KR102267815B1 - 방오성이 개선된 셸 앤드 튜브형 산화 반응기 - Google Patents

방오성이 개선된 셸 앤드 튜브형 산화 반응기 Download PDF

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KR102267815B1
KR102267815B1 KR1020207016530A KR20207016530A KR102267815B1 KR 102267815 B1 KR102267815 B1 KR 102267815B1 KR 1020207016530 A KR1020207016530 A KR 1020207016530A KR 20207016530 A KR20207016530 A KR 20207016530A KR 102267815 B1 KR102267815 B1 KR 102267815B1
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reactor
tubes
catalyst
tube
interstage
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KR20200070429A (ko
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마이클 에스. 드커시
존 엘. 스테인바흐
니콜라 뒤퐁
로저 엘. 라운디
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알케마 인코포레이티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/065—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J15/00—Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor
    • B01J15/005—Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0046—Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J19/2415—Tubular reactors
    • B01J19/242—Tubular reactors in series
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/00849—Stationary elements outside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00893—Feeding means for the reactants
    • B01J2208/0092—Perforated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2219/00274—Sequential or parallel reactions; Apparatus and devices for combinatorial chemistry or for making arrays; Chemical library technology
    • B01J2219/00277—Apparatus
    • B01J2219/00479—Means for mixing reactants or products in the reaction vessels
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2219/00495—Means for heating or cooling the reaction vessels
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
    • B01J8/048—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being superimposed one above the other
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D21/0001—Recuperative heat exchangers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
KR1020207016530A 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기 Active KR102267815B1 (ko)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US201261704636P 2012-09-24 2012-09-24
US61/704,636 2012-09-24
US13/652,522 2012-10-16
US13/652,522 US9440903B2 (en) 2012-09-24 2012-10-16 Shell and tube oxidation reactor with improved resistance to fouling
KR1020157010626A KR102123219B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기
PCT/US2013/055689 WO2014046829A2 (en) 2012-09-24 2013-08-20 Shell and tube oxidation reactor with improved resistance to fouling

Related Parent Applications (1)

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KR1020157010626A Division KR102123219B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기

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KR20200070429A KR20200070429A (ko) 2020-06-17
KR102267815B1 true KR102267815B1 (ko) 2021-06-23

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KR1020207016562A Active KR102267820B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기
KR1020207016530A Active KR102267815B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기

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KR1020207016562A Active KR102267820B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기

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US (4) US9440903B2 (enExample)
EP (2) EP3682967B1 (enExample)
JP (3) JP6290219B2 (enExample)
KR (3) KR102123219B1 (enExample)
CN (2) CN104661738B (enExample)
BR (1) BR112015006503B1 (enExample)
MX (1) MX341436B (enExample)
MY (1) MY175594A (enExample)
SA (1) SA515360178B1 (enExample)
SG (3) SG10201610892QA (enExample)
TW (2) TWI583447B (enExample)
WO (1) WO2014046829A2 (enExample)
ZA (1) ZA201501789B (enExample)

Families Citing this family (30)

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Publication number Priority date Publication date Assignee Title
US9134064B2 (en) * 2013-10-04 2015-09-15 Aggreko, Llc Process vessel cooldown apparatus and method
WO2017035055A1 (en) 2015-08-24 2017-03-02 Rohm And Haas Company Method of determining the inertness of materials for use in monomer production
BR112018002554B1 (pt) 2015-08-24 2021-07-13 Rohm And Haas Company Método de determinação da inércia de materiais para uso na produção de monômero
CN108290130B (zh) * 2015-11-09 2021-07-13 国际壳牌研究有限公司 易清洗的催化剂滤筐
WO2017089935A1 (en) 2015-11-23 2017-06-01 Sabic Global Technologies B.V. Structural catalyst with internal heat transfer system for exothermic and endothermic reactions
WO2017184496A1 (en) 2016-04-21 2017-10-26 Rohm And Haas Company Methods for using macroporous inert materials in monomer production
EP3296255A1 (de) * 2016-09-14 2018-03-21 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Reformerrohr mit strukturiertem katalysator und verbessertem wärmehaushalt
US10981735B2 (en) * 2017-05-16 2021-04-20 Sumitomo Chemical Company, Limited Pneumatic conveyance method for methionine
CN107638852B (zh) * 2017-10-17 2019-12-03 龙星化工股份有限公司 一种氟化工裂解炉
EP3476470B1 (en) 2017-10-26 2022-11-09 ALFA LAVAL OLMI S.p.A. Shell-and-tube equipment with distribution device
CN108398040B (zh) * 2018-05-02 2024-01-12 江苏远方涂装环保科技有限公司 旋转换热器
CN109293407B (zh) * 2018-11-20 2021-10-15 大连理工大学 一种厨余垃圾快速制肥装置及方法
CN111249999A (zh) * 2018-11-30 2020-06-09 中国科学院大连化学物理研究所 一种用于硝酸肼催化还原六价铀的固定床反应器及应用
CN110496572B (zh) * 2019-08-01 2021-08-31 江苏科圣化工机械有限公司 有机硅流化床反应器管束支撑格栅及其制造方法
US11891302B2 (en) * 2020-03-17 2024-02-06 Bayotech, Inc. Hydrogen generation systems
JP7467192B2 (ja) * 2020-03-25 2024-04-15 三菱重工業株式会社 ガス状生成物を得るための装置およびガス状生成物を得るための方法
EP3892367A1 (en) * 2020-04-09 2021-10-13 Röhm GmbH A tube bundle reactor and method for the production of methacrylic acid through the partial oxidation of methacrolein
CN111544921B (zh) * 2020-06-29 2020-10-16 天津乐科节能科技有限公司 一种自回热连续熔融结晶系统及方法
CN111849563B (zh) * 2020-07-30 2025-01-07 中冶焦耐(大连)工程技术有限公司 一种干式多通道煤气净化塔及其工作方法
CN112007587B (zh) * 2020-10-22 2021-01-22 山东神驰石化有限公司 一种烷烃催化脱氢立式固定床反应器
KR20240006646A (ko) 2021-05-11 2024-01-15 알케마 인코포레이티드 열 교환기의 튜브 시트를 모니터링하기 위한 방법
WO2022240723A2 (en) 2021-05-11 2022-11-17 Arkema Inc. Method for monitoring a tube sheet of a heat exchanger
WO2022251737A1 (en) * 2021-05-28 2022-12-01 Eaton Gerald B System and method for producing ultra-high molecular weight polyalphaolefins for use as pipeline drag reducing agents
US12409426B2 (en) 2021-11-22 2025-09-09 Schneider Electric Systems Usa, Inc. Direct electrical heating of process heater tubes using galvanic isolation techniques
JP2025515082A (ja) * 2022-05-04 2025-05-13 ノバ ケミカルズ（インターナショナル）ソシエテ アノニム エタンの酸化的脱水素化（ｏｄｈ）のための反応器システム
KR20250077577A (ko) * 2022-09-29 2025-05-30 유로떼름 오또마씨옹 에스아에스 갈바닉 절연 기술을 사용한 공정 히터 튜브의 직접 전기 가열
WO2024080208A1 (ja) * 2022-10-12 2024-04-18 日本化薬株式会社 不飽和アルデヒドの製造方法および不飽和アルデヒドの製造装置
EP4603472A1 (en) * 2022-10-12 2025-08-20 Nippon Kayaku Kabushiki Kaisha Method for producing unsaturated aldehyde, and apparatus for producing unsaturated aldehyde
CN117049685B (zh) * 2023-08-29 2024-03-26 江苏易简环保科技有限公司 一种高效催化氧化装置
JP2025110559A (ja) * 2024-01-16 2025-07-29 日本特殊陶業株式会社 反応装置

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060099131A1 (en) 2004-11-03 2006-05-11 Kellogg Brown And Root, Inc. Maximum reaction rate converter system for exothermic reactions
US20080021242A1 (en) 2006-07-19 2008-01-24 Michio Tanimoto Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it
US20090253934A1 (en) 2006-09-15 2009-10-08 Fungau Ho Process for Producing Acrylic Acid

Family Cites Families (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2238851B2 (de) * 1972-08-07 1979-08-30 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Acrolein und/oder Acrylsäure unter Vermeidung von Nachreaktionen bei der katalytischen Oxidation von Propylen und/oder Acrolein
US4029636A (en) 1974-11-12 1977-06-14 Celanese Corporation Method for reducing molybdenum trioxide content of gases issuing from reactors containing molybdenum-based catalysts
JPS52108917A (en) 1976-03-11 1977-09-12 Nippon Shokubai Kagaku Kogyo Co Ltd Preparation of acrylic acid by vapor-phase catalytic oxidation of prop ylene
US4201736A (en) 1977-07-26 1980-05-06 Bott Theodore R Fluid distribution and contacting elements
JPS5673041A (en) * 1979-11-19 1981-06-17 Mitsubishi Petrochem Co Ltd Preparation of acrylic acid
US4518574A (en) * 1983-03-07 1985-05-21 Exxon Research & Engineering Co. Catalytic gas synthesis process
DE4308087C2 (de) 1993-03-13 1997-02-06 Basf Ag Verfahren zur Abtrennung von Acrylsäure aus den Reaktionsgasen der katalytischen Oxidation von Propylen und/oder Acrolein
JP3948798B2 (ja) 1997-10-27 2007-07-25 株式会社日本触媒 アクリル酸の製造方法
US6384274B1 (en) 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
TW527218B (en) 1999-03-16 2003-04-11 Basf Ag Multitube reactor, especially for catalytic gas-phase reactions
US6639106B1 (en) 1999-07-23 2003-10-28 Rohm And Haas Company Process for preparing and purifying acrylic acid from propylene having improved capacity
EP1104822B1 (en) 1999-11-17 2007-02-14 Kao Corporation Method for producing pulp molded articles
DE10000584A1 (de) * 2000-01-10 2001-07-12 Basf Ag Verfahren zur katalytischen Gasphasenoxidation zu Maleinsäureanhydrid
JP4325146B2 (ja) 2002-03-11 2009-09-02 三菱化学株式会社 （メタ）アクリル酸類の製造方法
JP3908118B2 (ja) 2002-08-08 2007-04-25 株式会社日本触媒 アクリル酸の製造方法
DE10258180A1 (de) * 2002-12-12 2004-06-24 Basf Ag Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff
WO2005040084A1 (en) 2003-09-24 2005-05-06 Dow Global Technologies Inc. Metal surfaces to inhibit ethylenically unsaturated monomer polymerization
CN100491302C (zh) 2003-12-24 2009-05-27 Lg;化学株式会社 在具有提高热控制系统的固定床催化部分氧化反应器中制备不饱和酸的方法
DE102004018267B4 (de) * 2004-04-15 2007-05-03 Man Dwe Gmbh Reaktoranordnung zur Durchführung katalytischer Gasphasenreaktionen
DE102005020942A1 (de) 2005-05-04 2006-11-09 Linde Ag Gas-Gas-Mischer
KR100868454B1 (ko) * 2005-07-08 2008-11-11 주식회사 엘지화학 고정층 촉매 부분산화 반응기에서 고효율의 불포화산의제조방법
US7491368B2 (en) * 2005-07-14 2009-02-17 Equistar Chemicals, Lp Method for temporary closing and reopening of a reactor tube
FR2897059B1 (fr) 2006-02-07 2008-04-18 Arkema Sa Procede de preparation d'acide acrylique
JP5171031B2 (ja) * 2006-07-19 2013-03-27 株式会社日本触媒 接触気相酸化用反応器およびそれを用いたアクリル酸の製造方法
TWI373375B (en) 2007-03-01 2012-10-01 Rohm & Haas Apparatus and method for dislodging and extracting solid materials from tubes
KR100942648B1 (ko) * 2007-04-03 2010-02-17 주식회사 엘지화학 고정층 촉매 부분 산화 반응기를 이용한 불포화 알데히드및/또는 불포화 지방산의 제조방법
DE102007019597A1 (de) 2007-04-24 2008-05-15 Basf Ag Verfahren der Inbetriebnahme einer heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure oder von Methacrolein zu Methacrylsäure
RU2440400C2 (ru) * 2010-02-01 2012-01-20 Инфра Текнолоджиз Лтд Способ получения синтетических жидких углеводородов и реактор для проведения синтеза фишера-тропша

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060099131A1 (en) 2004-11-03 2006-05-11 Kellogg Brown And Root, Inc. Maximum reaction rate converter system for exothermic reactions
US20080021242A1 (en) 2006-07-19 2008-01-24 Michio Tanimoto Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it
US20090253934A1 (en) 2006-09-15 2009-10-08 Fungau Ho Process for Producing Acrylic Acid

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