KR102478771B1 - 3d 프린팅 재료로서의 폴리시클로올레핀 단량체 및 광산발생화합물에 의해 활성화하는 촉매 - Google Patents

3d 프린팅 재료로서의 폴리시클로올레핀 단량체 및 광산발생화합물에 의해 활성화하는 촉매 Download PDF

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KR102478771B1
KR102478771B1 KR1020217001421A KR20217001421A KR102478771B1 KR 102478771 B1 KR102478771 B1 KR 102478771B1 KR 1020217001421 A KR1020217001421 A KR 1020217001421A KR 20217001421 A KR20217001421 A KR 20217001421A KR 102478771 B1 KR102478771 B1 KR 102478771B1
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alkyl
aryl
formula
methyl
hept
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KR20210028196A (ko
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올레크산드르 부토비이
매튜 엘. 바르쵸크
웨이 장
래리 에프. 로도스
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스미토모 베이클리트 컴퍼니 리미티드
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
    • C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00—Materials specially adapted for additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0244—Nitrogen containing compounds with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B33—ADDITIVE MANUFACTURING TECHNOLOGY
    • B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00—Processes of additive manufacturing
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/30—Monomer units or repeat units incorporating structural elements in the main chain
    • C08G2261/33—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain
    • C08G2261/332—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms
    • C08G2261/3325—Monomer units or repeat units incorporating structural elements in the main chain incorporating non-aromatic structural elements in the main chain containing only carbon atoms derived from other polycyclic systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/40—Polymerisation processes
    • C08G2261/41—Organometallic coupling reactions
    • C08G2261/418—Ring opening metathesis polymerisation [ROMP]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Manufacturing & Machinery (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
KR1020217001421A 2018-06-29 2019-06-28 3d 프린팅 재료로서의 폴리시클로올레핀 단량체 및 광산발생화합물에 의해 활성화하는 촉매 Active KR102478771B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201862691833P 2018-06-29 2018-06-29
US62/691,833 2018-06-29
US201962798047P 2019-01-29 2019-01-29
US62/798,047 2019-01-29
US201962831250P 2019-04-09 2019-04-09
US62/831,250 2019-04-09
PCT/US2019/039712 WO2020006345A1 (en) 2018-06-29 2019-06-28 Polycycloolefin monomers and catalyst activated by compound capable of generating photoacid as 3d printing materials

Publications (2)

Publication Number Publication Date
KR20210028196A KR20210028196A (ko) 2021-03-11
KR102478771B1 true KR102478771B1 (ko) 2022-12-19

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KR1020217001421A Active KR102478771B1 (ko) 2018-06-29 2019-06-28 3d 프린팅 재료로서의 폴리시클로올레핀 단량체 및 광산발생화합물에 의해 활성화하는 촉매

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US (1) US11230624B2 (https=)
JP (1) JP7456950B2 (https=)
KR (1) KR102478771B1 (https=)
CN (1) CN112335252B (https=)
TW (1) TWI794520B (https=)
WO (1) WO2020006345A1 (https=)

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US11939410B2 (en) * 2018-06-29 2024-03-26 Apeiron Synthesis S.A. Organoruthenium complexes as precatalysts for olefin metathesis
KR102513170B1 (ko) 2018-12-21 2023-03-24 스미토모 베이클리트 컴퍼니 리미티드 폴리사이클로올레핀 모노머 및 가교제에서 유래하는 고충격 강도의 3d 인쇄 재료
WO2021072206A1 (en) 2019-10-10 2021-04-15 PolySpectra, Inc. Olefin metathesis photopolymers
TWI848199B (zh) * 2020-01-02 2024-07-11 日商住友電木股份有限公司 作為光學材料之保存期限延長的本體聚合型多環烯烴組成物
TWI834019B (zh) * 2020-01-09 2024-03-01 日商住友電木股份有限公司 作為3d列印材料之穩定本體聚合型多環烯烴組成物及其製備方法
US20230078824A1 (en) * 2020-02-28 2023-03-16 Carbon, Inc. Methods of making a three-dimensional object
US12435163B2 (en) * 2020-04-01 2025-10-07 3M Innovative Properties Company Compositions comprising romp catalyst and dispersant, cartridges, and methods
JP7762668B2 (ja) 2020-06-10 2025-10-30 インクビット， エルエルシー 光開始カチオン開環重合用材料及びその用途
EP4225824A4 (en) * 2020-10-09 2024-10-30 Polyspectra, Inc. ORAL PRODUCTS AND THEIR PRODUCTION PROCESSES
US11718710B2 (en) * 2020-10-14 2023-08-08 The Board Of Trustees Of The University Of Illinois Method of light-promoted frontal ring-opening metathesis polymerization
WO2022167944A1 (en) * 2021-02-02 2022-08-11 Apeiron Synthesis S.A. Long shelf life stable organoruthenium complexes as (pre)catalysts for olefin metathesis
CN116848170A (zh) * 2021-02-02 2023-10-03 普罗米鲁斯有限责任公司 作为光学材料的保存期限长期稳定的光活性本体聚合型多环烯烃组合物
TWI895585B (zh) 2021-02-02 2025-09-01 日商住友電木股份有限公司 作為光學材料之保存期限長期穩定的光活性本體聚合型多環烯烴組成物
US11840586B2 (en) 2021-03-08 2023-12-12 National Technology & Engineering Solutions Of Sandia, Llc Use of latent metathesis polymerization systems for additive manufacturing
KR20240052050A (ko) 2021-08-31 2024-04-22 메르크 파텐트 게엠베하 조성물
JP2025534788A (ja) 2022-10-21 2025-10-17 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフツング 組成物
WO2025012183A1 (en) 2023-07-10 2025-01-16 Merck Patent Gmbh Composition

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US20050040564A1 (en) 2003-08-18 2005-02-24 Jones Oliver Systems and methods for using norbornene based curable materials
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US20020008333A1 (en) 2000-03-13 2002-01-24 Eduardo Napadensky Compositions and methods for use in three dimensional model printing
US20050040564A1 (en) 2003-08-18 2005-02-24 Jones Oliver Systems and methods for using norbornene based curable materials
JP2010260916A (ja) 2009-04-30 2010-11-18 Sumitomo Bakelite Co Ltd 感光性組成物、光導波路、光配線、光電気混載基板、電子機器、および光導波路の形成方法
WO2016063282A1 (en) 2014-10-21 2016-04-28 Stratasys Ltd. Three-dimensional inkjet printing using ring-opening metathesis polymerization

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CN112335252A (zh) 2021-02-05
JP7456950B2 (ja) 2024-03-27
JP2021529855A (ja) 2021-11-04
KR20210028196A (ko) 2021-03-11
CN112335252B (zh) 2023-07-04
WO2020006345A1 (en) 2020-01-02
US11230624B2 (en) 2022-01-25
US20200002466A1 (en) 2020-01-02
TW202000722A (zh) 2020-01-01
TWI794520B (zh) 2023-03-01

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