KR102123219B1 - 방오성이 개선된 셸 앤드 튜브형 산화 반응기 - Google Patents

방오성이 개선된 셸 앤드 튜브형 산화 반응기 Download PDF

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KR102123219B1
KR102123219B1 KR1020157010626A KR20157010626A KR102123219B1 KR 102123219 B1 KR102123219 B1 KR 102123219B1 KR 1020157010626 A KR1020157010626 A KR 1020157010626A KR 20157010626 A KR20157010626 A KR 20157010626A KR 102123219 B1 KR102123219 B1 KR 102123219B1
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reactor
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KR20150060895A (ko
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마이클 에스. 드커시
존 엘. 스테인바흐
니콜라 뒤퐁
로저 엘. 라운디
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알케마 인코포레이티드
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J15/00—Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor
    • B01J15/005—Chemical processes in general for reacting gaseous media with non-particulate solids, e.g. sheet material; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0046—Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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    • B01J19/2415—Tubular reactors
    • B01J19/242—Tubular reactors in series
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    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/065—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
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    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
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    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00823—Mixing elements
    • B01J2208/00831—Stationary elements
    • B01J2208/00849—Stationary elements outside the bed, e.g. baffles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00893—Feeding means for the reactants
    • B01J2208/0092—Perforated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023—Details
    • B01J2208/024—Particulate material
    • B01J2208/025—Two or more types of catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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    • B01J2219/00277—Apparatus
    • B01J2219/00479—Means for mixing reactants or products in the reaction vessels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2219/00277—Apparatus
    • B01J2219/00495—Means for heating or cooling the reaction vessels
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    • B01J2219/302—Basic shape of the elements
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    • B01J8/048—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being superimposed one above the other
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
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    • F28D21/0001—Recuperative heat exchangers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020157010626A 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기 Active KR102123219B1 (ko)

Priority Applications (2)

Application Number Priority Date Filing Date Title
KR1020207016562A KR102267820B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기
KR1020207016530A KR102267815B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261704636P 2012-09-24 2012-09-24
US61/704,636 2012-09-24
US13/652,522 2012-10-16
US13/652,522 US9440903B2 (en) 2012-09-24 2012-10-16 Shell and tube oxidation reactor with improved resistance to fouling
PCT/US2013/055689 WO2014046829A2 (en) 2012-09-24 2013-08-20 Shell and tube oxidation reactor with improved resistance to fouling

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KR1020207016562A Division KR102267820B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기
KR1020207016530A Division KR102267815B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기

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KR20150060895A KR20150060895A (ko) 2015-06-03
KR102123219B1 true KR102123219B1 (ko) 2020-06-16

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KR1020207016562A Active KR102267820B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기
KR1020157010626A Active KR102123219B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기

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KR1020207016562A Active KR102267820B1 (ko) 2012-09-24 2013-08-20 방오성이 개선된 셸 앤드 튜브형 산화 반응기

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US (4) US9440903B2 (enExample)
EP (2) EP3682967B1 (enExample)
JP (3) JP6290219B2 (enExample)
KR (3) KR102267815B1 (enExample)
CN (2) CN106955646B (enExample)
BR (1) BR112015006503B1 (enExample)
MX (1) MX341436B (enExample)
MY (1) MY175594A (enExample)
SA (1) SA515360178B1 (enExample)
SG (3) SG10201911923SA (enExample)
TW (2) TWI626988B (enExample)
WO (1) WO2014046829A2 (enExample)
ZA (1) ZA201501789B (enExample)

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US9134064B2 (en) * 2013-10-04 2015-09-15 Aggreko, Llc Process vessel cooldown apparatus and method
EP3341351B1 (en) 2015-08-24 2019-10-02 Rohm and Haas Company Method of determining the inertness of materials for use in monomer production
JP6799581B2 (ja) 2015-08-24 2020-12-16 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ モノマー生成で使用するための材料の不活性度を決定する方法
US10562002B2 (en) * 2015-11-09 2020-02-18 Shell Oil Company Easy clean catalyst filter basket
WO2017089935A1 (en) 2015-11-23 2017-06-01 Sabic Global Technologies B.V. Structural catalyst with internal heat transfer system for exothermic and endothermic reactions
US10577299B2 (en) 2016-04-21 2020-03-03 Rohm And Haas Company Methods for using macroporous inert materials in monomer production
EP3296255A1 (de) * 2016-09-14 2018-03-21 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Reformerrohr mit strukturiertem katalysator und verbessertem wärmehaushalt
CN110621657B (zh) * 2017-05-16 2021-08-13 住友化学株式会社 甲硫氨酸的气流传送方法
CN107638852B (zh) * 2017-10-17 2019-12-03 龙星化工股份有限公司 一种氟化工裂解炉
EP3476470B1 (en) 2017-10-26 2022-11-09 ALFA LAVAL OLMI S.p.A. Shell-and-tube equipment with distribution device
CN108398040B (zh) * 2018-05-02 2024-01-12 江苏远方涂装环保科技有限公司 旋转换热器
CN109293407B (zh) * 2018-11-20 2021-10-15 大连理工大学 一种厨余垃圾快速制肥装置及方法
CN111249999A (zh) * 2018-11-30 2020-06-09 中国科学院大连化学物理研究所 一种用于硝酸肼催化还原六价铀的固定床反应器及应用
CN110496572B (zh) * 2019-08-01 2021-08-31 江苏科圣化工机械有限公司 有机硅流化床反应器管束支撑格栅及其制造方法
US11891302B2 (en) 2020-03-17 2024-02-06 Bayotech, Inc. Hydrogen generation systems
JP7467192B2 (ja) * 2020-03-25 2024-04-15 三菱重工業株式会社 ガス状生成物を得るための装置およびガス状生成物を得るための方法
EP3892367A1 (en) * 2020-04-09 2021-10-13 Röhm GmbH A tube bundle reactor and method for the production of methacrylic acid through the partial oxidation of methacrolein
CN111544921B (zh) * 2020-06-29 2020-10-16 天津乐科节能科技有限公司 一种自回热连续熔融结晶系统及方法
CN111849563B (zh) * 2020-07-30 2025-01-07 中冶焦耐(大连)工程技术有限公司 一种干式多通道煤气净化塔及其工作方法
CN112007587B (zh) * 2020-10-22 2021-01-22 山东神驰石化有限公司 一种烷烃催化脱氢立式固定床反应器
WO2022240737A1 (en) 2021-05-11 2022-11-17 Arkema Inc. Method for monitoring a tube sheet of a heat exchanger
CN117642257A (zh) 2021-05-11 2024-03-01 阿科玛股份有限公司 用于监测热交换器的管片的方法
WO2022251737A1 (en) * 2021-05-28 2022-12-01 Eaton Gerald B System and method for producing ultra-high molecular weight polyalphaolefins for use as pipeline drag reducing agents
US12409426B2 (en) 2021-11-22 2025-09-09 Schneider Electric Systems Usa, Inc. Direct electrical heating of process heater tubes using galvanic isolation techniques
WO2023214222A1 (en) * 2022-05-04 2023-11-09 Nova Chemicals (International) S.A. Reactor systems for oxidative dehydrogenation (odh) of ethane
EP4594000A1 (en) * 2022-09-29 2025-08-06 Schneider Electric Systems USA, Inc. Direct electrical heating of process heaters tubes using galvanic isolation techniques
JP7551027B2 (ja) * 2022-10-12 2024-09-13 日本化薬株式会社 不飽和アルデヒドの製造方法および不飽和アルデヒドの製造装置
CN119948003A (zh) * 2022-10-12 2025-05-06 日本化药株式会社 不饱和醛的制造方法和不饱和醛的制造装置
CN117049685B (zh) * 2023-08-29 2024-03-26 江苏易简环保科技有限公司 一种高效催化氧化装置
JP2025110559A (ja) * 2024-01-16 2025-07-29 日本特殊陶業株式会社 反応装置

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4518574A (en) 1983-03-07 1985-05-21 Exxon Research & Engineering Co. Catalytic gas synthesis process
US4873368A (en) 1979-11-19 1989-10-10 Mitsubishi Petrochemical Company Limited Process for producing acrylic acid
US6384274B1 (en) 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
US20060099131A1 (en) 2004-11-03 2006-05-11 Kellogg Brown And Root, Inc. Maximum reaction rate converter system for exothermic reactions
US20080021242A1 (en) 2006-07-19 2008-01-24 Michio Tanimoto Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it
US20090253934A1 (en) 2006-09-15 2009-10-08 Fungau Ho Process for Producing Acrylic Acid

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2238851B2 (de) * 1972-08-07 1979-08-30 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Acrolein und/oder Acrylsäure unter Vermeidung von Nachreaktionen bei der katalytischen Oxidation von Propylen und/oder Acrolein
US4029636A (en) 1974-11-12 1977-06-14 Celanese Corporation Method for reducing molybdenum trioxide content of gases issuing from reactors containing molybdenum-based catalysts
JPS52108917A (en) 1976-03-11 1977-09-12 Nippon Shokubai Kagaku Kogyo Co Ltd Preparation of acrylic acid by vapor-phase catalytic oxidation of prop ylene
US4201736A (en) 1977-07-26 1980-05-06 Bott Theodore R Fluid distribution and contacting elements
DE4308087C2 (de) 1993-03-13 1997-02-06 Basf Ag Verfahren zur Abtrennung von Acrylsäure aus den Reaktionsgasen der katalytischen Oxidation von Propylen und/oder Acrolein
JP3948798B2 (ja) * 1997-10-27 2007-07-25 株式会社日本触媒 アクリル酸の製造方法
TW527218B (en) 1999-03-16 2003-04-11 Basf Ag Multitube reactor, especially for catalytic gas-phase reactions
US6639106B1 (en) 1999-07-23 2003-10-28 Rohm And Haas Company Process for preparing and purifying acrylic acid from propylene having improved capacity
EP1104822B1 (en) 1999-11-17 2007-02-14 Kao Corporation Method for producing pulp molded articles
DE10000584A1 (de) * 2000-01-10 2001-07-12 Basf Ag Verfahren zur katalytischen Gasphasenoxidation zu Maleinsäureanhydrid
JP4325146B2 (ja) 2002-03-11 2009-09-02 三菱化学株式会社 （メタ）アクリル酸類の製造方法
JP3908118B2 (ja) 2002-08-08 2007-04-25 株式会社日本触媒 アクリル酸の製造方法
DE10258180A1 (de) * 2002-12-12 2004-06-24 Basf Ag Verfahren zur Herstellung von Chlor durch Gasphasenoxidation von Chlorwasserstoff
EP1667953B1 (en) 2003-09-24 2008-12-10 Dow Global Technologies Inc. Metal surfaces to inhibit ethylenically unsaturated monomer polymerization
TWI288127B (en) * 2003-12-24 2007-10-11 Lg Chemical Ltd Method of producing unsaturated acid in fixed-bed catalytic partial oxidation reactor with enhanced heat control system
DE102004018267B4 (de) * 2004-04-15 2007-05-03 Man Dwe Gmbh Reaktoranordnung zur Durchführung katalytischer Gasphasenreaktionen
DE102005020942A1 (de) 2005-05-04 2006-11-09 Linde Ag Gas-Gas-Mischer
KR100868454B1 (ko) * 2005-07-08 2008-11-11 주식회사 엘지화학 고정층 촉매 부분산화 반응기에서 고효율의 불포화산의제조방법
US7491368B2 (en) * 2005-07-14 2009-02-17 Equistar Chemicals, Lp Method for temporary closing and reopening of a reactor tube
FR2897059B1 (fr) * 2006-02-07 2008-04-18 Arkema Sa Procede de preparation d'acide acrylique
JP5171031B2 (ja) * 2006-07-19 2013-03-27 株式会社日本触媒 接触気相酸化用反応器およびそれを用いたアクリル酸の製造方法
JP5091715B2 (ja) 2007-03-01 2012-12-05 ローム アンド ハース カンパニー 管から固形物を取り外し、抜き出すための装置および方法
BRPI0802625B1 (pt) * 2007-04-03 2017-04-04 Lg Chemical Ltd método para preparar aldeído não-saturado e/ou ácido graxo não-saturado usando reator de oxidação parcial catalítica de leito fixo
DE102007019597A1 (de) * 2007-04-24 2008-05-15 Basf Ag Verfahren der Inbetriebnahme einer heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure oder von Methacrolein zu Methacrylsäure
RU2440400C2 (ru) * 2010-02-01 2012-01-20 Инфра Текнолоджиз Лтд Способ получения синтетических жидких углеводородов и реактор для проведения синтеза фишера-тропша

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4873368A (en) 1979-11-19 1989-10-10 Mitsubishi Petrochemical Company Limited Process for producing acrylic acid
US4518574A (en) 1983-03-07 1985-05-21 Exxon Research & Engineering Co. Catalytic gas synthesis process
US6384274B1 (en) 1998-09-27 2002-05-07 Rohm And Haas Company Single reactor process for preparing acrylic acid from propylene having improved capacity
US20060099131A1 (en) 2004-11-03 2006-05-11 Kellogg Brown And Root, Inc. Maximum reaction rate converter system for exothermic reactions
US20080021242A1 (en) 2006-07-19 2008-01-24 Michio Tanimoto Reactor for gas phase catalytic oxidation and a process for producing acrylic acid using it
US20090253934A1 (en) 2006-09-15 2009-10-08 Fungau Ho Process for Producing Acrylic Acid

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