KR20010113710A - Method for producing a wear-resistant surface on components consisting of steel and machine with at least one component of this type - Google Patents
Method for producing a wear-resistant surface on components consisting of steel and machine with at least one component of this type Download PDFInfo
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- KR20010113710A KR20010113710A KR1020017010796A KR20017010796A KR20010113710A KR 20010113710 A KR20010113710 A KR 20010113710A KR 1020017010796 A KR1020017010796 A KR 1020017010796A KR 20017010796 A KR20017010796 A KR 20017010796A KR 20010113710 A KR20010113710 A KR 20010113710A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
- C23C26/02—Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/021—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/023—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
- C23C28/02—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
- C23C28/028—Including graded layers in composition or in physical properties, e.g. density, porosity, grain size
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
- F02F7/00—Casings, e.g. crankcases or frames
- F02F2007/0097—Casings, e.g. crankcases or frames for large diesel engines
Abstract
Description
단단한 표면을 형성하기 위해 철강으로 이루어진 부품들의 표면을 경화 처리하는 것은 이미 잘 알려져 있다. 그렇지만 경화 처리에 필요한 열처리는 비용이 많이 들 뿐만 아니라 경험도 많이 필요하다. 뿐만 아니라 여러 번에 걸친 경화 처리를 통해 얻을 수 있는 경도도 충분치 않다. 또한 표면을 경화 처리하면 경도가 대체로 작고, 플레이킹(flaking)의 위험이 크다는 단점도 있다. 따라서 공구의 수명이 대체로 짧다.It is well known to harden the surface of parts made of steel to form a hard surface. However, the heat treatment required for the curing treatment is expensive and requires much experience. In addition, the hardness obtained from several hardening treatments is not sufficient. Hardening of the surface also has the disadvantage that the hardness is generally small and the risk of flaking is high. Therefore, the tool life is generally short.
본 발명은 마모에 강한 철강 부품의 표면을 제조하기 위한 방법 및 적어도 부분적으로 마모에 강한 표면을 구비하는 철강 부품을 적어도 하나 포함하는 장치에 관한 것이다.The present invention relates to a method for producing a surface of a wear resistant steel part and to an apparatus comprising at least one steel part having a surface which is at least partially resistant to wear.
도 1은 2행정-대형 디젤 엔진의 크로스 헤드 안내부 부분도1 is a partial head cross section of a two-stroke diesel engine;
도 2는 보호용 피복을 구비한 도 1에 따른 장치의 단면을 확대한 도면2 an enlarged view of the cross section of the device according to FIG. 1 with a protective sheath;
본 발명의 목적은 이러한 문제점들로부터 출발하여 앞서 언급한 종류의 방법 및 장치를 간단하고도 저렴한 방법으로 개선하여, 마모에 강한 영역의 경도 및 두께를 크게 할 뿐만 아니라 지지(support)를 신빙성 있게 하고 또한 제조를 간단하게 하는 데 있다.The object of the present invention is to start from these problems and improve the method and apparatus of the kind mentioned above in a simple and inexpensive way, which not only increases the hardness and thickness of the area resistant to wear, but also makes the support reliable. It is also to simplify manufacturing.
본 발명의 목적은 특허청구범위의 상위의 개념에 따른 방법과 연관하여 철강에 비해 단단한 중간층(intermediative layer) 및 훨씬 더 단단한 외층(outer layer)을 형성하기 위해 철강 기본 재료(steel base material)에, 알루미늄-청동 합금으로 이루어지는 서로 겹치는 다수의 층을 용해시킴으로써 달성된다. 또한 본 발명의 목적은 상위의 개념에 따른 장치와 관련하여 마모에 강한 표면을 형성하기 위해 구비되는 보호용 피복(protective coat)이 철강 기본 재료에 용해되는 다수의, 주로 두 개의 서로 겹치는 알루미늄-청동 합금 층으로 이루어짐으로써 달성된다.The object of the present invention is to provide a steel base material to form a harder intermediate layer and a much harder outer layer compared to steel in connection with the method according to the concepts above in the claims, It is achieved by dissolving a plurality of overlapping layers of aluminum-bronze alloys. It is also an object of the present invention to provide a plurality of, mainly two, overlapping aluminum-bronze alloys in which a protective coat, which is provided for forming a wear resistant surface in connection with the device according to the above concept, is dissolved in a steel base material. Achieved by layering.
주로 용접을 통해 용해되는 알루미늄-청동 합금은 놀랍게도 외층이 내층보다 더 단단한 것으로 입증된다. 차례로 용접되는 두 층에 대한 실험에서 내층의 경도는 300HV 내지 400HV였고, 외층의 경도는 500HV 내지 600HV로 내층보다 훨씬 컸다. 따라서 철강으로 이루어지고 경도가 100HV 내지 200HV인 기본 재료에, 비교적 단단한 외층 및 외층에 비해 부드럽지만 철강에 비해서는 훨씬 더 단단한 중간층이 바람직하게 자동적으로 생겨난다. 이로써 기본 재료 및 마모에 강한 외층 사이의 경도는 한 단계가 아니라 여러 단계를 통해 균형을 이루게 된다는 점이 확실해졌다. 그 결과 바람직하게는 표면에 작용하는 평행한 전단력(shearing force) 및 표면에 수직인 항력이 기본 재료에 확실히 잘 전달된다. 이로써 바람직하게는 플레이킹의 높은 안정성이 보장된다. 그 결과 외층의 경도가 큼으로써 보장된 수명은 대단히 효과적일 수 있다. 따라서 본 발명에 따른 방안들은 바람직하게 높은 경제성을 보장해준다.Aluminum-bronze alloys, which primarily dissolve through welding, surprisingly prove that the outer layer is harder than the inner layer. In the experiments on the two layers welded in turn, the hardness of the inner layer was 300HV to 400HV and the hardness of the outer layer was 500HV to 600HV, which was much larger than the inner layer. Thus, in a base material consisting of steel and having a hardness of 100 HV to 200 HV, an intermediate layer is preferably automatically formed which is relatively hard outer layer and softer than the outer layer but much harder than steel. This ensures that the hardness between the base material and the outer layer resistant to wear is balanced in several steps, not just one. As a result, the parallel shearing force acting on the surface and the drag force perpendicular to the surface are reliably transmitted to the base material. This preferably ensures high stability of flaking. As a result, the lifetime guaranteed by the high hardness of the outer layer can be extremely effective. The measures according to the invention thus preferably ensure high economics.
바람직한 형태 및 본 발명의 목적에 맞는 상기한 방안들의 변형 형태는 청구항에 제시되어 있다. 알루미늄-청동 합금으로 이루어진 층을 용해하기 전에 각각 수용하는 재료를 우선 노(爐)에서 사전 가열하는 것은 특히 본 발명의 목적에 부합되는 것으로 입증된다. 사전 가열을 통해 내층 내지 외층의 경도값은 올라갈 수 있다. 따라서 원하는 경도를 개별적인 상황에 적합하도록 간단하게 맞출 수 있다.Preferred forms and variations of the foregoing measures suitable for the purpose of the invention are set forth in the claims. It is proved to be particularly suitable for the purpose of the present invention to preheat the respective receiving materials first in the furnace before dissolving the layer made of aluminum-bronze alloy. By preheating, the hardness value of the inner layer to the outer layer can be raised. Thus, the desired hardness can be simply adjusted to suit the individual situation.
사전 가열 온도는 350℃가 특히 선호되는 것으로 밝혀졌다. 이로써 기본 재료의 구조를 변경시키지 않고도 최대 경도값을 얻을 수 있다.The preheating temperature was found to be particularly preferred at 350 ° C. This allows a maximum hardness value to be obtained without changing the structure of the base material.
원하는 경도값을 개별적인 상황에 적합하게 할 수 있는 또 다른 가능성으로, 바람직하게는 활용 가능한 알루미늄-청동 합금 합성의 변화를 들 수 있다. 특히 큰 경도를 원할 때는 알루미늄 13% 내지 16%, 철 4% 내지 5%, 규소 0.2% 내지 0.8%, 망간 1% 내지 2%, 탄소 0.2% 이하 및 잔류 구리를 포함하는 알루미늄-청동 합금을 사용하는 것이 적합하다. 알루미늄 8% 내지 11%, 니켈 4% 내지 5%, 철 3% 내지 5%, 망간 1% 내지 2% 및 잔류 구리를 포함하는 알루미늄-청동 합금을 사용하면 경도가 비교적 작아질 수 있다. 이런 방식으로 외층 및/또는 내층의 경도는 개별적인 필요성에 맞추어질 수 있다.Another possibility of adapting the desired hardness value to the individual situation is a change in the aluminum-bronze alloy synthesis that is preferably available. Particularly, for greater hardness, aluminum-bronze alloys containing 13% to 16% aluminum, 4% to 5% iron, 0.2% to 0.8% silicon, 1% to 2% manganese, 0.2% carbon or less and residual copper are used. It is appropriate. The use of an aluminum-bronze alloy comprising 8% to 11% aluminum, 4% to 5% nickel, 3% to 5% iron, 1% to 2% manganese and residual copper can result in relatively low hardness. In this way the hardness of the outer and / or inner layers can be tailored to the individual needs.
대부분의 경우, 보호용 피복을 형성하는 전체 층이 동일한 알루미늄-청동 합금으로 이루어지는 것은 바람직하다. 이로써 보다 쉽게 제조할 수 있게 되고, 연속되는 층들 간에 특히 동질의 결합이 생겨난다.In most cases, it is preferred that the entire layer forming the protective coating consists of the same aluminum-bronze alloy. This makes it easier to manufacture and results in particularly homogeneous bonding between successive layers.
또 다른 바람직한 형태에서는 입구의 품질(input quality)을 좋게 하기 위해, 알루미늄-청동 합금으로 이루어지는 마모에 강한 외층에 마모되기 쉬운 MoS2 등으로 코팅을 할 수도 있다. 유입 단계가 진행되는 동안 저절로 사라지는 이 입구층(input layer) 때문에, 알루미늄-청동 합금으로 이루어진 외층에 의해 형성된 단단한 지지층(support layer)은 유입 시간이 어느 정도 흐른 후 비로소 노출되고 효력을 발휘한다. 이것은 수명 연장에 바람직한 영향을 미친다.In another preferred form, in order to improve the input quality, the coating may be coated with MoS2 or the like which is liable to wear on an outer layer made of aluminum-bronze alloy. Because of this input layer, which disappears by itself during the inflow phase, the rigid support layer formed by the outer layer of aluminum-bronze alloy is exposed and effective only after some inflow time. This has a desirable effect on life extension.
기타 바람직한 실시형태 및 상기한 방안들의 적절한 변형 형태는 나머지 종속항에 제시되어 있고, 하기의 실시예에서 도면을 참조하여 보다 상세히 설명된다.Other preferred embodiments and suitable variations of the foregoing solutions are set forth in the remaining dependent claims and are explained in more detail with reference to the drawings in the following examples.
본 발명은 철강 부품의 표면에 철강의 경도가 100HV 내지 200HV를 넘는 보호용 피복이 필요한 경우 어디에나 적용될 수 있다. 이것은 예를 들어 피스톤 링(piston ring), 크로스 헤드 안내부처럼 고부하의 베어링면(bearing face)을 구비하는 상이한 엔진 부품들의 경우에 적합하다. 기본 재료에 비해 단단한 보호용 피복을 이용하여, 마모 속도를 줄이고 또 수명을 늘릴 수 있다. 따라서 부하를 받는 표면의 경도가 가능한 한 크고 기본 재료와의 결합은 가능한 한 좋아진다.The present invention can be applied wherever the protective coating on the surface of the steel component requires a hardness of more than 100HV to 200HV. This is suitable for the case of different engine parts with high load bearing faces, for example piston rings, cross head guides. By using a hard protective coating compared to the base material, the wear rate can be reduced and the service life can be extended. Therefore, the hardness of the surface under load is as large as possible and the bonding with the base material is as good as possible.
도 1의 2행정-대형 디젤 엔진의 프레임(frame) 단면은 크로스 헤드(1)의 양 측면에 있는 스탠드 벽(standing wall; 2)을 포함한다. 크로스 헤드(1)에 있는 측면 안내 블록(guide shoe; 3)의 단부에는 서로 대향된 베어링면을 구비하는안내판(guide plate; 4)이 제공된다. 안내판은 서로 향한 베어링면을 구비하고 스탠드 측에 제공되는 안내 레일(guide rail; 5) 상에서 움직인다.The frame cross section of the two-stroke diesel engine of FIG. 1 includes a standing wall 2 on both sides of the cross head 1. At the end of the side guide block 3 in the cross head 1 is provided a guide plate 4 with bearing surfaces facing each other. The guide plate has bearing surfaces facing each other and moves on a guide rail 5 provided on the stand side.
안내판(4) 및 안내 레일(5)은 표준 철강을 기본 재료로 하여 구성되고, 철강보다 경도가 커서 수명이 확실히 긴 보호용 피복(6)을 서로 마주보는 베어링면 영역에 구비한다. 예를 들어 베어링 부시(bearing bush)나 피스톤 링처럼 부하를 비슷하게 받는 다른 철강 부품들의 경우에도 물론 이와 같은 보호용 피복을 구비할 수 있다.The guide plate 4 and the guide rail 5 are made of standard steel as a base material, and are provided in the bearing surface area | region which mutually faces the protective sheath 6 which is larger in hardness and has a longer life. Such protective sheaths can of course also be applied to other steel parts under similar load, for example bearing bushes or piston rings.
보호용 피복(6)은 알루미늄-청동 합금으로 이루어지고, 도 2에서 잘 볼 수 있듯이 본 발명의 목적에 부합되게 철강 기본 재료(7)에 차례로 용접을 통해 용해되고 서로 겹치게 되는 두 개의 층(8, 9)으로 제조된다. 철강의 경도는 대체로 100HV 내지 200HV이다. 알루미늄-청동 합금의 경도 크기는 대체로 200HV이다. 철강으로 이루어지는 기본 재료(7)에 먼저 용접되는 내층(8)은 놀랍게도 이미 약 300HV 내지 400HV의 경도를 갖는다. 두 번째 층인 외층(9)의 경도는 놀랍게도 약 500HV 내지 600HV로 훨씬 크다. 따라서 외층(9)은 구동에 무리가 갈 때에도 긴 수명을 확실히 보장하는 마모에 강한 지지층으로 특히 적합하다.The protective sheath 6 is made of an aluminum-bronze alloy and, as can be seen in FIG. 2, two layers 8, which are in turn melted and overlapped with each other by welding to the steel base material 7 in accordance with the object of the invention. 9) is manufactured. The hardness of the steel is generally from 100 HV to 200 HV. The hardness size of the aluminum-bronze alloy is generally 200 HV. The inner layer 8 which is first welded to the base material 7 made of steel surprisingly already has a hardness of about 300 HV to 400 HV. The hardness of the second layer, the outer layer 9, is surprisingly much higher, from about 500 HV to 600 HV. The outer layer 9 is therefore particularly suitable as a wear resistant support layer which ensures a long life even when driving is difficult.
우선 일정한 유입 단계를 거친 후 매우 단단한 지지층이 효력을 발휘한다면, 이는 대단히 바람직하다고 할 수 있다. 이러한 경우 외층(9)에 코팅되는 입구층(10)은 예를 들어 MoS2처럼 비교적 마모되기 쉬운 재료로 이루어지고 유입 단계가 진행되는 동안 저절로 사라지므로, 이에 이어서 알루미늄-청동 합금으로 이루어지고 경도가 큰 외층(9)이 도 2 우측에 도시된 것처럼 지지하기 위해 나타난다.If a very solid support layer is in effect after first going through a certain inflow step, this is highly desirable. In this case, the inlet layer 10 coated on the outer layer 9 is made of a relatively brittle material, for example MoS 2 , and disappears spontaneously during the inflow step, which is then made of an aluminum-bronze alloy and the hardness of A large outer layer 9 is shown for supporting as shown in the right side of FIG. 2.
비교적 경도가 작은 내층(8)은 실제로 대단히 단단한 외층(9) 및 외층에 비해 비교적 부드러운 기본 재료(7) 사이를 연결하는 보통 경도의 연결층(bonding layer)으로 쓰인다. 이로써 외층(9) 및 기본 재료(7) 사이의 경도는 단계적으로 균형을 이루게 된다. 이와 동시에 내층(8)은 경도가 비교적 작기 때문에 점성(viscocity) 및 충격 강도(impact strength)가 높아진다. 그 결과 표면에 평행한 전단력 및 표면에 수직인 항력(화살표(11, 12)로 도시됨)을 잘 흡수하여 기본 재료(7)에 전달할 수 있다. 도시된 예에서 차례로 용접되는 층(8, 9)은 두께가 같다. 두 층(8, 9)의 두께는 물론 다르거나 상이할 수 있다. 도시된 예에서 차례로 용접되는 두 개의 층(8, 9)을 갖는 실시 형태가 특히 선호된다고 해도, 두 층 이상을 차례로 용접하는 것도 마찬가지로 생각해볼 수 있다.The relatively low hardness inner layer 8 is actually used as a bonding layer of moderate hardness that connects between the very hard outer layer 9 and the base material 7 which is relatively soft compared to the outer layer. This ensures that the hardness between the outer layer 9 and the base material 7 is balanced in stages. At the same time, the inner layer 8 has a relatively small hardness, resulting in high viscosity and impact strength. As a result, the shear force parallel to the surface and the drag force (shown by arrows 11 and 12) perpendicular to the surface can be absorbed well and transferred to the base material 7. In the example shown, the layers 8, 9 to be welded in turn are of the same thickness. The thickness of the two layers 8, 9 can of course be different or different. Although the embodiment with two layers 8, 9 welded in turn in the example shown is particularly preferred, welding two or more layers in turn is likewise conceivable.
두 층(8, 9)을 제조할 때, 알루미늄 8% 내지 25%, 각각 0.2% 내지 10%의 스티븀(Sb), 코발트(Co), 베릴륨(Be), 크롬(Cr), 주석(Sn), 망간(Mn), 규소(Si), 카드뮴(Cd), 아연(Zn), 철(Fe), 니켈(Ni), 납(Pb) 및 탄소(C) 중 적어도 하나 및 잔류 구리를 포함하는 알루미늄-청동 합금을 사용하는 것은 바람직하다. 내층 및/또는 외층(8, 9)이 특히 큰 경도값을 갖기를 원한다면, 알루미늄 13% 내지 16%, 철 4% 내지 5%, 규소 0.2% 내지 0.8%, 망간 1% 내지 2%, 탄소 0.2% 이하 및 잔류 구리를 포함하는 알루미늄-청동 합금을 사용하는 것이 바람직하다. 내층 및/또는 외층(8, 9)의 경도가 약간 작기를 원한다면, 알루미늄 8% 내지 11%, 니켈 4% 내지 6%, 철 3% 내지 5%, 망간 1% 내지 2% 및 잔류 구리를 포함하는 알루미늄-청동 합금을 사용할 수 있다. 경도의 크기 따라 내층 또는 외층(8, 9)에 경도값이 크거나 작은 알루미늄-청동 합금을 사용할 수 있다. 그렇지만 두 층(8, 9)에 같은 알루미늄-청동 합금을 사용하는 것은 대체로 바람직하다.When producing the two layers 8 and 9, 8% to 25% of aluminum, 0.2% to 10% of each of styrene (Sb), cobalt (Co), beryllium (Be), chromium (Cr) and tin (Sn) ), At least one of manganese (Mn), silicon (Si), cadmium (Cd), zinc (Zn), iron (Fe), nickel (Ni), lead (Pb) and carbon (C) and residual copper Preference is given to using aluminum-bronze alloys. If the inner and / or outer layers 8, 9 are to have particularly high hardness values, aluminum 13% to 16%, iron 4% to 5%, silicon 0.2% to 0.8%, manganese 1% to 2%, carbon 0.2 Preference is given to using aluminum-bronze alloys comprising up to% and residual copper. If the hardness of the inner and / or outer layers 8, 9 is slightly small, it comprises 8% to 11% aluminum, 4% to 6% nickel, 3% to 5% iron, 1% to 2% manganese and residual copper. An aluminum-bronze alloy can be used. Depending on the size of the hardness, an aluminum-bronze alloy having a large or small hardness value may be used for the inner or outer layers 8 and 9. However, it is generally desirable to use the same aluminum-bronze alloy in both layers 8, 9.
앞서 언급했듯이, 두 층(8, 9)은 용접 공정으로 코팅될 수 있다. 이 경우 전기 아크(electro arc) 또는 레이저 광선 또는 화염(flame)이 사용될 수 있다.As mentioned above, the two layers 8, 9 can be coated by a welding process. In this case, an electric arc or laser beam or flame may be used.
원하는만큼 경도를 높이기 위해서는 매번 알루미늄 층을 용착시키기 전에 수용하는 부품을 사전 가열할 수 있다. 즉 내층(8)을 용착시키기 전에 기본 재료를 사전 가열하고, 외층(9)을 용착시키기 전에 코팅된 중간 제품을 사전 가열할 수 있다. 사전 가열은 노에서 하는 것이 바람직하다. 이때 사전 가열 온도는 약 350℃가 특히 바람직하다고 밝혀졌다.To increase the hardness as desired, the receiving parts can be preheated before each aluminum layer is deposited. That is, the base material can be preheated before the inner layer 8 is welded, and the coated intermediate product can be preheated before the outer layer 9 is welded. Preheating is preferably done in the furnace. It was found that the preheating temperature at this time is about 350 ° C. being particularly preferred.
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DE19908107.7 | 1999-02-25 | ||
DE19908107A DE19908107C2 (en) | 1999-02-25 | 1999-02-25 | Method for producing a wear-resistant surface in the case of components made of steel and machine with at least one such component |
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JP (1) | JP3859970B2 (en) |
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DE (2) | DE19908107C2 (en) |
ES (1) | ES2182792T3 (en) |
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- 2000-02-11 KR KR10-2001-7010796A patent/KR100440426B1/en active IP Right Grant
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KR20200047179A (en) * | 2018-10-26 | 2020-05-07 | 제주대학교 산학협력단 | Piezoelectric Nano Generator, Optical Sensor Comprising of the same, and Preparation method of Piezoelectric Nano Generator |
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NO20013876L (en) | 2001-10-18 |
KR100440426B1 (en) | 2004-07-14 |
PL192821B1 (en) | 2006-12-29 |
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PL349466A1 (en) | 2002-07-29 |
WO2000050660A1 (en) | 2000-08-31 |
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CN1341157A (en) | 2002-03-20 |
NO20013876D0 (en) | 2001-08-08 |
DE50000452D1 (en) | 2002-10-10 |
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DE19908107C2 (en) | 2003-04-10 |
AU3280100A (en) | 2000-09-14 |
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