KR102554874B1 - 비융화성 촉매 간의 전환 방법 - Google Patents
비융화성 촉매 간의 전환 방법 Download PDFInfo
- Publication number
- KR102554874B1 KR102554874B1 KR1020177020266A KR20177020266A KR102554874B1 KR 102554874 B1 KR102554874 B1 KR 102554874B1 KR 1020177020266 A KR1020177020266 A KR 1020177020266A KR 20177020266 A KR20177020266 A KR 20177020266A KR 102554874 B1 KR102554874 B1 KR 102554874B1
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- South Korea
- Prior art keywords
- catalyst
- zone
- reactor
- bis
- indenyl
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
- C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00743—Feeding or discharging of solids
- B01J2208/00752—Feeding
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP14199694 | 2014-12-22 | ||
| EP14199694.2 | 2014-12-22 | ||
| PCT/EP2015/080946 WO2016102548A1 (en) | 2014-12-22 | 2015-12-22 | Process for transitioning between incompatible catalysts |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20170109547A KR20170109547A (ko) | 2017-09-29 |
| KR102554874B1 true KR102554874B1 (ko) | 2023-07-12 |
Family
ID=52349945
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020177020266A Active KR102554874B1 (ko) | 2014-12-22 | 2015-12-22 | 비융화성 촉매 간의 전환 방법 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9944727B2 (enExample) |
| EP (1) | EP3237459B1 (enExample) |
| JP (1) | JP6761810B2 (enExample) |
| KR (1) | KR102554874B1 (enExample) |
| CN (1) | CN107207649B (enExample) |
| BR (1) | BR112017013272A2 (enExample) |
| EA (1) | EA032875B1 (enExample) |
| SA (1) | SA517381799B1 (enExample) |
| WO (1) | WO2016102548A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10822433B2 (en) * | 2015-12-22 | 2020-11-03 | Sabic Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| CN108884179B (zh) * | 2016-04-20 | 2021-09-21 | 尤尼威蒂恩技术有限责任公司 | 聚合物流动指数改性剂 |
| US11384166B2 (en) * | 2016-09-08 | 2022-07-12 | Sabic Global Technologies B.V. | Process of preparing polyolefin with the discontinuous addition of a thermal runaway reducing agent |
| US11584847B2 (en) * | 2017-12-22 | 2023-02-21 | Sabic Global Technologies B.V. | Polypropylene composition for tapes |
| KR102060531B1 (ko) * | 2018-07-20 | 2020-02-11 | 금호석유화학 주식회사 | 고무 조성물의 제조방법 |
| KR102778829B1 (ko) * | 2019-11-29 | 2025-03-12 | 롯데케미칼 주식회사 | 폴리올레핀 제조방법 |
| CN114621370B (zh) * | 2020-12-10 | 2023-11-28 | 中国石油天然气股份有限公司 | 一种气相法聚乙烯钛系向铬系催化剂在线快速切换方法 |
| CN114621371B (zh) * | 2020-12-10 | 2023-11-28 | 中国石油天然气股份有限公司 | 气相法聚乙烯茂金属催化剂向铬系催化剂在线快速切换方法 |
| CN114621369B (zh) * | 2020-12-10 | 2023-11-28 | 中国石油天然气股份有限公司 | 乙烯气相聚合牌号切换剂及其制备方法 |
| EP4330294A1 (en) * | 2021-04-30 | 2024-03-06 | ExxonMobil Chemical Patents Inc. | Processes for transitioning between different polymerization catalysts in a polymerization reactor |
| CN113578205B (zh) * | 2021-09-29 | 2021-12-03 | 东营科宏化工有限公司 | 邻叔丁基环己醇制备用催化剂的添加装置及添加方法 |
| CN117567676B (zh) * | 2024-01-16 | 2024-04-16 | 新疆独山子石油化工有限公司 | 一种钛系聚乙烯转产茂金属聚乙烯的生产方法 |
| CN117567675B (zh) * | 2024-01-16 | 2024-04-23 | 新疆独山子石油化工有限公司 | 一种铬系聚乙烯转产茂金属聚乙烯的生产方法 |
| CN119306873A (zh) * | 2024-12-16 | 2025-01-14 | 新疆独山子石油化工有限公司 | 减少钛系聚乙烯转产聚烯烃弹性体中过渡料的生产方法 |
| CN119306870A (zh) * | 2024-12-16 | 2025-01-14 | 新疆独山子石油化工有限公司 | 铬系聚乙烯转产聚烯烃弹性体的生产方法 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100389180B1 (ko) * | 1994-03-25 | 2004-03-30 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 비상용성 중합 촉매들간의 전이방법 |
| WO2013097936A1 (en) | 2011-12-28 | 2013-07-04 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
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| US3450183A (en) | 1964-10-02 | 1969-06-17 | Phillips Petroleum Co | Polymer recovery apparatus |
| US3594356A (en) | 1967-04-24 | 1971-07-20 | Phillips Petroleum Co | Polymer recovery process and apparatus |
| US4003712A (en) | 1970-07-29 | 1977-01-18 | Union Carbide Corporation | Fluidized bed reactor |
| US3687920A (en) | 1971-01-25 | 1972-08-29 | Union Carbide Corp | Polymerization of olefins with silane modified catalyst system |
| US4086408A (en) | 1973-12-20 | 1978-04-25 | Union Carbide Corporation | Ethylene polymerization with silane modified catalyst |
| LU70739A1 (enExample) | 1974-08-14 | 1976-08-19 | ||
| US4011382A (en) | 1975-03-10 | 1977-03-08 | Union Carbide Corporation | Preparation of low and medium density ethylene polymer in fluid bed reactor |
| GB1582955A (en) | 1976-07-28 | 1981-01-21 | Boc Ltd | Condensation of the vapour of a volatile liquid |
| US4101445A (en) | 1976-09-22 | 1978-07-18 | Union Carbide Corporation | Preparation of modified and activated chromocene catalysts for ethylene polymerization |
| US4302566A (en) | 1978-03-31 | 1981-11-24 | Union Carbide Corporation | Preparation of ethylene copolymers in fluid bed reactor |
| US4482687A (en) | 1979-10-26 | 1984-11-13 | Union Carbide Corporation | Preparation of low-density ethylene copolymers in fluid bed reactor |
| US4372758A (en) | 1980-09-02 | 1983-02-08 | Union Carbide Corporation | Degassing process for removing unpolymerized monomers from olefin polymers |
| US5019633A (en) | 1980-12-24 | 1991-05-28 | Technology Corporation | Catalyst composition for polymerizing ethylene |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4460755A (en) | 1982-09-30 | 1984-07-17 | Union Carbide Corporation | Direct conversion of a polymerization reaction catalyzed by a Ziegler-type catalyst into one catalyzed by a chromium-based catalyst |
| US4560671A (en) | 1983-07-01 | 1985-12-24 | Union Carbide Corporation | Olefin polymerization catalysts adapted for gas phase processes |
| US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| US4755495A (en) | 1986-02-27 | 1988-07-05 | Union Carbide Corporation | Process for activation of titanium and vanadium catalysts useful in ethylene polymerization |
| US4719193A (en) | 1986-09-30 | 1988-01-12 | Union Carbide Corporation | Processes for preparing polyethylene catalysts by heating catalyst precursors |
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| FR2618786B1 (fr) | 1987-07-31 | 1989-12-01 | Bp Chimie Sa | Procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
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| JP2006512446A (ja) | 2002-12-27 | 2006-04-13 | ユニベーション・テクノロジーズ・エルエルシー | チーグラー・ナッタ重合触媒とアルモキサンベースのシングルサイト重合触媒との間の移行方法 |
| US6858684B2 (en) | 2002-12-30 | 2005-02-22 | Univation Technologies, Llc | Processes for transitioning between various polymerization catalysts |
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| ES2353894T3 (es) * | 2004-12-21 | 2011-03-08 | Univation Technologies, Llc | Procedimiento de transición entre catalizadores a base de ziegler-natta y a base de cromo. |
| US7629422B2 (en) * | 2004-12-21 | 2009-12-08 | Univation Technologies, Llc | Process for transitioning between Ziegler-Natta-based and chromium-based catalysts |
| EP1731535A1 (en) * | 2005-06-07 | 2006-12-13 | Saudi Basic Industries Corporation Inc. | Process for polymerization of olefins |
| KR20160095020A (ko) | 2013-11-29 | 2016-08-10 | 사우디 베이식 인더스트리즈 코포레이션 | 알파 올레핀 단량체의 연속 중합용 다중구역 반응기 |
-
2015
- 2015-12-22 US US15/537,997 patent/US9944727B2/en active Active
- 2015-12-22 EA EA201791431A patent/EA032875B1/ru not_active IP Right Cessation
- 2015-12-22 EP EP15817346.8A patent/EP3237459B1/en active Active
- 2015-12-22 WO PCT/EP2015/080946 patent/WO2016102548A1/en not_active Ceased
- 2015-12-22 KR KR1020177020266A patent/KR102554874B1/ko active Active
- 2015-12-22 CN CN201580075645.4A patent/CN107207649B/zh active Active
- 2015-12-22 BR BR112017013272A patent/BR112017013272A2/pt not_active Application Discontinuation
- 2015-12-22 JP JP2017551361A patent/JP6761810B2/ja active Active
-
2017
- 2017-06-22 SA SA517381799A patent/SA517381799B1/ar unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100389180B1 (ko) * | 1994-03-25 | 2004-03-30 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 비상용성 중합 촉매들간의 전이방법 |
| WO2013097936A1 (en) | 2011-12-28 | 2013-07-04 | Saudi Basic Industries Corporation | Catalyst composition and method for preparing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| EA032875B1 (ru) | 2019-07-31 |
| SA517381799B1 (ar) | 2021-04-01 |
| EP3237459A1 (en) | 2017-11-01 |
| EP3237459B1 (en) | 2019-01-30 |
| JP6761810B2 (ja) | 2020-09-30 |
| JP2018502210A (ja) | 2018-01-25 |
| CN107207649A (zh) | 2017-09-26 |
| US20170342174A1 (en) | 2017-11-30 |
| US9944727B2 (en) | 2018-04-17 |
| KR20170109547A (ko) | 2017-09-29 |
| EA201791431A1 (ru) | 2018-01-31 |
| BR112017013272A2 (pt) | 2018-01-09 |
| CN107207649B (zh) | 2020-06-23 |
| WO2016102548A1 (en) | 2016-06-30 |
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