KR20010046042A - Calcium creosote extractant and manufacturing method thereof - Google Patents
Calcium creosote extractant and manufacturing method thereof Download PDFInfo
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- KR20010046042A KR20010046042A KR1019990049627A KR19990049627A KR20010046042A KR 20010046042 A KR20010046042 A KR 20010046042A KR 1019990049627 A KR1019990049627 A KR 1019990049627A KR 19990049627 A KR19990049627 A KR 19990049627A KR 20010046042 A KR20010046042 A KR 20010046042A
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- C05F5/00—Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
- C05F5/006—Waste from chemical processing of material, e.g. diestillation, roasting, cooking
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- C05C7/00—Fertilisers containing calcium or other cyanamides
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- C—CHEMISTRY; METALLURGY
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- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F1/00—Fertilisers made from animal corpses, or parts thereof
- C05F1/002—Fertilisers made from animal corpses, or parts thereof from fish or from fish-wastes
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
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- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
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- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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Abstract
Description
본 발명은 액상칼슘비료 및 그 제조방법에 관한 것으로서, 더욱 상세하게는 식물생장에 필요한 칼슘 성분을 효율적으로 공급하여 비료 효과가 우수하고 수경재배시 칼슘공급원으로 사용할 수 있는 액상칼슘비료 및 그 제조방법에 관한 것이다.The present invention relates to a liquid calcium fertilizer and a method for manufacturing the same, and more particularly, a liquid calcium fertilizer which is excellent in fertilizer effect and can be used as a calcium source in hydroponic cultivation by efficiently supplying calcium components necessary for plant growth, and a method of manufacturing the same. It is about.
목초액은 나무를 태우면 발생되는 연기를 냉각 응집시킨 후 이를 숙성·정제시켜 얻어지는 적갈색의 투명한 액체이다.Wood vinegar is a reddish brown transparent liquid obtained by cooling and coagulating the smoke generated when burning wood, and then aging and refining it.
각종 유기산과 페놀류를 포함한 200여종 이상의 다양한 성분을 함유하는 목초액은 그 주성분이 초산으로서 전체의 절반을 차지하나 목초액의 90% 이상이 수분이기 때문에 실제로는 전체 용액의 3% 정도밖에 되지 않는다.The wood vinegar containing more than 200 kinds of various components including various organic acids and phenols, the main component is acetic acid, which occupies half of the whole, but more than 90% of the wood vinegar is only about 3% of the total solution.
이와 같은 목초액은 식물이나 동물의 체내에서의 침투성·흡수성이 뛰어나므로 목초액의 이러한 특성을 잘 활용하면 식물성장에 필요한 비료 성분의 흡수를 좋게 하거나 병충해를 감소시킬 수 있다.Since such wood vinegar is excellent in permeability and absorption in the body of plants or animals, by utilizing this property of wood vinegar can improve the absorption of fertilizer components necessary for plant growth or reduce pests.
실제로 목초액은 액체 상태로 또는 적당한 흡착제를 흡착시킨 다음 추출하여 표 1과 같은 다양한 용도로 사용되고 있다.In fact, wood vinegar is used in a variety of uses as shown in Table 1 in the liquid state or by adsorbing and then adsorbing a suitable adsorbent.
또한, 목초액은 농작물의 발아, 발근 및 생장을 촉진시키며, 벼의 도열병을 예방하고, 과실의 단맛을 증가시키며, 광합성을 촉진시키고 엽록소의 양을 증가시켜 잎색을 짙게하는 등 비료 효과가 뛰어나다.In addition, wood vinegar is excellent fertilizer effect, such as to promote the germination, rooting and growth of crops, prevent rice blast, increase the sweetness of fruit, promote photosynthesis and increase the amount of chlorophyll to increase leaf color.
한편, 농가에서 수경재배시에 사용하는 영양액에는 칼슘원으로서 Ca(NO3)2·4H2O, Ca(H2PO4)2H2O, CaH4(PO4)2, CaCl2·6H2O, CaSO4·2H2O 등이 첨가되는데, 이 중에서도 물에 대한 용해도가 높은 Ca(NO3)2·4H2O, CaCl2·6H2O가 주로 사용되고 있다.On the other hand, nutrients used for hydroponic cultivation in farms include Ca (NO 3 ) 2 · 4H 2 O, Ca (H 2 PO 4) 2 H 2 O, CaH 4 (PO 4 ) 2 , and CaCl 2 · 6H as calcium sources. 2 O, CaSO 4 .2H 2 O, and the like are added. Among them, Ca (NO 3 ) 2 .4H 2 O and CaCl 2 · 6H 2 O, which have high solubility in water, are mainly used.
본 발명자는 산화된 계란칼슘 또는 굴칼슘 등을 타르 성분이 완전히 제거된 목초액인 목정수와 반응시키면 반응 전보다 수용성 형태의 칼슘량이 증가하여 칼슘 비료 효과를 증대시킬 수 있다는 점에 착안하여, 목초액으로부터 타르 성분과 수분을 제거하고 유효 성분만을 추출하여 제조되는 목정분말과 염산희석액을 반응시킨 결과, 수용성 칼슘이 10% 이상 함유되어 상기 칼슘원을 대체할 수 있는 액상칼슘을 추출할 수 있었다.The present inventors have focused on the fact that when oxidized egg calcium or oyster calcium is reacted with Mokjeongsoo, a wood vinegar solution from which tar is completely removed, the amount of calcium in the water-soluble form can be increased to increase the calcium fertilizer effect. As a result of reacting the wood powder prepared by removing the ingredients and moisture and extracting only the active ingredient and the dilute hydrochloric acid, the liquid calcium which can replace the source of calcium can be extracted by containing 10% or more of water-soluble calcium.
본 발명의 목적은 유효 칼슘의 흡수 효과를 향상시킨 경제적인 액상칼슘비료를 제공하는 것이다.It is an object of the present invention to provide an economical liquid calcium fertilizer with improved absorption effect of effective calcium.
본 발명의 다른 목적은 인체에 무해하고 계란 또는 굴 껍질 등의 버려지는 자원을 활용하여 환경오염을 방지할 수 있는 액상칼슘비료를 제공하는 것이다.Another object of the present invention is to provide a liquid calcium fertilizer that is harmless to the human body and can prevent environmental pollution by utilizing the discarded resources such as eggs or oyster shell.
본 발명의 또 다른 목적은 수경재배시 칼슘공급원으로 사용할 수 있는 액상칼슘비료를 제공하는 것이다.Another object of the present invention is to provide a liquid calcium fertilizer that can be used as a source of calcium in hydroponic cultivation.
본 발명의 이와 같은 목적들은, 타르 성분이 완전히 제거된 목초액과 산화칼슘을 반응시켜 합성되는 목정분말로부터 유효 칼슘 성분만을 추출하여 제조되는 액상칼슘비료를 제공함으로써 달성되는데, 이 액상비료칼슘은 흡수가 용이한 수용성 칼슘량이 증가되어 유효 칼슘의 흡수 효과가 매우 우수하다.This object of the present invention is achieved by providing a liquid calcium fertilizer prepared by extracting only the active calcium component from the wood grain powder synthesized by reacting the wood vinegar solution completely removed tar and calcium oxide, the liquid fertilizer calcium is absorbed The amount of easy water-soluble calcium is increased, and the absorption effect of effective calcium is very excellent.
본 발명은 참나무 목초액을 증류하고 정제하여 타르 성분이 완전히 제거된 목정수를 얻는 단계와, 계란 또는 굴 껍질을 물로 세척하고 건조하여 분쇄하는 단계와, 분쇄된 계란 또는 굴 껍질을 1,000 ∼ 1,200℃에서 연소시킨 후 냉각시켜 계란칼슘 또는 굴칼슘을 얻는 단계와, 상기 목정수와 계란칼슘 또는 굴칼슘을 각각 2:3 ∼ 3:2(w/v)로 혼합·교반하여 반응시키는 단계와, 상기 반응물을 건조시킨 후 분쇄하여 목정분말을 얻는 단계와, 상기 목정분말에 염산희석액을 혼합하여 반응시키는 단계와, 상기 반응이 진행되는 동안 목정수를 첨가하고 가열하는 단계와, 상기 반응이 끝난 후에 냉각시켜 여과하는 단계로 구성된다.The present invention is a step of distilling and purifying oak vinegar solution to obtain a wooden water from which tar components are completely removed, washing and drying the egg or oyster shell with water and drying it, and grinding the ground egg or oyster shell at 1,000 to 1,200 ° C. Burning and cooling to obtain egg calcium or oyster calcium; and mixing and stirring the wood-coated water and egg calcium or oyster calcium at 2: 3 to 3: 2 (w / v), respectively, and reacting the reactants. Drying and pulverizing to obtain wood powder, reacting the wood powder with dilute hydrochloric acid dilution, reacting with water, adding wood heating water and heating while the reaction is in progress, and cooling after completion of the reaction. Filtration.
이 때, 상기 염산희석액은 염산과 물이 11:4 ∼ 14:1(w/v)의 비율로 혼합된 것이며, 상기 목정분말과 염산희석액은, 굴목정분말의 경우에 2:9 ∼ 4:7(w/v), 계란목정분말의 경우에 2:7 ∼ 4:5(w/v)의 비율로 혼합된 것이다.At this time, the hydrochloric acid diluent is a mixture of hydrochloric acid and water in the ratio of 11: 4 to 14: 1 (w / v), the wood powder and hydrochloric acid diluent is 2: 9 to 4: 7 (w / v) and eggwood powder are mixed at a ratio of 2: 7 to 4: 5 (w / v).
또한, 상기 목정분말과 염산희석액의 반응이 진행되고 있는 동안 첨가되는 목정수의 양은 굴목정분말의 경우 염산희석액의 1/5 ∼ 1/2 배, 계란목정분말의 경우 염산희석액의 1/3 ∼ 4/5 배이다.In addition, the amount of wood crystal water added during the reaction between the wood powder and hydrochloric acid diluent is 1/5 to 1/2 times the hydrochloric acid diluent in the case of lumber wood powder and 1/3 to the hydrochloric acid diluent in the case of egg wood powder. 4/5 times.
이하 본 발명을 실시예를 들어 상세히 설명하고자 하나, 본 발명이 기술된 실시예에 제한되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited to the described embodiments.
실시예Example
실시예 1Example 1
1. 참나무 목초액을 증류하고 정제하여 타르 성분을 완전히 제거한 목정수를 제조하였다.1. Oak tree vinegar was distilled and purified to prepare wood purified water from which tar was completely removed.
2. 계란 껍질을 물로 세척하고 건조한 다음 1∼5㎜ 크기로 분쇄하였다.2. The egg shells were washed with water, dried and ground to a size of 1 to 5 mm.
3. 분쇄된 계란 껍질을 1,000∼1,200℃에서 충분히 연소시킨 후 하루 정도 냉각시켰다.3. The ground egg shells were sufficiently burned at 1,000-1,200 ° C. and then cooled for about one day.
계란껍질 1000g을 연소시켜 약 600g 정도의 계란칼슘을 얻을 수 있었다.By burning 1000 g of egg shell, about 600 g of egg calcium could be obtained.
4. 목정수와 완전 산화된 계란칼슘을 각각 1:1(w/v)로 혼합하고 교반하면서 5∼10분 정도 반응시키고, 발열 반응이 끝나면 반응물을 열풍건조기(50℃)로 2시간 정도 건조시켰다.4. Mix Mokjeong water and fully oxidized egg calcium at 1: 1 (w / v), and react for 5 to 10 minutes with stirring. After exothermic reaction, dry the reaction product with a hot air dryer (50 ℃) for 2 hours. I was.
5. 건조된 반응물은 1,680㎛체를 통과할 수 있도록 분쇄하여 회백색의 목정분말을 얻었다.5. The dried reactant was pulverized to pass through a 1,680㎛ sieve to obtain an off-white wood powder.
6. 상기 목정분말을 염산희석액(염산과 물을 5 : 1(w/v)로 혼합)과 1 : 2(w/v)의 비율로 혼합하였다. 이 때, 내용물의 온도는 70∼80℃까지 상승하였다.6. The wood grain powder was mixed at a ratio of dilute hydrochloric acid (hydrochloric acid and water in a ratio of 5: 1 (w / v)) and 1: 2 (w / v). At this time, the temperature of the content rose to 70-80 degreeC.
7. 반응이 진행되고 있는 동안 목정수를 염산희석액의 2/3 수준이 되도록 조심스럽게 첨가하고 200℃에서 30분간 가열하였다.7. While the reaction was in progress, Mokjeong water was carefully added to 2/3 of the dilute hydrochloric acid solution and heated at 200 ° C. for 30 minutes.
8. 반응이 끝나면 내용물의 온도를 30℃로 유지하면서 여과(No. 2. Toyo)하여 액상칼슘을 얻었다.8. After the reaction was completed while maintaining the temperature of the content to 30 ℃ (No. 2. Toyo) to obtain a liquid calcium.
실시예 2Example 2
1. 참나무 목초액을 증류하고 정제하여 타르 성분을 완전히 제거한 목정수를 제조하였다.1. Oak tree vinegar was distilled and purified to prepare wood purified water from which tar was completely removed.
2. 굴 껍질을 물로 세척하고 건조한 다음 1∼5㎜ 크기로 분쇄하였다.2. The oyster shells were washed with water, dried and ground to a size of 1-5 mm.
3. 분쇄된 굴 껍질을 1,000∼1,200℃에서 충분히 연소시킨 후 하루 정도 냉각시켰다.3. The crushed oyster shell was burned sufficiently at 1,000 ~ 1,200 ℃ and then cooled for about one day.
굴 껍질 1,000g을 연소시켜 약 800g 정도의 굴칼슘을 얻을 수 있었다.About 800 g of oyster calcium was obtained by burning 1,000 g of oyster shell.
4. 목정수와 완전 산화된 굴칼슘을 각각 1:1(w/v)로 혼합하고 교반하면서 5∼10 분 정도 반응시키고, 발열 반응이 끝나면 반응물을 열풍건조기(50℃)로 2시간 정도 건조시켰다.4. Mix wood hydrated water and fully oxidized oyster calcium at 1: 1 (w / v), and react for 5 to 10 minutes with stirring. After exothermic reaction, dry the reactants with a hot air dryer (50 ℃) for 2 hours. I was.
5. 건조된 반응물은 1,680㎛체를 통과할 수 있도록 분쇄하여 회백색의 목정분말을 얻었다.5. The dried reactant was pulverized to pass through a 1,680㎛ sieve to obtain an off-white wood powder.
6. 상기 목정분말을 염산희석액(염산과 물을 5 : 1(w/v)로 혼합)과 3 : 8(w/v)의 비율로 혼합하였다. 이 때, 내용물의 온도는 70∼80℃까지 상승하였다.6. The wood grain powder was mixed at a ratio of hydrochloric acid diluent (mixing hydrochloric acid and water at 5: 1 (w / v)) and 3: 8 (w / v). At this time, the temperature of the content rose to 70-80 degreeC.
7. 반응이 진행되고 있는 동안 목정수를 염산희석액의 1/4 수준이 되도록 조심스럽게 첨가하고 200℃에서 30분간 가열하였다.7. While the reaction was in progress, Mokjeong water was carefully added to 1/4 level of dilute hydrochloric acid solution and heated at 200 ° C. for 30 minutes.
8. 반응이 끝나면 내용물의 온도를 30℃로 유지하면서 여과(No. 2. Toyo)하여 액상칼슘을 얻었다.8. After the reaction was completed while maintaining the temperature of the content to 30 ℃ (No. 2. Toyo) to obtain a liquid calcium.
본 발명의 실시에서 참나무 목초액을 증류하고 정제하여 타르 성분을 완전히 제거한 목정수와 반응시키는 산화칼슘은 이미 패화석으로 생산된 제품(농림부 고시 제96-96호, 비료공정규격)을 사용하여도 되나, 저렴한 비용으로 대량 생산하기 위하여 양계 또는 굴양식 부산물인 계란 껍질이나 굴껍질을 사용하였다.In the practice of the present invention, distilled and purified oak vinegar solution and calcium oxide reacted with wood purified water completely removed from the tar component may be used already manufactured products of calcite (Ministry of Agriculture, Notice No. 96-96, fertilizer process standard). Egg shells or oyster shells, which are by-products of poultry or oyster farming, are used for mass production at low cost.
이 때, 산화칼슘을 얻기 위한 연소 전과 연소 후의 계란 껍질과 굴 껍질에 함유된 칼슘량은 표 2 및 3과 같다.At this time, the amounts of calcium contained in egg shells and oyster shells before and after combustion to obtain calcium oxide are shown in Tables 2 and 3.
상기 표에서 알 수 있듯이, 식물에 직접 이용될 수 있는 수용성 형태의 칼슘이 연소전 보다 연소 후에 약 140배 이상 증가한 반면 가용성 형태나 전량의 칼슘은 1.2∼1.6 배 정도 증가하는데 그쳤다.As can be seen from the table, the water-soluble form of calcium that can be directly used in plants increased about 140 times after combustion than before combustion, while the soluble form or total amount of calcium increased only by 1.2-1.6 times.
목정수와 계란칼슘 또는 굴칼슘의 반응물은 50℃의 열풍건조기로 건조시키지 않고 실온에서 건조시켜도 되는데, 10시간 이상이 소요되기는 하나 비료 성분량에는 차이가 없었다.The reactants of wood crystal water and egg calcium or oyster calcium may be dried at room temperature without drying with a hot air dryer at 50 ° C., although it takes more than 10 hours, there is no difference in the amount of fertilizer.
또한, 이렇게 건조된 입자는 특별한 분쇄기를 사용하지 않아도 쉽게 분쇄되는데, 이와 같은 방법으로 계란칼슘이나 굴칼슘 1,000g을 목정수 1,000㎖를 반응시키면 약 1,300∼1,400g의 목정분말을 얻을 수 있었다.In addition, the dried particles are easily pulverized even without using a special grinder. In this way, when 1,000 g of egg calcium or oyster calcium are reacted with 1,000 ml of wood water, wood powder of about 1,300 to 1,400 g was obtained.
상기와 같이 제조된 목정분말에 함유된 형태별 칼슘 함량은 표 4 및 5에서 보는 바와 같다.The calcium content of each type contained in the wood powder prepared as described above is as shown in Tables 4 and 5.
즉, 계란칼슘과 굴칼슘을 목정수와 반응시키면 반응전보다 가용성 형태나 전량의 칼슘은 1∼2% 정도 증가하는 반면 수용성 형태의 칼슘은 6∼7% 정도나 증가하였다.In other words, when the egg calcium and oyster calcium were reacted with Moksu water, the soluble form and the total amount of calcium increased by 1 to 2%, while the water soluble form increased by 6 to 7%.
한편, 계란칼슘 및 굴칼슘과 목정수 반응물의 물에 대한 pH는 표 6에서 보는 바와 같이 거의 비슷한 값을 나타내어 pH 차이가 거의 없었다.On the other hand, the pH of the water of the egg calcium, oyster calcium and wood jeongsu water reactant showed almost similar values as shown in Table 6, there was almost no pH difference.
상기와 같이 제조된 목정분말은 다량의 칼슘이 함유되어 있는데, 이 칼슘을 추출하여 액상칼슘비료를 만들었다.The wood grain powder prepared as described above contains a large amount of calcium, which was extracted to form a liquid calcium fertilizer.
즉, 계란껍질을 이용한 목정분말 또는 굴목정분말을 이용하여 수용성 칼슘이 17% 이상인 액상칼슘비료(농림부 고시 제96-96호, 비료공정규격)를 만들었다.That is, liquid calcium fertilizer (notified by the Ministry of Agriculture and Forestry No. 96-96, fertilizer process standard) having 17% or more water-soluble calcium was made using wood powder or oyster wood powder using egg shell.
상기 실시예에 의하면 굴과 계란목정분말 1,000g을 사용하여 각각 약 2,000㎖와 2,600㎖의 액상칼슘을 얻을 수 있었다.According to the above embodiment, about 2,000 ml and 2,600 ml of liquid calcium were obtained using 1,000 g of oyster and egg wood powder, respectively.
굴목정분말의 경우 2차 반응이 완료된 후에 겔과 같은 상태로 되므로 계란목정분말의 경우보다 얻어지는 양이 적었다.In the case of the lumberjack powder, it was in a gel-like state after the completion of the secondary reaction.
이 여액에 함유된 수용성 칼슘(CaO)량은 굴목정분말의 경우 18.3%, 계란목정분말의 경우 18.7% 수준이었다.The amount of water-soluble calcium (CaO) contained in this filtrate was 18.3% for the wood grain powder and 18.7% for the eggwood powder.
한편, 농가에서 수경재배시 영양액을 조제하는데 이용하는 칼슘원을 목정분말에서 추출한 액상칼슘으로 대체할 수 있는지 조사하기 위해 기본 양액에 액상칼슘비료, Ca(NO3)2·4H2O, CaCl2·6H2O을 각각 칼슘이온(Ca2+) 농도가 200ppm 수준이 되도록 첨가하여 양액을 만들었다.On the other hand, in order to investigate whether the calcium source used to prepare nutrient solution for hydroponic cultivation in farmhouses can be replaced with liquid calcium extracted from wood powder, the liquid nutrient fertilizer, Ca (NO 3 ) 2 · 4H 2 O, CaCl 2 · 6H 2 O was added to the calcium ion (Ca 2+ ) concentration of 200ppm, respectively, to prepare a nutrient solution.
이때, 액상칼슘이 첨가되는 양은 굴목정분말에서 추출된 액상칼슘의 경우 30.58㎖/10ℓ, 계란목정분말에서 추출된 액상칼슘의 경우 31.94㎖/10ℓ이었다. 시금치, 배추, 열무, 보리 및 오이 등을 30일 동안 담수 수경재배한 결과, 사용한 칼슘원에 따라 작물의 생육상태에서 통계적인 차이가 없었다. 따라서 기존에 사용되고 있는 칼슘비료원을 새로 제조한 액상칼슘비료로 대체해서 사용해도 작물재배에는 무방하며 관주용이나 엽면시비용으로 사용하여도 효과적이다. 단지 액상칼슘비료는 강산성(pH 1.3)이기 때문에 양액의 pH 조절이 필요하다.At this time, the amount of added liquid calcium was 30.58ml / 10l for the liquid calcium extracted from oyster wood powder, 31.94ml / 10l for the liquid calcium extracted from egg wood powder. Freshwater hydroponic cultivation of spinach, Chinese cabbage, radish, barley and cucumber for 30 days showed no statistical difference in the growth of crops depending on the calcium source used. Therefore, it can be used for crop cultivation by replacing the existing calcium fertilizer source with newly prepared liquid calcium fertilizer, and it is also effective for irrigation or foliar cost. Only liquid calcium fertilizer is strongly acidic (pH 1.3), so it is necessary to adjust the pH of the nutrient solution.
상기 반응물의 분석은 전북대학교 농과대학 토양비료학 실험실과 기기 분석실에서 실시하였으며 그 방법은 다음과 같다.The reactants were analyzed in the soil fertilizer laboratory and instrument analysis room of the College of Agriculture Chonbuk National University, the method is as follows.
수용성 칼슘량은 시료 1∼2g을 물 100㎖에 넣고 환류 가열시킨 다음 냉각시키고 여과(No. 2. Toyo)하였다. 가용성 칼슘량은 시료 1∼2g을 0.5N HCl 200㎖와 혼합하고 30분 정도 가열하고 냉각시킨 다음 여과하였다. 총 칼슘량은 시료 2∼5g을 진한 HCl 30㎖와 진한 HCO310㎖와 혼합한 다음 30분간 가열하고 냉각시킨 다음 여과하였다. 이 여액을 유도결합프라즈마 분광기(Inductively Coupled Plasma Spectro- meter, Shimadzu, ICPS-7500, 일본)를 사용하여 정량 하였다.The water-soluble calcium amount was added to 1-2 g of the sample in 100 ml of water, heated to reflux, cooled, and filtered (No. 2. Toyo). The amount of soluble calcium was mixed with 200 ml of 0.5 N HCl, heated for about 30 minutes, cooled, and filtered. The total amount of calcium was mixed with 30 ml of concentrated HCl and 10 ml of concentrated HCO 3 after heating 2-5 g of the sample, followed by heating for 30 minutes, cooling, and filtration. This filtrate was quantified using an Inductively Coupled Plasma Spectrometer (Shimadzu, ICPS-7500, Japan).
또한, 액상칼슘제제에 함유된 칼슘량은 증류수로 적당히 희석한 다음 유도결합플라즈마 분광기로 측정하였으며, 반응물의 pH는 시료 5g을 증류수 50㎖와 혼합하고 1시간 동안 교반한 후 pH meter(Jenco, 1671, USA)를 사용하여 측정하였다.In addition, the amount of calcium contained in the liquid calcium preparation was properly diluted with distilled water and measured by an inductively coupled plasma spectrometer. , USA).
본 발명은 특별한 장치 없이도 간단·용이하게 양계 또는 굴양식 부산물인 계란껍질이나 굴껍질 및 기타 조개껍질 등을 사용하여 저렴한 비용으로 액상칼슘비료를 대량 생산할 수 있다.The present invention can easily and easily produce a large amount of liquid calcium fertilizer at low cost by using egg shells or oyster shells and other shells, such as poultry or oyster farming by-products, without a special device.
상기 액상칼슘비료는 산화된 계란칼슘 또는 굴칼슘보다 식물에 직접 이용될 수 있는 수용성 칼슘을 다량 함유하여 유효 칼슘의 흡수 효과가 매우 우수하며, 수경재배용, 관주용이나 엽면시비용으로 사용될 수 있다.The liquid calcium fertilizer contains a large amount of water-soluble calcium which can be directly used in plants than oxidized egg calcium or oyster calcium, and has an excellent effect of absorbing effective calcium, and can be used for hydroponic cultivation, irrigation or foliar cost.
또한, 본 발명은 인체에 해가 없고 토양 개량 및 병해 방지 효과가 있어 농약을 사용하지 않는 유기농법 또는 환경보존형 농법에 효율적으로 활용될 수 있다.In addition, the present invention is harmless to the human body and has an effect of improving the soil and preventing diseases can be effectively utilized in organic farming or environmental conservation farming methods do not use pesticides.
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| JPH073263A (en) * | 1993-06-14 | 1995-01-06 | Nippon Suisan Kaisha Ltd | Soil improver of pulverized eggshell with good affinity to soil and production thereof |
| KR960034140A (en) * | 1995-03-21 | 1996-10-22 | 최영수 | Method for preparing hardwood charcoal-wood vinegar mixture |
| KR100275586B1 (en) * | 1996-12-11 | 2001-03-02 | 배광효 | Soil conditioner using natural mineral and method for producing the same |
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