KR20030091452A - Method of forming pattern inhibiting pitting effect - Google Patents
Method of forming pattern inhibiting pitting effect Download PDFInfo
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- KR20030091452A KR20030091452A KR1020020029497A KR20020029497A KR20030091452A KR 20030091452 A KR20030091452 A KR 20030091452A KR 1020020029497 A KR1020020029497 A KR 1020020029497A KR 20020029497 A KR20020029497 A KR 20020029497A KR 20030091452 A KR20030091452 A KR 20030091452A
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- 238000000034 method Methods 0.000 title claims abstract description 30
- 230000000694 effects Effects 0.000 title description 3
- 230000002401 inhibitory effect Effects 0.000 title 1
- 238000005530 etching Methods 0.000 claims abstract description 26
- 230000002093 peripheral effect Effects 0.000 claims abstract description 15
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 12
- 229920005591 polysilicon Polymers 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract 3
- 238000000059 patterning Methods 0.000 claims abstract 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract 3
- 239000010408 film Substances 0.000 claims description 28
- 239000010409 thin film Substances 0.000 claims description 6
- 229920002120 photoresistant polymer Polymers 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910021332 silicide Inorganic materials 0.000 claims description 4
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052721 tungsten Inorganic materials 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 238000000206 photolithography Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28035—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4916—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen
- H01L29/4925—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement
- H01L29/4933—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement with a silicide layer contacting the silicon layer, e.g. Polycide gate
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Ceramic Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Electrodes Of Semiconductors (AREA)
- Drying Of Semiconductors (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
Abstract
Description
본 발명은 반도체 제조 공정에서의 패턴 형성 방법에 관한 것으로, 특히 로딩 효과(loading effect)로 인한 피팅(pitting) 현상을 억제할 수 있는 패턴 형성 방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a pattern forming method in a semiconductor manufacturing process, and more particularly, to a pattern forming method capable of suppressing a fitting phenomenon due to a loading effect.
로딩 효과(loading effect)는 식각 공정 시에 발생하는 문제로써, 패턴 밀도(pattern density)의 차이에 따라 식각 속도가 달라지는 현상을 일컫는다. 이는 패턴 밀도가 부위별로 다를 때는 식각해야 하는 면적의 차이가 나게 된다. 따라서, 동일한 플라즈마 밀도(Plasma density)로 식각을 하게 되면 부분적으로 공급되는 에천트(etchant)의 밀도가 반응 면적에 따라 달라져 식각 속도가 달라진다.The loading effect is a problem that occurs during the etching process, and refers to a phenomenon in which the etching speed is changed according to a difference in pattern density. This results in a difference in the area to be etched when the pattern density varies from site to site. Therefore, when etching at the same plasma density, the density of the partially supplied etchant varies depending on the reaction area, thereby changing the etching rate.
도 1a 및 도 1b는 종래기술에 의한 게이트 패턴 형성 방법을 나타내는 단면도들이다. 도면에서 도면부호 '50'은 패턴이 상대적으로 고밀도로 형성되는 셀 영역이며, 도면부호 '80'은 패턴이 상대적으로 저밀도로 형성되는 주변 회로 영역이다.1A and 1B are cross-sectional views illustrating a gate pattern forming method according to the prior art. In the drawing, reference numeral 50 denotes a cell region in which a pattern is formed at a relatively high density, and reference numeral 80 denotes a peripheral circuit region in which a pattern is formed at a relatively low density.
도 1a를 참조하면, 셀 영역(50) 및 주변 회로 영역(80)의 기판(2) 상에 게이트 절연막(4), 폴리실리콘막(6), 및 게이트막(8)을 순서대로 형성한다. 상기 게이트막(8)은 텅스텐막 또는 금속 실리사이드막으로 형성할 수 있다. 상기 게이트막(8) 상에 하드마스크막을 형성하고 통상의 사진공정에 의하여 하드마스크막 패턴(10)을 형성한다.Referring to FIG. 1A, a gate insulating film 4, a polysilicon film 6, and a gate film 8 are sequentially formed on the substrate 2 of the cell region 50 and the peripheral circuit region 80. The gate layer 8 may be formed of a tungsten layer or a metal silicide layer. A hard mask film is formed on the gate film 8, and the hard mask film pattern 10 is formed by a general photolithography process.
도 1b를 참조하면, 상기 패터닝된 하드마스크막(10)을 식각마스크로 이용하여 상기 게이트막(8)을 식각하여 패터닝한다. 이 때 상기 게이트막(8)은 식각시에 패턴 밀도가 낮은 주변 회로 영역(80)이 상대적으로 패턴 밀도가 높은 셀 영역(50)보다 식각 속도가 빠르기 때문에 셀 영역(50)보다는 주변 회로 영역(80)에서 하부의 폴리실리콘막(6)이 더 빨리 노출된다. 따라서, 셀 영역(50)의 상기 게이트막(8)을 제거하기 위한 과식각(overetch) 과정에서 주변 회로 영역(80)의 상기 폴리실리콘막(8) 및 게이트 절연막(2)이 상기 게이트막(8)의 식각시에 같이 제거되어 기판(2)이 노출될 수 있다. 결국 게이트 패턴을 형성하기 위한 식각 과정에서 기판이 손상(attack)되는 피팅(pitting) 현상이 발생하는 문제점이 있다. 이와 같은 피팅 현상은 상기 게이트막(8)을 이루는 금속 실리사이드막 및 텅스텐막이 두껍게 형성되거나 또는 상기 폴리실리콘막(8)이 얇게 형성될 경우에 더 쉽게 발생할 수 있다.Referring to FIG. 1B, the gate layer 8 is etched and patterned using the patterned hard mask layer 10 as an etch mask. At this time, the gate layer 8 may have a peripheral circuit region (rather than the cell region 50) because the peripheral circuit region 80 having a low pattern density is faster than the cell region 50 having a relatively high pattern density at the time of etching. At 80, the lower polysilicon film 6 is exposed faster. Accordingly, the polysilicon layer 8 and the gate insulating layer 2 of the peripheral circuit region 80 may be in contact with the gate layer in an overetch process for removing the gate layer 8 of the cell region 50. The substrate 2 may be exposed by being removed together with the etching of 8). As a result, a pitting phenomenon occurs in which the substrate is attacked in the etching process for forming the gate pattern. Such a fitting phenomenon may occur more easily when the metal silicide layer and the tungsten layer forming the gate layer 8 are formed thick or the polysilicon layer 8 is formed thin.
본 발명은 상기와 같은 문제점을 해결하기 위하여 안출된 것으로, 식각 공정에서 패턴 밀도가 높은 고밀도 영역과 상대적으로 패턴 밀도가 낮은 저밀도 영역에서 식각속도의 차이로 인하여 발생하는 피팅(pitting) 현상을 억제하는 패턴 형성 방법을 제공하는데 목적이 있다.The present invention has been made to solve the above problems, in the etching process to suppress the fitting (pitting) caused by the difference in the etching speed in the high density region with a high pattern density and the low density region having a relatively low pattern density It is an object to provide a pattern forming method.
도 1a 및 도 1b는 종래기술에 의한 게이트 패턴 형성 방법을 나타내는 단면도들, 및1A and 1B are cross-sectional views illustrating a gate pattern forming method according to the prior art, and
도 2a 내지 도 2d는 본 발명의 일실시예에 의한 게이트 패턴 형성 방법을 순서대로 도시한 단면도들이다.2A to 2D are cross-sectional views sequentially illustrating a gate pattern forming method according to an embodiment of the present invention.
*도면의 주요 부분에 대한 부호의 설명* Explanation of symbols for the main parts of the drawings
2, 102 : 기판 4, 104 : 게이트 절연막2, 102: substrate 4, 104: gate insulating film
6, 106 : 폴리실리콘막 8, 108 : 게이트막6, 106 polysilicon film 8, 108 gate film
10, 110 : 하드마스크막 50, 100 : 셀 영역10, 110: hard mask film 50, 100: cell area
80, 200 : 주변 회로 영역80, 200: peripheral circuit area
상기 목적을 달성하기 위하여, 본 발명의 패턴 형성 방법은 패턴 밀도가 상대적으로 높은 고밀도 영역 및 상대적으로 낮은 저밀도 영역의 기판 상에 박막을 형성하고, 먼저 상기 고밀도 영역의 박막 일부분을 선택적으로 식각한다. 이어서, 고밀도 영역 및 저밀도 영역을 같이 식각함으로써 패턴 밀도 차이에 의한 식각 속도의 차이를 보상해주게 된다.In order to achieve the above object, the pattern forming method of the present invention forms a thin film on a substrate of a high density region and a relatively low low density region having a relatively high pattern density, and firstly selectively etch a portion of the thin film of the high density region. Subsequently, the high density region and the low density region are etched together to compensate for the difference in etching speed due to the difference in pattern density.
상술한 목적, 특징들 및 장점은 첨부된 도면과 관련한 다음의 상세한 설명을 통하여 보다 분명해 질 것이다. 이하, 첨부된 도면을 참조하여 본 발명에 따른 바람직한 일실시예를 상세히 설명한다.The above objects, features and advantages will become more apparent from the following detailed description taken in conjunction with the accompanying drawings. Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도 2a 내지 도 2d는 본 발명의 일실시예에 의한 게이트 패턴 형성 방법을 순서대로 도시한 단면도들이다.2A to 2D are cross-sectional views sequentially illustrating a gate pattern forming method according to an embodiment of the present invention.
도 2a을 참조하면, 셀 영역(100) 및 주변 회로 영역(200)의 기판(102) 상에 게이트 절연막(104), 폴리실리콘막(106), 및 게이트막(108)을 순서대로 형성한다. 상기 게이트막(108)은 텅스텐막 또는 금속 실리사이드막으로 형성할 수 있다. 상기 게이트막(108) 상에 하드마스크막을 형성하고 통상의 사진공정에 의하여 하드마스크막 패턴(110)을 형성한다. 도면에 도시한 바와 같이 셀 영역(100)에서는 하드마스크막 패턴(110)이 조밀하게 형성되어 고밀도의 패턴 밀도를 갖는데 반하여, 주변회로 영역(200)에서는 저밀도의 패턴 밀도를 갖는다.Referring to FIG. 2A, a gate insulating film 104, a polysilicon film 106, and a gate film 108 are sequentially formed on the substrate 102 of the cell region 100 and the peripheral circuit region 200. The gate film 108 may be formed of a tungsten film or a metal silicide film. A hard mask layer is formed on the gate layer 108, and a hard mask layer pattern 110 is formed by a general photolithography process. As shown in the drawing, the hard mask film pattern 110 is densely formed in the cell region 100 to have a high density of pattern density, whereas the peripheral circuit region 200 has a low density of pattern density.
도 2b를 참조하면, 상기 하드마스크막 패턴(110) 및 상기 게이트막(108) 상에 전면적으로 감광막을 도포한다. 이어서, 통상의 사진 공정을 진행하여 상기 주변 회로 영역(200)은 덮되, 상기 셀 영역(100)의 하드마스크막(110) 및 게이트막(108)을 노출시키는 감광막 패턴(112)을 형성한다.Referring to FIG. 2B, a photoresist is coated on the hard mask layer pattern 110 and the gate layer 108. Subsequently, the photolithography pattern 112 is formed to cover the peripheral circuit region 200 to expose the hard mask layer 110 and the gate layer 108 of the cell region 100 by performing a normal photo process.
도 2c을 참조하면, 상기 감광막 패턴(112) 및 상기 노출된 패터닝된 하드마스크막(110)을 식각마스크로 이용하여 상기 셀 영역(100)의 상기 게이트막(108)을 일정 부분 선택적으로 식각한다. 이어서, 상기 감광막 패턴(110)을 제거한다.Referring to FIG. 2C, the gate layer 108 of the cell region 100 is selectively etched using the photoresist pattern 112 and the exposed patterned hard mask layer 110 as an etch mask. . Next, the photoresist layer pattern 110 is removed.
도 2d를 참조하면, 상기 패터닝된 하드마스크막(110)을 식각마스크로 이용하여 상기 게이트막(108), 상기 폴리실리콘막(106), 상기 게이트 절연막(104)을 상기 기판(102)의 표면이 노출될 때까지 식각하여 게이트 스택을 형성한다. 상기 식각 공정에서는 로딩 현상으로 인하여 상기 주변 회로 영역(200)에서는 상기 셀영역(100)에 비교하여 상대적으로 빠르게 식각이 진행되게 된다. 결국, 셀 영역(100)의 게이트막(108)은 일정 부분을 미리 식각한 상태이므로 로딩 현상으로 인하여 주변 회로 영역(200)이 셀 영역(100)보다 빠르게 식각되더라도 하층의 폴리실리콘막(106)이 손상되지 않게 되며, 피팅 현상도 발생하지 않는다.2D, the gate layer 108, the polysilicon layer 106, and the gate insulating layer 104 are formed on the surface of the substrate 102 using the patterned hard mask layer 110 as an etch mask. It is etched until it is exposed to form a gate stack. In the etching process, etching is performed in the peripheral circuit region 200 relatively faster than the cell region 100 due to a loading phenomenon. As a result, since the gate layer 108 of the cell region 100 is etched in advance, the lower polysilicon layer 106 may be etched faster than the cell region 100 due to the loading phenomenon. This is not damaged, and no fitting phenomenon occurs.
이상에서 설명한 본 발명은 전술한 실시예 및 첨부된 도면에 의해 한정되는 것이 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 여러 가지 치환, 변형 및 변경이 가능하다는 것이 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자에게 있어 명백할 것이다.The present invention described above is not limited to the above-described embodiments and the accompanying drawings, and various substitutions, modifications, and changes are possible in the art without departing from the technical spirit of the present invention. It will be clear to those of ordinary knowledge.
상기와 같이 이루어진 본 발명은, 패턴 밀도가 높은 고밀도 영역과 패턴 밀도가 상대적으로 낮은 저밀도 영역에서 패턴을 형성하는데 있어서, 고밀도 영역을 미리 일부분 선택적으로 식각함으로써 식각 속도의 차이로 인하여 발생하는 피팅 현상을 방지할 수 있다.According to the present invention made as described above, in forming a pattern in a high density region having a high pattern density and a low density region having a relatively low pattern density, the fitting phenomenon caused by the difference in etching speed by selectively etching part of the high density region in advance is avoided. You can prevent it.
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Cited By (2)
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KR100604535B1 (en) * | 2004-12-31 | 2006-07-24 | 동부일렉트로닉스 주식회사 | Method for improving the metal pitting |
KR100876804B1 (en) * | 2007-07-03 | 2009-01-07 | 주식회사 하이닉스반도체 | Method for manufacturing semiconductor device |
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2002
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100604535B1 (en) * | 2004-12-31 | 2006-07-24 | 동부일렉트로닉스 주식회사 | Method for improving the metal pitting |
KR100876804B1 (en) * | 2007-07-03 | 2009-01-07 | 주식회사 하이닉스반도체 | Method for manufacturing semiconductor device |
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