CN109561677A - Anti-fungus agent composition, mould proof spray product and mold-proof method - Google Patents
Anti-fungus agent composition, mould proof spray product and mold-proof method Download PDFInfo
- Publication number
- CN109561677A CN109561677A CN201780046983.4A CN201780046983A CN109561677A CN 109561677 A CN109561677 A CN 109561677A CN 201780046983 A CN201780046983 A CN 201780046983A CN 109561677 A CN109561677 A CN 109561677A
- Authority
- CN
- China
- Prior art keywords
- agent composition
- fungus agent
- mould
- alcohol
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
- A01N25/06—Aerosols
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
- D06M13/358—Triazines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/10—Processes in which the treating agent is dissolved or dispersed in organic solvents; Processes for the recovery of organic solvents thereof
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
Abstract
There is provided a kind of can play the anti-fungus agent composition than previous superior anti-mold effect in the mould inhibitor of organic system.A kind of anti-fungus agent composition, contain: three azole compounds, glycol and alcohol, three azole compounds are Tebuconazole, glycol is propylene glycol and/or 1,3- butanediol, alcohol is ethyl alcohol and/or 2- propyl alcohol, and the match ratio (weight ratio) of three azole compounds and glycol is 1: 10~1: 0.5, also contains deodorization ingredient.
Description
Technical field
The present invention relates to the anti-fungus agent compositions for the generation for preventing mould, mould proof spray product and mold-proof method.
Background technique
House in recent years is in air-tightness height, and moisture lodges in environment that is indoor and being easy to produce mould.Mould hobby
Moisture, appropriateness temperature and nutrition existing for place and generate.In general house, it is easy curtain, the wallpaper on the window side of moisture condensation
The mattress etc. that sweat with closet or in going to bed easily infiltrates into can be described as the place of mould hobby.Therefore, in these places, the phase
The countermeasure for resulting from possible trouble of mould to be prevented.
As the method for the generation for preventing mould, mould inhibitor is usually coated on object.As previous mould inhibitor,
Such as it has been known that there is use silver-colored person (referring for example to patent document 1), the person's (referring for example to patent document 2) etc. that uses photochemical catalyst.This
A little mould inhibitors are the mould inhibitor of inorganic system.On the other hand, it is also known that the mould inhibitor of organic system, such as exist and use triazole
(triazole) (referring for example to patent document 3) the case where mould inhibitor of the based compound as timber.
Existing technical literature
Patent document
Patent document 1: Japanese Unexamined Patent Publication 2007-31857 bulletin
Patent document 2: Japanese Unexamined Patent Publication 2001-245781 bulletin
Patent document 3: Japanese Unexamined Patent Publication 2012-71471 bulletin
Summary of the invention
Problems to be solved by the invention
The mould inhibitor of inorganic system representated by patent document 1 or patent document 2 has the shortcomings that being easy discoloration.Therefore, have not
It is suitble to the situation of the household supplies such as curtain, wallpaper, mattress.What although the mould inhibitor of organic system representated by patent document 3 changed colour
Problem is few, but still has room for improvement in terms of effect.
Therefore, the present inventors concentrates particularly on the mould inhibitor of the organic system good with the compatibility of household supplies, attempts
The establishment of new Prevention of Mould Development.That is, it is an object of the present invention to provide a kind of can to play in the mould inhibitor of organic system than with contact
The anti-fungus agent composition of excellent anti-mold effect.Moreover, it is intended that providing one kind by using this anti-fungus agent composition
Good mould proof of service condition uses spray product.In turn, a kind of using the mould proof mold-proof method with spray product the purpose is to provide.
The solution to the problem
The feature composition of anti-fungus agent composition of the present invention for solving the above problems is:
A kind of anti-fungus agent composition, contains: three azole compounds, glycol (glycol) and alcohol (alcohol).
The present inventors's new discovery: if glycol and three azole compounds are used in combination, the mildew resistance of three azole compounds
Enhanced by glycol, and if then and with alcohol, three azole compounds moderately disperse.Therefore, it is combined according to the mould inhibitor of this composition
Object can play superior anti-mold effect compared with the situation that three azole compounds are used alone.
In anti-fungus agent composition of the present invention,
It is preferred that above-mentioned three azole compounds are Tebuconazole (tebuconazole).
It can be played according to the anti-fungus agent composition of this composition by using Tebuconazole as preferred three azole compounds
Excellent anti-mold effect.
In anti-fungus agent composition of the present invention,
It is preferred that above-mentioned glycol is propylene glycol and/or 1,3-BDO.
According to the anti-fungus agent composition of this composition, by using propylene glycol and/or 1,3-BDO as preferred glycol,
To which the reinforcing effect of the mildew resistance of three azole compounds is especially excellent.
In anti-fungus agent composition of the present invention,
It is preferred that above-mentioned alcohol is ethyl alcohol and/or 2- propyl alcohol.
According to the anti-fungus agent composition of this composition, by using ethyl alcohol and/or 2- propyl alcohol as preferred alcohol, thus triazole
The dispersibility of based compound is especially excellent.
In anti-fungus agent composition of the present invention,
It is preferred that the match ratio (weight ratio) of above-mentioned three azole compounds and above-mentioned glycol is 1: 10~1: 0.5.
According to the anti-fungus agent composition of this composition, because the match ratio (weight ratio) of three azole compounds and glycol is set to
Range appropriate, therefore effectively enhance using glycol the mildew resistance of three azole compounds.
In anti-fungus agent composition of the present invention,
It is preferred that also containing deodorization ingredient.
According to the anti-fungus agent composition of this composition, because also containing deodorization ingredient, therefore having in mould hobby can inhibit
The uncomfortable stink that can be generated in the environment of moisture.
In anti-fungus agent composition of the present invention,
It is preferred that with selected from by branch spore bacterium (Cladosporium sp.), alternaric bacteria (Alternaria sp.), Fusariumsp
(Fusarium sp.), Penicillium notatum (Penicillium sp.), Aspergillus (Aspergillus), bulk bacteria (Eurotium
Sp.) and at least one of group mould composed by section load bacterium (Wallemia sp.) is object.
According to the anti-fungus agent composition of this composition, because can prevent the branch spore bacterium being easy to produce in daily living space,
The generation of alternaric bacteria, Fusariumsp, Penicillium notatum, Aspergillus, bulk bacteria and section load bacterium, therefore daily with height can be obtained on the way
Anti-mold effect.Moreover, because of above-mentioned mould presentation dead color to heavy colour, therefore pass through and assigned using the anti-fungus agent composition of this composition
Fibre or paper products mildew resistance are given, the excellent use of consumer impression really can be given.
In anti-fungus agent composition of the present invention,
It is preferably used for curtain.
According to the anti-fungus agent composition of this composition, can effectively inhibit especially became the breeding of problem in curtain in the past
Mould.
The mould proof feature composition of spray product of the present invention for solving the above problems is:
A kind of mould proof spray product will include the enclosed spray of the medicament of anti-fungus agent composition described in any of the above embodiments and water
Mist container forms,
The content of above-mentioned alcohol in above-mentioned medicament is set to 20~60 weight %.
Mould proof according to this composition uses spray product, because containing anti-fungus agent composition of the invention, therefore triazole system chemical combination
The mildew resistance of object is enhanced by glycol, and then using alcohol three azole compounds is moderately dispersed, and can be made into more more excellent than previous
Mould proof use product.Moreover, because the content of the alcohol in the medicament of enclosed automiser spray is set to 20~60 weight %, therefore three
Azole compounds will not be precipitated but are dissolved completely in medicament, assign the medicament of correct amount as a result, spray timings can be corresponded to
Give object to be processed.And then if above-mentioned alcohol content, then because foring spray pattern appropriate (spray pattern), because
This can make medicament be attached to object to be processed everywhere.
The feature composition of mold-proof method of the present invention for solving the above problems is:
A kind of mold-proof method, from it is above-mentioned it is mould proof with spray product by above-mentioned reagent spray to object to be processed, make above-mentioned
Medicament is attached at least part on the surface of above-mentioned object to be processed.
According to the mold-proof method of this composition, because mould proof making medicament be attached to processing with spray product by using of the invention
At least part on the surface of object makes object to be processed carry out mould proof processing, therefore the generation of mould can be effectively prevented.
Specific embodiment
Hereinafter, to anti-fungus agent composition of the invention, mould proof being illustrated with spray product and mold-proof method.But this
Invention is not intended to be defined to embodiments described below.
The present inventors's new discovery: when three azole compounds for using the previous mould inhibitor as timber are as general
When home-use mould inhibitor utilizes, if glycol and three azole compounds are used in combination, the mildew resistance of three azole compounds is enhanced,
And if then and with alcohol, three azole compounds moderately disperse, and new anti-fungus agent composition is contemplated according to the opinion.About detailed
Details condition is illustrated in aftermentioned embodiment, and anti-fungus agent composition of the invention is enclosed automiser spray structure together with water
Mould proof it confirmed excellent anti-mold effect if being applied to the curtain of fibre with spray product at of the invention.It needs
It is noted that in the present specification, so-called anti-mold effect, it is meant that predominantly prevent the possible trouble that results from of mould, and make institute
The mould of generation is eliminated, the expansion of generated mould is inhibited to be also contained in anti-mold effect.It is of the invention mould proof as that can utilize
Agent composition (mould proof to use spray product) inhibits the type of the mould of breeding, such as can enumerate: branch spore bacterium (so-called aspergillus niger
(Aspergillus niger)), alternaric bacteria, Fusariumsp, Penicillium notatum, Aspergillus, bulk bacteria, section load bacterium etc..These moulds are
In the bedroom, the mould being easy to produce in the daily living space such as living room, bathroom, lavatory, kitchen, because dead color is presented in its appearance
To heavy colour, if therefore assigning fibre (such as the window for being present in above-mentioned living space using anti-fungus agent composition of the invention
Curtain) or paper products (such as wallpaper) mildew resistance, the then coloring generated by mould be prevented from or dramatically improve, can give and consume
The excellent use of person impression really.If especially by product of the present invention be applied to setting in the bedroom, the curtain in living room, consumer
Clean feel, reassurance can be obtained.
<anti-fungus agent composition>
For anti-fungus agent composition of the invention, contain as principal component: three azole compounds, glycol and alcohol.
It as three azole compounds, can enumerate: Tebuconazole, amide azoles (imibenconazole)-db, Triadimenol
(triadimenol), paclobutrazol (paclobutrazol), propiconazole (propiconazole), hexaconazole
(hexaconazole), penconazole (penconazole), nitrile bacterium azoles (myclobutanil), metconazole (metconazole)
(registered trademark) etc..Among these compounds, preferred Tebuconazole.It should be noted that these three azole compounds both can be single
It solely uses, a variety of uses can also be mixed.
It as glycol, can enumerate: ethylene glycol (ethylene glycol), propylene glycol, 1,3-BDO, pentanediol, 1,2-
Hexylene glycol etc..Among these compounds, preferably propylene glycol, 1,3-BDO.It should be noted that these glycol both can be independent
It uses, a variety of uses can also be mixed.
It as alcohol, can enumerate: methanol, ethyl alcohol, 1- propyl alcohol, 2- propyl alcohol, butanol, amylalcohol, hexanol etc..These compounds it
In, preferred alcohol, 2- propyl alcohol.It should be noted that these alcohol both can be used alone, a variety of uses can also be mixed.
Anti-fungus agent composition of the invention, can also be also other than above-mentioned three azole compounds listed, two pure and mild alcohol
Contain deodorization ingredient, fragrance, pH regulator etc..If such as can inhibit as deodorization ingredient containing flavonoids (flavonoid)
The uncomfortable stink that can be generated in the moist environment of tool of mould hobby.
Anti-fungus agent composition of the invention cooperates the above-mentioned each ingredient listed with weight ratio appropriate, and then adds water and carry out
Adjustment is so that the concentration of each ingredient is suitable.
In the cooperation of the above-mentioned each ingredient listed, the match ratio (weight ratio) of three azole compounds and glycol is preferred to be adjusted
It is 1: 10~1: 0.5, is more preferably adjusted to 1: 10~1: 1.The case where match ratio of three azole compounds and glycol is less than 1: 10
Under (i.e. situation of the use level of three azole compounds relative to the use level of glycol less than 1/10), not because of three azole compounds
Foot, therefore have the worry that can not fully play anti-mold effect.The match ratio of three azole compounds and glycol is more than 1: 0.5 feelings
Under condition (i.e. the use level of three azole compounds is more than 2 times of situation relative to the use level of glycol), because of glycol deficiency, therefore have
Enhance the mildew resistance of three azole compounds worry with being unable to fully.
When adding water, medicament after preparation (three azole compounds, glycol, alcohol and water mixture, and according to needing to wrap
Containing other compositions person) in alcohol content be set to become 20~60 weight %.If the range, then three azole compounds energy
It will not enough precipitate but be dissolved completely in medicament.Therefore, it is easy to assign the medicament of correct amount to object to be processed.Moreover, structure
When at aftermentioned mould proof use spray product, because being formed with spray pattern appropriate, therefore medicament can be made to be attached to processing pair everywhere
As object.
<mould inhibitor spray product>
The preferred product form of anti-fungus agent composition of the invention is spray product.Such as by by above-mentioned medicament
(mixture of anti-fungus agent composition and water at least of the invention) encloses automiser spray, constitutes mould proof use of the invention and makes by spraying
Product.As automiser spray, it is preferably provided with the automiser spray of trigger-type sprayer (trigger-type sprayer).It is enclosed spray
The medicament of mist container is for example above-mentioned, and the content of the alcohol in medicament is set to become 20~60 weight %.Accordingly, medicament when spraying
Spread it is in a substantially circular, and can be formed be applied to the medicament of object to be processed coating weight become substantially uniform spray pattern.
The medicament of correct amount is assigned to object to be processed moreover, spray timings can be corresponded to.
<mold-proof method>
Above-mentioned mould proof implemented with spray product can be used in mold-proof method of the invention.Prevent specifically, operator holds
Medicament, is sprayed by the mould trigger with spray product towards the surface of object to be processed.Accordingly, medicament is attached to processing pair
As the surface of object.In turn, according to needing to make medicament dry.The spraying and drying of medicament can also be repeated as many times.Medicament is sprayed
Amount is preferably 9.0~13.5g/m2 relative to object to be processed.In the case that the spray amount of medicament is less than 9.0g/m2, as having
The adhesion amount of three azole compounds and glycol of imitating ingredient is insufficient, has and leads to not fully assign because of the raw material of object to be processed
Give the situation of anti-mold effect.The spray amount of medicament is more than 13.5g/m2In the case where, there is dry post-processing object still to leave hair
The situation of viscous sense.If to the object to be processed it is a series of it is mould proof processing terminate, object to be processed is played excellent
Anti-mold effect can continuously and effectively prevent the generation of mould for a long time.
Embodiment
In order to confirm the performance and service condition of anti-fungus agent composition of the invention, implement using curtain as the mould proof examination of object
It tests, while confirmed the appearance and spray pattern of medical fluid.In the preparation of anti-fungus agent composition, used as three azole compounds
Tebuconazole uses propylene glycol and/or 1,3-BDO as glycol, uses ethyl alcohol as alcohol, and to add ion exchange water, person makees
For medical fluid.Each ingredient of anti-fungus agent composition uses drug below.
Tebuconazole (name of an article: Biosaido R-BP20, TAISHO TECHNOS CORPORATION system)
Propylene glycol (industrial propylene glycol, ADEKA CORPORATION system)
1,3-BDO (industrial 1,3-BDO, DAICEL CORPORATION system)
Ethyl alcohol (industrial 95 weight % ethyl alcohol, Japanese synthol Co. Ltd. system)
By the enclosed automiser spray (model: T014, CANYONCORPORATION for having trigger-type sprayer of the medical fluid
System), it constitutes and of the invention mould proof uses spray product.
<prescription of medical fluid>
Prescription as Examples 1 to 7 and each medical fluid of the preparation of comparative example 1~3 is as follows.
[embodiment 1]
By 0.05 parts by weight of Tebuconazole, 20 parts by weight of ethyl alcohol (with 100 weight % of concentration conversion, about embodiment later
It is same with comparative example) and the mixing of 0.5 parts by weight of propylene glycol, in wherein addition ion exchange water and it is prepared for generally 100 weights
Measure the medical fluid of part.The match ratio (weight ratio) of Tebuconazole and propylene glycol in embodiment 1 is 1: 10.Moreover, the ethyl alcohol in medicament
Content be 20 weight %.
[embodiment 2]
0.1 parts by weight of Tebuconazole, 40 parts by weight of ethyl alcohol and 0.5 parts by weight of propylene glycol are mixed, are handed in wherein addition ion
It changes water and is prepared for the medical fluid of generally 100 parts by weight.The match ratio (weight ratio) of Tebuconazole and propylene glycol in embodiment 2 is
1:5.Moreover, the content of the ethyl alcohol in medicament is 40 weight %.
[embodiment 3]
By 0.2 parts by weight of Tebuconazole, 60 parts by weight of ethyl alcohol and 0.2 parts by weight of 1,3-BDO mix, in wherein add from
Sub- exchanged water and the medical fluid for being prepared for generally 100 parts by weight.The match ratio of Tebuconazole and 1,3-BDO in embodiment 3
(weight ratio) is 1: 1.Moreover, the content of the ethyl alcohol in medicament is 60 weight %.
[embodiment 4]
By 0.5 weight of 0.5 parts by weight of Tebuconazole, 50 parts by weight of ethyl alcohol and 0.5 parts by weight of propylene glycol and 1,3-BDO
Part mixing, in wherein adding ion exchange water and be prepared for the medical fluids of generally 100 parts by weight.Tebuconazole in embodiment 4 with
Propylene glycol and the match ratio (weight ratio) of 1,3-BDO are 1: 2.Moreover, the content of the ethyl alcohol in medicament is 50 weight %.
[embodiment 5]
0.1 parts by weight of Tebuconazole, 40 parts by weight of ethyl alcohol and 0.05 parts by weight of propylene glycol are mixed, are handed in wherein addition ion
It changes water and is prepared for the medical fluid of generally 100 parts by weight.The match ratio (weight ratio) of Tebuconazole and propylene glycol in embodiment 5 is
1:0.5.Moreover, the content of the ethyl alcohol in medicament is 40 weight %.
[embodiment 6]
0.2 parts by weight of Tebuconazole, 65 parts by weight of ethyl alcohol and 0.1 parts by weight of propylene glycol are mixed, are handed in wherein addition ion
It changes water and is prepared for the medical fluid of generally 100 parts by weight.The match ratio (weight ratio) of Tebuconazole and propylene glycol in embodiment 6 is
1:0.5.Moreover, the content of the ethyl alcohol in medicament is 65 weight %.
[embodiment 7]
0.1 parts by weight of Tebuconazole, 10 parts by weight of ethyl alcohol and 3 parts by weight of 1,3-BDO are mixed, in wherein adding ion
Exchanged water and the medical fluid for being prepared for generally 100 parts by weight.Match ratio (the weight of Tebuconazole and 1,3-BDO in embodiment 7
Measure ratio) it is 1: 30.Moreover, the content of the ethyl alcohol in medicament is 10 weight %.
[comparative example 1]
Ion exchange water is added to the medical fluid that 20 parts by weight of ethyl alcohol are prepared for generally 100 parts by weight.That is, comparative example 1
For the medical fluid without Tebuconazole and glycol (propylene glycol and/or 1,3-BDO), and by embodiment 1 prescription removal Tebuconazole and
Mixture after propylene glycol is equal.
[comparative example 2]
0.1 parts by weight of Tebuconazole and 0.5 parts by weight of propylene glycol are mixed, in wherein addition ion exchange water and are prepared for whole
Body is the medical fluid of 100 parts by weight.That is, comparative example 2 be the medical fluid without ethyl alcohol, and by embodiment 2 prescription remove ethyl alcohol after
Mixture is equal.
[comparative example 3]
0.1 parts by weight of Tebuconazole and 30 parts by weight of ethyl alcohol are mixed, in wherein addition ion exchange water and are prepared for entirety
For the medical fluid of 100 parts by weight.That is, comparative example 3 is the medical fluid without glycol (propylene glycol and/or 1,3-BDO).
<appearance of medical fluid>
Respectively with the appearance of visual confirmation Examples 1 to 7 and the medical fluid of comparative example 1~3.The evaluation criteria of appearance is as follows
It is shown.
Zero: do not observe precipitating in medical fluid, it is colorless and transparent.
×: precipitating is observed in medical fluid, it is muddy.
<anti-mold effect>
Flower will be sprayed to as the dextrose peptone medium of mould medium (glucose peptone medium)
Side window curtain (lace curtain) (spray area: 10cm × 10cm) air-dries it 1 hour.Examples 1 to 7 will be sealed with
The mould inhibitor of the invention of medical fluid is sprayed to the curtain lace (spray amount: 9.9~11.1g/m after drying with spray product2), make
It is air-dried 1 hour.Spray product about the medical fluid for being sealed with comparative example 1~3 has also carried out same operation.Then, make one
The mould (branch spore bacterium (aspergillus niger), Penicillium notatum) of fixed bacterium number is attached to curtain lace, and then is sprayed water with sprayer, is saved
In being maintained in the drier (desiccator) of humidity 90% and cultivate mould.Then it confirmed the mould after 1 week
Generation situation.The evaluation criteria of the generation situation of mould is as follows.
◎: mould does not generate completely.
Zero: mould slightly generates, but without apparent problem.
△: it observes and generates some moulds.
×: it is clearly observed and generates mould.
<spray pattern>
By the mould inhibitor spray product of the invention for the medical fluid for being sealed with Examples 1 to 7 and it is sealed with comparative example 1~3
The spray product of medical fluid distinguish with a distance from 20cm towards plastic plate each spraying primary, plastic plate is formed in visual confirmation
The shape of spray pattern, and then size is determined using graduated scale (scale).The following institute of the evaluation criteria of the shape of spray pattern
Show.
Zero: generally circular uniformly and without uneven shape.
×: shape that is uneven and having unevenness.
<test result>
Examples 1 to 7 and the test result of comparative example 1~3 are shown in table 1 below together with the prescription of medical fluid.
[table 1]
About the mould inhibitor spray product for the medical fluid for using Examples 1 to 7, the appearance of medical fluid is not observe in medical fluid
To precipitating, keeps colorless and transparent, do not find the problem.Although anti-mold effect is to have mould slightly to generate, do not become in practical
Problem.Especially with regard to Examples 1 to 4, mould does not generate completely, it is thus identified that excellent anti-mold effect.Implying that will be in medicament
The content of ethyl alcohol to be set as 20~60 weight % especially effective.About spray pattern, although the spray pattern of embodiment 6 and 7
Shape is a little uneven, but is on the whole good.
In contrast, cannot be considered in terms of the appearance and anti-mold effect of medical fluid using the spray product of the medical fluid of comparative example 1~3,
Aspect of performance, service condition are also more worse than Examples 1 to 7 (product of the present invention).
Industrial availability
Anti-fungus agent composition, mould proof use spray product and mold-proof method of the invention can be for such as curtain, clothing, quilt
The building materials such as the wall of the fibres such as cotton-padded mattress, mattress, pillow or closet, wallpaper are utilized.
Claims (10)
1. a kind of anti-fungus agent composition, contains: three azole compounds, two pure and mild alcohol.
2. anti-fungus agent composition according to claim 1, wherein three azole compounds are Tebuconazole.
3. anti-fungus agent composition according to claim 1 or 2, wherein the glycol is propylene glycol and/or 1,3- fourth two
Alcohol.
4. anti-fungus agent composition described in any one of claim 1 to 3, wherein the alcohol is ethyl alcohol and/or 2- third
Alcohol.
5. anti-fungus agent composition according to any one of claims 1 to 4, wherein three azole compounds with it is described
The match ratio of glycol is with weight ratio meter for 1: 10~1: 0.5.
6. anti-fungus agent composition according to any one of claims 1 to 5 also contains deodorization ingredient.
7. anti-fungus agent composition described according to claim 1~any one of 6, wherein selected from by branch spore bacterium, rod method
At least one of group composed by bacterium, Fusariumsp, Penicillium notatum, Aspergillus, bulk bacteria and section load bacterium mould is object.
8. anti-fungus agent composition according to any one of claims 1 to 7, is used for curtain.
9. a kind of mould proof spray product, by the medicine comprising anti-fungus agent composition according to any one of claims 1 to 8 and water
Agent is enclosed automiser spray and is formed,
The content of the alcohol in the medicament is set to 20 weight of weight %~60 %.
10. a kind of mold-proof method, from it is as claimed in claim 9 it is mould proof with spray product by the reagent spray to process object
Object makes the medicament be attached at least part on the surface of the object to be processed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111542981.9A CN114190391B (en) | 2016-08-09 | 2017-08-03 | Mildew preventive composition and mildew preventive method |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016156183 | 2016-08-09 | ||
| JP2016-156183 | 2016-08-09 | ||
| PCT/JP2017/028170 WO2018030251A1 (en) | 2016-08-09 | 2017-08-03 | Antifungal composition, antifungal spray formulation and antifungal method |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111542981.9A Division CN114190391B (en) | 2016-08-09 | 2017-08-03 | Mildew preventive composition and mildew preventive method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109561677A true CN109561677A (en) | 2019-04-02 |
Family
ID=61162542
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201780046983.4A Pending CN109561677A (en) | 2016-08-09 | 2017-08-03 | Anti-fungus agent composition, mould proof spray product and mold-proof method |
| CN202111542981.9A Active CN114190391B (en) | 2016-08-09 | 2017-08-03 | Mildew preventive composition and mildew preventive method |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111542981.9A Active CN114190391B (en) | 2016-08-09 | 2017-08-03 | Mildew preventive composition and mildew preventive method |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP6732916B2 (en) |
| KR (1) | KR102179873B1 (en) |
| CN (2) | CN109561677A (en) |
| AU (1) | AU2017309001B2 (en) |
| TW (1) | TWI652074B (en) |
| WO (1) | WO2018030251A1 (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002020207A (en) * | 2000-03-31 | 2002-01-23 | Dai-Ichi Building Maintenance Co Ltd | Antibacterial composition |
| JP2003096667A (en) * | 2001-09-27 | 2003-04-03 | Lion Corp | Deodorant, anti-microbial and wrinkle-removing agent composition for fiber |
| CN101099463A (en) * | 2006-06-26 | 2008-01-09 | 奥克西特诺工业与贸易公司 | Agrochemical composition, use for agrochemical composition and using method |
| JP2008120768A (en) * | 2006-11-15 | 2008-05-29 | Syngenta Japan Kk | Improved pesticide composition |
| EP2020180A1 (en) * | 2007-08-02 | 2009-02-04 | Wesso Ag | Dampening solution and its use in printing facilities |
| JP2011094283A (en) * | 2009-09-29 | 2011-05-12 | Osaka Kasei Kk | Antibacterial, antifungal and antiviral fiber product and method for producing the same |
| WO2014099821A2 (en) * | 2012-12-18 | 2014-06-26 | Allylix, Inc. | Solavetivone and 5-epi-beta-vertivone as pest repellants and pesticides |
| CN105284822A (en) * | 2015-11-19 | 2016-02-03 | 南京农业大学 | Tebuconazole-containing pesticide composition for preventing and treating wheat head blight and applications thereof |
| CN105432625A (en) * | 2014-09-10 | 2016-03-30 | 浙江新农化工股份有限公司 | Composition containing zinc 2-mercaptobenzothiazole and sterol demethylation inhibitors (DMIs) bactericide, and preparation and application thereof |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001245781A (en) | 2000-03-07 | 2001-09-11 | Toray Ind Inc | Curtains |
| JP2007031857A (en) | 2005-07-25 | 2007-02-08 | Taiko:Kk | Method for antibacterial treatment of textile product |
| CN101485314A (en) * | 2009-02-27 | 2009-07-22 | 利尔化学股份有限公司 | Sterilizing pesticide composition |
| CN101584323B (en) * | 2009-04-15 | 2012-06-27 | 陕西蒲城县美邦农药有限责任公司 | Azoxystrobin and hexaconazole-containing antiseptic composition |
| JP5970155B2 (en) | 2010-09-28 | 2016-08-17 | ロンザジャパン株式会社 | Wood fender composition |
| CN102972409A (en) * | 2012-12-10 | 2013-03-20 | 福建省莆田市友缘实业有限公司 | Seedling-protection micro-emulsion |
| JP2014159413A (en) * | 2013-01-28 | 2014-09-04 | Nippon Soda Co Ltd | Azolyloxime compound or salt thereof, pest control agent, insecticide or acaricide, sterilizer, and ectoparasite control agent |
-
2017
- 2017-07-20 TW TW106124317A patent/TWI652074B/en active
- 2017-08-03 JP JP2018532977A patent/JP6732916B2/en active Active
- 2017-08-03 CN CN201780046983.4A patent/CN109561677A/en active Pending
- 2017-08-03 KR KR1020197002439A patent/KR102179873B1/en active IP Right Grant
- 2017-08-03 AU AU2017309001A patent/AU2017309001B2/en active Active
- 2017-08-03 WO PCT/JP2017/028170 patent/WO2018030251A1/en active Application Filing
- 2017-08-03 CN CN202111542981.9A patent/CN114190391B/en active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002020207A (en) * | 2000-03-31 | 2002-01-23 | Dai-Ichi Building Maintenance Co Ltd | Antibacterial composition |
| JP2003096667A (en) * | 2001-09-27 | 2003-04-03 | Lion Corp | Deodorant, anti-microbial and wrinkle-removing agent composition for fiber |
| CN101099463A (en) * | 2006-06-26 | 2008-01-09 | 奥克西特诺工业与贸易公司 | Agrochemical composition, use for agrochemical composition and using method |
| JP2008120768A (en) * | 2006-11-15 | 2008-05-29 | Syngenta Japan Kk | Improved pesticide composition |
| EP2020180A1 (en) * | 2007-08-02 | 2009-02-04 | Wesso Ag | Dampening solution and its use in printing facilities |
| JP2011094283A (en) * | 2009-09-29 | 2011-05-12 | Osaka Kasei Kk | Antibacterial, antifungal and antiviral fiber product and method for producing the same |
| WO2014099821A2 (en) * | 2012-12-18 | 2014-06-26 | Allylix, Inc. | Solavetivone and 5-epi-beta-vertivone as pest repellants and pesticides |
| CN105432625A (en) * | 2014-09-10 | 2016-03-30 | 浙江新农化工股份有限公司 | Composition containing zinc 2-mercaptobenzothiazole and sterol demethylation inhibitors (DMIs) bactericide, and preparation and application thereof |
| CN105284822A (en) * | 2015-11-19 | 2016-02-03 | 南京农业大学 | Tebuconazole-containing pesticide composition for preventing and treating wheat head blight and applications thereof |
Non-Patent Citations (1)
| Title |
|---|
| JEHANGIR K. KHAN 等: "Interspecies Comparison of Pharmacokinetics of the Novel Triazole Antifungal Agent SYN-2869 and Its Derivatives", 《ANTIMICROBIAL AGENTS AND CHEMOTHERAPY》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20190022749A (en) | 2019-03-06 |
| CN114190391B (en) | 2024-02-20 |
| AU2017309001B2 (en) | 2019-12-19 |
| KR102179873B1 (en) | 2020-11-17 |
| CN114190391A (en) | 2022-03-18 |
| TW201805026A (en) | 2018-02-16 |
| WO2018030251A1 (en) | 2018-02-15 |
| TWI652074B (en) | 2019-03-01 |
| JPWO2018030251A1 (en) | 2019-06-06 |
| JP6732916B2 (en) | 2020-07-29 |
| AU2017309001A1 (en) | 2019-03-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2006006594A1 (en) | Antibacterial composition, antibacterial molding, solution containing antibacterial composition, detergent, surface of tatami mat and tatami mat | |
| WO2011062259A1 (en) | Composition, antibacterial processing agent and antibacterial molded article | |
| JP2007211238A (en) | Aqueous dispersion, surface coating treatment agent, wood treating agent, floor wax, air channel surface treating agent, fiber treating agent, and paint | |
| CN102388911A (en) | Suspension seed coating formulation | |
| JP2008119433A (en) | Storage method for paper napkin/hand towel | |
| CN103371190B (en) | Pesticide combination containing pyrimidine nucleosides antibiotics | |
| CN109561677A (en) | Anti-fungus agent composition, mould proof spray product and mold-proof method | |
| CN103798237A (en) | Ultra-low-volume liquid agent containing boscalid | |
| US20130071461A1 (en) | Methods employing anhydrous disinfectant | |
| CN105803851A (en) | Environment-friendly inflaming retardant wallpaper | |
| JP2006192225A (en) | Method for preserving wet paper towel/wet hand-towel | |
| KR20150122495A (en) | Manufacturing Method of Decorative Board and that's Decorative Board | |
| JP2002017828A (en) | Antimicrobial and deodorant daily goods or building materials | |
| CN105803857A (en) | Environment-friendly wallpaper | |
| CN1278785C (en) | Spray painting method of deodorant ,antiseptic and antifungal agents, and articles processed by the same | |
| CN105368119A (en) | Antibacterial water based putty for woodware | |
| CN106236672A (en) | Orange blossom hydrosol wet sanitary napkins and preparation method thereof | |
| CN104719306A (en) | Fungicidal composition containing isoprothiolane and propiconazole and application of fungicidal composition | |
| CN107047610A (en) | A kind of composition containing chlorine dioxide and preparation method thereof | |
| CN104012536B (en) | A kind of bactericidal composition of fluorine-containing mepanipyrim and methoxy acrylic | |
| CN104106582B (en) | A kind of bactericidal composition containing chlorine nalidixic bacterium ester and thiocarbamates | |
| CN102302008A (en) | Metalaxyl and azoxystrobin compound pesticide preparation | |
| CN107419601A (en) | A kind of mould proof processing coating of Art Design printing packaging paper and preparation method thereof | |
| KR100285276B1 (en) | Manufacturing method of wallpaper having antibacterial property and mildew resistance | |
| CN106035348A (en) | Bactericidal composition containing SYP-Z048 and triflumizole |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 40001289 Country of ref document: HK |