram.

Analytical results before and after the reaction in solution Purgatory lumps in the solution. (Sample 1): Purgall lump in solution (20 g)   Item     Before the reaction After reaction (48hr)    Change    pH     3.5      3.82       -    Ni     51.8 mg     51.75mg       -    Co     52.69mg     52.54mg       -    Cr     45.30mg     43.88mg       -    Mg     48.36mg     48.59 mg       -    Pb     13.76 mg     13.90mg       -

Results of analysis of purgatory lumps outside the solution. (Sample 2): lump of purgatory jade (20g)   Item     Before the reaction   After reaction (48hr)    Change    pH     3.5      3.65       -    Ni     51.8 mg     48.92mg       -    Co     52.69mg     49.83mg       -    Cr     45.30mg     41.23mg       -    Mg     48.36mg     47.97mg       -    Pb     13.76 mg     15.1mg       -

Analysis result when adding purgatory powder to solution. (Sample 3): Purgatory powder in solution (20g)   Item     Before the reaction After reaction (48hr)    Change    pH     3.5      6.8     +3.3    Ni     51.8 mg     1.733 mg  -50.06mg    Co     52.69mg     11.94mg  -40.75mg    Cr     45.30mg        0mg  -45.30mg    Mg     48.36mg     55.74mg   + 7.38mg    Pb     13.76 mg         0mg  -13.76 mg

Analysis result when purgatory powder was placed outside the solution (Sample 4): Purgatory powder outside the solution (20g)   Item     Before the reaction After reaction (48hr)    Change    pH     3.5      3.7       -    Ni     51.8 mg     51.53 mg       -    Co     52.69mg     52.55mg       -    Cr     45.30mg     43.0mg       -    Mg     48.36mg     48.39mg       -    Pb     13.76 mg     14.29 g       -

As described above, the digitalis lanata plant suspension cells cultured for one week with nephrite close showed proliferation of about 30% or more in the absence of purgatory. This is a rare proliferative result even in the various experiments performed for the proliferation effect on conventional Digigitalis lanata plant cells for high concentration culture. In addition, experiments on how purgatory water affects hard water showed that soft water softened hard water without contact with water. Particularly, in the component analysis experiments on water using distilled water, precipitation of nephrite was carried out. After 48 hours, in the component analysis, the pH was increased, the Ni and Co components were reduced, the Cr and Pb were removed. An unusual phenomenon was observed that led to the phenomenon of.

Thus, purgatory used in the present invention has not yet been clearly identified theoretically, it changes the hardness of the water without contact with water, and also proliferates more than 30% of the digitalis lant (Digitalis lanata) plant suspension cells, The elimination of heavy metals harmful to the human body, such as the reduction of Ni and Co components, and the removal of Cr and Pb, is believed to be due to the radiation effect of the electromagnetic wave wavelengths of the purgatory powder and the ionic reaction by the mineral components contained in the nephrite. Such facts will be proved by the efficacy shown in the product of the present invention described above.

Experimental Example 10

In this test example, the effects of the water and diet of the water purifier and the refrigerator treated with the interior materials made of Chuncheon nephrite used in the paint of the present invention on the growth rate, sperm capacity and muscle exercise were treated or fed to the experimental rats. It was.

The test treatment consisted of a control group (A) fed a water purifier water and a refrigerator storage diet and a jade treated group (B) fed a refrigerator storage diet using a water purifier containing jade water purifier. Approximately 10-week-old rats per test group were reared for 6 weeks with 3 numbers 3 repetitions of 9 numbers of 9 numbers. The growth rate, sperm vitality and sperm concentration, blood lipid concentration and exercise volume of rats during the test period were shown in Table 27. Measured.

Metric Treatment group ^* Control group (A) Jade treatment group (B) Growth rate (g / day) Feed intake (g / day) Drinking water (ml / day) Sperm ability (精子 能力) Sperm vitality (%) Sperm concentration (10 ⁸ / ml) Momentum Rotation bar (sec) Rotating basket (rotation / 10 minutes) Swimming endurance (sec) Blood pH Neutral fat (TG) Total cholesterol (TC) High density cholesterol (HDL) 2.33 ± 0.3715.52 ± 1.3035.8 ± 1.1 90.0 ± 0.005.7 ± 1.37 41.0 ± 1.61810,481 ± 5,315 7.66 ± 0.10171.5 ± 39.2 ^a 171.1 ± 62.382.8 ± 10.7 2.64 ± 0.4114.97 ± 1.0727.8 ± 0.9 88.3 ± 2.96.9 ± 1.08 41.5 ± 9.11711,713 ± 3,519 7.84 ± 0.09133.1 ± 33.3 ^b 146.6 ± 62.169.3 ± 7.4

* A: General Cage, Water Purifier, General Refrigerator Storage (AIN-diet)

B: Jade treatment tile, water purifier water, jade refrigerator freezer (AIN-diet)

P <0.05: statistically significant at 95% level.

<Test Results>

① There were no differences between the two treatments in terms of growth rate and delivery and blood lipid concentration.

② Sperm vitality was not different, but sperm concentration was about 17% higher in jade treatment group than in control.

③ In the exercise measurement results, swimming endurance was 1,200 seconds longer on average in the jade treatment group than in the control group.

④ blood pH of jade treatment group was slightly higher than control.

⑤ High density cholesterol (HDL) content in blood lipid was somewhat higher in the control group.

As can be seen from the above results, the jade treatment group showed better swimming endurance and sperm concentration than the control group. Especially, blood cholesterol (TC) and triglyceride concentration (TG) were significantly lower in the jade treatment group than the control group. .

Experimental Example 11

This test examined the pH change over time when jade ore, jade necklace and jade stone powder was immersed or added to other water for 8 to 11 days (Figs. 11 to 14).

In the case of jade ore, Chuncheon Mountain Purgne (made by Oxan ^R ) and Russia were used in the manufacture of the present invention, and Chuncheon Mountain Purgatory and Chinese products were used as the jade necklace. The water used to measure the pH change was general water purifier, groundwater and strong acid solution (pH3.2).

<Test Results>

① When jade ore and jade necklace were immersed in general water purifier and groundwater, pH of Chuncheon gemstone and necklace used in the present invention was higher than that of Russian or Chinese jade necklace.

② The average pH measured by adding 10%, 5%, and 1% to the strong acid solution of pH 3.2 was 10.59 ± 0.10, 8.58 ± 0.13, 8.57 ± 0.11, respectively. .

③ The pH of strong acid solution in Chuncheon nephrite jade treated milk bottle was consistently higher than that of regular milk bottle.

As can be seen from the above, the Chuncheon nephrite gemstones, powders and necklaces used in the present invention increased the hydrogen ion concentration (pH) of water compared to the Russian and Chinese gemstones and jade necklaces, but no statistically significant difference was recognized.

Experimental Example 12

In this test, as shown in Table 28 and Table 29, the rats of about 5 weeks old were published to evaluate the effect on the labor and weaning when other drinking water (에게) in drinking test (white rats). Drinking water was divided into three treatment groups of ground water (A), general water purifier water (B), Chuncheon mountain purgatory water purifier water (C) used in the present invention, the test feed was fed the same AIN-diet. The female rats (♀) were placed in a total of 27 numbers of 9 rats in 3 numbers and 3 repetitions. The male rats (♂) placed 24 numbers in 8 numbers for each treatment group. After breeding for 4 weeks, 7 days of breeding (種 付, mating), the ratio (mating ratio) was ♂ / ♀ = 1: 3. It was reared after weaning and weaning after about 3 weeks of gestation.

<Effect when drinking different water to rats> Metric ¹⁾ Treatment tool ^* A B C Daily gain (g / day) Feed intake (g / day) Drinking water (ml / day) Sperm ability (精子 能力) Sperm vitality (%) Sperm concentration (10 ⁸ / ml) Momentum Rotating basket (time, 10 minutes) (sec) Rotating rod (sec) Blood pH 4.32 ± 0.2616.25 ± 0.3220.3 ± 1.2 91.1 ± 2.34.01 ± 1.09 57.8 ± 3.164,082 ± 81339.6 ± 18.97.64 ± 0.09 4.20 ± 0.5716.51 ± 0.4522.00 ± 1.8 90.5 ± 2.84.26 ± 0.71 35.2 ± 19.05,087 ± 1,47132.9 ± 9.97.69 ± 0.12 4.33 ± 0.3717.01 ± 1.0619.8 ± 1.1 91.1 ± 2.84.87 ± 1.41 33.3 ± 14.75,332 ± 44531.5 ± 11.07.78 ± 0.24

¹⁾ Colony as measured in male rats

* A: groundwater, B: general water purifier, C: water purifier

Effects of Different Drinking Water on Labor in Rats Treatment Zone ¹⁾ Number of delivery days (days) Number of delivery individuals (birth rate,%) Total Childbirth Childbirth number per mother Reason cubs (♂ / ♀) A 24.2 ± 1.5 5 (55.6) 56 11.2 ± 1.9 53 (26/27) B 25.5 ± 2.3 6 (66.7) 46 7.7 ± 2.9 39 (17/22) C 24.7 ± 2.3 7 (77.8) 81 11.6 ± 0.5 69 (41/28)

<Test Results>

① There was no significant difference in growth rate, momentum and sperm capacity between treatments.

② The sperm concentration of Chuncheon nephrite water purifier (C) used in the present invention averaged 4.87 billion / ml, which was 21.4% and 14.3% higher than the average of 4.01 billion / ml (A) and 4.26 billion / ml (B) of the other two treatments, respectively. .

③ The delivery rate was 55.6%, 66.7%, and 77.8% in groundwater, general water purifier water, and jade water purifier water, respectively.

④ The number of bovine birds was 11.2 ± 1.9, 7.7 ± 2.9, and 11.6 ± 0.5 in groundwater, general water purifier, and jade water purifier.

⑤ The number of weaning weaning after 3 weeks of delivery was 53, 39 and 69 in three treatment groups A, B and C, respectively. Sex ratio was 26/27, 17/22 and 41, respectively. Male pups were higher in the Oksugi test zone (C) at / 28.

As can be seen from the above, sperm concentration was 21.4% and 14.3% higher in sperm concentration than the other two treatments, respectively, and female rats had 78% jade water treatment and 56,67% in the other two treatments. The sex ratio of weaning pups was higher in male pups than in other two treatments.

In particular, the above experimental results will be proved to have a useful effect on the human body due to the characteristics of the purgatory powder and the effect of purgatory when using the synthetic resin paint containing the purgatory powder of the present invention.

As described above, according to the present invention, by adding the purgatory powder to the raw material of the paint mainly composed of inorganic materials, the physical properties of the paint itself are improved, and from the purpura contained in the paint, Radiation of substances useful to the human body, ie, large amounts of negative ions and far infrared rays, has the effect of activating cellular functions, promoting blood circulation and metabolism of the human body.

In addition, as a result of the experiments that the large amount of anions are released from purgatory, it has the effect of having antibacterial and deodorizing effect in the room and neutralizing the toxicity of cement, etc. It can also be seen that it does not burn easily.

1 is a crystal structure diagram showing a purgatory powder used in the present invention by a scanning electron microscope (SEM),

2A and 2B are photographs showing untreated silk of jade water used in the present invention by scanning electron microscopy,

2C and 2D are photographs of a silk treated with jade water used in the present invention by scanning electron microscopy,

3 is a change chart of the test sphere (mouse) activity after drinking drinking water used in the present invention,

Figure 4 is a far-infrared emissivity measurement by the FT-IR Spectrometer of purgatory used in the present invention,

5 is a graph showing the results of observing the change in the total volume of the culture medium of digitalis lantana (Digitalis lanata) cells growing in the growth medium,

6 is a graph showing the change in the volume of digitalis lanata (Digitalis lanata),

7 is a graph showing changes in the bio weight of cells,

8 is a graph showing the change in dry weight of cells,

9 is a graph showing the pH change of the digitalis lantana (Digitalis lanata) culture medium,

10 is a graph showing the pH change of the production medium after the addition of purgatory powder,

11 is a view showing the result of the state condition of the analyzer;

12 is a view showing an output of an analysis result,

13 is a view showing the pH change of jade necklace and jade ore in a general water purifier,

14 is a view showing the pH change over time of jade necklace and jade ore in groundwater,

15 is a view showing the pH change of the strong acid solution by the Chuncheon nephrite powder treatment,

16 is a view showing the pH change over time of the strong acid solution (pH) stored in the milk bottle containing the purgatory powder and the normal milk bottle.

Claims (6)

A paint containing jadeite powder made by adding 1 to 30% by weight of jadeite powder having a particle size of 100 to 1000 mesh based on the total weight of paint raw materials mainly composed of inorganic materials such as ceramics. The paint containing the jadeite powder according to claim 1, wherein the jadeite powder is defined as butch δ ¹⁸ O as a hollow-trillite gemstone in high-quality surrogate rock. The paint containing the jade according to claim 1 or 2, wherein the composition ratio of the jade powder is used as follows. Semi QuanTitative Analysis (%) Silicon 34 Magnesium 10 Calcium 4.9 Iron 0.23 Aluminum 0.16 Copper 0.17 Cobalt 0.046 Manganese 0.14 Tin 0.024 Beryllium 0.00072 Is 0.0013 Titanium 0.0038 Nickel 0.0028 Chromium 0.0030 Miscellaneous 0 A method for producing a paint containing a jadeite powder, characterized in that 1 to 30% by weight of a jadeite powder having a particle size of 100 to 1000 mesh is added during the manufacture of a waste ste composition mainly composed of inorganic bioceramic. 5. The method for producing a paint containing jadeite powder according to claim 4, wherein the jadeite powder is defined as butch δ ¹⁸ O as a hollowstone jadeite in high-quality surrogate rock. The method of claim 4 or 5, wherein the composition ratio of the purgatory powder used in the above is made as follows. Semi QuanTitative Analysis (%) Silicon 34 Magnesium 10 Calcium 4.9 Iron 0.23 Aluminum 0.16 Copper 0.17 Cobalt 0.046 Manganese 0.14 Tin 0.024 Beryllium 0.00072 Is 0.0013 Titanium 0.0038 Nickel 0.0028 Chromium 0.0030  Miscellaneous 0