KR102490098B1 - 프탈레이트 화합물의 수소화 방법 - Google Patents

프탈레이트 화합물의 수소화 방법 Download PDF

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Publication number
KR102490098B1
KR102490098B1 KR1020190126748A KR20190126748A KR102490098B1 KR 102490098 B1 KR102490098 B1 KR 102490098B1 KR 1020190126748 A KR1020190126748 A KR 1020190126748A KR 20190126748 A KR20190126748 A KR 20190126748A KR 102490098 B1 KR102490098 B1 KR 102490098B1
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KR
South Korea
Prior art keywords
raw material
reaction
phthalate
reactor
hydrogenation
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KR1020190126748A
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English (en)
Korean (ko)
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KR20210043880A (ko
Inventor
김효석
정기택
박성민
이경일
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한화솔루션 주식회사
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Priority to KR1020190126748A priority Critical patent/KR102490098B1/ko
Priority to PCT/KR2020/010583 priority patent/WO2021075686A1/ko
Priority to TW109127679A priority patent/TWI747441B/zh
Publication of KR20210043880A publication Critical patent/KR20210043880A/ko
Application granted granted Critical
Publication of KR102490098B1 publication Critical patent/KR102490098B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/303—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by hydrogenation of unsaturated carbon-to-carbon bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1806—Stationary reactors having moving elements inside resulting in a turbulent flow of the reactants, such as in centrifugal-type reactors, or having a high Reynolds-number
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2405—Stationary reactors without moving elements inside provoking a turbulent flow of the reactants, such as in cyclones, or having a high Reynolds-number
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/462—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C69/75—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring of acids with a six-membered ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020190126748A 2019-10-14 2019-10-14 프탈레이트 화합물의 수소화 방법 KR102490098B1 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1020190126748A KR102490098B1 (ko) 2019-10-14 2019-10-14 프탈레이트 화합물의 수소화 방법
PCT/KR2020/010583 WO2021075686A1 (ko) 2019-10-14 2020-08-11 프탈레이트 화합물의 수소화 방법
TW109127679A TWI747441B (zh) 2019-10-14 2020-08-14 苯二甲酸酯化合物的氫化方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020190126748A KR102490098B1 (ko) 2019-10-14 2019-10-14 프탈레이트 화합물의 수소화 방법

Publications (2)

Publication Number Publication Date
KR20210043880A KR20210043880A (ko) 2021-04-22
KR102490098B1 true KR102490098B1 (ko) 2023-01-18

Family

ID=75538158

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020190126748A KR102490098B1 (ko) 2019-10-14 2019-10-14 프탈레이트 화합물의 수소화 방법

Country Status (3)

Country Link
KR (1) KR102490098B1 (zh)
TW (1) TWI747441B (zh)
WO (1) WO2021075686A1 (zh)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140148613A1 (en) 2010-09-20 2014-05-29 ExxonMobil Chemical Patents Inc. - Law Technology Process for Liquid Phase Hydrogenation of Phthalates
JP2014524932A (ja) * 2011-07-29 2014-09-25 イーストマン ケミカル カンパニー テレフタル酸からの１，４−シクロヘキサンジメタノールの調製方法
KR101550765B1 (ko) 2014-09-03 2015-09-18 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법
JP2016069587A (ja) 2014-10-01 2016-05-09 リケンテクノス株式会社 塩化ビニル系樹脂組成物
JP2016141729A (ja) 2015-02-02 2016-08-08 新日本理化株式会社 シクロヘキサンジカルボン酸ジエステルからなる塩化ビニル系樹脂用可塑剤
KR101797220B1 (ko) 2015-08-27 2017-11-13 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102753266B (zh) * 2009-12-15 2015-09-02 巴斯夫欧洲公司 用于氢化芳族化合物的催化剂和方法
KR101489040B1 (ko) * 2012-10-29 2015-02-04 주식회사 엘지화학 알데히드의 수소화 처리방법
KR101556340B1 (ko) * 2013-12-19 2015-09-30 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법
WO2015093849A1 (ko) * 2013-12-19 2015-06-25 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법
KR20160076320A (ko) * 2014-12-22 2016-06-30 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법 및 장치
KR101905165B1 (ko) * 2015-04-01 2018-10-05 한화케미칼 주식회사 프탈레이트 화합물의 수소화 촉매의 재생 방법
CN109675453B (zh) * 2017-10-19 2021-05-04 中国石油化工股份有限公司 一种气液混合设备及应用
KR102506281B1 (ko) * 2017-11-29 2023-03-06 한화솔루션 주식회사 프탈레이트 화합물의 수소화 방법
KR102458721B1 (ko) * 2017-11-29 2022-10-26 한화솔루션 주식회사 프탈레이트 화합물의 수소화 방법
KR102496349B1 (ko) * 2017-11-29 2023-02-03 한화솔루션 주식회사 프탈레이트 화합물의 수소화 방법

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140148613A1 (en) 2010-09-20 2014-05-29 ExxonMobil Chemical Patents Inc. - Law Technology Process for Liquid Phase Hydrogenation of Phthalates
JP2014524932A (ja) * 2011-07-29 2014-09-25 イーストマン ケミカル カンパニー テレフタル酸からの１，４−シクロヘキサンジメタノールの調製方法
KR101550765B1 (ko) 2014-09-03 2015-09-18 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법
JP2016069587A (ja) 2014-10-01 2016-05-09 リケンテクノス株式会社 塩化ビニル系樹脂組成物
JP2016141729A (ja) 2015-02-02 2016-08-08 新日本理化株式会社 シクロヘキサンジカルボン酸ジエステルからなる塩化ビニル系樹脂用可塑剤
KR101797220B1 (ko) 2015-08-27 2017-11-13 한화케미칼 주식회사 프탈레이트 화합물의 수소화 방법

Also Published As

Publication number Publication date
TW202114978A (zh) 2021-04-16
WO2021075686A1 (ko) 2021-04-22
KR20210043880A (ko) 2021-04-22
TWI747441B (zh) 2021-11-21

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