KR102086608B1 - Deodorant for removing livestock manure - Google Patents
Deodorant for removing livestock manure Download PDFInfo
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Abstract
Description
본 발명은 축산 분뇨 악취제거용 탈취제에 관한 것으로서, 보다 상세하게는 축산 분뇨는 물론 구제역이나 AI 등에 의해 살처분된 동물들의 사체 매립지로부터 발생되는 심각한 악취를 자연환경적 미생물 분해 작용을 이용하여 신속하게 분해 제거하여 환경친화적으로 개선된 축산 분뇨 악취제거용 탈취제에 관한 것이다.The present invention relates to a deodorant for removing odor of livestock manure, and more specifically, a rapid odor generated from dead landfills of animals killed by foot-and-mouth disease or AI, as well as livestock manure, by using a natural environmental microbial decomposition effect. The present invention relates to a deodorant for removing livestock manure malodor by decomposing and removing environmentally friendly substances.
현재 가축의 사육환경의 대형화 및 집단화에 의해 가축은 상대적으로 면역력이 약화되고 있다.Currently, livestock is relatively weakened due to the enlargement and grouping of livestock.
때문에, 축산농가에서는 각종 동물의 전염병을 막기 위하여 예방접종이나 환경 개선등의 노력에도 불구하고 해마다 많은 가축이 전염병에 의해 살처분되고 있다.Therefore, in livestock farming, many livestock are killed by infectious diseases every year, despite efforts to prevent vaccination and environmental improvement in order to prevent infectious diseases of various animals.
그러나, 매립후 시간이 지나면서 부패과정이 심각하게 진행되어 토양이 오염되고 많은 악취와 함께 발생하는 침출수로 인하여 지하수가 오염 되는등 심각한 2차, 3차 환경오염이 유발되는 문제가 있다.However, there is a problem that serious secondary and tertiary environmental pollution is caused, such as a serious progression of the decay process over time after landfilling, soil contamination and groundwater contamination due to leachate generated with many odors.
뿐만 아니라, 축산 농가에서는 가축의 축분에서 나는 악취 때문에 축산 농가 자신은 물론 주변 거주자들의 민원문제로 상당한 어려움을 겪고 있다.In addition, livestock farmers are experiencing considerable difficulties due to the complaints of livestock farming due to the complaints of the livestock farmers themselves and their neighbors.
이와 같은 악취를 유발시키는 가장 큰 성분들은 휘발성 지방산, 황화수소, p-크레졸, 인솔, 스키톨, 디아세틸 및 암모니아 등을 들 수 있다.The largest constituents that cause such odors include volatile fatty acids, hydrogen sulfide, p-cresol, insoles, scitol, diacetyl and ammonia.
하지만, 이러한 성분들을 효과적으로 분해 제거할 수 있는 약액을 구현하기 어려워 아직까지 이를 효과있게 해소하고 있는 예는 많지 않다.However, it is difficult to implement a chemical solution that can effectively decompose and remove these components, so there are not many examples that solve this effect effectively.
본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 축산 분뇨는 물론 구제역이나 AI 등에 의해 살처분된 동물들의 사체 매립지로부터 발생되는 심각한 악취를 자연환경적 미생물 분해 작용을 이용하여 신속하게 분해 제거하여 환경친화적으로 개선된 축산 분뇨 악취제거용 탈취제를 제공함에 그 주된 목적이 있다.The present invention was created in view of the above-mentioned problems in the prior art, and it is a natural odor decomposing action of a serious odor generated from a landfill of animal slaughtered by not only livestock manure but also foot-and-mouth disease or AI. Its main purpose is to provide a deodorant for removing livestock manure malodor odor is improved environmentally friendly by rapid decomposition removal.
본 발명은 상기한 목적을 달성하기 위한 수단으로, 고온호기성 미생물인 균들이 함유된 탈취액으로 축산 분뇨에 살포되어 악취를 분해 제거하는 축산 분뇨 악취제거용 탈취제에 있어서; 상기 탈취액은 당밀액 1ℓ를 기준으로 정제포도당 500g, 벤토나이트 분말 250g, 망간아세테이트 150g, 요구르트 100g, 누룩 20g, 아스트균 10㎖를 혼합한 후 35℃에서 5일 동안 증식시켜 요구르트로부터 생성된 유산균 1억-10억개/㎖, 아스트균 5천만개 이상/㎖, 누룩으로부터 생성된 누룩곰팜이균 1조개 이상/㎖ 유지되게 한 것을 특징으로 하는 축산 분뇨 악취제거용 탈취제를 제공한다.The present invention as a means for achieving the above object, in the deodorant for removing livestock manure odor deodorant is sprayed on livestock manure with deodorant liquid containing bacteria that are high temperature aerobic microorganisms; The deodorant is a lactic acid bacterium produced from yogurt by mixing 500 g of purified glucose, 250 g of bentonite powder, 250 g of manganese acetate, 150 g of yoghurt, 100 g of yoghurt, 20 g of yeast, and 10 ml of aseptic bacteria based on 1 L of molasses It provides a deodorant for removing livestock manure odor, characterized in that the billion-billion / ml, more than 50 million / ml of Aster bacteria, the yeast gom palm produced from yeast is maintained at 1 trillion / ml.
이때, 상기 탈취액에 질산망간 10g과, NTA(Nitrilotriacetic acid) 50g과, 수가용성 철염 10g과, 주석산 5g과, FeSO4.7H2O 수용액 10㎖을 더 첨가한 것에도 그 특징이 있다.At this time, also with 10g of manganese nitrate in the liquid deodorant, NTA (Nitrilotriacetic acid) and 50g, 10g and water-soluble iron salt, tartaric acid and 5g, FeSO 4 .7H 2 O was added to a further aqueous solution 10㎖ has its features.
본 발명에 따르면, 축산 분뇨는 물론 구제역이나 AI 등에 의해 살처분된 동물들의 사체 매립지로부터 발생되는 심각한 악취를 자연환경적 미생물 분해 작용을 이용하여 신속하게 분해 제거하여 환경친화적으로 개선된 효과를 얻을 수 있다.According to the present invention, it is possible to obtain an environmentally-improved effect by rapidly decomposing and removing livestock manure as well as serious odors generated from dead landfills of animals killed by foot-and-mouth disease or AI by using natural microbial decomposition. have.
이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, a preferred embodiment according to the present invention will be described in more detail.
본 발명 설명에 앞서, 이하의 특정한 구조 내지 기능적 설명들은 단지 본 발명의 개념에 따른 실시예를 설명하기 위한 목적으로 예시된 것으로, 본 발명의 개념에 따른 실시예들은 다양한 형태로 실시될 수 있으며, 본 명세서에 설명된 실시예들에 한정되는 것으로 해석되어서는 아니된다.Prior to the description of the present invention, the following specific structures or functional descriptions are merely illustrated for the purpose of describing embodiments according to the inventive concept, and the embodiments according to the inventive concept may be implemented in various forms, It should not be construed as limited to the embodiments described herein.
또한, 본 발명의 개념에 따른 실시예는 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있으므로, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경물, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다.In addition, the embodiment according to the concept of the present invention may be variously modified and may have various forms, it should be understood to include all modifications, equivalents, or substitutes included in the spirit and scope of the present invention. .
본 발명은 가축 전염병에 의해 살처분된 매립지는 물론 특히, 가축이 사육되는 축산 농가의 축사에 주기적으로 살포하는 것만으로도 아주 쉽고 효과적인 악취 제거 및 환경오염 예방에 기여할 수 있도록 한 것이다.The present invention is intended to contribute to very easy and effective removal of odor and prevention of environmental pollution only by spraying periodically in a livestock farm where livestock are raised, as well as landfills killed by livestock infectious diseases.
특히, 본 발명에 따른 탈취제 살포를 통해 적정한 미생물이 활성화되는 조건을 갖추어 발효를 촉진하고, 그 과정에서 탈취 기능을 향상시키면서 발효열을 급상승시켜 각종 병원균 및 기생충을 살균할 수 있도록 한 것에 특징이 있다.In particular, the deodorant spray according to the present invention is characterized in that the appropriate microorganisms are activated to promote fermentation, sterilize various pathogens and parasites by rapidly increasing the fermentation heat while improving the deodorizing function in the process.
예컨대, 본 발명은 특히, 축산 분료에서 악취의 원인인 암모니아를 유산균과의 중화반응을 통해 유산암모늄으로 변환시켜 양질의 퇴비가 되게 하면서 악취 발생도 억제시킬 수 있도록 하고, 호기성 미생물의 먹이 기능을 충실히 유지하여 발효열을 높여 수분을 증발시킴으로써 악취 발생을 또다시 억제하며, 그 과정에서 발효열을 높여 각종 병원균 및 기생충을 살균하고, 추후 퇴비화될 때 양질의 퇴비로 전환되어 토양 개량, 토양 비옥화에도 기여할 수 있도록 한 것이다.For example, the present invention converts ammonia, which is the cause of malodor, from animal husbandry to ammonium lactate through neutralization with lactic acid bacteria, thereby making it possible to suppress the occurrence of malodor while providing good compost and faithfully feeding the aerobic microorganisms. By keeping the fermentation heat up and evaporating the moisture, it suppresses the occurrence of odor again.In the process, it raises the heat of fermentation to sterilize various pathogens and parasites, and when it is later composted, it can be converted into high quality compost to contribute to soil improvement and soil fertilization. It would be.
이를 위해, 본 발명에 따른 축산 분뇨 악취제거용 탈취제는 고온호기성 미생물인 균들이 함유된 탈취액으로서, 상기 탈취액은 주성분인 당밀액 1ℓ를 기준으로 정제포도당 500g, 벤토나이트 분말 250g, 망간아세테이트 150g, 요구르트 100g, 누룩 20g, 아스트균 10㎖를 혼합한 후 35℃에서 5일 동안 증식시켜 요구르트로부터 생성된 유산균 1억-10억개/㎖, 아스트균 5천만개 이상/㎖, 누룩으로부터 생성된 누룩곰팜이균 1조개 이상/㎖ 유지되게 한 것이다.To this end, the deodorant for removing livestock manure odor according to the present invention is a deodorant containing microorganisms, which are high temperature aerobic microorganisms. 100 g of yoghurt, 20 g of yeast, 10 ml of aster bacterium are mixed, and then grown at 35 ° C. for 5 days, resulting in lactic acid bacteria of 100 billion to 100 million / ml, more than 50 million aster bacteria / ml, and yeast gom palm bacteria One trillion / ml is maintained.
이때, 정제포도당과 당밀액은 요쿠르트로부터 생성된 유산균ㆍ아스트균ㆍ누룩곰팡이균의 충실한 먹이가 되어 증식을 빠르게 하도록 유도한다.At this time, the purified glucose and molasses become faithful foods of lactic acid bacteria, asbestos, and yeast fungi produced from yogurt, leading to rapid growth.
그리하여, 탈취액이 축산 분료에 살포되었을 때 유산균은 잡균 및 미네날을 킬레이트화하고 당류를 발효시켜 에너지를 얻은 다량의 유산이 유기산을 생성해 pH를 낮추게 된다.Thus, when the deodorant is sprayed on the livestock powder, the lactic acid bacteria chelate the various bacteria and minerals, ferment the sugars, and a large amount of lactic acid, which is energy-produced, produces organic acids to lower the pH.
아울러, 벤토나이트 분말은 다공성 분말로서 미네날이 풍부하여 균들의 증식과 먹이의 배지 기능을 충실히 수행하게 된다. 특히, 벤토나이트는 66종의 미네랄을 포함하고 있어 미생물 증식에 매우 유용하다.In addition, bentonite powder is a porous powder, rich in minerals to faithfully perform the growth of bacteria and the medium of food. In particular, bentonite contains 66 minerals, which is very useful for microbial growth.
나아가, 망간아세테이트는 사방형의 결정성 분말로 분해되어 망간산화물을 형성할 때 서서히 산화되면서 유기물 분해 촉진 효과를 높이는 작용을 위해 첨가된다.Further, manganese acetate is added to the action of increasing the organic decomposition decomposition promoting effect while being slowly oxidized when decomposed into a crystalline powder of a rectangular shape to form a manganese oxide.
또한, 단백질이 분해되어 생기는 아미노산이 암모니아와 같은 독성 물질로 분해되면 유산균이 그 암모니아 성분을 분해하게 된다.In addition, when amino acids produced by the breakdown of proteins are broken down into toxic substances such as ammonia, the lactic acid bacteria break down the ammonia components.
뿐만 아니라, 누룩곰팡이균은 암모니아는 물론 아질산염 등 악취물질을 분해 제거한다. 특히, 단백질을 가수분해하는 프레테아제나 전분을 분해하여 α-아밀라제 효소를 생성하여 유산균의 단백질 분해를 촉진하게 된다.In addition, yeast fungi decompose and remove odorous substances such as ammonia as well as nitrites. In particular, the degradation of pretease or starch, which hydrolyzes proteins, produces α-amylase enzymes to promote proteolytic degradation of lactic acid bacteria.
아울러, 아스트균은 누룩곰팜이균 등이 분해한 유기물을 아미노산, 비타민, 성장인자로 재합성시켜 발효를 촉진하고 발효열을 60-80℃까지 끌어 올리는데 기여하여 각종 병원균과 기생충을 사멸시키는데 기여한다.In addition, Ast bacteria contribute to killing various pathogens and parasites by resynthesizing organic matters decomposed by Nuruk gom palm bacteria etc. into amino acids, vitamins and growth factors, promoting fermentation and raising fermentation heat to 60-80 ℃.
사멸되는 병원균과 기생충은 주로 60℃ 이하에서 활성을 갖는 것들로서, 60℃를 초과한 채 20-30분이 경과하면 대부분 사멸된다.The pathogens and parasites that are killed are mainly those having an activity at 60 ° C. or lower. Most of them are killed after 20-30 minutes in excess of 60 ° C.
이러한 병원균과 기생충은 표 1에 나타내었다.These pathogens and parasites are shown in Table 1.
이에 더하여, 본 발명에서는 질산망간 10g과, NTA(Nitrilotriacetic acid) 50g과, 수가용성 철염 10g과, 주석산 5g과, FeSO4.7H2O 수용액 10㎖을 더 첨가할 수 있다.In addition, in the present invention may be further added to the manganese nitrate and 10g, NTA (Nitrilotriacetic acid) and 50g, 10g and water-soluble iron salt, tartaric acid and 5g, FeSO 4 .7H 2 O solution 10㎖.
이때, 질산망간은 가시광선 영역에서 광촉매 효과를 발현하여 유기물 및 악취 분해 제거능력을 높여 준다.At this time, manganese nitrate expresses a photocatalytic effect in the visible light region, thereby enhancing the organic matter and odor decomposition ability.
또한, NTA는 니트릴로트리아세트산으로서, 암모니아와 모노클로로아세트산의 혼합물에 시안화칼륨, 포르말린을 작용시켜 얻는 백색 결정성 분말이며, 철염과의 킬레이트화를 통해 암모니아, 트리메틸아민, 황화수소, 메르캅탄과 같은 악취제거에 탁월한 킬레이트제이다.NTA is a nitrilotriacetic acid, which is a white crystalline powder obtained by reacting potassium cyanide and formalin on a mixture of ammonia and monochloroacetic acid. Excellent chelating agent for removal.
그리고, 수가용성 철염은 Fe(NO3)3, FeCl3, FeSO4 중에서 선택된 어느 하나이며, 상기 킬레이트제와 반응하여 황화수소 제거에 직접적인 영향을 미친다.The water-soluble iron salt is any one selected from Fe (NO 3 ) 3 , FeCl 3 , and FeSO 4 , and reacts with the chelating agent to directly affect hydrogen sulfide removal.
뿐만 아니라, 주석산은 철염과의 안정적인 킬레이트화를 통해 황화수소를 효과적으로 분해 제거하기 위해 첨가되며, FeSO4.7H2O 수용액은 철염, 즉 철이온을 제공하는 킬레이트화를 위한 베이스 용액이다.In addition, the tartaric acid is through a stable chelation of the iron salt is added in order to effectively remove hydrogen sulfide decomposition, FeSO 4 .7H 2 O solution is a base solution for chelation to provide a iron salt, namely iron ions.
덧붙여, 미생물 증식을 촉진하기 위해 정장석 분말을 20g, 미네날을 보충하여 미생물의 생장 활성화를 더욱 촉진하도록 조선간강 40㎖를 더 첨가할 수 있다.In addition, 20 g of feldspar powder may be added to supplement the minerals to promote microbial growth, and 40 ml of Chogangan Steel may be further added to further promote the growth activation of microorganisms.
다시 말해, 상기 정장석 분말은 규산염 광물인 정장석을 분말화시킨 것으로, 정장석은 유기물을 비롯한 70여종 미네랄과 필수 미량 희귀원소가 풍부한 광물이며, 특히 원적외선 방사율이 92.6%이고, ph 6.5~7.5이며, 70여종의 미네랄과 토착 미생물이 다량 함유되어 있어 미생물 증식에 지대한 역할을 한다.In other words, the feldspar powder is a powder of feldspar, a silicate mineral, feldspar is a mineral rich in 70 kinds of minerals including organics and essential trace elements, in particular, the far-infrared emissivity is 92.6%, ph 6.5-7.5, 70 It contains a large amount of minerals and indigenous microorganisms, and plays a huge role in the growth of microorganisms.
이러한 정장석 분말은 작토층을 깊게 하고 흙을 살리는 효과가 있으며, 토양중의 유기물 분해 작용, 토양 산성 중화 작용을 하여 토양을 개량시켜 주는 기능을 수행한다.These powders have a function of deepening the soil layer and saving soil, and decomposing organic matter in soil, neutralizing soil acid, and improving soil.
뿐만 아니라, 상기 조선간장은 자연발효시킨 천연 염액으로서 미생물의 배양 및 발효 작용을 더욱 향상시키고 미네랄을 보충하는 역할을 한다.In addition, the soy sauce is a natural fermentation of natural fermentation and serves to further enhance the culture and fermentation of microorganisms and minerals.
이와 같은 본 발명의 탈취제에 대한 탈취 성능을 확인하기 위해 4대 악취에 대해 탈취 효율을 테스트하였고, 그 결과는 표 2에 나타내었다.In order to confirm the deodorizing performance for the deodorant of the present invention, the deodorization efficiency was tested for the four major odors, the results are shown in Table 2.
또한, 축산폐수처리장 저류조에 본 발명에 따른 탈취제를 폐수 1㎥ 당 1ℓ를 투입한 후 암모니아, 유화수소, 메틸메르캅탄에 대한 제거효율을 가스검지관법으로 측정하였고, 취기농도는 관능법으로 측정하였으며, 그 결과는 표 3에 나타내었다.In addition, 1 liter of deodorant according to the present invention was added to the storage tank of the livestock wastewater treatment plant, and the removal efficiency for ammonia, hydrogen sulfide, and methyl mercaptan was measured by gas detection method, and the odor concentration was measured by the sensory method. The results are shown in Table 3.
이와 같이, 본 발명에 따른 탈취제는 탈취효율이 매우 뛰어난 것으로 확인되었다.As such, the deodorant according to the present invention was found to be very excellent deodorizing efficiency.
Claims (2)
상기 탈취액은 당밀액 1ℓ를 기준으로 정제포도당 500g, 벤토나이트 분말 250g, 망간아세테이트 150g, 요구르트 100g, 누룩 20g, 아스트균 10㎖를 혼합한 후 35℃에서 5일 동안 증식시켜 요구르트로부터 생성된 유산균 1억-10억개/㎖, 아스트균 5천만개 이상/㎖, 누룩으로부터 생성된 누룩곰팜이균 1조개 이상/㎖ 유지되게 하되,
상기 탈취액에 질산망간 10g과, NTA(Nitrilotriacetic acid) 50g과, 수가용성 철염 10g과, 주석산 5g과, FeSO4.7H2O 수용액 10㎖을 더 첨가한 것을 특징으로 하는 축산 분뇨 악취제거용 탈취제.A deodorant for removing livestock manure odor which is sprayed on livestock manure with deodorant containing microorganisms which are high temperature aerobic microorganisms;
The deodorant is a lactic acid bacterium produced from yogurt by mixing 500 g of purified glucose, 250 g of bentonite powder, 250 g of manganese acetate, 150 g of yoghurt, 100 g of yeast, 20 g of yeast, and 10 ml of aseptic bacteria, and then growing at 35 ° C. for 5 days. Billion-billion / ml, more than 50 million / ml Aster, yeast gom palm produced from yeast to maintain more than 1 trillion / ml,
10g of manganese nitrate and the deodorizing liquid, NTA (Nitrilotriacetic acid) for deodorants and 50g, 10g and water-soluble iron salt, tartaric acid and 5g, FeSO 4 .7H 2 O solution livestock waste odor, characterized in that the further added 10㎖ .
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