JP2002538016A - Method for forming a wear-resistant surface on a steel part and an apparatus comprising at least one such part - Google Patents

Method for forming a wear-resistant surface on a steel part and an apparatus comprising at least one such part

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Publication number
JP2002538016A
JP2002538016A JP2000601221A JP2000601221A JP2002538016A JP 2002538016 A JP2002538016 A JP 2002538016A JP 2000601221 A JP2000601221 A JP 2000601221A JP 2000601221 A JP2000601221 A JP 2000601221A JP 2002538016 A JP2002538016 A JP 2002538016A
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JP
Japan
Prior art keywords
layer
steel
forming
aluminum bronze
hardness
Prior art date
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Granted
Application number
JP2000601221A
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Japanese (ja)
Other versions
JP3859970B2 (en
Inventor
レック・モクズルスキー
アーリング・ブレダル・アンデルセン
Original Assignee
エムエーエヌ・ビー・アンド・ダブリュ・ディーゼル・エーエス
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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • C23C26/02Coating not provided for in groups C23C2/00 - C23C24/00 applying molten material to the substrate
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/021Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material including at least one metal alloy layer
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/023Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material only coatings of metal elements only
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/02Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D only coatings only including layers of metallic material
    • C23C28/028Including graded layers in composition or in physical properties, e.g. density, porosity, grain size
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02FCYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F7/00Casings, e.g. crankcases or frames
    • F02F2007/0097Casings, e.g. crankcases or frames for large diesel engines

Abstract

According to the invention, components consisting of steel are provided with a protective coat (6) with an intermediate layer which is harder than steel and a still harder outer layer by successively melting superposed layers (8, 9) consisting of aluminium-bronze onto the steel base material (7).

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】TECHNICAL FIELD OF THE INVENTION

本発明は、発明の第一の概念によれば、鋼製の部材に耐摩耗性を有する表面を
設ける方法に関し、さらなる発明の概念によれば、少なくとも部分的に耐摩耗性
を有する表面が設けられた鋼製の部材を少なくとも1つ有して成る装置に関する
The invention relates, according to a first aspect of the invention, to a method for providing a wear-resistant surface on a steel part, and according to a further inventive concept, to provide an at least partially wear-resistant surface. Device comprising at least one steel member provided.

【0002】[0002]

【従来の技術】[Prior art]

固い表面を形成するために鋼製の部材の表面側を硬化させることは周知である
が、表面を硬化させるには手間のかかる熱処理が必要であり、これには熟練が要
求される。しかもこのような処理によって実現可能な硬度はおよそ十分とは言い
難い。さらなる不利点は、表面側を硬化させる場合には比較的小さな深度でしか
硬化が実現できず、剥離する恐れが大きく、従って比較的短い寿命しか得られな
いということである。
It is well known to harden the surface side of a steel member to form a hard surface, but hardening the surface requires a lengthy heat treatment, which requires skill. Moreover, the hardness achievable by such a treatment is hardly sufficient. A further disadvantage is that when hardening the front side, hardening can only be achieved at a relatively small depth, there is a high risk of delamination and therefore a relatively short life.

【0003】[0003]

【発明が解決しようとする課題】[Problems to be solved by the invention]

上記の点から本発明の課題は上記のような類の方法および装置を容易かつ廉価
な手段を用いて改良し、耐摩耗性を有する領域の硬度と厚みを大きくするととも
に、確実に固着させ、容易に製造できるものとすることである。
In view of the above, the object of the present invention is to improve methods and apparatuses of the kind described above by means of easy and inexpensive means, to increase the hardness and thickness of the wear-resistant area, and to firmly secure them, It should be easy to manufacture.

【0004】[0004]

【課題を解決するための手段】[Means for Solving the Problems]

前記の課題は本発明に係る方法により、鋼製の母材に鋼よりも硬い中間層およ
びさらに硬い外部層が形成されるように、アルミニウム青銅から成る複数の層形
成体を順次、上下に重なるように溶着させることによって解決され、また、本発
明に関する装置により、耐摩耗性を有する表面を形成するために、保護コーティ
ングが設けられていることによって解決される。この保護コーティングは、鋼製
の母材にアルミニウム青銅から成る複数の、好適には2つの層形成体を上下に重
なるように溶着させて形成されている。
According to the method of the present invention, a plurality of layer forming bodies made of aluminum bronze are sequentially stacked on the steel base material such that an intermediate layer harder than steel and an outer layer harder than the steel are formed by the method according to the present invention. And by means of the device according to the invention that a protective coating is provided in order to form a wear-resistant surface. This protective coating is formed by welding a plurality of, preferably two, layer formers of aluminum bronze onto a steel base material, one above the other.

【0005】 アルミニウム青銅はうまい具合に溶接によって溶着され、驚くべきことに、こ
の溶着されたアルミニウム青銅の外側の層形成体の方が、内側の層形成体よりも
硬いことが明らかにされている。2つの層形成体を上下に重なるように溶接させ
たものを用いて行った実験では、内側の層形成体で300〜400HVの硬度が
得られたのに対して、外側の層形成体では500〜600HVというはるかに大
きな硬度が得られた。このような結果から自ずと比較的硬い外部層と、外部層よ
りは柔らかいが、硬度が100〜200HVである鋼製の母材に対して、鋼より
も依然として硬い中間層とがうまく形成されることになる。従って母材と耐摩耗
性を有する外部層との硬度の差は一度にではなく、何段階かを経て解消されるこ
とが確実となり、表面に平行に働く剪断力、および、表面に垂直に働く横力は、
上手い具合に確実に母材に伝達される。これにより剥離防止に対する信頼性が高
まり、外部層の硬度が大きいことによって保証される寿命の長さが十分活かされ
る結果となる。すなわち、本発明による手段により、好適に全体的な経済効率が
確実に高くなる。
[0005] Aluminum bronze is successfully welded, and it has surprisingly been found that the outer layer former of the deposited aluminum bronze is harder than the inner layer former. . In an experiment performed using two layer-formed bodies welded so as to overlap one another, a hardness of 300 to 400 HV was obtained with the inner layer-formed body, whereas a hardness of 500 HV was obtained with the outer layer-formed body. A much higher hardness of ~ 600 HV was obtained. From these results, a relatively hard outer layer and an intermediate layer that is softer than the outer layer but still harder than the steel are formed successfully on a steel base material having a hardness of 100 to 200 HV. become. Therefore, it is ensured that the difference in hardness between the base material and the outer layer having abrasion resistance is eliminated not at once but through several stages, and the shear force acting parallel to the surface and acting perpendicular to the surface Lateral force is
Properly and reliably transmitted to the base material. As a result, the reliability with respect to the prevention of peeling is increased, and the long life assured by the high hardness of the outer layer is fully utilized. In other words, the measures according to the invention ensure a favorable overall economic efficiency.

【0006】 上位の請求項に記載の手段の好適な形態や目的に適ったさらなる発展態様は下
位請求項に記載されている。特に好適である形態は、アルミニウム青銅から成る
層形成体を溶着させる前に、その都度、目下の被溶接材料を炉で予熱するもので
ある。予熱することにより、下側または上側の層形成体の硬度は増大する。この
ようにして所望の硬度を個々の場合の条件に合わせて個別に適応させるための簡
単な方法が可能となる。
[0006] Preferred embodiments and further developments suitable for the purpose of the measures recited in the dependent claims are described in the dependent claims. A particularly preferred embodiment is to preheat the material to be welded in the furnace each time before depositing the layer former made of aluminum bronze. Preheating increases the hardness of the lower or upper layer former. In this way, a simple method for individually adapting the desired hardness to the conditions of the individual case is possible.

【0007】 特に好適であるのは予熱の温度が350℃である場合であった。この場合、母
材の構造を変えることなく最適な硬度が得られる。
[0007] Particularly preferred was the case where the preheating temperature was 350 ° C. In this case, optimum hardness can be obtained without changing the structure of the base material.

【0008】 実現可能な硬度を個々の場合の条件に適合させるさらなる方法は、使用される
アルミニウム青銅の組成を好適に変化させるものである。特に大きな硬度を実現
しなければならない場合は、13%〜16%のAl、4%〜5%のFe、0.2%〜
0.8%のSi、1%〜2%のMn、最大で0.2%のC、残りの成分としてCuを含
むアルミニウム青銅が好適に用いられる。8%〜11%のAl、4%〜6%のNi、
3%〜5%のFe、1%〜2%のMn、そして、残りの成分としてCuを含むアルミニ
ウム青銅を使用すると、硬度はより小さくなる。このようにして外側の層形成体
、及び/又は下側の層形成体の硬度を個々の場合の要求に適合させることができ
る。
A further way of adapting the achievable hardness to the requirements of the individual case is to suitably change the composition of the aluminum bronze used. When a particularly large hardness has to be realized, 13% to 16% of Al, 4% to 5% of Fe, 0.2% to
Aluminum bronze containing 0.8% Si, 1% to 2% Mn, up to 0.2% C, and Cu as the remaining component is preferably used. 8% to 11% Al, 4% to 6% Ni,
Using aluminum bronze containing 3% to 5% Fe, 1% to 2% Mn, and Cu as the remaining component results in lower hardness. In this way, the hardness of the outer layer former and / or the lower layer former can be adapted to the individual requirements.

【0009】 大抵の場合は、保護コーティングを形成する全ての層形成体が同一のアルミニ
ウム青銅から成るのが望ましい。このように形成すると製造が容易となり、上下
に重ねて設けられた層形成体と層形成体の間の一様な接合が得られる。
[0009] In most cases, it is desirable that all layer formers forming the protective coating consist of the same aluminum bronze. When formed in this manner, manufacturing becomes easy, and uniform bonding between layer-formed bodies provided one above the other is obtained.

【0010】 さらなる好適な手段として、慣らし運転時の特性を良好にするために、外側の
、アルミニウム青銅から成る耐摩耗性を有する層形成体に、MoS2などから成る迅
速に摩耗する被覆層を設けてもよい。このような慣らし運転層は慣らし運転段階
で自ずから消失するものであるが、それによって、アルミニウム青銅から成る外
側の硬い耐久層が確実に一定の慣らし運転時間をおいてから露出され、効果を発
揮することになり、長い寿命を実現する上で有利な効果を及ぼす。
As a further preferred measure, in order to obtain good running-in properties, the outer, wear-resistant layer-former made of aluminum bronze is provided with a rapidly wearable coating, such as MoS 2. It may be provided. Such a running-in layer is one that disappears by itself during the running-in phase, thereby ensuring that the outer hard durable layer made of aluminum bronze is exposed after a certain running-in time and is effective. This has an advantageous effect in achieving a long life.

【0011】[0011]

【発明の実施の形態】BEST MODE FOR CARRYING OUT THE INVENTION

上位の請求項に記載された手段のさらなる有効な形態および目的に適った発展
態様は、残りの従属請求項に記載され、以下に説明する実施の形態において図面
に基づいて詳細に記載される。
Further advantageous embodiments and expedient developments of the measures described in the dependent claims are set out in the remaining dependent claims and in the embodiments described below in detail with reference to the drawings.

【0012】 本発明は、鋼から成る構成部材が、その表面に、硬度が100〜200HVの
鋼の硬さを上回るような硬さを有する保護コーティングを必要とする場所であれ
ば、どんな所にも応用できる。そのような例としてピストンリング、クロスヘッ
ドガイドなど、大きな負荷を受ける走行面を有するエンジンの種々の構成部材が
挙げられる。母材よりも硬い保護コーティングを用いることにより、摩耗の速度
を減少させて寿命を増大させる必要がある。そのため、負荷を受ける表面の硬度
をできるだけ大きくするとともに、母材との接着をできるだけ良好に行うことが
求められる。
The present invention is directed to any location where a component made of steel requires a protective coating on its surface that has a hardness greater than that of steel having a hardness of 100 to 200 HV. Can also be applied. Examples of such components include various components of an engine having a running surface that receives a large load, such as a piston ring and a crosshead guide. By using a protective coating that is harder than the parent material, there is a need to reduce the rate of wear and increase life. Therefore, it is required that the hardness of the surface receiving the load be as large as possible and that the adhesion with the base material be performed as well as possible.

【0013】 図1に示す2サイクル大型ディーゼルエンジンのフレームの部分図には、クロ
スヘッド1の側面に設けられた2つの支持壁2が示されている。クロスヘッド1
の側方には、ガイドシュー3が設けられ、ガイドシュー3の両端部には、互いに
背反する支持面を有するガイド板4が設けられている。ガイド板4は、フレーム
側に設けられていて、互いに対向する走行面を有するガイドレール5上を動く。
FIG. 1 is a partial view of a frame of a two-cycle large diesel engine, showing two support walls 2 provided on a side surface of a crosshead 1. Crosshead 1
A guide shoe 3 is provided on a side of the guide shoe 3, and guide plates 4 having support surfaces that are opposed to each other are provided on both ends of the guide shoe 3. The guide plate 4 is provided on the frame side and moves on a guide rail 5 having running surfaces facing each other.

【0014】 ガイド板4およびガイドレール5は母材として通常の鋼から成り、これらの部
材の対向的に設けられた走行面の領域に、保護コーティング6が設けられている
。保護コーティングは鋼よりも大きな硬度を有するので、寿命は確実に長くなる
。軸受ブシュ、ピストンリングなど、同様の負荷を常時受けるその他の鋼から成
る部材にも当然、このような保護コーティングを設けることができる。
The guide plate 4 and the guide rail 5 are made of normal steel as a base material, and a protective coating 6 is provided in the region of the running surface of these members opposed to each other. Since the protective coating has a higher hardness than steel, the service life is definitely longer. Of course, other steel components, such as bearing bushings and piston rings, which are always subjected to similar loads, can also be provided with such a protective coating.

【0015】 保護コーティング6は、アルミニウム青銅から成り、図2が明瞭に示す通り、
鋼から成る母材7に順次、望ましくは溶接によって溶着され、上下に重ねて設け
られた2つの層形成体8,9から形成される。鋼の硬度は通常100〜200H
Vであり、アルミニウム青銅の硬度は通常200HVの値を取る。鋼からなる母
材7に最初に溶接される下側の層形成体8は、驚くべきことにすでにおよそ30
0〜400HVの硬度を有している。2番目の外側の層形成体9では、驚いたこ
とにこれよりはるかに大きな500〜600HVの硬度が得られる。このことか
ら外側の層形成体9は、耐摩耗性を有する耐久層として特に好適であり、このよ
うな耐久層は運転条件が過酷な場合でも確実に長い寿命を実現する。
The protective coating 6 is made of aluminum bronze, and FIG.
It is formed by two layer formers 8, 9 which are successively welded, preferably by welding, to a base material 7 made of steel and which are provided one above the other. Steel hardness is usually 100-200H
V, and the hardness of aluminum bronze usually takes a value of 200 HV. The lower layer former 8, which is first welded to the steel matrix 7, is surprisingly already approximately 30
It has a hardness of 0 to 400 HV. The second outer layer former 9 surprisingly achieves a much higher hardness of 500-600 HV. For this reason, the outer layer forming body 9 is particularly suitable as a durable layer having abrasion resistance, and such a durable layer surely achieves a long life even under severe operating conditions.

【0016】 一定の慣らし運転段階を経てから、初めて非常に硬い耐久層が効果を発揮する
ならば非常に好適である。このような場合には、外側の層形成体9に比較的速く
摩耗するMoS2などの材料から成る慣らし運転層10を設けることができる。慣ら
し運転層は、慣らし運転段階の間に自ずから消失するため、図2の右方に示す通
り、アルミニウム青銅から成り、大きな硬度を有する外側の層形成体9が続いて
使用に供される。
It is very advantageous if a very hard, durable layer is only effective after a certain running-in phase. In such a case, the outer layer former 9 can be provided with a run-in layer 10 made of a material such as MoS 2 which wears relatively quickly. Since the running-in layer naturally disappears during the running-in phase, as shown on the right in FIG. 2, an outer layer former 9 made of aluminum bronze and having a high hardness is subsequently ready for use.

【0017】 小さい方の硬度を有する下側の層形成体8は実際には非常に硬い外側の層形成
体9とこれに対して比較的柔らかい母材7とをつなぐ中等度の硬さの結合層の働
きをしている。これによって外側の層形成体9と母材7との間で硬度が段階的に
調整されるとともに、内側の層形成体8は硬度がより小さいために靱性および衝
撃強さはより大きくなるので、矢印11,12によって示されるように表面に平
行に働く剪断力と表面に垂直に働く横力が上手く受け止められて母材7に伝達さ
れる。図に示す実施形態では、上下に重ねて溶接された層形成体8,9の厚みは
等しい。これらの層形成体の厚みはおよそ1.5mmとすることができる。これ
以外の厚みにすることも、層形成体8,9の厚みを異なるものにすることも当然
可能である。本実施形態に係る上下に重ねて溶接された2つの層形成体8,9を
有する構成が特に好適であることが明らかであるとはいえ、2つ以上の層形成体
を上下に重ねて溶接することも考えることができよう。
The lower layer former 8 having the lower hardness is in fact a medium hardness bond connecting the very hard outer layer former 9 to the relatively soft matrix 7. It works as a layer. As a result, the hardness between the outer layer-forming body 9 and the base material 7 is adjusted stepwise, and the inner layer-forming body 8 has a lower hardness, so that the toughness and the impact strength are higher. The shear forces acting parallel to the surface and the lateral forces acting perpendicular to the surface, as indicated by arrows 11 and 12, are successfully received and transmitted to the base material 7. In the embodiment shown in the figures, the thicknesses of the layer formers 8, 9 which are welded one above the other are equal. The thickness of these layered bodies can be about 1.5 mm. Naturally, it is also possible to make the thickness different from this, or to make the thickness of the layer forming bodies 8 and 9 different. Although it is apparent that the configuration having two layer forming bodies 8 and 9 welded one above the other according to the present embodiment is particularly suitable, two or more layer forming bodies are welded one above the other. You can also think about

【0018】 層形成体8,9の製造には8%〜25%のAl、ならびに、Sb, Co, Be, Cr, Sn
, Mn, Si, Cd, Zn, Fe, Ni, Pb およびCのうち少なくとも1つの成分をそれぞれ
0.2%〜10%、および残りの成分としてCuを含むアルミニウム青銅が好適に
使用される。一方、及び/又は、他方の層形成体8,9が特に大きな硬度を有す
ることが望まれる場合は、13%〜16%のAlと、4%〜5%のFe、0.2%〜
0.8%のSi、1%〜2%のMn、最大でも0.2%のC、残りの成分としてCuを
含むアルミニウム青銅が好適に使用される。一方、及び/又は、他方の層形成体
8,9がやや小さ目の硬度を有することが望まれる場合は8%〜11%のAl、4
%〜6%のNi、3%〜5%のFe、1%〜2%のMn、残りの成分としてCuを含むア
ルミニウム青銅が使用される。個々の場合に応じてそれぞれの層形成体8,9に
対し、それぞれ好適なアルミニウム青銅を使用すればよいが、通常は2つの層形
成体8,9に対して同一のアルミニウム青銅を使用するのが好適である。
For the production of the layer formers 8, 9, 8% to 25% of Al and Sb, Co, Be, Cr, Sn
, Mn, Si, Cd, Zn, Fe, Ni, Pb and aluminum bronze containing 0.2% to 10% each of C and Cu as the remaining component are preferably used. If it is desired that one and / or the other layer formers 8, 9 have a particularly high hardness, 13% to 16% Al, 4% to 5% Fe, 0.2% to
Aluminum bronze containing 0.8% Si, 1% to 2% Mn, at most 0.2% C, and the remaining component Cu is preferably used. When it is desired that one and / or the other layer forming bodies 8 and 9 have a slightly lower hardness, 8% to 11% of Al,
% Bronze containing 6% Ni, 3% to 5% Fe, 1% to 2% Mn, and Cu as the remaining component. Depending on the individual case, a suitable aluminum bronze may be used for each of the layer formers 8, 9, but usually the same aluminum bronze is used for the two layer formers 8, 9. Is preferred.

【0019】 層形成体8,9は、上述したように、溶接工程を通じて母材上にもたらされう
るものである。溶接の際にはアーク放電、またはレーザー光線、またはガス焔が
用いられる。
As described above, the layer forming bodies 8 and 9 can be provided on the base material through the welding process. Arc welding, laser beam, or gas flame is used for welding.

【0020】 実現可能な硬度を増大させるために、アルミニウム層を設ける前に、その都度
、目下の被溶接部材を予熱してもよい。すなわち、下側の層形成体8を設ける前
に母材7を、また、2番目の層形成体9を設ける前に、このように被覆された中
間生成品を予熱してもよい。予熱は好ましくは炉で行われ、およそ350℃の予
熱温度が特に好適であることが判明している。
In order to increase the achievable hardness, the current workpiece may be preheated before each application of the aluminum layer. That is, the base material 7 may be preheated before the lower layer forming body 8 is provided, and the intermediate product thus coated may be preheated before the second layer forming body 9 is provided. The preheating is preferably carried out in a furnace, a preheating temperature of around 350 ° C. has proven to be particularly suitable.

【図面の簡単な説明】[Brief description of the drawings]

【図1】2サイクル大型ディーゼルエンジンのクロスヘッドガイドの一部を
示す図である。
FIG. 1 is a view showing a part of a crosshead guide of a two-cycle large diesel engine.

【図2】図1の保護コーティングが施された部分を拡大して示す図である。FIG. 2 is an enlarged view showing a portion provided with a protective coating of FIG. 1;

【符号の説明】[Explanation of symbols]

6・・・保護コーティング 7・・・母材 8・・・層形成体(中間層を形成する層形成体) 9・・・層形成体(外部層を形成する層形成体) 10・・・慣らし運転層 6 Protective coating 7 Base material 8 Layer-forming body (layer-forming body forming intermediate layer) 9 Layer-forming body (layer-forming body forming outer layer) 10 Break-in operation layer

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C23C 28/02 C23C 28/02 F02F 5/00 F02F 5/00 F // F16C 33/12 F16C 33/12 Z (81)指定国 EP(AT,BE,CH,CY, DE,DK,ES,FI,FR,GB,GR,IE,I T,LU,MC,NL,PT,SE),OA(BF,BJ ,CF,CG,CI,CM,GA,GN,GW,ML, MR,NE,SN,TD,TG),AP(GH,GM,K E,LS,MW,SD,SL,SZ,TZ,UG,ZW ),EA(AM,AZ,BY,KG,KZ,MD,RU, TJ,TM),AE,AL,AM,AT,AU,AZ, BA,BB,BG,BR,BY,CA,CH,CN,C R,CU,CZ,DE,DK,DM,EE,ES,FI ,GB,GD,GE,GH,GM,HR,HU,ID, IL,IN,IS,JP,KE,KG,KP,KR,K Z,LC,LK,LR,LS,LT,LU,LV,MA ,MD,MG,MK,MN,MW,MX,NO,NZ, PL,PT,RO,RU,SD,SE,SG,SI,S K,SL,TJ,TM,TR,TT,TZ,UA,UG ,US,UZ,VN,YU,ZA,ZW Fターム(参考) 3J011 CA05 QA02 QA03 SB03 SB04 SB05 4E001 AA03 CA07 DC09 DG03 4F100 AB02B AB02C AB03A AB09B AB09C AB10B AB10C AB11B AB11C AB13B AB13C AB14B AB14C AB15B AB15C AB16B AB16C AB17B AB17C AB18B AB18C AB21B AB21C AB22B AB22C AB23B AB23C AB31B AB31C AR00D BA03 BA04 BA07 BA10A BA10C EC032 EJ421 JK16B JK16C JK16D YY00B YY00C 4K031 AA02 AB03 AB06 AB08 BA07 CB35 EA10 EA11 4K044 AA02 BA06 BA10 BB03 BC01 CA02 CA11 ──────────────────────────────────────────────────の Continued on the front page (51) Int.Cl. 7 Identification symbol FI theme coat ゛ (Reference) C23C 28/02 C23C 28/02 F02F 5/00 F02F 5/00 F // F16C 33/12 F16C 33/12 Z (81) Designated countries EP (AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE), OA (BF, BJ, CF, CG, CI, CM, GA, GN, GW, ML, MR, NE, SN, TD, TG), AP (GH, GM, KE, LS, MW, SD, SL, SZ, TZ, UG, ZW), EA (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), AE, AL, AM, AT, AU, AZ, BA, BB, BG, BR, BY, CA, CH, CN, CR, CU, CZ, DE, DK, DM, EE, ES, FI, GB, GD, GE, GH, GM, HR, HU, ID, IL, IN, IS, JP , KE, KG, KP, KR, KZ, LC, LK, LR, LS, LT, LU, LV, MA, MD, MG, MK, MN, MW, MX, NO, NZ, PL, PT, RO, RU, SD, SE, SG, SI, SK, SL, TJ, TM, TR, TT, TZ, UA, UG, US, UZ, VN, YU, ZA, ZWF term (reference) 3J011 CA05 QA02 QA03 SB03 SB04 SB05 4E001 AA03 CA07 DC09 DG03 4F100 AB02B AB02C AB03A AB09B AB09C AB10B AB10C AB11B AB11C AB13B AB13C AB14B AB14C AB15B AB15C AB16B AB16C AB17B Y17C AB18B AB18C AB21B AB21C BA22B AB23ABAB12A 4K031 AA02 AB03 AB06 AB08 BA07 CB 35 EA10 EA11 4K044 AA02 BA06 BA10 BB03 BC01 CA02 CA11

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 鋼から成る部材に耐摩耗性を有する表面を設けるための方法
であって、 鋼から成る母材(7)に、鋼よりも硬い中間層とさらに硬い外部層を有する保
護コーティング(6)を形成するために、アルミニウム青銅から成る複数の層形
成体(8,9)を上下に重なるように順次溶着することを特徴とする方法。
1. A method for providing a wear-resistant surface on a component made of steel, comprising a base material (7) made of steel having an intermediate layer harder than steel and an outer layer harder than the steel. A method of forming (6), wherein a plurality of layer forming bodies (8, 9) made of aluminum bronze are sequentially welded one above the other.
【請求項2】 アルミニウム青銅から成る2つの層形成体(8,9)を溶着
することを特徴とする請求項1に記載の方法。
2. The method as claimed in claim 1, wherein two layer formers made of aluminum bronze are deposited.
【請求項3】 前記保護コーティング(6)を形成する層形成体(8,9)
を溶接することを特徴とする請求項1乃至2のいずれか1項に記載の方法。
3. A layer former (8, 9) forming said protective coating (6).
3. The method according to claim 1, wherein the welding is performed.
【請求項4】 前記保護コーティング(6)の各層形成体(8または9)を
設ける前に、その都度被溶接材料を好ましくは炉において予熱することを特徴と
する請求項1乃至3のいずれか1項に記載の方法。
4. The method as claimed in claim 1, wherein the material to be welded is preheated in each case before the application of the layer formations (8 or 9) of the protective coating (6). Item 2. The method according to item 1.
【請求項5】 およそ350℃で予熱を行なうことを特徴とする請求項4に
記載の方法。
5. The method according to claim 4, wherein the preheating is performed at about 350 ° C.
【請求項6】 前記保護コーティング(6)を形成する層形成体(8,9)
が同一の組成を有することを特徴とする請求項1乃至5のいずれか1項に記載の
方法。
6. A layer forming body (8, 9) forming said protective coating (6).
6. The method according to any one of claims 1 to 5, wherein have the same composition.
【請求項7】 前記保護コーティング(6)を形成する層形成体(8,9)
が8%〜25%のAlと、Sb, Co, Be, Cr, Sn, Mn, Si, Cd, Zn, Fe, Ni, Pb お
よびC のうち少なくとも1つの成分をそれぞれ0.2%〜10%、および残りの
成分としてCuとを含むアルミニウム青銅から成ることを特徴とする請求項1乃至
6のいずれか1項に記載の方法。
7. Layer-forming bodies (8, 9) forming said protective coating (6).
Contains 8% to 25% of Al and at least one component of Sb, Co, Be, Cr, Sn, Mn, Si, Cd, Zn, Fe, Ni, Pb and C respectively in 0.2% to 10%. A method according to any one of the preceding claims, comprising aluminum bronze containing, and the remaining component Cu.
【請求項8】 前記保護コーティング(6)の少なくとも1つの層形成体(
8,9)が13%〜16%のAlと、4%〜5%のFe、0.2%〜0.8%のSi、
1%〜2%のMn、最大でも0.2%のC、残りの成分としてCuを含むアルミニウ
ム青銅から成ることを特徴とする請求項7に記載の方法。
8. The at least one layer former (6) of said protective coating (6).
8, 9) is 13% to 16% Al, 4% to 5% Fe, 0.2% to 0.8% Si,
8. The method according to claim 7, comprising aluminum bronze containing 1% to 2% Mn, at most 0.2% C and the balance Cu.
【請求項9】 前記保護コーティング(6)の少なくとも1つの層形成体(
8,9)が8%〜11%のAlと、4%〜6%のNi、3%〜5%のFe、1%〜2%
のMn、残りの成分としてCuを含むアルミニウム青銅から成ることを特徴とする請
求項6または7に記載の方法。
9. At least one layered body of said protective coating (6).
8, 9) 8% to 11% Al, 4% to 6% Ni, 3% to 5% Fe, 1% to 2%
The method according to claim 6, comprising aluminum bronze containing Mn and Cu as a remaining component.
【請求項10】 鋼から成る部材を少なくとも1つ有し、前記部材には、少
なくとも部分的に耐摩耗性を有する表面が設けられて成る装置であって、 前記耐摩耗性を有する表面を形成するために保護コーティング(6)が設けら
れ、該保護コーティングは、鋼から成る母材(7)に、アルミニウム青銅から成
る複数の、とりわけ2つの層形成体(8,9)が互いに重なるように溶着されて
成ることを特徴とする装置。
10. A device comprising at least one member made of steel, said member provided with an at least partially wear-resistant surface, said device forming said wear-resistant surface. A protective coating (6) is provided, such that a plurality of, especially two, layer-forming bodies (8, 9) of aluminum bronze are superimposed on a base material (7) of steel. An apparatus characterized by being welded.
【請求項11】 前記母材の近く設けられた層形成体(8)の硬度は300
〜400HVとされるとともに、前記表面側に設けられた層形成体(9)の硬度
は500〜600HVとされていることを特徴とする請求項10に記載の装置。
11. The hardness of the layer forming body (8) provided near the base material is 300.
The apparatus according to claim 10, wherein the hardness is set to 500 to 600 HV, and the hardness of the layer forming body (9) provided on the front surface side is set to 500 to 600 HV.
【請求項12】 新品の状態において、アルミニウム青銅から成る前記外側
の層形成体(9)に、迅速に摩耗する材料から成る慣らし運転層(10)が設け
られていることを特徴とする請求項10または11に記載の装置。
12. In a new condition, said outer layer former (9) made of aluminum bronze is provided with a running-in layer (10) made of a material that wears quickly. 12. The apparatus according to 10 or 11.
JP2000601221A 1999-02-25 2000-02-11 Method for forming a wear-resistant surface on a steel member and apparatus comprising at least one such member Expired - Lifetime JP3859970B2 (en)

Applications Claiming Priority (3)

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DE19908107.7 1999-02-25
DE19908107A DE19908107C2 (en) 1999-02-25 1999-02-25 Method for producing a wear-resistant surface in the case of components made of steel and machine with at least one such component
PCT/EP2000/001129 WO2000050660A1 (en) 1999-02-25 2000-02-11 Method for producing a wear-resistant surface on components consisting of steel and machine with at least one component of this type

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JP3859970B2 JP3859970B2 (en) 2006-12-20

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JP (1) JP3859970B2 (en)
KR (1) KR100440426B1 (en)
CN (1) CN1152975C (en)
AT (1) ATE223512T1 (en)
AU (1) AU3280100A (en)
DE (2) DE19908107C2 (en)
ES (1) ES2182792T3 (en)
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JP2008521630A (en) * 2004-12-02 2008-06-26 セラティチット オーストリア ゲゼルシャフト ミット ベシュレンクテル ハフツング Machining tools
USRE45154E1 (en) 2004-12-02 2014-09-23 Ceratizit Austria Gesellschaft Mbh Tool for machining
JP2010525222A (en) * 2007-04-25 2010-07-22 エムエーエヌ・ディーゼル・フィリアル・アフ・エムエーエヌ・ディーゼル・エスイー・ティスクランド Mechanical member belonging to sliding pair and method for manufacturing the mechanical member
JP2011522731A (en) * 2008-06-09 2011-08-04 プラズマ システム エス. アー. Railway wheel with wear-resistant flange
JP2011530008A (en) * 2008-08-06 2011-12-15 フェデラル−モーグル ブルシャイト ゲゼルシャフト ミット ベシュレンクテル ハフツング Sliding part with conformable coating and method for manufacturing the same
CN102848634A (en) * 2012-03-22 2013-01-02 福州联其铜铅钢带制造有限公司 Easily-molded environment-friendly beryllium bronze-steel bimetallic bearing material and manufacturing method thereof
CN102848634B (en) * 2012-03-22 2015-07-08 福州联其铜铅钢带制造有限公司 Easily-molded environment-friendly beryllium bronze-steel bimetallic bearing material and manufacturing method thereof

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KR100440426B1 (en) 2004-07-14
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RU2239000C2 (en) 2004-10-27
PL349466A1 (en) 2002-07-29
WO2000050660A1 (en) 2000-08-31
ES2182792T3 (en) 2003-03-16
CN1341157A (en) 2002-03-20
NO20013876D0 (en) 2001-08-08
DE50000452D1 (en) 2002-10-10
NO332021B1 (en) 2012-05-29
EP1157142A1 (en) 2001-11-28
EP1157142B1 (en) 2002-09-04
KR20010113710A (en) 2001-12-28
JP3859970B2 (en) 2006-12-20
CN1152975C (en) 2004-06-09
DE19908107C2 (en) 2003-04-10
AU3280100A (en) 2000-09-14
DE19908107A1 (en) 2000-08-31
ATE223512T1 (en) 2002-09-15

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