KR102606942B1 - 1액형 강화 에폭시 접착제 - Google Patents

1액형 강화 에폭시 접착제 Download PDF

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Publication number
KR102606942B1
KR102606942B1 KR1020207009906A KR20207009906A KR102606942B1 KR 102606942 B1 KR102606942 B1 KR 102606942B1 KR 1020207009906 A KR1020207009906 A KR 1020207009906A KR 20207009906 A KR20207009906 A KR 20207009906A KR 102606942 B1 KR102606942 B1 KR 102606942B1
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adhesive
component
epoxy
weight
curing
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Korean (ko)
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KR20200058438A (ko
Inventor
펠릭스 코치
안드레아스 럿츠
캐시 그로시니켈
지닌 플루에키저
Original Assignee
디디피 스페셜티 일렉트로닉 머티리얼즈 유에스, 엘엘씨
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/6715—Unsaturated monofunctional alcohols or amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/675—Low-molecular-weight compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C08G18/698—Mixtures with compounds of group C08G18/40
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/30—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen
    • C08G59/304—Di-epoxy compounds containing atoms other than carbon, hydrogen, oxygen and nitrogen containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4021—Ureas; Thioureas; Guanidines; Dicyandiamides

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
KR1020207009906A 2017-09-12 2018-07-20 1액형 강화 에폭시 접착제 Active KR102606942B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762557224P 2017-09-12 2017-09-12
US62/557,224 2017-09-12
PCT/US2018/043022 WO2019055128A1 (en) 2017-09-12 2018-07-20 EPOXY ADHESIVES REINFORCED WITH A COMPONENT

Publications (2)

Publication Number Publication Date
KR20200058438A KR20200058438A (ko) 2020-05-27
KR102606942B1 true KR102606942B1 (ko) 2023-11-29

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Country Status (6)

Country Link
US (2) US20210130663A1 (enExample)
EP (1) EP3681966A1 (enExample)
JP (1) JP7295095B2 (enExample)
KR (1) KR102606942B1 (enExample)
CN (1) CN111630130B (enExample)
WO (1) WO2019055128A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110429005B (zh) * 2019-09-04 2024-07-23 上海乐研电气有限公司 一种在线监测气体微水含量的气体密度继电器及监测系统
JP7615528B2 (ja) * 2019-11-26 2025-01-17 Dic株式会社 硬化性組成物、硬化物及び接着剤
EP4107203A1 (en) * 2020-02-19 2022-12-28 Covestro LLC Flexibilizing capped prepolymers
US11795341B2 (en) * 2020-10-29 2023-10-24 Potters Industries, Llc Protective coating for wood products and method of making same
US12110425B2 (en) 2021-08-17 2024-10-08 Uniseal, Inc. Electromagnetic curable novel toughened epoxy-hybrid structural adhesives and applications using the same
KR20230031522A (ko) 2021-08-27 2023-03-07 국립공원공단 IoT 기반 지능형 야생동물 위치정보 추적 시스템
EP4549484A1 (en) 2023-10-30 2025-05-07 Henkel AG & Co. KGaA One component composition based on epoxy resins

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017044359A1 (en) * 2015-09-10 2017-03-16 Dow Global Technologies Llc High modulus, toughened one-component epoxy structural adhesives with high aspect ratio fillers

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3686359A (en) 1969-12-19 1972-08-22 Union Carbide Corp Curable polyepoxide compositions
JPS5863758A (ja) 1981-10-09 1983-04-15 Asahi Denka Kogyo Kk 被覆用組成物
CA1259897A (en) 1985-04-02 1989-09-26 Madan M. Bagga Bonding process using curable epoxide resin adhesive
DE3864484D1 (de) 1987-08-26 1991-10-02 Ciba Geigy Ag Modifizierte epoxidharze.
US5278257A (en) 1987-08-26 1994-01-11 Ciba-Geigy Corporation Phenol-terminated polyurethane or polyurea(urethane) with epoxy resin
US5202390A (en) 1988-07-28 1993-04-13 Ciba-Geigy Corporation Butadiene/polar comonomer copolymer and aromatic reactive end group-containing prepolymer
GB8912952D0 (en) 1989-06-06 1989-07-26 Dow Rheinmuenster Epoxy-terminated polyoxazolidones,process for the preparation thereof and electrical laminates made from the epoxy-terminated polyoxazolidones
JPH05163330A (ja) * 1991-12-16 1993-06-29 Dow Chem Nippon Kk エポキシ燐酸エステル樹脂、その製造方法、及びその樹脂を含む塗料組成物
JP2004269679A (ja) * 2003-03-07 2004-09-30 Toyo Ink Mfg Co Ltd 接着剤及び前記接着剤の製造方法並びにプラスチックフィルムラミネート鋼板
EP2843022B1 (en) 2003-07-07 2020-12-16 Dow Global Technologies LLC Adhesive epoxy composition and process for applying it
EP1498441A1 (de) 2003-07-16 2005-01-19 Sika Technology AG Hitzehärtende Zusammensetzungen mit Tieftemperatur-Schlagzähigkeitsmodifikatoren
ES2276182T5 (es) 2004-03-12 2015-04-10 Dow Global Technologies Llc Composición adhesiva epoxídica
EP1602702B2 (en) 2004-06-01 2020-09-16 Dow Global Technologies LLC Epoxy adhesive composition
DE602005020260D1 (de) 2005-06-02 2010-05-12 Dow Global Technologies Inc Schlagzähmodifizierter Strukturklebstoff auf Epoxid Basis
EP1741734A1 (de) 2005-07-05 2007-01-10 Sika Technology AG Tieftemperaturschlagzähe hitze-härtbare Epoxidharzzusammensetzung mit Epoxidfestharzen
JP5307714B2 (ja) 2006-07-31 2013-10-02 ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン 硬化性エポキシ樹脂系粘着組成物
JP2008031343A (ja) * 2006-07-31 2008-02-14 Dainippon Ink & Chem Inc 接着用樹脂組成物
EP1916270A1 (de) 2006-10-24 2008-04-30 Sika Technology AG Hitzehärtende Epoxidharzzusammensetzung mit blockiertem Polyurethanprepolymer
EP1916272A1 (de) 2006-10-24 2008-04-30 Sika Technology AG Hitzehärtende Epoxidharzzusammensetzung enthaltend ein blockiertes und ein epoxidterminiertes Polyurethanprepolymer
EP1916269A1 (de) 2006-10-24 2008-04-30 Sika Technology AG Blockierte Polyurethanprepolymere und hitzehärtende Epoxidharzzusammensetzungen
EP1916285A1 (de) 2006-10-24 2008-04-30 Sika Technology AG Derivatisiertes Epoxid-Festharz und dessen Verwendungen
JP5248798B2 (ja) 2007-03-28 2013-07-31 株式会社Ａｄｅｋａ 硬化性樹脂組成物及びそれを含有してなる自動車構造用接着剤
US8097119B2 (en) * 2007-04-11 2012-01-17 Dow Global Technologies Llc Heat-resistant structural epoxy resins
DE502007002766D1 (de) 2007-11-14 2010-03-18 Sika Technology Ag Hitzehärtende Epoxidharzzusammensetzung enthaltend nichtaromatische Harnstoffe als Beschleuniger
EP2110397A1 (de) 2008-04-16 2009-10-21 Sika Technology AG Auf amphiphilen Block-Copolymer basierendes Polyurethan-Polymer und dessen Verwendung als Schlagzähigkeitsmodifikator
WO2010019539A2 (en) 2008-08-11 2010-02-18 Dow Global Technologies Inc. One-part structural epoxy resin adhesives containing elastomeric tougheners capped with phenols and hydroxy-terminated acrylates or hydroxy-terminated methacrylates
US9206284B2 (en) * 2008-12-29 2015-12-08 Basf Coatings Gmbh Coating compositions with branched phosphorous-containing resin
JP5337526B2 (ja) * 2009-02-24 2013-11-06 国立大学法人 東京大学 金属と樹脂との接着方法、及びそれを用いた回路形成部品の製法、並びに回路形成部品
EP2468792A1 (en) * 2010-12-23 2012-06-27 3M Innovative Properties Company Curable adhesive composition
EP2655516B1 (en) * 2010-12-26 2018-12-26 Dow Global Technologies LLC Structural epoxy resin adhesives containing chain-extended elastomeric tougheners capped with phenol, polyphenol or aminophenol compounds
JP6806488B2 (ja) * 2016-07-29 2021-01-06 株式会社Adeka 硬化性樹脂組成物、及び該組成物を用いた構造材料接合用接着剤

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017044359A1 (en) * 2015-09-10 2017-03-16 Dow Global Technologies Llc High modulus, toughened one-component epoxy structural adhesives with high aspect ratio fillers

Also Published As

Publication number Publication date
JP2020533441A (ja) 2020-11-19
EP3681966A1 (en) 2020-07-22
US20240093072A1 (en) 2024-03-21
CN111630130B (zh) 2022-09-30
US20210130663A1 (en) 2021-05-06
JP7295095B2 (ja) 2023-06-20
KR20200058438A (ko) 2020-05-27
WO2019055128A1 (en) 2019-03-21
CN111630130A (zh) 2020-09-04

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