KR102179873B1 - Anti-Flaming Agent Composition, Anti-Flaming Spray Product and Anti-Flaming Method - Google Patents
Anti-Flaming Agent Composition, Anti-Flaming Spray Product and Anti-Flaming Method Download PDFInfo
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- KR102179873B1 KR102179873B1 KR1020197002439A KR20197002439A KR102179873B1 KR 102179873 B1 KR102179873 B1 KR 102179873B1 KR 1020197002439 A KR1020197002439 A KR 1020197002439A KR 20197002439 A KR20197002439 A KR 20197002439A KR 102179873 B1 KR102179873 B1 KR 102179873B1
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Abstract
유기계의 방미제에 있어서, 종래보다도 우수한 방미 효과를 발휘할 수 있는 방미제 조성물을 제공한다. 트리아졸계 화합물과, 글리콜과, 알코올을 함유하는 방미제 조성물이고, 트리아졸계 화합물은 테부코나졸이며, 글리콜은 프로필렌글리콜 및/또는 1,3-부틸렌글리콜이고, 알코올은 에탄올 및/또는 2-프로판올이며, 트리아졸계 화합물과 글리콜의 배합비(중량비)가 1:10∼1:0.5이고, 소취 성분을 더 함유한다.In the organic-based anti-fog agent, there is provided an anti-fog agent composition capable of exhibiting a better anti-fogging effect than the conventional one. It is a flame retardant composition containing a triazole-based compound, glycol, and alcohol, the triazole-based compound is tebuconazole, the glycol is propylene glycol and/or 1,3-butylene glycol, and the alcohol is ethanol and/or 2-propanol And the triazole-based compound and glycol have a blending ratio (weight ratio) of 1:10 to 1:0.5, and further contain a deodorizing component.
Description
본 발명은, 곰팡이의 발생을 방지하는 방미제(防微劑) 조성물, 방미용 스프레이 제품 및 방미 방법에 관한 것이다.The present invention relates to an anti-fog composition for preventing the occurrence of mold, a spray product for anti-mold, and a method for anti-fog.
최근의 주택은 기밀성이 높고, 실내에 습기가 고여 곰팡이가 발생하기 쉬운 환경에 있다. 곰팡이는 수분, 적당한 온도, 및 영양이 존재하는 장소를 좋아하여 발생한다. 일반 주택에 있어서는, 결로되기 쉬운 창가의 커튼, 벽지 및 벽장이나, 취침 중의 땀이 스며들기 쉬운 매트리스 등은 곰팡이가 좋아하는 장소라고 말할 수 있다. 그래서, 이들 장소에 있어서는, 미연에 곰팡이의 발생을 방지하는 대책이 요망되고 있다.Recent houses have high airtightness and are in an environment where moisture accumulates in the room and mold is likely to occur. Mold occurs because it likes moisture, moderate temperatures, and places where nutrients are present. In a general house, it can be said that curtains, wall coverings, closets, and mattresses that are susceptible to sweat while sleeping are favorite places for mold. Therefore, in these places, measures to prevent the occurrence of mold in advance are desired.
곰팡이의 발생을 방지하는 방법으로서는, 대상물에 방미제를 도포하는 것이 일반적이다. 종래의 방미제로서, 예를 들면 은을 사용하는 것(예를 들면, 특허문헌 1을 참조), 광촉매를 사용하는 것(예를 들면, 특허문헌 2를 참조) 등이 알려져 있다. 이들은 무기계의 방미제이다. 한편, 유기계의 방미제도 알려져 있고, 예를 들면 트리아졸계 화합물을 목재의 방미제로서 사용하는 것이 존재한다(예를 들면, 특허문헌 3을 참조).As a method of preventing the occurrence of mold, it is common to apply an anti-fog agent to an object. As a conventional anti-foaming agent, for example, silver is used (for example, refer to patent document 1), a photocatalyst is used (for example, refer to patent document 2), etc. are known. These are inorganic antifouling agents. On the other hand, organic-based anti-foaming agents are also known, and for example, a triazole-based compound is used as a wood anti-fogging agent (for example, see Patent Document 3).
특허문헌 1이나 특허문헌 2에 대표되는 무기계의 방미제는, 변색되기 쉽다는 결점이 있다. 그 때문에, 커튼, 벽지, 매트리스 등의 가정용품에는 적당하지 않을 경우가 있다. 특허문헌 3에 대표되는 유기계의 방미제는, 변색의 문제는 적지만, 효력의 점에서는 개선의 여지가 있다.The inorganic anti-foaming agent represented by Patent Document 1 and Patent Document 2 has a drawback that it is easy to discolor. For this reason, it may not be suitable for household items such as curtains, wallpaper, and mattresses. The organic anti-foaming agent represented by Patent Document 3 has few problems of discoloration, but there is room for improvement in terms of effectiveness.
그래서, 본 발명자들은, 특히 가정용품과의 상성(相性)이 양호한 유기계의 방미제에 착안하고, 새로운 방미 기술의 확립을 시도하였다. 즉, 본 발명은, 유기계의 방미제에 있어서, 종래보다도 우수한 방미 효과를 발휘할 수 있는 방미제 조성물을 제공하는 것을 목적으로 한다. 또한, 그와 같은 방미제 조성물을 사용하는 것에 의해, 사용하기 편리한 방미용 스프레이 제품을 제공하는 것을 목적으로 한다. 또한, 방미용 스프레이 제품을 사용한 방미 방법으로 제공하는 것을 목적으로 한다.Therefore, the present inventors have tried to establish a new anti-fogging technology, particularly focusing on organic anti-fogging agents having good compatibility with household products. That is, it is an object of the present invention to provide an anti-foaming agent composition capable of exhibiting an anti-fogging effect superior to that of the prior art in an organic-based anti-fogging agent. In addition, it is an object of the present invention to provide a spray product for anti-fogging that is convenient to use by using such an anti-fog composition. In addition, it aims to provide by the anti-fog method using the anti-fog spray product.
상기 과제를 해결하기 위한 본 발명에 관한 방미제 조성물의 특징 구성은,The characteristic configuration of the anti-foaming agent composition according to the present invention for solving the above problems,
트리아졸계 화합물과, 글리콜과, 알코올을 함유하는 것에 있다.It contains a triazole-based compound, a glycol, and an alcohol.
본 발명자들은, 트리아졸계 화합물에 글리콜을 병용하면, 트리아졸계 화합물의 방미성이 글리콜에 의해 증강되고, 알코올을 더 병용하면, 트리아졸계 화합물이 적당하게 분산되는 것을 새롭게 발견하였다. 따라서, 본 구성의 방미제 조성물에 의하면, 트리아졸계 화합물을 단독으로 사용한 경우와 비교하여, 보다 우수한 방미 효과를 발휘할 수 있다.The present inventors newly discovered that when glycol is used in combination with a triazole-based compound, the anti-fogging property of the triazole-based compound is enhanced by glycol, and when an alcohol is further used in combination, the triazole-based compound is suitably dispersed. Therefore, according to the anti-fogging agent composition of this constitution, compared with the case where a triazole-based compound is used alone, a more excellent anti-fogging effect can be exhibited.
본 발명에 관한 방미제 조성물에 있어서,In the anti-fog composition according to the present invention,
상기 트리아졸계 화합물은, 테부코나졸인 것이 바람직하다.It is preferable that the said triazole-type compound is tebuconazole.
본 구성의 방미제 조성물에 의하면, 바람직한 트리아졸계 화합물로서, 테부코나졸을 사용함으로써, 우수한 방미 효과를 발휘할 수 있다.According to the anti-fog composition according to the present configuration, an excellent anti-fog effect can be exhibited by using tebuconazole as a preferable triazole-based compound.
본 발명에 관한 방미제 조성물에 있어서,In the anti-fog composition according to the present invention,
상기 글리콜은 프로필렌글리콜 및/또는 1,3-부틸렌글리콜인 것이 바람직하다.The glycol is preferably propylene glycol and/or 1,3-butylene glycol.
본 구성의 방미제 조성물에 의하면, 바람직한 글리콜로서 프로필렌글리콜 및/또는 1,3-부틸렌글리콜을 사용함으로써, 트리아졸계 화합물의 방미성의 증강 효과가 특히 우수한 것으로 된다.According to the anti-fog composition according to the present configuration, by using propylene glycol and/or 1,3-butylene glycol as a preferred glycol, the effect of enhancing the anti-fogging property of the triazole-based compound is particularly excellent.
본 발명에 관한 방미제 조성물에 있어서,In the anti-fog composition according to the present invention,
상기 알코올은 에탄올 및/또는 2-프로판올인 것이 바람직하다.It is preferable that the alcohol is ethanol and/or 2-propanol.
본 구성의 방미제 조성물에 의하면, 바람직한 알코올로서 에탄올 및/또는 2-프로판올을 사용함으로써, 트리아졸계 화합물의 분산성이 특히 우수한 것으로 된다.According to the anti-fog composition according to the present configuration, by using ethanol and/or 2-propanol as a preferable alcohol, the dispersibility of the triazole-based compound is particularly excellent.
본 발명에 관한 방미제 조성물에 있어서,In the anti-fog composition according to the present invention,
상기 트리아졸계 화합물과 상기 글리콜의 배합비(중량비)가, 1:10∼1:0.5인 것이 바람직하다.It is preferable that the mixing ratio (weight ratio) of the triazole-based compound and the glycol is 1:10 to 1:0.5.
본 구성의 방미제 조성물에 의하면, 트리아졸계 화합물과 글리콜의 배합비(중량비)가 적절한 범위로 설정되어 있으므로, 트리아졸계 화합물의 방미성을 글리콜에 의해 효율적으로 증강할 수 있다.According to the anti-fogging composition of the present configuration, since the mixing ratio (weight ratio) of the triazole-based compound and glycol is set in an appropriate range, the anti-fogging property of the triazole-based compound can be efficiently enhanced by glycol.
본 발명에 관한 방미제 조성물에 있어서,In the anti-fog composition according to the present invention,
소취(消臭) 성분을 더 함유하는 것이 바람직하다.It is preferable to further contain a deodorant component.
본 구성의 방미제 조성물에 의하면, 소취 성분을 더 함유하기 때문에, 곰팡이가 좋아하는 습기가 있는 환경에서 발생할 수 있는 불쾌한 냄새를 억제할 수 있다.According to the anti-fog composition according to the present configuration, since it further contains a deodorizing component, it is possible to suppress an unpleasant odor that may occur in a humid environment that mold likes.
본 발명에 관한 방미제 조성물에 있어서,In the anti-fog composition according to the present invention,
클라도스포륨(Cladosporium), 알터나리아(Alternaria), 붉은 곰팡이, 푸른 곰팡이, 누룩 곰팡이, 유로튬(Eurotium) 및 왈레미아(Wallemia)로 이루어지는 군으로부터 선택되는 적어도 일종의 곰팡이를 대상으로 하는 것이 바람직하다.It is preferable to target at least a kind of fungus selected from the group consisting of Cladosporium, Alternaria, red fungus, blue fungus, yeast fungus, eurotium and wallemia. Do.
본 구성의 방미제 조성물에 의하면, 일상의 생활 공간에 있어서 발생하기 쉬운 클라도스포륨, 알터나리아, 붉은 곰팡이, 푸른 곰팡이, 누룩 곰팡이, 유로튬 및 왈레미아의 발생을 방지할 수 있기 때문에, 일상의 용도에 있어서 높은 방미 효과를 얻을 수 있다. 또한, 상기의 곰팡이는 어두운 색 내지 짙은 색을 띠고 있으므로, 본 구성의 방미제 조성물에 의해 섬유 제품이나 종이 제품에 방미성이 부여되는 것에 의해, 소비자에게 우수한 사용 실감을 부여할 수 있다.According to the anti-foaming composition of this configuration, it is possible to prevent the occurrence of cladosporium, alternaria, red mold, blue mold, yeast mold, eurotium, and wallemia that are likely to occur in everyday living spaces. High anti-fogging effect can be obtained in everyday use. In addition, since the above mold has a dark color to a dark color, the anti-fogging property is imparted to the fiber product or paper product by the anti-fogging agent composition of the present configuration, so that an excellent feeling of use can be imparted to the consumer.
본 발명에 관한 방미제 조성물에 있어서,In the anti-fog composition according to the present invention,
커튼용인 것이 바람직하다.It is preferably for curtains.
본 구성의 방미제 조성물에 의하면, 종래부터 특히 문제가 되고 있던 커튼에 번식하는 곰팡이를 효과적으로 억제할 수 있다.According to the anti-fog composition of the present configuration, it is possible to effectively suppress mold propagating on curtains, which has been a problem in the past.
상기 과제를 해결하기 위한 본 발명에 관한 방미용 스프레이 제품의 특징 구성은,The characteristic configuration of the spray product for anti-weathering according to the present invention for solving the above problems,
스프레이 용기에, 상기 어느 한 항에 기재된 방미제 조성물과 물을 포함하는 약제를 봉입하여 이루어지는 방미용 스프레이 제품으로서,In a spray container, a spray product for flavoring, comprising encapsulating a drug containing the flavoring agent composition according to any one of the above and water,
상기 약제 중의 상기 알코올의 함유량이, 20∼60 중량%로 설정되어 있는 것에 있다.The content of the alcohol in the drug is set to 20 to 60% by weight.
본 구성의 방미용 스프레이 제품에 의하면, 본 발명의 방미제 조성물을 함유하고 있으므로, 트리아졸계 화합물의 방미성이 글리콜에 의해 증강되고, 또한 알코올에 의해 트리아졸계 화합물이 적당하게 분산되어, 종래보다도 우수한 방미용 제품으로 할 수 있다. 또한, 스프레이 용기에 봉입되는 약제 중의 알코올의 함유량이 20∼60 중량%로 설정되어 있으므로, 트리아졸계 화합물이 침전되지 않고 약제 중에 완전히 용해되고, 그 결과, 스프레이 횟수에 따라서 처리 대상물에 정확한 양의 약제를 부여할 수 있다. 또한, 상기의 알코올 함유량이면, 적절한 스프레이 패턴이 형성되므로, 처리 대상물에 약제를 남김없이 부착시킬 수 있다.According to the anti-fog spray product of this configuration, since it contains the anti-fog composition of the present invention, the anti-fogging property of the triazole-based compound is enhanced by glycol, and the triazole-based compound is suitably dispersed by alcohol, which is superior to the conventional one. It can be used as an anti-beauty product. In addition, since the content of alcohol in the drug enclosed in the spray container is set to 20 to 60% by weight, the triazole-based compound is completely dissolved in the drug without precipitation, and as a result, the correct amount of the drug is contained in the object to be treated depending on the number of sprays. Can be given. In addition, since the above alcohol content forms an appropriate spray pattern, it is possible to attach the drug to the object to be treated completely.
상기 과제를 해결하기 위한 본 발명에 관한 방미 방법의 특징 구성은,The characteristic configuration of the anti-glare method according to the present invention for solving the above problem,
처리 대상물에, 상기 기재된 방미용 스프레이 제품으로부터 상기 약제를 분무하고, 상기 처리 대상물의 표면 중 적어도 일부에 상기 약제를 부착시키는 것에 있다.The agent is sprayed onto the object to be treated from the spray product for anti-beauty spray described above, and the agent is adhered to at least a part of the surface of the object to be treated.
본 구성의 방미 방법에 의하면, 본 발명의 방미용 스프레이 제품을 사용하여 처리 대상물의 표면 중 적어도 일부에 약제를 부착시킴으로써, 처리 대상물에 방미 처리가 행해지므로, 곰팡이의 발생을 효과적으로 방지할 수 있다.According to the anti-fog method of the present configuration, the anti-fogging treatment is performed on the object to be treated by attaching a drug to at least a part of the surface of the object to be treated using the spray product for anti-fogging of the present invention, so that the occurrence of mold can be effectively prevented.
이하, 본 발명의 방미제 조성물, 방미용 스프레이 제품 및 방미 방법에 대하여 설명한다. 다만, 본 발명은, 이하에 설명하는 실시형태에 한정되는 것을 의도하지 않는다.Hereinafter, an anti-fog composition, a spray product for anti-fog, and a method of anti-fog of the present invention will be described. However, the present invention is not intended to be limited to the embodiments described below.
본 발명자들은, 종래, 목재의 방미제로서 사용되었던 트리아졸계 화합물을 일반 가정용 방미제로서 이용함에 있어서, 트리아졸계 화합물에 글리콜을 병용하면, 트리아졸계 화합물의 방미성이 증강되고, 알코올을 더 병용하면, 트리아졸계 화합물이 적당하게 분산되는 것을 새롭게 발견하고, 이 지견에 기초하여, 새로운 방미제 조성물을 착상한 것이다. 상세한 내용에 대해서는 후술하는 실시예에서 설명하지만, 본 발명의 방미제 조성물을 물과 함께 스프레이 용기에 봉입하여 본 발명의 방미용 스프레이 제품을 구성하고, 이것을 섬유 제품인 커튼에 적용하면, 우수한 방미 효과가 인정되었다. 그리고, 본 명세서에 있어서, 방미 효과란, 주로 곰팡이의 발생을 미연에 방지하는 것을 의미하지만, 발생한 곰팡이를 소멸시키는 것이나, 발생한 곰팡이의 확대를 억제하는 것도 방미 효과에 포함된다. 본 발명의 방미제 조성물(방미용 스프레이 제품)에 의해 번식을 억제하는 것이 가능한 곰팡이의 종류로서는, 예를 들면 클라도스포륨(이른바, 검은 곰팡이), 알터나리아, 붉은 곰팡이, 푸른 곰팡이, 누룩 곰팡이, 유로튬, 왈레미아 등을 들 수 있다. 이들 곰팡이는 침실, 거실, 욕실, 화장실, 부엌 등의 일상의 생활 공간에 있어서 발생하기 쉬운 곰팡이고, 그 외관은 어두운 색 내지 짙은 색을 띠고 있으므로, 본 발명의 방미제 조성물에 의해 상기 생활 공간에 존재하는 섬유 제품(예를 들면, 커튼)이나 종이 제품(예를 들면, 벽지)에 방미성이 부여되면, 곰팡이에 의해 발생하고 있었던 착색이 방지 또는 크게 개선되어, 소비자에게 우수한 사용 실감을 부여할 수 있다. 특히, 침실이나 거실에 비치되어 있는 커튼에 본 발명품을 적용하면, 소비자는 청결감이나 안심감을 얻을 수 있다.In the present inventors, in using a triazole-based compound, which has been conventionally used as a flame retardant for wood, as a general household flame retardant, when a glycol is used in combination with a triazole-based compound, the anti-fogging property of the triazole-based compound is enhanced, and if alcohol is further used in combination, , It newly discovered that a triazole-based compound was suitably dispersed, and based on this knowledge, a new anti-fogicide composition was conceived. Details will be described in the examples to be described later, but when the anti-foaming agent composition of the present invention is enclosed in a spray container together with water to construct the anti-fog spray product of the present invention, and applied to a curtain which is a textile product, excellent anti-fogging effect is obtained. Was admitted. Incidentally, in the present specification, the anti-fogging effect mainly means preventing the occurrence of mold in advance, but the anti-fogging effect also includes extinguishing the mold and suppressing the spread of the mold. Examples of the types of molds capable of inhibiting reproduction by the anti-foam composition (anti-fog spray product) of the present invention include cladosporium (so-called black mold), alternaria, red mold, blue mold, and koji Mold, eurotium, and wallemia. These molds are molds that are prone to occur in everyday living spaces such as bedrooms, living rooms, bathrooms, toilets, kitchens, etc., and their appearances are dark or dark colors, and therefore, the anti-foaming composition of the present invention can be used in the living space. If anti-fog properties are given to existing textile products (for example, curtains) or paper products (for example, wallpaper), coloration caused by mold is prevented or greatly improved, giving consumers an excellent feeling of use. I can. In particular, when the present invention is applied to curtains provided in bedrooms or living rooms, consumers can obtain a sense of cleanliness and security.
<방미제 조성물><Flaminant composition>
본 발명의 방미제 조성물은, 주성분으로서 트리아졸계 화합물과, 글리콜과, 알코올을 함유한다.The anti-fog composition of the present invention contains a triazole-based compound, glycol, and alcohol as main components.
트리아졸계 화합물로서는 테부코나졸, 이미벤코나졸-db, 트리아디메놀, 파크로부트라졸, 프로피코나졸, 헥사코나졸, 펜코나졸, 미크로부타닐, 메트코나졸(등록상표) 등을 들 수 있다. 이들 중, 테부코나졸이 바람직하다. 그리고, 이들 트리아졸계 화합물은 단독으로 사용해도 되고, 복수 종류를 혼합하여 사용해도 된다.Examples of triazole compounds include tebuconazole, imibenconazole-db, triadimenol, paclobutrazole, propiconazole, hexaconazole, fenconazole, microbutanyl, metconazole (registered trademark), and the like. have. Among these, tebuconazole is preferable. In addition, these triazole-based compounds may be used alone, or a plurality of types may be mixed and used.
글리콜로서는 에틸렌글리콜, 프로필렌글리콜, 1,3-부틸렌글리콜, 펜틸렌글리콜, 1,2-헥산디올 등을 들 수 있다. 이들 중, 프로필렌글리콜, 1,3-부틸렌글리콜이 바람직하다. 그리고, 이들 글리콜은 단독으로 사용해도 되고, 복수 종류를 혼합하여 사용해도 된다.Examples of glycols include ethylene glycol, propylene glycol, 1,3-butylene glycol, pentylene glycol, and 1,2-hexanediol. Among these, propylene glycol and 1,3-butylene glycol are preferable. In addition, these glycols may be used alone, or a plurality of types may be mixed and used.
알코올로서는 메탄올, 에탄올, 1-프로판올, 2-프로판올, 부탄올, 펜탄올, 헥산올 등을 들 수 있다. 이들 중, 에탄올, 2-프로판올이 바람직하다. 그리고, 이들 알코올은 단독으로 사용해도 되고, 복수 종류를 혼합하여 사용해도 된다.As alcohol, methanol, ethanol, 1-propanol, 2-propanol, butanol, pentanol, hexanol, etc. are mentioned. Among these, ethanol and 2-propanol are preferable. And these alcohols may be used alone, or may be used by mixing plural types.
본 발명의 방미제 조성물은, 상기의 트리아졸계 화합물, 글리콜 및 알코올 외에, 소취 성분, 향료, pH 조정제 등을 더 함유해도 된다. 예를 들면, 소취 성분으로서 플라보노이드를 함유시키면, 곰팡이가 좋아하는 습기가 있는 환경에서 발생할 수 있는 불쾌한 냄새를 억제할 수 있다.In addition to the above-described triazole-based compound, glycol and alcohol, the anti-fog composition of the present invention may further contain a deodorant component, a fragrance, a pH adjuster, and the like. For example, when flavonoids are included as a deodorant component, an unpleasant odor that may occur in a humid environment that mold likes can be suppressed.
본 발명의 방미제 조성물은, 상기의 각 성분을 적절한 중량비로 배합하고, 물을 더 첨가하여 각 성분의 농도가 적절하게 되도록 조정된다.In the anti-fog composition of the present invention, each of the above components is blended in an appropriate weight ratio, and water is further added to adjust the concentration of each component to be appropriate.
상기의 각 성분의 배합에 있어서는, 트리아졸계 화합물과 글리콜의 배합비 (중량비)는, 1:10∼1:0.5로 조정되는 것이 바람직하고, 1:10∼1:1로 조정되는 것이 보다 바람직하다. 트리아졸계 화합물과 글리콜의 배합비가 1:10 미만인 경우(즉, 트리아졸계 화합물의 배합량이 글리콜의 배합량에 대하여 1/10 미만인 경우), 트리아졸계 화합물이 부족하므로, 방미 효과를 충분히 발휘할 수 없을 우려가 있다. 트리아졸계 화합물과 글리콜의 배합비가 1:0.5를 넘는 경우(즉, 트리아졸계 화합물의 배합량이 글리콜의 배합량에 대하여 2배를 넘는 경우), 글리콜이 부족하므로, 트리아졸계 화합물의 방미성을 충분히 증강할 수 없을 우려가 있다.In the formulation of each of the above components, the mixing ratio (weight ratio) of the triazole-based compound and glycol is preferably adjusted to 1:10 to 1:0.5, and more preferably adjusted to 1:10 to 1:1. When the blending ratio of the triazole-based compound and glycol is less than 1:10 (i.e., the blending amount of the triazole-based compound is less than 1/10 of the blending amount of the glycol), there is a fear that the anti-fogging effect cannot be sufficiently exhibited due to insufficient triazole-based compounds. have. When the blending ratio of the triazole-based compound and glycol exceeds 1:0.5 (i.e., when the blending amount of the triazole-based compound exceeds twice the blending amount of the glycol), glycol is insufficient, so that the anti-flameability of the triazole-based compound can be sufficiently enhanced. There is a fear that it cannot be done.
물을 첨가하는 데 있어서는, 조제 후의 약제(트리아졸계 화합물, 글리콜, 알코올 및 물의 혼합물로서, 필요에 따라 기타 성분을 포함하는 것) 중의 알코올의 함유량이, 20∼60 중량%로 되도록 설정된다. 이 범위이면, 트리아졸계 화합물은, 약제 중에 침전되지 않고 완전히 용해할 수 있다. 따라서, 처리 대상물에 정확한 양의 약제를 부여하는 것이 용이해진다. 또한, 후술한 방미용 스프레이 제품을 구성했을 때, 적절한 스프레이 패턴이 형성되므로, 처리 대상물에 약제를 남김없이 부착시킬 수 있다.When water is added, the content of alcohol in the prepared drug (a mixture of a triazole-based compound, glycol, alcohol, and water, including other components as necessary) is set to be 20 to 60% by weight. Within this range, the triazole-based compound can be completely dissolved without precipitation in the drug. Therefore, it becomes easy to impart the correct amount of the drug to the object to be treated. In addition, when constructing the spray product for anti-beauty spray, which will be described later, an appropriate spray pattern is formed, so that the drug can be adhered to the object to be treated without leaving behind.
<방미제용 스프레이 제품><Spray product for anti-repellant>
본 발명의 방미제 조성물이 바람직한 제품 형태는 스프레이 제품이다. 예를 들면, 스프레이 용기에 전술한 약제(적어도, 본 발명의 방미제 조성물과 물의 혼합물)를 봉입함으로써, 본 발명의 방미용 스프레이 제품이 구성된다. 스프레이 용기로서는, 트리거식 스프레이어를 구비하는 것이 바람직하다. 스프레이 용기에 봉입되는 약제는 전술한 바와 같이, 약제 중의 알코올의 함유량이 20∼60 중량%로 되도록 설정된다. 이에 의해, 스프레이했을 때 약제가 대략 원형으로 확산되고, 또한 처리 대상물로의 약제의 도포량이 대략 균일하게 되는 스프레이 패턴을 형성할 수 있다. 또한, 스프레이 횟수에 따라서 처리 대상물에 정확한 양의 약제를 부여할 수 있다.The preferred product form of the anti-foaming composition of the present invention is a spray product. For example, by encapsulating the above-described agent (at least a mixture of the anti-fog composition of the present invention and water) in a spray container, the spray product for anti-moldering of the present invention is constituted. As the spray container, it is preferable to provide a trigger sprayer. As described above, the drug to be enclosed in the spray container is set so that the content of alcohol in the drug is 20 to 60% by weight. Thereby, when sprayed, it is possible to form a spray pattern in which the drug spreads in a substantially circular shape and the amount of the drug applied to the object to be treated becomes substantially uniform. In addition, it is possible to impart an exact amount of the drug to the object to be treated according to the number of sprays.
<방미 방법><How to visit the US>
본 발명의 방미 방법은, 전술한 방미용 스프레이 제품을 사용하여 실시할 수 있다. 구체적으로는, 작업자가 방미용 스프레이 제품의 트리거를 파지하고, 처리 대상물의 표면을 향하여 약제를 분무한다. 이에 의해, 처리 대상물의 표면에 약제가 부착한다. 또한, 필요에 따라 약제를 건조시킨다. 약제의 분무 및 건조는 복수 회 반복해도 된다. 약제의 분무량은, 처리 대상물에 대하여 9.0∼13.5g/㎡가 바람직하다. 약제의 분무량이 9.0g/㎡ 미만인 경우, 유효 성분인 트리아졸계 화합물 및 글리콜의 부착량이 부족하고, 처리 대상물의 소재에 따라서는 방미 효과를 충분히 부여할 수 없는 경우가 있다. 약제의 분무량이 13.5g/㎡를 넘는 경우, 건조 후에도 처리 대상물에 끈적거리는 느낌이 남는 경우가 있다. 상기 처리 대상물에 대한 일련의 방미 처리가 완료되면, 처리 대상물에는 우수한 방미 효과가 발휘되어, 곰팡이의 발생을 장기에 걸쳐 효과적으로 방지할 수 있다.The anti-fog method of the present invention can be carried out using the spray product for anti-fogging. Specifically, the operator grips the trigger of the anti-beauty spray product, and sprays the drug toward the surface of the object to be treated. Thereby, the drug adheres to the surface of the object to be treated. Also, if necessary, the drug is dried. Spraying and drying of the drug may be repeated a plurality of times. The spraying amount of the drug is preferably 9.0 to 13.5 g/m 2 relative to the object to be treated. When the spraying amount of the drug is less than 9.0 g/m 2, the amount of adhesion of the active ingredient triazole-based compound and glycol is insufficient, and depending on the material of the object to be treated, the anti-fog effect may not be sufficiently imparted in some cases. When the spraying amount of the drug exceeds 13.5 g/m 2, a sticky feeling may remain on the object to be treated even after drying. When a series of anti-fog treatment for the object to be treated is completed, an excellent anti-fogging effect is exhibited on the object to be treated, and the occurrence of mold can be effectively prevented over a long period of time.
<실시예><Example>
본 발명의 방미제 조성물의 성능 및 사용 편리성을 확인하기 위해, 커튼을 대상으로 한 방미 시험을 실제로 행하고, 이와 함께 약액의 외관, 및 스프레이 패턴을 확인하였다. 방미제 조성물의 조제에 있어서는, 트리아졸계 화합물로서 테부코나졸, 글리콜로서 프로필렌글리콜 및/또는 1,3-부틸렌글리콜, 알코올로서 에탄올을 사용하고, 이온 교환수를 더한 것을 약액으로 하였다. 방미제 조성물의 각 성분은, 이하의 약품을 사용하였다.In order to confirm the performance and convenience of use of the anti-foaming agent composition of the present invention, an anti-fogging test was actually conducted on a curtain, and the appearance of the chemical solution and a spray pattern were confirmed. In the preparation of the anti-fog composition, tebuconazole as a triazole-based compound, propylene glycol and/or 1,3-butylene glycol as a glycol, ethanol as an alcohol, and ion-exchanged water were added as a chemical solution. As each component of the anti-fog composition, the following drugs were used.
·테부코나졸(품명: 비오사이드 R-BP20, 가부시키가이샤 다이쇼테크노스 제조)Tebuconazole (Product name: Bioside R-BP20, manufactured by Daisho Technos Co., Ltd.)
·프로필렌글리콜(공업용 프로필렌글리콜, 가부시키가이샤 ADEKA 제조)Propylene glycol (Industrial propylene glycol, manufactured by ADEKA Co., Ltd.)
·1,3-부틸렌글리콜(공업용 1,3-부틸렌글리콜, 가부시키가이샤 다이셀 제조)·1,3-butylene glycol (industrial 1,3-butylene glycol, manufactured by Daicel)
·에탄올(공업용 95 중량% 에탄올, 닛폰 고세이 알코올 가부시키가이샤 제조)Ethanol (95% by weight industrial ethanol, manufactured by Nippon Kosei Alcohol Co., Ltd.)
상기 약액을, 트리거식 스프레이어를 구비하는 스프레이 용기[일련번호: T014, 캐니언(Canyon)사 제조]에 봉입하여, 본 발명의 방미제용 스프레이 제품을 구성하였다.The above-described chemical solution was enclosed in a spray container (serial number: T014, manufactured by Canyon Corporation) equipped with a trigger sprayer to construct the spray product for an anti-fog agent of the present invention.
<약액의 처방><Prescription of drug solution>
실시예 1∼실시예 7 및 비교예 1∼비교예 3으로서 조제한 각각의 약액 처방은 이하와 같다.Formulations for each of the chemicals prepared as Examples 1 to 7 and Comparative Examples 1 to 3 are as follows.
[실시예 1][Example 1]
테부코나졸 0.05 중량부, 에탄올 20 중량부(농도 100 중량% 환산이고, 이후의 실시예 및 비교예에 대해서도 동일함), 및 프로필렌글리콜 0.5 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 실시예 1에 있어서의 테부코나졸과 프로필렌글리콜의 배합비(중량비)는 1:10이다. 또한, 약제 중의 에탄올의 함유량은 20 중량%이다.0.05 parts by weight of tebuconazole, 20 parts by weight of ethanol (concentration in terms of 100% by weight, the same for the following Examples and Comparative Examples), and 0.5 parts by weight of propylene glycol were mixed, and ion-exchanged water was added to the total. A chemical solution of 100 parts by weight was prepared. The blending ratio (weight ratio) of tebuconazole and propylene glycol in Example 1 is 1:10. In addition, the content of ethanol in the drug is 20% by weight.
[실시예 2][Example 2]
테부코나졸 0.1 중량부, 에탄올 40 중량부 및 프로필렌글리콜 0.5 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 실시예 2에 있어서의 테부코나졸과 프로필렌글리콜의 배합비(중량비)는 1:5이다. 또한, 약제 중의 에탄올의 함유량은 40 중량%이다.0.1 parts by weight of tebuconazole, 40 parts by weight of ethanol, and 0.5 parts by weight of propylene glycol were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. The blending ratio (weight ratio) of tebuconazole and propylene glycol in Example 2 is 1:5. In addition, the content of ethanol in the drug is 40% by weight.
[실시예 3][Example 3]
테부코나졸 0.2 중량부, 에탄올 60 중량부 및 1,3-부틸렌글리콜 0.2 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 실시예 3에 있어서의 테부코나졸과 1,3-부틸렌글리콜의 배합비(중량비)는 1:1이다. 또한, 약제 중의 에탄올의 함유량은 60 중량%이다.Tebuconazole 0.2 parts by weight, ethanol 60 parts by weight, and 1,3-butylene glycol 0.2 parts by weight were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. The blending ratio (weight ratio) of tebuconazole and 1,3-butylene glycol in Example 3 is 1:1. In addition, the content of ethanol in the drug is 60% by weight.
[실시예 4][Example 4]
테부코나졸 0.5 중량부, 에탄올 50 중량부, 및 프로필렌글리콜 0.5 중량부, 및 1,3-부틸렌글리콜 0.5 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 실시예 4에 있어서의 테부코나졸과 프로필렌글리콜 및 1,3-부틸렌글리콜의 배합비(중량비)는 1:2이다. 또한, 약제 중의 에탄올의 함유량은 50 중량%이다.Tebuconazole 0.5 parts by weight, ethanol 50 parts by weight, propylene glycol 0.5 parts by weight, and 1,3-butylene glycol 0.5 parts by weight were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. The blending ratio (weight ratio) of tebuconazole, propylene glycol, and 1,3-butylene glycol in Example 4 is 1:2. In addition, the content of ethanol in the drug is 50% by weight.
[실시예 5][Example 5]
테부코나졸 0.1 중량부, 에탄올 40 중량부 및 프로필렌글리콜 0.05 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 실시예 5에 있어서의 테부코나졸과 프로필렌글리콜의 배합비(중량비)는 1:0.5이다. 또한, 약제 중의 에탄올의 함유량은 40 중량%이다.0.1 parts by weight of tebuconazole, 40 parts by weight of ethanol, and 0.05 parts by weight of propylene glycol were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. The blending ratio (weight ratio) of tebuconazole and propylene glycol in Example 5 is 1:0.5. In addition, the content of ethanol in the drug is 40% by weight.
[실시예 6][Example 6]
테부코나졸 0.2 중량부, 에탄올 65 중량부 및 프로필렌글리콜 0.1 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 실시예 6에 있어서의 테부코나졸과 프로필렌글리콜의 배합비(중량비)는 1:0.5이다. 또한, 약제 중의 에탄올의 함유량은 65 중량%이다.Tebuconazole 0.2 parts by weight, ethanol 65 parts by weight, and propylene glycol 0.1 parts by weight were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. The blending ratio (weight ratio) of tebuconazole and propylene glycol in Example 6 is 1:0.5. In addition, the content of ethanol in the drug is 65% by weight.
[실시예 7][Example 7]
테부코나졸 0.1 중량부, 에탄올 10 중량부 및 1,3-부틸렌글리콜 3 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 실시예 7에 있어서의 테부코나졸과 1,3-부틸렌글리콜의 배합비(중량비)는 1:30이다. 또한, 약제 중의 에탄올의 함유량은 10 중량%이다.0.1 parts by weight of tebuconazole, 10 parts by weight of ethanol, and 3 parts by weight of 1,3-butylene glycol were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. The blending ratio (weight ratio) of tebuconazole and 1,3-butylene glycol in Example 7 is 1:30. In addition, the content of ethanol in the drug is 10% by weight.
[비교예 1][Comparative Example 1]
에탄올 20 중량부에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 즉, 비교예 1은 테부코나졸, 및 글리콜(프로필렌글리콜 및/또는 1,3-부틸렌글리콜)을 포함하지 않는 약액이고, 실시예 1의 처방으로부터 테부코나졸 및 프로필렌글리콜을 제외한 것과 동등하다.Ion-exchanged water was added to 20 parts by weight of ethanol to prepare a chemical solution having a total of 100 parts by weight. That is, Comparative Example 1 is a chemical solution that does not contain tebuconazole and glycol (propylene glycol and/or 1,3-butylene glycol), and is equivalent to excluding tebuconazole and propylene glycol from the formulation of Example 1. .
[비교예 2][Comparative Example 2]
테부코나졸 0.1 중량부 및 프로필렌글리콜 0.5 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 즉, 비교예 2는 에탄올을 포함하지 않는 약액이고, 실시예 2의 처방으로부터 에탄올을 제외한 것과 동등하다.0.1 parts by weight of tebuconazole and 0.5 parts by weight of propylene glycol were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. That is, Comparative Example 2 is a chemical solution that does not contain ethanol, and is equivalent to removing ethanol from the formulation of Example 2.
[비교예 3][Comparative Example 3]
테부코나졸 0.1 중량부 및 에탄올 30 중량부를 혼합하고, 이것에 이온 교환수를 더하여 전체가 100 중량부인 약액을 조제하였다. 즉, 비교예 3은 글리콜(프로필렌글리콜 및/또는 1,3-부틸렌글리콜)을 포함하지 않는 약액이다.0.1 parts by weight of tebuconazole and 30 parts by weight of ethanol were mixed, and ion-exchanged water was added thereto to prepare a chemical solution having a total of 100 parts by weight. That is, Comparative Example 3 is a chemical solution that does not contain glycol (propylene glycol and/or 1,3-butylene glycol).
<약액의 외관><Appearance of the chemical solution>
실시예 1∼실시예 7, 및 비교예 1∼비교예 3의 약액 외관을 각각 육안에 의해 확인하였다. 외관의 평가 기준은 이하와 같다.The appearances of the chemical solutions of Examples 1 to 7, and Comparative Examples 1 to 3 were visually confirmed, respectively. The evaluation criteria of the appearance are as follows.
○: 약액 중에 침전이 인지되지 않고, 무색 투명임○: No precipitation is recognized in the chemical solution, and it is colorless and transparent
×: 약액 중에 침전이 인지되고, 탁해지고 있음×: Precipitation is recognized in the chemical solution and becomes cloudy
<방미 효과><Flight effect>
레이스 커튼에 곰팡이 배양 배지로서 글루코오스·펩톤 배지를 분무하고(분무영역: 10cm×10cm), 1시간 풍건시켰다. 건조 후의 레이스 커튼에, 실시예 1∼실시예 7의 약액을 봉입한 본 발명의 방미제용 스프레이 제품을 분무하고(분무량: 9.9∼11.1g/㎡), 1시간 풍건시켰다. 비교예 1∼비교예 3의 약액을 봉입한 스프레이 제품에 대해서도 동일한 조작을 행하였다. 이어서, 레이스 커튼에 일정한 균수의 곰팡이([클라도스포륨(검은 곰팡이), 푸른 곰팡이]를 부착시키고, 분무기로 물을 더 분사하고, 이것을 습도 90%로 유지한 데시케이터 내에 보존하여 곰팡이를 배양하였다. 그리고, 1주일 경과 후의 곰팡이의 발생 상황을 확인하였다.A glucose-peptone medium was sprayed on the lace curtain as a fungal culture medium (spray area: 10 cm x 10 cm), and air-dried for 1 hour. The dried lace curtain was sprayed with the spray product for an anti-fog agent of the present invention in which the chemical solutions of Examples 1 to 7 were enclosed (spray amount: 9.9 to 11.1 g/m 2 ), and air-dried for 1 hour. The same operation was performed for the spray products containing the chemical solutions of Comparative Examples 1 to 3. Subsequently, a certain number of fungi ([Cladosporium (black fungus), blue fungus]) is attached to the lace curtain, and water is further sprayed with a sprayer, and this is preserved in a desiccator maintained at 90% humidity to prevent fungus. The culture was carried out, and the state of occurrence of mold after 1 week was confirmed.
곰팡이의 발생 상황의 평가 기준은 이하와 같다.The evaluation criteria of the occurrence situation of mold are as follows.
◎: 곰팡이는 전혀 발생하지 않음◎: No mold occurs at all
○: 곰팡이는 약간 발생하지만, 외관상의 문제는 없음○: Mold is slightly generated, but there is no problem in appearance
△: 다소의 곰팡이의 발생이 인지됨△: The occurrence of some mold is recognized
×: 곰팡이의 발생이 분명히 인지됨×: occurrence of mold is clearly recognized
<스프레이 패턴><Spray pattern>
실시예 1∼실시예 7의 약액을 봉입한 본 발명의 방미제용 스프레이 제품 및 비교예 1∼비교예 3의 약액을 봉입한 스프레이 제품을, 플라스틱판을 향하여 20cm의 거리로부터 각각 1회씩 스프레이하고, 플라스틱판에 형성된 스프레이 패턴의 형상을 육안에 의해 확인하고, 또한 스케일을 이용하여 사이즈를 측정하였다. 스프레이 패턴의 형상 평가 기준은 이하와 같다.The spray product for anti-fog agent of the present invention containing the chemical solution of Examples 1 to 7 and the spray product containing the chemical solution of Comparative Examples 1 to 3 were sprayed once each from a distance of 20 cm toward the plastic plate, The shape of the spray pattern formed on the plastic plate was visually confirmed, and the size was measured using a scale. The shape evaluation criteria of the spray pattern are as follows.
○: 대략 원형의 균일하고 고른 형상임○: Approximately circular, uniform and even shape
△: 불균일하고 고르지 않은 형상임△: Uneven and uneven shape
<시험 결과><Test result>
실시예 1∼실시예 7 및 비교예 1∼비교예 3의 시험 결과를, 약액의 처방과 함께, 이하의 표 1에 나타낸다.The test results of Examples 1 to 7 and Comparative Examples 1 to 3 are shown in Table 1 below together with the prescription of the chemical solution.
[표 1][Table 1]
실시예 1∼실시예 7의 약액을 사용한 방미제용 스프레이 제품에 대하여, 약액의 외관은 약액 중에 침전은 인지되지 않고, 무색 투명을 유지하고 있고, 문제는 보이지 않았다. 방미 효과는, 곰팡이가 약간 발생한 것도 있었으나, 실용상에서 문제가 되는 것은 아니었다. 특히, 실시예 1∼실시예 4에 대해서는, 곰팡이는 전혀 발생하고 있지 않고, 우수한 방미 효과가 확인되었다. 약제 중의 에탄올의 함유량을, 20∼60 중량%로 설정하는 것이 특히 유효한 것이 시사되었다. 스프레이 패턴은, 실시예 6 및 7의 스프레이 패턴 형상이 약간 불균일하였으나, 전체적으로는 양호한 것이었다.With respect to the spray products for anti-foaming agents using the chemical solutions of Examples 1 to 7, the appearance of the chemical liquid was not recognized as precipitation in the chemical liquid, remained colorless and transparent, and no problem was observed. As for the anti-fogging effect, there was some occurrence of mold, but it was not a problem in practical use. In particular, in Examples 1 to 4, no mold was generated at all, and an excellent anti-fogging effect was confirmed. It has been suggested that it is particularly effective to set the content of ethanol in the drug to 20 to 60% by weight. As for the spray pattern, although the shape of the spray pattern of Examples 6 and 7 was slightly uneven, it was good overall.
이에 대하여, 비교예 1∼비교예 3의 약액을 사용한 스프레이 제품은, 약액의 외관 및 방미 효과를 양립시킬 수 없고, 성능적으로도, 사용 편리성도 실시예 1∼실시예 7(본 발명품)과 비교하면 뒤떨어지는 것이었다.On the other hand, spray products using the chemical solutions of Comparative Examples 1 to 3 are incompatible with the appearance and anti-glare effect of the chemical solution, and both in terms of performance and ease of use are also compared with Examples 1 to 7 (invention products). It was inferior in comparison.
<산업상 이용 가능성><Industrial availability>
본 발명의 방미제 조성물, 방미용 스프레이 제품 및 방미 방법은, 예를 들면 커튼, 의류, 이불, 매트리스, 베개 등의 섬유 제품이나, 벽장의 벽, 벽지 등의 건재에 대하여 이용 가능하다.The anti-fog composition, anti-fog product, and anti-fog method of the present invention can be used, for example, for textile products such as curtains, clothes, blankets, mattresses, and pillows, and for building materials such as walls of closets and wallpaper.
Claims (10)
상기 알코올이 에탄올 및/또는 2-프로판올인, 방미제 조성물.As a flame retardant composition containing a triazole-based compound, glycol, and alcohol,
The alcohol is ethanol and/or 2-propanol.
상기 트리아졸계 화합물이 테부코나졸인, 방미제 조성물.The method of claim 1,
The triazole-based compound is tebuconazole.
상기 글리콜이 프로필렌글리콜 및/또는 1,3-부틸렌글리콜인, 방미제 조성물.The method according to claim 1 or 2,
The glycol is propylene glycol and/or 1,3-butylene glycol.
상기 트리아졸계 화합물과 상기 글리콜의 배합비(중량비)가, 1:10∼1:0.5인, 방미제 조성물.The method according to claim 1 or 2,
The blending ratio (weight ratio) of the triazole-based compound and the glycol is 1:10 to 1:0.5.
소취(消臭) 성분을 더 함유하는, 방미제 조성물.The method according to claim 1 or 2,
A deodorant composition further containing a deodorant component.
클라도스포륨(Cladosporium), 알터나리아(Alternaria), 붉은 곰팡이, 푸른 곰팡이, 누룩 곰팡이, 유로튬(Eurotium) 및 왈레미아(Wallemia)로 이루어지는 군으로부터 선택되는 적어도 일종의 곰팡이를 대상으로 하는, 방미제 조성물.The method according to claim 1 or 2,
Anti-mildew, targeting at least a type of fungus selected from the group consisting of Cladosporium, Alternaria, red fungus, blue fungus, yeast fungus, Eurotium and Wallemia First composition.
방미제 조성물이 커튼용인, 방미제 조성물.The method according to claim 1 or 2,
The flame retardant composition is for curtains.
상기 약제 중의 상기 알코올의 함유량이 20∼60 중량%로 설정되어 있는,
방미용 스프레이 제품.A spray product for flavoring and beauty comprising a spray container containing a drug containing the flavoring agent composition according to claim 1 or 2 and water,
The content of the alcohol in the drug is set to 20 to 60% by weight,
Spray product for anti-beauty.
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| JP2008019260A (en) * | 2006-06-26 | 2008-01-31 | Oxiteno Sa Industria & Comercio | Agrochemical composition, and use and scattering method of the same |
| JP2011094283A (en) * | 2009-09-29 | 2011-05-12 | Osaka Kasei Kk | Antibacterial, antifungal and antiviral fiber product and method for producing the same |
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| JP2008120768A (en) * | 2006-11-15 | 2008-05-29 | Syngenta Japan Kk | Improved pesticide composition |
| EP2022331A1 (en) * | 2007-08-02 | 2009-02-11 | Wesso Ag | Disinfectant for reducing the number of bacteria and biofilms |
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| JP5970155B2 (en) | 2010-09-28 | 2016-08-17 | ロンザジャパン株式会社 | Wood fender composition |
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| CN105432625B (en) * | 2014-09-10 | 2018-07-27 | 浙江新农化工股份有限公司 | Polybenzobisoxazole zinc and sterol demethylation inhibitor class（DMIs）The composition and its preparation of fungicide and application |
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| KR20190022749A (en) | 2019-03-06 |
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