KR20050059558A - Adhesive composition which contains nephrite jade and process for preparing thereof - Google Patents

Abstract

An object of the present invention is to provide an adhesive containing a purgatory powder and a method of manufacturing the same.

In the present invention, 70 to 99% by weight of bio-ceramic mixed and stirred 1 to 30% by weight of nephrite powder having a particle size of 100 to 1000 mesh to form a mixed powder, and 50 to 60% by weight of the mixed powder and a binder in a liquid state. 40 to 50% by weight will be mixed uniformly for 5 minutes. As a result, the anion and far-infrared emissivity useful for the human body can be increased, and antibacterial and deodorizing properties and toxic gas generation can be reduced in case of fire.

Description

Adhesive Composition Which Contains Nephrite Jade And Process For Preparing Thereof}

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an adhesive (grass) containing nephrite jade powder used to bond ondol floors, ceramic tiles and wallpaper, and a method of manufacturing the same. Fine crumb powder having a very fine fiber-like fine brown fiber structure of stone-based fibers is mixed with raw materials based on inorganic materials such as ceramics to form a powder, and then the mixed powder is mixed with a liquid binder. The present invention relates to an adhesive containing a jadeite powder which has a high anion and far-infrared emissivity useful for the human body, and which is odorless, nontoxic, and has antibacterial and deodorizing properties by kneading at an appropriate ratio.

In general, it is well known that adhesives used to attach interior and exterior materials of a house or building are classified into animal, vegetable, and synthetic resins.

Animal adhesives include casein, which is a protein in milk, and glycogen, which is contained in the liver, muscles, and the like of animals. Examples of vegetable adhesives include lacquer and grass. In addition, there are epoxy resins and phenol resins made of synthetic resins, which mainly constitute industrial adhesives.

Non-water-soluble adhesives are adhesives using organic solvents. Non-water-soluble adhesives using organic solvents have better adhesive strength than water-soluble adhesives, but are difficult to remove when using recycled paper. The manufactured container has a disadvantage in that the adhesive is not completely removed and thus the quality of the regeneration container is degraded because the adhesive and impurities are contained. In addition, there is a risk of generating toxic gas and fire because organic solvents are used in the preparation of the adhesive, and the toxic gas also has a problem of weakening the working environment.

Water-soluble adhesives have been developed to solve this problem, but there is a problem in that the adhesion is somewhat deteriorated, especially when left in a humid environment for a long time in the adhesive area, such as the growth of bacteria, such as mold and smells.

Accordingly, an object of the present invention is to solve the above-mentioned shortcomings, and to add fine purgum powder to the adhesive raw material based on minerals, to provide useful anion and far-infrared radiation properties to the human body, and to exhibit non-toxic, odorless and antibacterial properties. To provide an adhesive containing a jade powder and a method for producing the same.

In order to achieve the above object, the adhesive containing the nephrite powder of the present invention mixes and stirs 1 to 30 wt% of the nephrite powder having a particle size of 100 to 1000 mesh to 70 to 99 wt% of the bio-ceramic to form a mixed powder, and 40 to 50% by weight of the liquid binder is added to 50 to 60% by weight of the mixed powder, and the mixture is uniformly mixed for 5 minutes.

In addition, the adhesive preparation method containing the purgatory powder of the present invention for achieving the above object is mixed and stirred by mixing and mixing 1 to 30% by weight of the nephrite powder having a particle size of 100 to 1000 mesh with 70 to 99% by weight of the bio-ceramic After the composition, 40 to 50% by weight of the liquid binder is added to 50 to 60% by weight of the mixed powder, which is characterized in that the mixture is uniformly mixed for 5 minutes.

The jadeite powder is characterized in that it is defined as butch δ ¹⁸ O as a hollowstone jadeite in high-quality surrogate rock.

Composition ratio of the purgatory powder used in the above is characterized in that it is made as follows.

Semi QuanTitative Analysis (%)

Silicon 34

Magnesium 10

Calcium 4.9

Iron 0.23

Aluminum 0.16

Copper 0.17

Cobalt 0.046

Manganese 0.14

Tin 0.024

Beryllium 0.00072

Is 0.0013

Titanium 0.0038

Nickel 0.0028

Chromium 0.0030

Miscellaneous 0

The nephrite used above is an inosilicates monolithic ore-stone mineral, which is divided into nephrite and serpentine superbasic nephrite in high-quality surrogate rock and their The quality is determined by its fine structure, that is, the degree of fineness of the hollowstone-positive stone sperm into fastenings and fibers, and it is known that the finer the fiber, the better the quality.

In addition, the particle size of the nephrite powder used in the present invention is selected in consideration of the adhesive raw material, etc., generally, 100-360 mesh is suitable. However, when the ductility of the adhesive properties should be increased, it is more advantageous to use fine particles of 360-1000 mesh, which are finer particles. If the jade powder has a particle size larger than the above range, the surface roughness of the product becomes severe, which is not preferable, and finer particles than the above range are not preferable because of difficulty in grinding.

In addition, if the addition amount of jadeite powder is less than 1% by weight, it is not preferable because the effect due to the addition of jadeite powder is not preferable. In addition to lowering the properties, in particular, the ductility of the product, there is a risk of weakening the product, and due to the high price of the nephrite powder, the price of the product increases, so about 30% by weight or less of the total weight of the resin raw material is appropriate.

Still another object of the present invention is to provide a maximal use of purgatory by using jade powder obtained from residues or debris purgatory derived from mining or jewelry processing. For this purpose, it is economically advantageous in terms of cost reduction.

Hereinafter, a preferred embodiment of the adhesive containing the purgatory powder according to the present invention and a manufacturing method thereof will be described in detail.

Example 1

Mix and stir 30% by weight of the nephrite powder having a particle size of 100 mesh to 70% by weight of the bio-ceramic to form a mixed powder, and 40% by weight of the liquid binder is added to 60% by weight of the mixed powder to mix uniformly for 5 minutes. To obtain the product.

As a result of the test on the physical properties of the product, it was an aqueous solution of pH 10-12, specific gravity was 1.5 ± 0.1 and viscosity was 1500CPS ± 100.

Example 2

99 wt% of bio ceramics are mixed and stirred to form a mixed powder by mixing and stirring 1 wt% of nephrite powder having a particle size of 1000 mesh, and 50 wt% of the mixed powder is added to 50 wt% of a liquid binder and mixed uniformly for 5 minutes. To obtain the product.

As a result of the test on the physical properties of the product, it was in the form of an aqueous solution of pH 10-12, and the specific gravity was 1.5 ± 0.1 and the viscosity was 1500 CPS ± 100.

As the binder used in the above examples, any one of geogel (trade name), casein, latex, acrylic resin emulsion, and EVA emulsion zone may be used.

Through the following experimental examples it can be confirmed indirectly that the adhesive containing the purgatory powder has a useful effect on the human body.

Experimental Example 1

In order to find out how beneficial the adhesive containing the purgatory powder prepared by the above-described examples have a beneficial effect on the human body, it was carried out by the Daejeon University Oriental Medicine Hospital, and the experimental method was performed using the adhesive containing the purgatory powder of the present invention. The adult males and females aged 45 and over stayed for about 12 hours in the place where the wallpaper (tile) and the wallpaper using the general adhesive were attached, and then the change of the human body was measured. It was as the indication of 1-3.

<Test object: 45-year-old adult man> division General adhesive Glue-containing adhesive of the present invention Heart rate HR (SaO2) 81 BPM     76 BPM Blood pressure NIBP SYS 127 mmHg     128 mmHg MEAN (average) 107 mmHg     104 mmHg DIAS 80 mmHg     76 mmHg Oxygen Concentration (SaO2) 91%     93%  Pulse rate 81 BPM     76 BPM

<Test object: Adult man 55 years old> division General adhesive Glue-containing adhesive of the present invention Heart rate HR (SaO2)   81 BPM 85 BPM Blood pressure NIBP SYS    181mmHg  173 mmHg Average (MEAN)   142 mmHg  127 mmHg  Diastolic (DIAS)    111mmHg 110 mmHg Oxygen Concentration (SaO2)  95% 95% Pulse rate    83 BPM   85 BPM

<Inspection subject: 64 years old adult woman> division  General adhesive  Sheet containing the jade powder of the present invention Heart rate HR (SaO2) 68 BPM  68 BPM Blood pressure NIBP SYS   185 mmHg   176 mmHg Average (MEAN)   117 mmHg   125 mmHg Diastolic (DIAS)   104 mmHg    105 mmHg Oxygen Concentration (SaO2)  74% 96% Pulse rate     68 BPM   68 BPM

As shown in Tables 1 to 3 above, as a result of using the adhesive containing the purgatory powder of the present invention, the oxygen concentration, that is, the amount of oxygen is generally increased as compared to the existing adhesive to promote the metabolism of the human body, and blood circulation It can be seen that there is an effect to smooth.

Lead Content Test  sample       Jade minutes  Sample property       White powder  Job number       United States F.D.A.Affiliated Research Institute Federal IW 091394-1   Way       Atomic absorption analysis   result       Not detected

<Heavy Metals (Pb, etc.)>         sample           Jade powder         Sample property           White         Job number       Federal IW 080894-4         Way        USP 23         result        Not detected

<Inorganic elution test>         sample          Jade powder          Sample property          White          Job number     Federal IW 080894-4          Way       As          result       As

100 g of the sample was extracted with 1 liter of water by autoclave treatment, and the extract liquid was analyzed.

     Analyte     Results (ppm)     Detection limit (ppm)      Arsenic (As) ND  0.05      Barium (Ba) ND 0.20      Cadmium (Cd) 0.005 0.007      Chlorine (Cl) ND One      Chrome (Cr) ND 0.01      Copper (Cu) ND 0.05      Fe ND 0.10      Pb ND 0.05      Manganese (Mn) ND 0.02      Mercury (Hg) ND 0.0005      Nitrate (NO3) ND 0.1      Selenium (Se) ND 0.05      Silver (Ag) ND 0.01      Sulfate (SO4) ND  One      Zinc (Zn) ND 0.01

(ND = concentration is below detection limit or not detected)

As shown in the above experimental results, the purgatory powder used in the present invention was indirectly proved to be safe even when used as a raw material of the adhesive because no harmful lead, heavy metals or other toxic components were detected.

Experimental Example 2

In this experiment, the effect of purgatory used in the present invention on the growth and development of silkworms was examined (see FIGS. 1 to 2D).

① Material and method

1. Disclosed silkworm breed: Baekokjam

2. Breeding time: November-December

3. Breeding method: constant temperature and humidity, heraldic mulberry leaf meat

4. Number of Disclosures: Control-150 Repeat

Treatment-130 Heads 2 Repeat

5. Treatment details: Control-Mulberry feed by distilled water spray

Treatment-Mulberry feed by spraying purgatory

Processing Period: From 2nd Stage Sleep

Breeding Results by Oxygen Treatment division repeat Treated Larvae 5th Infancy Total larvae Chrysalis percentage Work time Work time % Indices Control One 150 7 07 23 07 91.3 100 2 150 7 07 23 07 76.6 Average 150 7 07 23 07 84.0 Treatment group One 130 7 15 23 15 74.1 85 2 130 7 15 23 15 68.2 Average 130 7 15 23 15 71.2 division repeat High yield Cocoon weight Cocoon shell weight Cocoon shell percentage (kg / 10,000) Indices g Indices cg time % Indices Control One 17.9 100 2.08 100 43.0 100 20.7 100 2 15.0 1.96 39.0 19.9 Average 16.5 2.02 41.0 20.3 Treatment group One 16.2 93 2.14 106 44.0 109 20.6 102 2 14.6 2.14 45.0 21.0 Average 15.4 2.14 44.5 20.8

<Threading from cocoon with Oxygen Treatment> division Cocoon filament length (m) Cocoon filament weight (cg) Silk size (d) Specific cutting length (m) Specific Cutting Filament Weight (cg) Thread Pulling Ability (%) Control 1,222 33.7 2.48 3.47 23.4 69 Treatment group 1,283 36.3 2.55 1,005 28.5 78 division Percentage of unprocessed silk (%) Refinement (score) Adhesion (g / d) Elongation (%) Raw silk weight (kg) Control 19.68 95 3.80 3.47 2.75 Treatment group 16.96 96 3.93 1,005 2.61

Change in Larvae Weight due to Jade Treatment division Weight of larvae immediately away from the third slough Weight of larvae immediately away from the fourth slough 3rd day weight of 5 Mature caterpillars Control 0.46 1.85 20.80 47.4 Treatment group 0.47 1.94 23.03 52.2

<Reduction effect of blood glucose by jade solution> Silkworm extract Blood sugar Reduction effect of blood glucose Injection with maltose '(A) Injection into silkworm extract (B) Reduction amount (C = A-B) efficiency Water treatment mg / 100ml mg / ml mg / ml% 64.0 ± 1.87 27.7 ± 1.70 36.3 56.7 Treated with jade solution 69.6 ± 1.62 20.7 ± 1.62 48.9 70.3

': Injection of Silkworm Extract Previous

result

The weight of larvae was heavier than the control of distilled water in the age of messenger, especially 0.48 g / kg.

2. The rate of fire was 71.2%, which was 15% lower than that of control, and 15.4g of 10,000 head was 7% lower than control.

3. The total weight of the necrosis was 2.14 g, 6% heavier than the control, and 44.5 g, 9% heavier. The silk ratio was 2% higher than the control.

4. The purgative group showed better overall performance than the control. In particular, the length of silk thread was long, the amount of silk was high, and the rate of hatchery was much higher than that of the control by about 9%.

5. In the sands, the nephrophylls showed slightly thicker fine grains, and showed a higher ratio of strength, elongation, and yield than those of the control.

6. No significant difference was found between the control and the treated surface structures.

7. The crystal structure of the impregnated purgatory had a pointed rod structure.

Experimental Example 3

In this experiment, we observed changes in the activity of mice drinking jade flour drinking water added with jade jade used in the present invention.

As shown in Figure 3, the mice in the positive control in the stabilization experiment, the central nerve starts to stabilize from 5 minutes after drinking Ubabito (Note: Chinese name) medicine, and gradually returns to normal after 30 minutes, Mice in the control group showed ups and downs in activity rates and declined overall. The activity rate of the drinking test group (mouse) of the drinking water of jade powder was similar to that of the normal control group, but the average value of the overall activity rate was higher than that of the normal control group, and the difference was more significant compared to the positive control group. .

Experimental Example 4

In this experimental example, infrared experiments were performed on purgatory powder (FIG. 4).

     sample       Jade minutes      Sample property       White      method of inspection     Perkin elmer 137      result         As

<IR spec in IR spectrum>

Form: Tetrahydrofran Liquefied Thin Film

It appeared to match the pattern of polycarbonate resin and radiated electromagnetic waves with a wavelength of 6-52μ.

Experimental Example 5

In this Experimental Example, the chemical and biological oxygen requirements for the purgatory powder sample used in the present invention were performed as shown in Table 13 and Table 14 below.

sample Jade minutes Sample property White Way Standard method result Same as Table 17

division Water (control) Jade addition 5-day BOD 224 mg / l 223 mg / l COD 115 mg / l 110 mg / l

Experimental Example 6

In this experimental example, the experiment on the effect of the purgatory powder used in the present invention on the breeding and growth of the test sphere (rat) was performed as shown in Table 15.

Effect of Jade Adhesive and Agate on Delivery and Sperm Performance in Rats Childbirth and sperm ability Treatment group ^* A B C Childbirth Number (n = 10) Total Childbirth Sexual number of offspring (♂ / ♀) Average childbirth per mother Weight at birth Childbirth at birth (pups, g) Weight after delivery at day of birth (g) Weight at slaughter (♂) (g) sperm weight (g) sperm concentration (10 ⁸ / ml) sperm vitality (%) 99657: 3911.8 ± 1.94.73 ± 1.1023.8 ± 1.4 ^a 43.45 ± 8.04294.0 ± 10.93.90 ± 0.21 ^a 6.32 ± 2.491.0 ± 4.2 99457: 3710.9 ± 1.45.79 ± 0.9525.1 ± 1.7 ^b 42.73 ± 8.76274.4 ± 8.63.57 ± 0.30 ^b 4.80 ± 1.392.0 ± 2.7 810 254: 4812.8 ± 2.15.35 ± 0.3525.5 ± 3.7 ^b 42.07 ± 10.71288.4 ± 26.73.99 ± 0.15 ^a 4.60 ± 1.988.0 ± 7.6

* A: Purgatory treatment group

B: Purgatory Corn Salary

C: control

p <0.05: Statistically significant at 95% level.

This study was conducted to investigate the effects on the reproduction and growth rate of rats when treated with the adhesive prepared from Chuncheon Mountain Purgne and the precipitated cornmeal used in the present invention. Thirty water samples were prepared, respectively. The test treatment was carried out with three treatment groups of nephrite paint (A), chalcedony (B) and control group (C). In all treatment groups, male rats were isolated for 9 days and then slaughtered for sperm concentration and vitality test.

<Test Results>

(1) The jadeite paint (A) and maize (B) treatment groups were superior to the control group (C).

② The delivery rate was 90% in the jade (A, B) treatment group and 80% in the control group (C), respectively.

③ Although the litter size was 6-8 more in the control group (C), the male number was higher in the jade treatment group (A, B).

④ The number of days after delivery was significantly shortened by jade treatment group, and sperm activity of sperm concentration was also excellent in jade treatment group (A).

Experimental Example 7

In this experimental example, the effect of purgatory powder used in the present invention on the freshness of pork was performed as shown in Table 16.

<Effect on freshness when storing pork in purgatory bowl> Temperature 0 4 Vessel Control purgatory Control purgatory Day 0 pHVBNTBAcolor (ΔE) 5.83 ± 0.04 3.50 ± 0.43 0.063 ± 0.013 53.70 ± 4.34 Day 4 Drip loss (%) pHVBNTBAColor (ΔE) 0.14 0.57 0.54 0.01 5.46 ± 0.04 5.42 ± 0.00 5.59 ± 0.01 5.69 ± 0.01 5.56 ± 0.20 4.29 ± 0.20 5.65 ± 0.39 5.42 ± 1.41 0.153 ± 0.00 0.104 ± 0.032 0.122 ± 0.006 0.099 ± 0.025 55.80 ± 0.01 49.30 ± 0.11 54.90 ± 0.08 56.50 ± 0.07 DAY7 Drip loss (%) pHVBNTBAColor (ΔE) 1.02 0.17 1.90 0.43 5.77 ± 0.03 5.84 ± 0.01 5.56 ± 0.01 5.65 ± 0.01 2.36 ± 0.00 2.32 ± 0.00 3.48 ± 0.45 2.59 ± 0.22 0.234 ± 0.013 0.203 ± 0.006 0.239 ± 0.006 0.203 ± 0.019 55.50 ± 0.47 52.60 ± 0.75 52.80 ± 0.06 52.90 ± 0.05 DAY14 Drip loss (%) pHVBNTBAColor (ΔE) 0.92 0.27 2.70 0.19 5.50 ± 0.01 5.67 ± 0.03 6.71 ± 0.00 5.91 ± 0.02 3.00 ± 0.39 3.98 ± 0.18 6.17 ± 0.87 3.85 ± 0.53 0.162 ± 0.013 0.176 ± 0.019 2.406 ± 0.191 0.811 ± 0.089 51.70 ± 0.10 53.80 ± 0.13 62.80 ± 0.00 56.70 ± 0.04 DAY21 Drip loss (%) pHVBNTBAColor (ΔE) 1.11 0.35 0.85 0.25 6.41 ± 0.01 6.07 ± 0.00 7.24 ± 0.00 6.69 ± 0.01 5.32 ± 0.36 7.35 ± 0.42 30.67 ± 3.31 15.08 ± 0.98 10.220 ± 0.230 6.852 ± 0.274 10.15 ± 0.198 2.298 ± 0.102 52.40 ± 0.06 59.20 ± 0.13 58.20 ± 0.13 66.30 ± 0.33

Drip Loss:%

VBN (protein variability): mg%

TBN (fatty acidity degree): mg Mal / kg of meat

Color

The test was carried out to measure the effect on freshness change over time when the pork is stored in the bowl (bowl) prepared with Chuncheon mountain purgatory used in the present invention. There were two types of test materials: purgatory and normal (control). The storage temperature was 0 ℃, 4 ℃, and the storage period was 0,4,7,14,21. The ham (Ham) of pork cut about 100g while storing the juice (Drip Loss), meat color (meat Color), pH, volatile basic nitrogen (VBN), fatty acid septic (TBA) was measured.

<Test Results>

① When the pork was stored in the purgatory bowl (jug), the juicy outflow rate was much lower than that of the general bowl, regardless of the storage temperature.

② As an important indicator of postmortem change of muscle, pH was higher at 4 ℃ than 0 ℃, but there was no clear difference according to storage container.

③ VBN, which shows protein deterioration, was slightly higher at Day 14 and Day 21 at 0 ° C, but was significantly lower at 4 ° C in purgatory.

④ TBA (價), which indicates fatty acid loss, was much lower in jade purge regardless of storage temperature.

Primary skin irritation test sample Jade minutes Sample property White powder Way As result As

Method: US Federal Register Vol. 43, no. 163

CTFA (The Cosmetic, Toiletry and Fragrance Association, Washington, D.C.) Technical Guidelines

Experimental procedure: Patch testing was performed on the skin of the white rabbit and the original skin. The hair was cut short at the back and sides. Two areas, about 10 cm away, were selected as patch locations. One area is made of 4 small epidermal incisions in the patch area to remove the skin (two of which are perpendicular to the other and are "tic-tac-toe"). The patch is attached using a thin rubber band and adhesive tape Samples are introduced in each part in an amount of 0.5 ml (g) under the patch The body of the animal is wrapped with a rubberized cloth for 24 hours of exposure. After the patch was removed, the reaction at each site was evaluated based on the scores described below (see Table 18).

Evaluation of Skin Response

Erythema and crust formation

No erythema-0

Very weak erythema (recognizable barely)-1

Properly Identified Erythema-2

Moderate to severe erythema-3

Severe erythema (beat red) to slight crust formation (deep damage)-4

Edema

No edema-0

Very mild edema (recognizable barely)-1

Slight edema (it is obvious that the edges of the area are prominent)-2

Moderate edema (approximately 1 mm up)-3

rabbit 24 hours 72 hours Original skin Worn skin Original skin Worn skin ER ED ER ED ER ED ER ED #One 0 0 0 0 0 0 0 0 #2 0 0 0 0 0 0 0 0 # 3 0 0 0 0 0 0 0 0 #4 0 0 0 0 0 0 0 0 # 5 0 0 0 0 0 0 0 0 # 6 0 0 0 0 0 0 0 0

Conclusion: This sample was determined to have no skin irritation. Therefore, it is found that there is no big problem even when used in the product in contact with the human body.

<Acute oral toxicity [(0.5 g) / 100 g body weight] experiment> sample Purgatory powder Sample property White powder Way As result Same as Table 24 below

rat gender Initial weight (g) Dosage (ml) Lag weight (g) Toxicity One F 207 1.0 219 none 2 F 211 1.1 226 none 3 F 215 1.1 225 none 4 F 208 1.0 217 none 5 F 200 1.0 213 none 6 M 227 1.1 235 none 7 M 216 1.1 224 none 8 M 205 1.0 218 none 9 M 210 1.1 224 none 10 M 212 1.1 221 none

Preparation of Samples: A portion of the sample was placed in sterile distilled water and boiled for 10 minutes to extract, and the extract was administered by intubation in an amount of 0.5 g per 100 g of body weight.

CONCLUSIONS: The sample meets the criteria for no oral toxicity.

Experimental Example 8

This experiment example is a process and results of the experiment performed by the Inha University bioinformatics system engineering laboratory to investigate the various effects of the purgatory powder used in the present invention on the living body. In this experiment, 70% of the constituent elements of the human body are water, so it is determined that there is a lot of relationship between the change of water and the effect on the human body. Experiments on the effects were performed.

A. Hard water change

Experiment 1

100 ml of artificially-made hard water was transferred to each of the four flasks by 50 ml, and purgatory was placed on the bottom of two flasks for about 10 minutes.

To determine the change in hardness, a titration method using ethylene diamineacetic acid (hereinafter referred to as "EDTA" titer 2.9412) was used. 1 ml of a buffer solution of pH 10, EBT was used as an indicator.

The change in hardness was measured by the amount of EDTA until the moment when the color of the hard water was changed by EDTA. At this time, the color returned to its original state over time, but in this experiment, the measurement was made based on the changing moment.

<Result 1>

At 100ppm hard water, EDTA 1.70ml is required

It takes 1.25ml of EDTA after purgatory test, so the hardness of 100.00ppm is lowered to 73.53ppm. That is, the hardness of 100.00 ppm was softened 26.47%.

Experiment 2

200 ml of 100ppm hard water made in the same manner as in Experiment 1 was transferred to a beaker to immerse the purgatory.

After about 30 minutes, the water in the beaker was divided into three flasks to measure the change in hardness. In this experiment, the hardness was measured by adding EDTA until the color of hard water did not change any more after the color of hard water changed by EDTA.

<Result 2>

Each 100ppm hard water before purgatory experiment

89.62 ppm

91.19ppm

89.62 ppm

Average 90.14ppm, thus 9.9% hardness decrease

Experiment 3

This experiment was conducted with tap water. Tap water was placed in a container and transferred to six flasks, and purgatory was placed at the bottom of three flasks, and hardness was measured after about 5 minutes.

<Result 3>

* Tap water without purgatory

97.48 ppm

97.48 ppm

97.48 ppm

Average 97.48 ppm

* Tap water after purgatory experiment

 91.19ppm

 91.19ppm

 91.19ppm

 Average 91.19ppm therefore, hardness decrease of 6.5%

I. Effect of Purgatory on the Proliferation of Digital Plant Suspensions of Digitalis lanata

Effects of Purgatory on the Growth of Digitalis lanata Cells in Growth Medium

Figure 5 is a graph showing the change in the total volume of the culture medium of the cells proliferating in the growth medium for 11 days, Figure 6 is a graph showing the change in the cell volume, in proportion to the increase of the cells growing over time medium components As the depletion of and the evaporation of the medium occur, the volume change of the whole culture reflects these factors. In particular, humidity and temperature in the atmosphere are closely related to the evaporation of the medium, and such factors also affect the cell growth rate.

As shown in the figure, the use of purgatory shows that the volume of the total culture solution is slightly decreased compared to the control group which is not used. This is because the use of purgatory rather than the control group has a faster cell growth rate against the evaporation of the medium or the depletion of nutrients, and thus, it is possible to offset the rapid decrease of the depleted medium to some extent. This phenomenon is observed in the case of continuous purgatory use from 4 to 11 days after inoculation of cells as shown in Figure 6, which measured the volume change of only the submerged cells, it is observed that the cell volume increases more than the control group not used. This fact can be estimated. Therefore, the use of nephrite showed a faster cell growth rate than the control without the nephrite. These results can be said to be the result of delaying the decrease of the total volume than the control by offsetting the decrease in the total culture volume due to nutrient depletion and medium evaporation. In addition, the result of comparing the volume of the increased cell alone is also observed to show a tendency to gradually increase the cell volume after 4 days, it is thought that can support this result.

Cell proliferation and dry weight are the most common measures of cell proliferation. In general, the growth curve of all cells is represented by the S-shaped curve, which can be classified into four stages. Lag phase, which is a period of adaptation to the medium, in which there is no cell proliferation and no mass growth, and an exponential curve showing a steep slope due to a mass increase at a rapid proliferation rate after this period. phase), the stationary phase, which has a maximum growth to some extent, and the Chinese food is slowed down and shows no mass increase, and the cell ruptures due to the depletion of nutrients, the release of toxic components, and the saturation of cell density. It can be divided into a dead phase where the total cell volume or mass decreases due to the tendency to die.

7 and 8 are the results of measuring the cell biomass and dry weight.

7 follows the growth curve of these four stages. In the case of using jade, after 7 days, the growth rate was slightly higher than that of the control without jade, and the growth stopped until 10 days, unlike the control showing the decrease in cell biomass. have. This is remarkable in that cell growth is continued even when the concentration of nutrient is almost depleted and the concentration in the medium becomes zero compared with the change in the concentration of glucose, a nutrient that acts as the main metabolic substrate in the medium. It is common to show a tendency to stop the growth and decrease the growth rate at the point of depletion of the influenced ingredients, like the control without purgatory, but the effect of purgatory on cell growth is different when purgatory is used. It is assumed that there is. This result is also shown in Figure 8 shows the cell growth proliferating at a higher rate than the control after 3 days, and from 9 days after, the same phenomenon as in FIG. As a result, cells grown near nephrite in the growth medium showed better effect on cell growth than the control group that did not. Digitalis lanata plant cells, which have a growth limit of about 10 days, are maintained in a stable state that does not cause necrosis of cells without exchanging with new medium even after 10 days when cultured with purgatory. Rather, it is expected that cell proliferation may be an advantageous method for optimizing cell growth and concentration in the production process for the production of useful substances.

② Effect of Purgatory on Changes in Medium pH

9 is a graph showing the pH change in the cell growth medium, Figure 10 is a graph showing the pH change of the production medium after the addition of purgatory powder.

Figure 9 is a measure of the change in the pH of the medium in the control medium with and without the purgatory in the growth medium. The control group shows a general tendency of pH in the medium applied to the plant cells, which gradually decreases over time and is maintained at a certain level. However, by using the purgatory, it showed a similar pattern to the control group until the 7th day and then increased gradually. This phenomenon is extreme in the result of FIG. 9 which shows the result in the production medium in which the purgatory powder was added directly to the culture medium. . The control group without added jade powder showed a consistent drop in pH, while the addition of jade powder showed a tendency to maintain the value to some extent. It is assumed that it acts as a cause.

③ Results of analysis of water quality for purgatory

FIG. 11 is a view showing the condition of the water analyzer containing the purgatory powder used in the present invention, and FIG. 12 is a view showing the analysis results of the water containing the purgatory powder used in the present invention.

The data from FIG. 11 and FIG. 12 is summarized in Table 21 in Table 21. Table 21 shows the analysis of each analysis item for Sample 1 after 48 hours of 20 g of purgatory lumps in solution. In Table 21, there is almost no change in each measurement item, and the effect of purgatory is hardly seen.

Table 22 shows the measured values for each analysis item in Sample 2 after 48 hours after placing 20g of jade purgatory lumps outside the solution.

Table 24 also shows the measured values for each analysis item in Sample 4 after 48 hours after placing the purgatory powder outside the solution. There was no change for each analysis item in this experiment. However, in the case of Sample 3, the data measured for each analysis item of the sample 48 hours passed after adding 20 g of purgatory powder in the solution is shown in Table 23. This change is as follows.

Cr, Pb, Ni, and Co, which are harmful to the human body, changed significantly after 48 hours. Cr was removed in the absence of purgatory powder, that is, 45.30 mg before the reaction was removed to 0 after 48 hours in the purifying powder, and Pb was also completely removed from 13.76 mg to zero. Ni decreased from 51.8 mg to 1.733 mg and Co also decreased from 52.69 mg to 11.94 mg. Mg, one of the necessary elements in the human body, increased from 48.36mg to 55.74mg.

The hydrogen ion concentration of distilled water was acidic to pH 3.5, but after the reaction, it was neutral to pH6.8, and the conductivity rapidly decreased. The adsorption force is physically large, about 3-4 mmol.q (equivalent) per gram.

Analytical results before and after the reaction in solution Purgatory lumps in the solution. (Sample 1): Purgall lump in solution (20 g)   Item     Before the reaction After reaction (48hr)    Change    pH     3.5      3.82       -    Ni     51.8 mg     51.75mg       -    Co     52.69mg     52.54mg       -    Cr     45.30mg     43.88mg       -    Mg     48.36mg     48.59 mg       -    Pb     13.76 mg     13.90mg       -

Results of analysis of purgatory lumps outside the solution. (Sample 2): lump of purgatory jade (20g)   Item     Before the reaction   After reaction (48hr)    Change    pH     3.5      3.65       -    Ni     51.8 mg     48.92mg       -    Co     52.69mg     49.83mg       -    Cr     45.30mg     41.23mg       -    Mg     48.36mg     47.97mg       -    Pb     13.76 mg     15.1mg       -

Analysis result when adding purgatory powder to solution. (Sample 3): Purgatory powder in solution (20g)   Item     Before the reaction After reaction (48hr)    Change    pH     3.5      6.8     +3.3    Ni     51.8 mg     1.733 mg  -50.06mg    Co     52.69mg     11.94mg  -40.75mg    Cr     45.30mg        0mg  -45.30mg    Mg     48.36mg     55.74mg   + 7.38mg    Pb     13.76 mg         0mg  -13.76 mg

Analysis result when purgatory powder was placed outside the solution (Sample 4): Purgatory powder outside the solution (20g)   Item     Before the reaction After reaction (48hr)    Change    pH     3.5      3.7       -    Ni     51.8 mg     51.53 mg       -    Co     52.69mg     52.55mg       -    Cr     45.30mg     43.0mg       -    Mg     48.36mg     48.39mg       -    Pb     13.76 mg     14.29 g       -

As described above, the digitalis lanata plant suspension cells cultured for one week with nephrite close showed proliferation of about 30% or more in the absence of purgatory. This is a rare proliferative result even in the various experiments performed for the proliferation effect on conventional Digigitalis lanata plant cells for high concentration culture. In addition, experiments on how purgatory water affects hard water showed that soft water softened hard water without contact with water. Particularly, in the component analysis experiments on water using distilled water, precipitation of nephrite was carried out. After 48 hours, in the component analysis, the pH was increased, the Ni and Co components were reduced, the Cr and Pb were removed. An unusual phenomenon was observed that led to the phenomenon of.

Thus, purgatory used in the present invention has not yet been clearly identified theoretically, it changes the hardness of the water without contact with water, and also proliferates more than 30% of the digitalis lant (Digitalis lanata) plant suspension cells, The elimination of heavy metals harmful to the human body, such as the reduction of Ni and Co components, and the removal of Cr and Pb, is believed to be due to the radiation effect of the electromagnetic wave wavelengths of the purgatory powder and the ionic reaction by the mineral components contained in the nephrite. Such facts will be proved by the efficacy shown in the product of the present invention described above.

Experimental Example 9

In this test example, the effects of the water and diet of the water purifier and the refrigerator treated with the interior material made of Chuncheon nephrite used in the adhesive of the present invention on the growth rate, sperm capacity, and muscle motility in the experimental group (rats) were evaluated. It was.

The test treatment consisted of a control group (A) fed a water purifier water and a refrigerator storage diet and a jade treated group (B) fed a refrigerator storage diet using a water purifier containing jade water purifier. Approximately 10-week-old rats per test group were reared for 6 weeks with 3 numbers 3 repetitions of 9 numbers of 9 numbers. The growth rate, sperm vitality and sperm concentration, blood lipid concentration and exercise volume of rats during the test period were shown in Table 27. Measured.

Metric Treatment group ^* Control group (A) Jade treatment group (B) Growth rate (g / day) Feed intake (g / day) Drinking water (ml / day) Sperm ability (精子 能力) Sperm vitality (%) Sperm concentration (10 ⁸ / ml) Momentum Rotation bar (sec) Rotating basket (rotation / 10 minutes) Swimming endurance (sec) Blood pH Neutral fat (TG) Total cholesterol (TC) High density cholesterol (HDL) 2.33 ± 0.3715.52 ± 1.3035.8 ± 1.1 90.0 ± 0.005.7 ± 1.37 41.0 ± 1.61810,481 ± 5,315 7.66 ± 0.10171.5 ± 39.2 ^a 171.1 ± 62.382.8 ± 10.7 2.64 ± 0.4114.97 ± 1.0727.8 ± 0.9 88.3 ± 2.96.9 ± 1.08 41.5 ± 9.11711,713 ± 3,519 7.84 ± 0.09133.1 ± 33.3 ^b 146.6 ± 62.169.3 ± 7.4

* A: General Cage, Water Purifier, General Refrigerator Storage (AIN-diet)

B: Jade treatment tile, water purifier water, jade refrigerator freezer (AIN-diet)

P <0.05: statistically significant at 95% level.

<Test Results>

① There were no differences between the two treatments in terms of growth rate and delivery and blood lipid concentration.

② Sperm vitality was not different, but sperm concentration was about 17% higher in jade treatment group than in control.

③ In the exercise measurement results, swimming endurance was 1,200 seconds longer on average in the jade treatment group than in the control group.

④ blood pH of jade treatment group was slightly higher than control.

⑤ High density cholesterol (HDL) content in blood lipid was somewhat higher in the control group.

As can be seen from the above results, the jade treatment group showed better swimming endurance and sperm concentration than the control group. Especially, blood cholesterol (TC) and triglyceride concentration (TG) were significantly lower in the jade treatment group than the control group. .

Experimental Example 10

This experiment investigated the pH change over time when jade ore, jade necklace and jade stone powder was immersed or added to other water for 8 to 11 days (Figs. 11 to 14).

In the case of jade ore, Chuncheon Mountain Purgne (made by Oxan ^R ) and Russia were used in the manufacture of the present invention, and Chuncheon Mountain Purgatory and Chinese products were used as the jade necklace. The water used to measure the pH change was general water purifier, groundwater and strong acid solution (pH3.2).

<Experiment Result>

① When jade ore and jade necklace were immersed in general water purifier and groundwater, pH of Chuncheon gemstone and necklace used in the present invention was higher than that of Russian or Chinese jade necklace.

② The average pH measured by adding 10%, 5%, and 1% to the strong acid solution of pH 3.2 was 10.59 ± 0.10, 8.58 ± 0.13, 8.57 ± 0.11, respectively. .

③ The pH of strong acid solution in Chuncheon nephrite jade treated milk bottle was consistently higher than that of regular milk bottle.

As can be seen from the above, the Chuncheon nephrite gemstones, powders and necklaces used in the present invention increased the hydrogen ion concentration (pH) of water compared to the Russian and Chinese gemstones and jade necklaces, but no statistically significant difference was recognized.

Experimental Example 11

In this test, as confirmed from Table 26 and Table 27, the rats of about 5 weeks old were published to evaluate the effect on the labor and weaning when drinking the other drinking water (white rats). Drinking water was divided into three treatment groups of ground water (A), general water purifier water (B), Chuncheon mountain purgatory water purifier water (C) used in the present invention, the test feed was fed the same AIN-diet. The female rats (♀) were placed in a total of 27 numbers of 9 rats in 3 numbers and 3 repetitions. The male rats (♂) placed 24 numbers in 8 numbers for each treatment group. After breeding for 4 weeks, 7 days of breeding (種 付, mating), the ratio (mating ratio) was ♂ / ♀ = 1: 3. It was reared after weaning and weaning after about 3 weeks of gestation.

<Effect when drinking different water to rats> Metric ¹⁾ Treatment tool ^* A B C Daily gain (g / day) Feed intake (g / day) Drinking water (ml / day) Sperm ability (精子 能力) Sperm vitality (%) Sperm concentration (10 ⁸ / ml) Momentum Rotating basket (time, 10 minutes) (sec) Rotating rod (sec) Blood pH 4.32 ± 0.2616.25 ± 0.3220.3 ± 1.2 91.1 ± 2.34.01 ± 1.09 57.8 ± 3.164,082 ± 81339.6 ± 18.97.64 ± 0.09 4.20 ± 0.5716.51 ± 0.4522.00 ± 1.8 90.5 ± 2.84.26 ± 0.71 35.2 ± 19.05,087 ± 1,47132.9 ± 9.97.69 ± 0.12 4.33 ± 0.3717.01 ± 1.0619.8 ± 1.1 91.1 ± 2.84.87 ± 1.41 33.3 ± 14.75,332 ± 44531.5 ± 11.07.78 ± 0.24

¹⁾ Colony as measured in male rats

* A: groundwater, B: general water purifier, C: water purifier

Effects of Different Drinking Water on Labor in Rats Treatment Zone ¹⁾ Number of delivery days (days) Number of delivery individuals (birth rate,%) Total Childbirth Childbirth number per mother Reason cubs (♂ / ♀) A 24.2 ± 1.5 5 (55.6) 56 11.2 ± 1.9 53 (26/27) B 25.5 ± 2.3 6 (66.7) 46 7.7 ± 2.9 39 (17/22) C 24.7 ± 2.3 7 (77.8) 81 11.6 ± 0.5 69 (41/28)

<Test Results>

① There was no significant difference in growth rate, momentum and sperm capacity between treatments.

② The sperm concentration of Chuncheon nephrite water purifier (C) used in the present invention averaged 4.87 billion / ml, which was 21.4% and 14.3% higher than the average of 4.01 billion / ml (A) and 4.26 billion / ml (B) of the other two treatments, respectively. .

③ The delivery rate was 55.6%, 66.7%, and 77.8% in groundwater, general water purifier water, and jade water purifier water, respectively.

④ The number of bovine birds was 11.2 ± 1.9, 7.7 ± 2.9, and 11.6 ± 0.5 in groundwater, general water purifier, and jade water purifier.

⑤ The number of weaning weaning after 3 weeks of delivery was 53, 39 and 69 in three treatment groups A, B and C, respectively. Sex ratio was 26/27, 17/22 and 41, respectively. Male pups were higher in the Oksugi test zone (C) at / 28.

As can be seen from the above, sperm concentration was 21.4% and 14.3% higher in sperm concentration than the other two treatments, respectively, and female rats had 78% jade water treatment and 56,67% in the other two treatments. The sex ratio of weaning pups was higher in male pups than in other two treatments.

In particular, the above experimental results will be sufficient to prove that the use of the adhesive or glue containing the purgatory powder of the present invention has a useful effect on the human body due to the properties of the purgatory powder and the effect of purgatory.

As described above, according to the present invention, by adding nephrite powder to the raw material of the adhesive mainly made of an inorganic material such as ceramic, the physical properties of the adhesive itself are improved, as well as from the purgatory particles contained in the adhesive, As a result, there is an effect of activating cellular functions, promoting blood circulation and metabolism of the human body by releasing a large amount of substances useful for the human body, that is, anion and far infrared rays.

In addition, as a result of the experiments that a large amount of negative ions are released from the purgatory, it has the effect of antibacterial and deodorizing effect in the room, and because the main material is inorganic, it is not easily burned in the fire, and also has the effect of non-toxic and odorless.

1 is a crystal structure diagram showing a purgatory powder used in the present invention by a scanning electron microscope (SEM),

2A and 2B are photographs showing untreated silk of jade water used in the present invention by scanning electron microscopy,

2C and 2D are photographs of a silk treated with jade water used in the present invention by scanning electron microscopy,

3 is a change chart of the test sphere (mouse) activity after drinking drinking water used in the present invention,

Figure 4 is a far-infrared emissivity measurement by the FT-IR Spectrometer of purgatory used in the present invention,

5 is a graph showing the results of observing the change in the total volume of the culture medium of digitalis lantana (Digitalis lanata) cells growing in the growth medium,

6 is a graph showing the change in the volume of digitalis lanata (Digitalis lanata),

7 is a graph showing changes in the bio weight of cells,

8 is a graph showing the change in dry weight of cells,

9 is a graph showing the pH change of the digitalis lantana (Digitalis lanata) culture medium,

10 is a graph showing the pH change of the production medium after the addition of purgatory powder,

11 is a view showing the result of the state condition of the analyzer;

12 is a view showing an output of an analysis result,

13 is a view showing the pH change of jade necklace and jade ore in a general water purifier,

14 is a view showing the pH change over time of jade necklace and jade ore in groundwater,

15 is a view showing the pH change of the strong acid solution by the Chuncheon nephrite powder treatment,

16 is a view showing the pH change over time of the strong acid solution (pH) stored in the milk bottle containing the purgatory powder and the normal milk bottle.

Claims (6)

70-99% by weight of bio-ceramic mixed 1 to 30% by weight of the nephrite powder having a particle size of 100 ~ 1000 mesh to form a mixed powder, 40 to 50% by weight of the liquid binder to the mixed powder 50 to 60% by weight Adhesive containing jade powder, which is mixed uniformly for 5 minutes by adding%. The adhesive agent according to claim 1, wherein the nephrite powder is defined as butch δ ¹⁸ O as a diaphragm nephrite in high-quality surrogate rock. The adhesive agent according to claim 1 or 2, wherein the composition ratio of the nephrite powder used in the above is made as follows. Semi QuanTitative Analysis (%) Silicon 34 Magnesium 10 Calcium 4.9 Iron 0.23 Aluminum 0.16 Copper 0.17 Cobalt 0.046 Manganese 0.14 Tin 0.024 Beryllium 0.00072 Is 0.0013 Titanium 0.0038 Nickel 0.0028 Chromium 0.0030 Miscellaneous 0 After mixing and stirring 1 to 30% by weight of the nephrite powder having a particle size of 100 to 1000 mesh to 70 to 99% by weight of the bio-ceramic, after forming the mixed powder, the binder 40 to 50 in the liquid 50 to 60% by weight of the mixed powder. A method for producing an adhesive containing jadeite powder obtained by uniformly mixing for 5 minutes by adding weight%. The method of producing an adhesive containing a jadeite powder according to claim 4, wherein the jadeite powder is defined as butch δ ¹⁸ O as a hollow-trillite gemstone in high-quality surrogate rock. The method of claim 4 or 5, wherein the composition ratio of the purgatory powder used in the above is made as follows. Semi QuanTitative Analysis (%) Silicon 34 Magnesium 10 Calcium 4.9 Iron 0.23 Aluminum 0.16 Copper 0.17 Cobalt 0.046 Manganese 0.14 Tin 0.024 Beryllium 0.00072 Is 0.0013 Titanium 0.0038 Nickel 0.0028 Chromium 0.0030  Miscellaneous 0