KR19990046665A - The manufacture method of bacteria activated by sewage and wastes water treatment - Google Patents
The manufacture method of bacteria activated by sewage and wastes water treatment Download PDFInfo
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- KR19990046665A KR19990046665A KR1019990012950A KR19990012950A KR19990046665A KR 19990046665 A KR19990046665 A KR 19990046665A KR 1019990012950 A KR1019990012950 A KR 1019990012950A KR 19990012950 A KR19990012950 A KR 19990012950A KR 19990046665 A KR19990046665 A KR 19990046665A
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- Prior art keywords
- sewage
- oxide
- wastewater
- microbial activator
- microbial
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- 239000010865 sewage Substances 0.000 title claims abstract description 34
- 238000011282 treatment Methods 0.000 title claims abstract description 27
- 241000894006 Bacteria Species 0.000 title claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 22
- 238000000034 method Methods 0.000 title description 11
- 239000002699 waste material Substances 0.000 title 1
- 230000000813 microbial effect Effects 0.000 claims abstract description 45
- 239000012190 activator Substances 0.000 claims abstract description 38
- 241000193830 Bacillus <bacterium> Species 0.000 claims abstract description 33
- 239000002351 wastewater Substances 0.000 claims abstract description 24
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims abstract description 22
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000004065 wastewater treatment Methods 0.000 claims abstract description 13
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims abstract description 11
- 235000019341 magnesium sulphate Nutrition 0.000 claims abstract description 11
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 9
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 9
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000002893 slag Substances 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 9
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 8
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000292 calcium oxide Substances 0.000 claims abstract description 7
- 229940099596 manganese sulfate Drugs 0.000 claims abstract description 7
- 235000007079 manganese sulphate Nutrition 0.000 claims abstract description 7
- 239000011702 manganese sulphate Substances 0.000 claims abstract description 7
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 7
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 6
- XDJWZONZDVNKDU-UHFFFAOYSA-N 1314-24-5 Chemical compound O=POP=O XDJWZONZDVNKDU-UHFFFAOYSA-N 0.000 claims abstract description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- VSAISIQCTGDGPU-UHFFFAOYSA-N phosphorus trioxide Inorganic materials O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 8
- 241000194110 Bacillus sp. (in: Bacteria) Species 0.000 claims description 4
- 229910000831 Steel Inorganic materials 0.000 claims description 3
- CDUFCUKTJFSWPL-UHFFFAOYSA-L manganese(II) sulfate tetrahydrate Chemical compound O.O.O.O.[Mn+2].[O-]S([O-])(=O)=O CDUFCUKTJFSWPL-UHFFFAOYSA-L 0.000 claims description 3
- 239000010959 steel Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 238000010298 pulverizing process Methods 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims 1
- 230000012010 growth Effects 0.000 abstract description 11
- 239000013543 active substance Substances 0.000 abstract description 8
- 102000004190 Enzymes Human genes 0.000 abstract description 7
- 108090000790 Enzymes Proteins 0.000 abstract description 7
- 238000000926 separation method Methods 0.000 abstract description 6
- 239000007787 solid Substances 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 abstract description 5
- 244000144972 livestock Species 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 abstract description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 3
- 210000003608 fece Anatomy 0.000 abstract description 3
- 239000010871 livestock manure Substances 0.000 abstract description 3
- -1 manganese sulfate tetrahydrochloride Chemical compound 0.000 abstract description 3
- 238000012856 packing Methods 0.000 abstract description 3
- 238000004062 sedimentation Methods 0.000 abstract description 3
- 230000028070 sporulation Effects 0.000 abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 2
- 238000003723 Smelting Methods 0.000 abstract description 2
- 239000000356 contaminant Substances 0.000 abstract description 2
- 238000005303 weighing Methods 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 10
- 244000005700 microbiome Species 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- 102000039446 nucleic acids Human genes 0.000 description 5
- 108020004707 nucleic acids Proteins 0.000 description 5
- 150000007523 nucleic acids Chemical class 0.000 description 5
- 229910052698 phosphorus Inorganic materials 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 238000004457 water analysis Methods 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 230000001737 promoting effect Effects 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 150000004676 glycans Chemical class 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- 229920001282 polysaccharide Polymers 0.000 description 3
- 239000005017 polysaccharide Substances 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- NIOPZPCMRQGZCE-WEVVVXLNSA-N 2,4-dinitro-6-(octan-2-yl)phenyl (E)-but-2-enoate Chemical compound CCCCCCC(C)C1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1OC(=O)\C=C\C NIOPZPCMRQGZCE-WEVVVXLNSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 210000003705 ribosome Anatomy 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 241000008371 Alseis Species 0.000 description 1
- 241000193764 Brevibacillus brevis Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/006—Regulation methods for biological treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/005—Black water originating from toilets
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/20—Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/06—Nutrients for stimulating the growth of microorganisms
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Microbiology (AREA)
- Engineering & Computer Science (AREA)
- Biodiversity & Conservation Biology (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Molecular Biology (AREA)
- Health & Medical Sciences (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Activated Sludge Processes (AREA)
Abstract
본 발명은 하·폐수, 분뇨, 오수 및 축산폐수 처리용 미생물활성제 및 그 제조방법에 관한 것으로서, 더 자세하게는 규산, 산화칼슘, 산화철, 산화마그네슘, 산화알미늄 및 산화망간 등이 함유된 제철 용광로에서 나오는 광재를 분쇄하여 이를 일정량의 황산마그네슘과 황산망간을 혼합하여 일정량씩 계량한 후 포장하여 제품으로 출하한 미생물활성제를 제조하되, 바실러스 종 혼합균을 이용한 하·폐수 등의 처리장에 미생물활성제를 소량씩 지속적으로 투입하면 하·폐수 등에 함유된 오염물질을 분해·섭취하여 정화시키는 바실러스 종 혼합균의 성장 및 분열을 도와 대수증식을 할 수 있게 하고 효소 생산을 촉진하여 난분해성 물질을 분해토록 하며, 포자형성을 유도함과 동시에 포자 형성물질을 제공함으로 침전지에서 고·액분리가 잘 이루어져 처리효율을 높일 수 있도록 된 하·폐수 처리용 미생물활성제 및 그 제조방법에 관한 것이다.The present invention relates to a microbial active agent for treatment of sewage, wastewater, manure, sewage and livestock wastewater, and a method of manufacturing the same, and more particularly, in an iron-smelting furnace containing silicic acid, calcium oxide, iron oxide, magnesium oxide, aluminum oxide, and manganese oxide. Manufacture the microbial activator shipped as a product by crushing the slag coming out, mixing a certain amount of magnesium sulfate and manganese sulfate, and then packing and weighing a predetermined amount, and preparing a microbial activator in a treatment plant such as sewage and wastewater using Bacillus species mixed bacteria. Continuously put in, it will help the growth and division of Bacillus species mixed bacteria that decompose, ingest and purify contaminants contained in sewage and waste water, so that it can grow logarithmically and promote enzyme production to decompose hardly decomposable substances. Induces sporulation and at the same time provides spore forming material, so solid and liquid separation in sedimentation basin And, the microbial active agents for waste water treatment so as to ensure a high efficiency and to a method of manufacturing the same.
본 발명은 특히, 바실러스 종 혼합균을 이용한 하·폐수, 분뇨, 오수 및 축산 폐수 처리를 위한 미생물활성제를 조성함에 있어서, 상기 미생물활성제를 산화칼슘 25∼38%, 규산 25∼35%, 황산마그네슘·7수염 7∼15%, 산화알미늄 7∼15%, 산화마그네슘 5∼9%, 황산망간·4수염 1∼5%, 산화티타늄 1∼3%, 산화철 0.1∼1.0%, 유황 0.1∼1.0%, 이산화망간 0.1∼1.0%, 삼산화인 0.01∼0.05%, 기타물질 1∼5%의 혼합 비율로 조성한 특징이 있다.In particular, the present invention provides a microbial activator for treating sewage, wastewater, manure, sewage and livestock wastewater using Bacillus species mixed bacteria, wherein the microbial activator is 25 to 38% calcium oxide, 25 to 35% silicate, magnesium sulfate 7 hydrochloride 7-15%, aluminum oxide 7-15%, magnesium oxide 5-9%, manganese sulfate tetrahydrochloride 1-5%, titanium oxide 1-3%, iron oxide 0.1-1.0%, sulfur 0.1-1.0% , Manganese dioxide, 0.1 to 1.0%, phosphorus trioxide 0.01 to 0.05%, and other substances 1 to 5% of the composition is characterized by the composition.
Description
본 발명은 하·폐수, 분뇨, 오수 및 축산폐수 처리용 미생물활성제 및 그 제조방법에 관한 것으로서, 더 자세하게는 규산, 산화칼슘, 산화철, 산화마그네슘, 산화알미늄 및 산화망간 등이 함유된 제철 용광로에서 나오는 광재를 분쇄하여 이를 일정량의 황산마그네슘과 황산망간을 혼합하여 일정량씩 계량한 후 포장하여 제품으로 출하한 미생물활성제를 제조하되, 바실러스 종 혼합균을 이용한 하·폐수 등의 처리장에 미생물활성제를 소량씩 지속적으로 투입하면 하·폐수 등에 함유된 오염물질을 분해·섭취하여 정화시키는 바실러스 종 혼합균의 성장 및 분열을 도와 대수증식을 할 수 있게 하고 효소 생산을 촉진하여 난분해성 물질을 분해토록 하며, 포자형성을 유도함과 동시에 포자 형성물질을 제공함으로 침전지에서 고·액분리가 잘 이루어져 처리효율을 높일 수 있도록 된 하·폐수 처리용 미생물활성제 및 그 제조방법에 관한 것이다.The present invention relates to a microbial active agent for treatment of sewage, wastewater, manure, sewage and livestock wastewater, and a method of manufacturing the same, and more particularly, in an iron-smelting furnace containing silicic acid, calcium oxide, iron oxide, magnesium oxide, aluminum oxide, and manganese oxide. Manufacture the microbial activator shipped as a product by crushing the slag coming out, mixing a certain amount of magnesium sulfate and manganese sulfate, and then packing and weighing a predetermined amount, and preparing a microbial activator in a treatment plant such as sewage and wastewater using Bacillus species mixed bacteria. Continuously put in, it will help the growth and division of Bacillus species mixed bacteria that decompose, ingest and purify contaminants contained in sewage and waste water, so that it can grow logarithmically and promote enzyme production to decompose hardly decomposable substances. Induces sporulation and at the same time provides spore forming material, so solid and liquid separation in sedimentation basin And, the microbial active agents for waste water treatment so as to ensure a high efficiency and to a method of manufacturing the same.
일반적으로 하·폐수 등의 처리에 있어서 미생물의 활성화 및 우점화를 위하여 질소원 및 인을 투입하거나 종균제라고 하는 여러 가지 제품들이 개발되어 적용 및 활용되고 있다. 예컨데, 표준활성슬러지방법에서는 요소나 인산을 투여하여 미생물의 영양원으로서 활용케 하고 있으며 유효 미생물을 분말 및 액화시켜 정기적으로 일정량씩 투여하므로서 미생물의 농도를 필요로 하는 만큼 유지시키면서 활성화를 꾀하도록 하고 있다.In general, various products such as nitrogen source and phosphorus, or spawning agents have been developed, applied and utilized for the activation and dominance of microorganisms in treatment of sewage and wastewater. For example, in standard activated sludge method, urea or phosphoric acid is administered to be used as a nutrient source of microorganisms, and effective microorganisms are powdered and liquefied to be administered at regular doses to maintain the concentration of microorganisms as needed and to activate them. .
그러나, 이의 기술은 질소 및 인의 제거효율이 떨어지며, 수온, 수질 및 수량 변동에 민감하여 안정된 수질을 얻을 수 없는 등의 문제점이 내재되어 있었는 바, 이는 결국 정체된 호수 및 해안에 부영양화 및 적조현상을 발생시켜 자연환경을 훼손하고 있으며, 인간생활에 막대한 손실을 주고 있음은 공지된 사실이다.However, its technology is inefficient in nitrogen and phosphorus removal efficiency, and it is inherent in the problem of not being able to obtain stable water quality because it is sensitive to fluctuations in water temperature, water quality and quantity, which eventually leads to eutrophication and red tide in stagnant lakes and shores. It is known that it is causing damage to the natural environment and causing enormous loss to human life.
따라서 근래들어 질소 및 인의 제거기술로서 획기적인 바실러스 종 혼합균에 의한 하·폐수 등의 정화 처리방법이 개발되어 상술한 문제점을 해결하고 있으나, 바실러스 종 혼합균의 사상체의 성장을 촉진시키고 내생포자화를 구성하는 물질 및이를 촉진시키는 물질을 구성하여 하·폐수 등의 고도처리의 효율을 향상시키는 방법 등이 미비하여 바실러스 종 혼합균에 의한 하·폐수 정화처리 효율을 극대화시키지 못한 단점이 있었다.Therefore, in recent years, as a technique for removing nitrogen and phosphorus, a treatment method for purification of sewage and wastewater by the innovative Bacillus species mixed bacteria has been developed to solve the above problems, but it promotes the growth of filamentous bodies and endogenous spores of Bacillus species mixed bacteria. There was a problem in that the composition of the material and the material promoting the same to improve the efficiency of the advanced treatment of sewage, wastewater, etc. was not sufficient to maximize the efficiency of treatment of sewage and wastewater treatment by mixed Bacillus species.
본 발명은 상기와 같이 바실러스 종 혼합균의 사상체의 성장을 촉진시키고 내생포자화를 구성하는 물질 및 이를 촉진시키는 물질을 구비하여 하·폐수 등의 고도처리 효율을 일층 향상시키기 위해 안출한 것으로서, 특히 바실러스 종 혼합균이 필라멘트 성장과정에서 대수성장을 하여 균체의 농도가 107∼1011/㎖ 정도 되도록 유도하며, 가수분해효소 생산을 촉진하여 분해가 어려운 다당류, 단백질, 핵산 및 지질을 바실러스 종 혼합균이 섭취 가능한 상태로 분해시켜 섭취하도록 하고, 포자화 과정에서는 포자막, 리보솜 및 핵산 등의 구조를 안정화시키는데 관여하는 무기영양제를 제조되도록 한 하·폐수 처리용 미생물활성제 및 그 제조방법을 제공하는데 그 목적이 있다.The present invention has been devised to further enhance the high-treatment efficiency of sewage and wastewater by promoting growth of filamentous bodies of Bacillus sp. Mixed bacteria and constituting endogenous spores, and substances promoting the same. Bacillus spp.Bacterium grows logarithmically during filament growth process to induce the concentration of cells to be about 10 7 ~ 10 11 / ml and promotes hydrolytic enzyme production to mix polysaccharides, proteins, nucleic acids and lipids that are difficult to degrade It provides a microbial active agent for sewage and wastewater treatment, and a method for producing the same, in which the bacteria are ingested in an ingestible state, and the inorganic nutrients involved in stabilizing the structure of the spore membrane, ribosomes, and nucleic acids are produced during the sporeing process. The purpose is.
상기와 같은 목적을 달성하기 위한 본 발명은 바실러스 종 혼합균을 이용한 하·폐수 처리를 위한 미생물활성제를 조성함에 있어서, 상기 미생물활성제를 산화칼슘 25∼38%, 규산 25∼35%, 황산마그네슘·7수염 7∼15%, 산화알미늄 7∼15%, 산화마그네슘 5∼9%, 황산망간·4수염 1∼5%, 산화티타늄 1∼3%, 산화철 0.1∼1.0%, 유황 0.1∼1.0%, 이산화망간 0.1∼1.0%, 삼산화인 0.01∼0.05%, 기타물질 1∼5%의 혼합 비율로 조성한 특징이 있다.The present invention for achieving the above object in the composition of microbial activator for sewage and wastewater treatment using Bacillus species mixed bacteria, the microbial activator 25 to 38% calcium oxide, 25 to 35% silicic acid, magnesium sulfate 7, 7-15% of hydrochloride, 7-15% of aluminum oxide, 5-9% of magnesium oxide, 1-5% of manganese sulfate tetrahydrate, 1-3% of titanium oxide, 0.1-1.0% of sulfur oxide, 0.1-1.0% of sulfur, It is characterized by the composition ratio of manganese dioxide 0.1 to 1.0%, phosphorus trioxide 0.01 to 0.05%, and other substances 1 to 5%.
또, 본 발명의 다른 특징으로는 바실러스 종 혼합균을 이용한 하·폐수 처리를 위한 미생물활성제 제조방법에 있어서, 제철소 용광로에서 배출되는 광재 덩어리를 분쇄기로 분쇄하는 분쇄단계와, 체로써 상기 분쇄단계에 의해 분쇄되는 분말을 거르되 100메쉬 이상의 분말만 구분하는 구분단계와, 상기 구분단계에서 얻어진 광재 분말과 황산마그네슘, 황산망간을 혼합기에 넣어 혼합하되 그 혼합비율을 산화칼슘 25∼38%, 규산 25∼35%, 황산마그네슘·7수염 7∼15%, 산화알미늄 7∼15%, 산화마그네슘 5∼9%, 황산망간·4수염 1∼5%, 산화티타늄 1∼3%, 산화철 0.1∼1.0 %, 유황 0.1∼1.0%, 이산화망간 0.1∼1.0%, 삼산화인 0.01∼0.05%, 기타물질 1∼5%로 이루어지도록 한 혼합단계를 거친후 일정량씩 계량되어 제품으로 출하되도록 함에 있다.In addition, another feature of the present invention is a method for producing microbial activator for sewage and wastewater treatment using Bacillus species mixed bacteria, the grinding step of pulverizing the slag mass discharged from the steelworks furnace with a pulverizer, the sieve step Filter the powder to be pulverized by the separation step of separating only the powder of 100 mesh or more, and the slag powder obtained in the separation step and magnesium sulfate, manganese sulfate mixed in a mixer, the mixing ratio of calcium oxide 25 to 38%, silicate 25 -35%, Magnesium sulfate, 7-% salt, 7-15%, aluminum oxide 7-15%, magnesium oxide 5-9%, manganese sulfate, 4-hydrochloride 1-5%, titanium oxide 1-3%, iron oxide 0.1-1.0% After a mixing step consisting of 0.1 to 1.0% of sulfur, 0.1 to 1.0% of manganese dioxide, 0.01 to 0.05% of phosphorus trioxide, and 1 to 5% of other substances, it is weighed by a certain amount and shipped to the product.
이하, 본 발명을 좀 더 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail.
본 발명의 원료로서, 제철소의 용광로에서 나오는 광재의 성분은 무정형규산, 산화칼슘, 산화마그네슘, 이산화망간, 산화알미늄, 산화철 등이 함유되어 있는데, 이를 100메쉬 이상으로 분쇄한 분말에 황산마그네슘(황산망간)을 첨가하여 표 1에서와 같은 비율의 혼합물질로 제조한다.As a raw material of the present invention, the components of the slag from the blast furnace of the steel mill contain amorphous silicic acid, calcium oxide, magnesium oxide, manganese dioxide, aluminum oxide, iron oxide, and the like, which are pulverized to 100 mesh or more to magnesium sulfate (manganese sulfate). ) To make a mixture in the same ratio as in Table 1.
본 미생물활성제에 함유된 무정형규산은 바실러스 종 혼합균의 필라멘트 성장을 촉진하는 역할을 하며, 망간성분은 효소의 활성제로 작용하며 미생물에 유독한 산소유도체를 해독하는데 중요한 역할을 하는 불균등화 효소의 생산에 관여하며, 마그네슘 성분은 포자화 과정에서 포자막, 리보솜 및 핵산 등의 구조를 안정화시키는데 관여하며 여러 가지 효소, 특히 인산전이 효소의 활성화에도 필요로 하며 칼슘성분은 포자껍질 형성에 필요로 한다. 여기서 바실러스 종 혼합균이라 하면 하·폐수 등의 성상에 따라 존재하는 균들의 구성이 다르나 다음과 같은 바실러스 종들이 그룹별로 관찰되었다. 즉, 그룹Ⅰ에 속하는 바실러스 알세이, 바실러스 브레비스, 바실러스 서투란스, 바실러스 서비키리스, 바실러스 더링지엔시스와 그룹Ⅱ에 속하는 바실러스 파스퇴리, 바실러스 스패리커스와 미확인 그룹의 바실러스 패스티디오스 등이었으며 이들 바실러스 종은 그람양성인 막대모의 진정세균으로서 단세포이며 사상체로 성장을 하다가 생활환경이 나빠지면 생존수단으로서 세포1개당 1개의 내생포자를 형성하는 특징을 가지고 있으며, 바실러스 종 혼합균은 분해가 어려운 다당류, 단백질, 전분 및 지질을 분해하고 이들을 섭취하여 성장·증식을 활발하게 한다.The amorphous silicic acid contained in this microbial activator plays a role in promoting the filament growth of Bacillus species, and the manganese component acts as an activator of the enzyme and plays an important role in detoxifying oxygen derivatives toxic to microorganisms. Magnesium component is involved in stabilizing the structure of the spore membrane, ribosomes and nucleic acids during the sporulation process, it is also required for the activation of various enzymes, in particular phosphate transfer enzymes, calcium components are required for the formation of spore shells. Here, if Bacillus species are mixed, the composition of bacteria is different depending on the characteristics of sewage and wastewater, but the following Bacillus species were observed in each group. Bacillus alsei, Bacillus brevis, Bacillus suturans, Bacillus survivisris, Bacillus dervishis and Bacillus pasteuris belonging to group II, Bacillus spalicus and Bacillus pastides of the unidentified group. The species is a gram-positive rod-shaped bacterium that is a single cell and grows into filamentous filaments, and when the living environment worsens, one endogenous spore is formed per cell as a means of survival.Bacillus species mixed bacteria are difficult to degrade polysaccharides, proteins, Decomposes starch and lipids and ingests them to promote growth and growth.
본 발명이 적용되는 하·폐수 처리용 미생물활성제의 조성은 표 1과 같다.Composition of the microbial active agent for sewage and wastewater treatment to which the present invention is applied is shown in Table 1.
상기 표 1의 재료의 제조방법은 다음과 같다.The manufacturing method of the material of the said Table 1 is as follows.
첫째, 제철소 용광로에서 폐기 처분하는 광재 덩어리를 분쇄기에서 분쇄한다.First, the slag lumps to be disposed of in the steel mill furnace are crushed in a crusher.
둘째, 체거름으로서 100메쉬 이상의 분말을 얻는다.Second, as a sieving, a powder of 100 mesh or more is obtained.
셋째, 광재분말과 황산마그네슘(황산망간)을 표 1과 같은 비율로 혼합기에 넣어 충분히 혼합한다.Third, the slag powder and magnesium sulfate (manganese sulfate) are put in the mixer in the ratio as shown in Table 1 and thoroughly mixed.
넷째, 일정량씩 계량한 다음 포장기에서 포장을 한다.Fourth, measure a certain amount and pack in a packing machine.
상기 방법으로 제조된 미생물활성제는 바실러스 종 혼합균을 이용하여 하·폐수 등의 처리장에 생물학적 산소요구량(BOD) ㎏당 0.01∼0.04㎏정도 투입되는데, 유기물 상태의 오염물질이 많이 함유된 하·폐수 중에서 바실러스 종 혼합균이 분열·성장을 하고 대수증식을 하면서 사상체를 형성한다. 이 과정에서 유기물, 질소, 인 등의 오염물질이 영양원으로서 섭취되어 고갈되면, 사상체의 바실러스 종 혼합균은 내생포자를 형성하게 되어 고·액분리가 되면서 하·폐수 등은 정화된다.The microbial activator prepared by the above method is charged with 0.01 ~ 0.04 ㎏ per kilogram of biological oxygen demand (BOD) to the treatment plant such as sewage and wastewater by using Bacillus species mixed bacteria, sewage and wastewater containing a lot of pollutants in the organic state. Among them, mixed Bacillus spp. Divide and grow, and grow in logarithmic form, forming filaments. In this process, when pollutants such as organic matter, nitrogen and phosphorus are ingested and depleted, filamentous Bacillus spp. Form endogenous spores, and solid and liquid separation separates the sewage and wastewater.
다음은 바실러스 종 혼합균을 이용하여 운전되고 있으면서 본 발명인 미생물 활성제를 투입한 하·폐수 등의 처리에 대한 실시예를 설명한다.The following describes an example of treatment of sewage and wastewater in which the microbial activator of the present invention is added while being operated using Bacillus species mixed bacteria.
실시예 1Example 1
H 아파트 오수처리장H Apartment Sewage Treatment Plant
본 처리장은 바실러스 종 혼합균을 이용하여 1일 400㎥의 오수를 처리하도록 시공되어 운전되고 있었는데, 관리자의 자질부족으로 인하여 처리장의 상태가 형편이 없었다. 즉, 침전조에서 고·액분리가 잘 안되어 부유물이 넘쳐서 방류되고 있었으며, 폭기조에서는 거품이 넘치고 있었으며, 지하에 설치된 오수처리장 내부는 악취가 진동하였으며, 배전반 등은 부식이 된 상태였다. 그리하여 생물학적 산소요구량(BOD) 1㎏당 0.015㎏ 정도의 본 발명 미생물활성제를 매일 투입하면서 1주일 정도 운전한 결과 표 2와 같은 처리수질의 분석결과를 얻었다.The plant was constructed and operated to treat 400㎥ of sewage per day using Bacillus species, but the condition of the plant was poor due to lack of manager's quality. In other words, the solids and liquids were not separated in the sedimentation tank, and the suspended solids were discharged. The foam was overflowing in the aeration tank. The odor vibrated in the sewage treatment plant installed underground, and the switchboard was corroded. Thus, the result of operating for about a week while injecting the present invention microbial activator about 0.015 kg per 1 kg of biological oxygen demand (BOD) for 1 week to obtain the analysis results of the treated water quality as shown in Table 2.
상기 표 2에서 보는 바와 같이, 미생물활성제를 투입한 후의 처리수의 수질이 미생물활성제를 투입하기 전의 수질에 비하여 처리수의 수질이 양호함을 나타내고 있다. 이는 미생물활성제에 의하여 바실러스 종 혼합균이 왕성한 성장 및 분열을 한 결과이며, 포자형성이 확실하게 이루어졌기 때문에 SS도 10㎖/ℓ 정도를 나타내고 있다. 또한 총질소와 총인에 대한 규제는 없으나 높은 처리효율을 나타내고 있다. 또한 본 발명인 미생물활성제를 투입하므로서 운전경험이 없는 미경험자라도 쉽게 관리할 수 있었다.As shown in Table 2, the water quality of the treated water after the addition of the microbial activator shows that the water quality of the treated water is better than that of the water before the microbial activator is added. This is a result of vigorous growth and division of Bacillus sp. Mixed microorganisms by the microbial activator, and SS also shows about 10 ml / l because spore formation was performed reliably. In addition, there is no regulation on total nitrogen and total phosphorus, but it shows high processing efficiency. In addition, by injecting the present invention microbial activator was able to easily manage even inexperienced people without driving experience.
실시예 2Example 2
L 우유 및 공장폐수 처리장L Milk and factory wastewater treatment plants
본 처리장은 1일 2,500㎥의 폐수를 처리하도록 시공되어 운전을 하고 있었는데, 바실러스 종 혼합균에 의하여 처리되도록 시설개선을 하였으나 종전과 마찬가지로 벌킹현상 등의 문제점이 줄지를 않고 있었다. 그리하여 생물화학적 산소요구량(BOD) 1㎏당 0.02㎏ 정도의 본 발명 미생물활성제를 매일 투입하면서 2주일 정도 운전한 결과 표 3와 같은 처리수질의 분석결과를 얻었다.The plant was constructed and operated to treat 2,500㎥ of wastewater per day, and the facility was improved to be treated by mixed Bacillus species, but the problems such as bulking were not reduced as before. Thus, the biochemical oxygen demand (BOD) of about 0.02 kg per day of the present invention, the microbial activator of about 2 weeks while operating for about two weeks as a result of the treated water quality as shown in Table 3.
상기 표 3에서 보는 바와 같이, 미생물활성제를 지속적으로 투입함으로서 안정된 처리수질을 유지할 수 있었다.As shown in Table 3, by continuously adding the microbial activator was able to maintain a stable treated water quality.
실시예 3Example 3
W시 축산폐수처리장W City Livestock Wastewater Treatment Plant
본 처리장은 바실러스 종 혼합균을 이용하여 1일 100㎘의 축산폐수를 처리하도록 시공되어 운전되고 있었는데, 폭기조에서 바실러스 종 혼합균의 성장이 더디고 포자형성이 잘 이루어지지 않아서 본 발명 미생물활성제를 생물학적 산소요구량 (BOD) 1㎏당 0.04㎏ 정도를 매일 투입하면서 한달정도 운전한 결과 표 4와 같은 처리수의 분석결과를 얻었다.The treatment plant was constructed and operated to treat livestock wastewater of 100 일 a day using mixed Bacillus spp., But the growth of the Bacillus spp. In the aeration tank was slow and spore formation was not good. As a result of operating for about a month while adding about 0.04kg / kg of BOD daily, the analysis results of treated water as shown in Table 4 were obtained.
상기 표 4에서 보는 바와 같이, 미생물활성제를 투입한 후의 처리수가 미생물활성제를 투입하기 전의 처리수에 비하여 수질이 월등하게 낮았다.As shown in Table 4, the water quality after the addition of the microbial activator was significantly lower than the treated water before the addition of the microbial activator.
실시예 4Example 4
U시 위생처리장U-shi sanitary treatment plant
본 처리장은 U시에서 수거하는 정화조 슬러지 1일 300㎘를 처리하는 시설로서 혐기성방법에 의한 처리를 하고 있었으나 바실러스 종 혼합균을 이용한 처리방법으로 개조한 후 운전을 하고 있음에도 불구하고 처리수의 수질이 방류기준에 미치지 못한 상태였었다. 그리하여 본 발명의 미생물활성제를 생물화학적 산소요구 량(BOD) 1㎏당 0.035㎏ 정도를 매일 투입하여 20일정도 운전한 결과 표 5와 같은 처리수질의 분석결과를 얻었다.This plant is a facility that treats 300 ㎘ of septic tank sludge collected in U city and treated by anaerobic method, but the water quality of treated water is not changed even though it is operated after converting to treatment method using mixed Bacillus species. The discharge criteria were not met. Thus, the microbial activator of the present invention was operated for about 20 days with about 0.035 kg of biochemical oxygen demand (BOD) per kilogram daily, resulting in analysis of the treated water quality as shown in Table 5.
상기 표 5에서 보는 바와 같이, 미생물 활성제를 지속적으로 투입한 후의 처리수가 미생물활성제를 투입하기 전보다 수질이 월등하였으며, 안정된 처리수의 수질을 유지할 수 있었다.As shown in Table 5, the treated water after the continuous input of the microbial active agent was superior to the water quality before the microbial active agent was added, it was possible to maintain a stable water quality.
이상 본 발명은 실시예에서 보는 바와 같이 바실러스 종 혼합균을 이용한 하·폐수 처리장에 있어서 본 발명인 미생물활성제를 미량씩 지속적으로 투입하면 바실러스 종 혼합균의 성장·분열 및 증식이 활발하여지도록 촉매제 역할을 하며, 효소의 생산량을 늘려 분해하기 어려운 다당류, 단백질, 핵산 및 지질 등을 섭취 가능하도록 분해하며, 포자형성을 유도하고 포자 외피를 형성하는 물질을 제공함으로 고·액분리를 명확하게 함으로서 처리효율을 한층 높이는 효과가 있었다.As described above, the present invention serves as a catalyst for active growth, cleavage and proliferation of Bacillus spp. Mixed bacteria when microbial activators of the present invention are continuously added to the wastewater treatment plant using Bacillus sp. Mixed bacteria as shown in Examples. It increases the production of enzymes to decompose polysaccharides, proteins, nucleic acids and lipids, which are difficult to decompose, and induces spore formation and provides a substance that forms a spore sheath, thereby clarifying solid and liquid separation. The height was effective.
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KR20010045177A (en) * | 1999-11-03 | 2001-06-05 | 김석기 | Microbial activator for using in treating sewage, night soil and industrial waste water and manufacturing method of them |
KR20020075033A (en) * | 2001-03-23 | 2002-10-04 | 주식회사 미래수 | Complex enzyme for treatment of domestic aninal's excretions |
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CN105776409B (en) * | 2016-05-26 | 2018-10-02 | 湖南农业大学 | Remove the preparation method of the load Mn oxide Scytonema arcangelii composite material of Cadmium In The Water Body |
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KR910006526B1 (en) * | 1989-03-02 | 1991-08-27 | 김영환 | Waste water purifying agent using microorganism |
JPH034988A (en) * | 1989-05-30 | 1991-01-10 | Nkk Corp | Water and bottom purifying material |
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KR20020075033A (en) * | 2001-03-23 | 2002-10-04 | 주식회사 미래수 | Complex enzyme for treatment of domestic aninal's excretions |
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