KR101945513B1 - 나노리소그래피용 폴리락티드/실리콘 함유 블록 공중합체 - Google Patents

나노리소그래피용 폴리락티드/실리콘 함유 블록 공중합체 Download PDF

Info

Publication number
KR101945513B1
KR101945513B1 KR1020147024163A KR20147024163A KR101945513B1 KR 101945513 B1 KR101945513 B1 KR 101945513B1 KR 1020147024163 A KR1020147024163 A KR 1020147024163A KR 20147024163 A KR20147024163 A KR 20147024163A KR 101945513 B1 KR101945513 B1 KR 101945513B1
Authority
KR
South Korea
Prior art keywords
substrate
block copolymer
monomer
silicon
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020147024163A
Other languages
English (en)
Korean (ko)
Other versions
KR20140133530A (ko
Inventor
크리스토퍼 존 엘리슨
칼튼 그랜트 윌슨
줄리아 쿠센
크리스토퍼 엠 베이츠
Original Assignee
보드 오브 리전츠, 더 유니버시티 오브 텍사스 시스템
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 보드 오브 리전츠, 더 유니버시티 오브 텍사스 시스템 filed Critical 보드 오브 리전츠, 더 유니버시티 오브 텍사스 시스템
Publication of KR20140133530A publication Critical patent/KR20140133530A/ko
Application granted granted Critical
Publication of KR101945513B1 publication Critical patent/KR101945513B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/695Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
    • C08G63/6952Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon derived from hydroxycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C21/00Accessories or implements for use in connection with applying liquids or other fluent materials to surfaces, not provided for in groups B05C1/00 - B05C19/00
    • B05C21/005Masking devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/002Processes for applying liquids or other fluent materials the substrate being rotated
    • B05D1/005Spin coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/14Monomers containing only one unsaturated aliphatic radical containing one ring substituted by hetero atoms or groups containing heteroatoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/02Alkylation
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0002Lithographic processes using patterning methods other than those involving the exposure to radiation, e.g. by stamping
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00Chemical modification of a polymer
    • C08F2810/40Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851Intermediate layer is discontinuous or differential
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mathematical Physics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Silicon Polymers (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020147024163A 2012-02-10 2013-02-07 나노리소그래피용 폴리락티드/실리콘 함유 블록 공중합체 Active KR101945513B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261597329P 2012-02-10 2012-02-10
US61/597,329 2012-02-10
US13/761,763 2013-02-07
US13/761,763 US9120117B2 (en) 2012-02-10 2013-02-07 Polylactide/silicon-containing block copolymers for nanolithography
PCT/US2013/025160 WO2013119820A1 (en) 2012-02-10 2013-02-07 Polyactide/silicon-containing block copolymers for nanolithography

Publications (2)

Publication Number Publication Date
KR20140133530A KR20140133530A (ko) 2014-11-19
KR101945513B1 true KR101945513B1 (ko) 2019-02-07

Family

ID=48948005

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020147024163A Active KR101945513B1 (ko) 2012-02-10 2013-02-07 나노리소그래피용 폴리락티드/실리콘 함유 블록 공중합체

Country Status (6)

Country Link
US (2) US9120117B2 (https=)
JP (1) JP6228932B2 (https=)
KR (1) KR101945513B1 (https=)
CN (1) CN104254557B (https=)
SG (1) SG11201404416RA (https=)
WO (1) WO2013119820A1 (https=)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20140136933A (ko) 2012-02-10 2014-12-01 보드 오브 리전츠, 더 유니버시티 오브 텍사스 시스템 블록 공중합체 박막에서 도메인 배향을 조절하기 위해 화학 증착된 필름의 사용
FR3014876B1 (fr) * 2013-12-13 2017-03-31 Arkema France Procede de realisation d'un film de copolymere a blocs sur un substrat
JP6264148B2 (ja) * 2014-03-28 2018-01-24 Jsr株式会社 パターン形成用組成物及びパターン形成方法
US9489974B2 (en) 2014-04-11 2016-11-08 Seagate Technology Llc Method of fabricating a BPM template using hierarchical BCP density patterns
US10259907B2 (en) 2015-02-20 2019-04-16 Az Electronic Materials (Luxembourg) S.À R.L. Block copolymers with surface-active junction groups, compositions and processes thereof
JP6413888B2 (ja) * 2015-03-30 2018-10-31 Jsr株式会社 パターン形成用組成物、パターン形成方法及びブロック共重合体
KR102463893B1 (ko) * 2015-04-03 2022-11-04 삼성전자주식회사 하드마스크 조성물 및 이를 이용한 패턴의 형성방법
US9982097B2 (en) * 2016-02-11 2018-05-29 International Business Machines Corporation Thin film self assembly of topcoat-free silicon-containing diblock copolymers
CN109153760B (zh) * 2016-02-23 2021-10-29 得克萨斯大学体系董事会 用于10nm以下构图的嵌段共聚物
JP2018046202A (ja) 2016-09-15 2018-03-22 東芝メモリ株式会社 パターン形成方法、自己組織化材料、半導体装置の製造方法
KR102448940B1 (ko) * 2017-01-19 2022-09-30 닛산 가가쿠 가부시키가이샤 미세상분리 패턴형성을 위한 자기조직화막 형성 조성물
CN110191930B (zh) * 2017-01-19 2022-01-04 日产化学株式会社 用于形成微细相分离图案的下层膜形成用组合物
CN108559084B (zh) * 2018-04-13 2020-12-04 华东理工大学 一种聚乳酸基疏水薄膜的制备方法
US11307496B2 (en) 2019-11-19 2022-04-19 International Business Machines Corporation Metal brush layer for EUV patterning
CN111253556B (zh) * 2020-03-20 2022-02-18 南京工业大学 一种功能化可回收高分子均聚物及其制备方法与应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998046655A1 (fr) 1997-04-14 1998-10-22 Yukio Nagasaki Polymere methacrylique possedant un groupe fonctionnel terminal, et composition a base de ce polymere
US20090239086A1 (en) 2008-03-18 2009-09-24 Kenichi Ishizuka Microphase-separated structure on flexible substrate, and method of manufacture thereof
CN101550229A (zh) 2009-05-12 2009-10-07 南开大学 聚乙丙交酯的制备与硅端基剪切的方法
WO2011116223A1 (en) 2010-03-18 2011-09-22 Board Of Regents The University Of Texas System Silicon-containing block co-polymers, methods for synthesis and use

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2986509B2 (ja) * 1989-05-26 1999-12-06 三井化学株式会社 変性ポリエステル樹脂組成物、その製造方法、およびその用途
JP3394347B2 (ja) * 1994-12-28 2003-04-07 株式会社島津製作所 生分解性ポリエステル組成物及びその成型品
US8101261B2 (en) 2008-02-13 2012-01-24 Micron Technology, Inc. One-dimensional arrays of block copolymer cylinders and applications thereof
US8114301B2 (en) * 2008-05-02 2012-02-14 Micron Technology, Inc. Graphoepitaxial self-assembly of arrays of downward facing half-cylinders
US8268545B2 (en) 2008-06-09 2012-09-18 Seagate Technology Llc Formation of a device using block copolymer lithography
CN101503497B (zh) * 2009-03-02 2010-08-25 江南大学 一种星型嵌段酸敏性纳米胶束的制备方法
JP5484817B2 (ja) * 2009-08-04 2014-05-07 株式会社東芝 パターン形成方法及び半導体装置の製造方法
KR20140136933A (ko) * 2012-02-10 2014-12-01 보드 오브 리전츠, 더 유니버시티 오브 텍사스 시스템 블록 공중합체 박막에서 도메인 배향을 조절하기 위해 화학 증착된 필름의 사용

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998046655A1 (fr) 1997-04-14 1998-10-22 Yukio Nagasaki Polymere methacrylique possedant un groupe fonctionnel terminal, et composition a base de ce polymere
US20090239086A1 (en) 2008-03-18 2009-09-24 Kenichi Ishizuka Microphase-separated structure on flexible substrate, and method of manufacture thereof
CN101550229A (zh) 2009-05-12 2009-10-07 南开大学 聚乙丙交酯的制备与硅端基剪切的方法
WO2011116223A1 (en) 2010-03-18 2011-09-22 Board Of Regents The University Of Texas System Silicon-containing block co-polymers, methods for synthesis and use

Also Published As

Publication number Publication date
KR20140133530A (ko) 2014-11-19
JP6228932B2 (ja) 2017-11-08
US20130266780A1 (en) 2013-10-10
SG11201404416RA (en) 2014-08-28
US9834700B2 (en) 2017-12-05
CN104254557A (zh) 2014-12-31
CN104254557B (zh) 2016-06-29
US9120117B2 (en) 2015-09-01
JP2015511402A (ja) 2015-04-16
WO2013119820A1 (en) 2013-08-15
US20150353763A1 (en) 2015-12-10

Similar Documents

Publication Publication Date Title
KR101945513B1 (ko) 나노리소그래피용 폴리락티드/실리콘 함유 블록 공중합체
JP6258227B2 (ja) 薄膜ブロックコポリマーの配向性の制御のための無水コポリマートップコート
JP6132854B2 (ja) ブロックコポリマー薄膜においてドメインの配向性を制御するための化学蒸着された膜の使用
JP5254642B2 (ja) ナノスケール構造を配向、位置決め、および形成する方法
US9541830B2 (en) Block copolymers and lithographic patterning using same
US9417520B2 (en) Methods of patterning block copolymer layers and patterned structures
Borah et al. Soft graphoepitaxy for large area directed self‐assembly of polystyrene‐block‐poly (dimethylsiloxane) block copolymer on nanopatterned POSS substrates fabricated by nanoimprint lithography
Borah et al. Soft-graphoepitaxy using nanoimprinted polyhedral oligomeric silsesquioxane substrates for the directed self-assembly of PS-b-PDMS
Padeste et al. Patterned grafting of polymer brushes onto flexible polymer substrates
TWI496800B (zh) 用於奈米微影術之含聚乳交酯/矽的嵌段共聚物
KR100983356B1 (ko) 산화티탄 촉매 작용에 의하여 폴리스티렌-블록-폴리카르보실란 이중블록공중합체로부터 유도된 실리카 나노점 어레이의 제조방법 및 이에 따라 제조된 실리카 나노점 어레이
TWI513577B (zh) 用於薄膜嵌段共聚物之取向控制之酸酐共聚物面塗層
Chen et al. Patterning nanocluster polystyrene brushes grafted from initiator cores on silicon surfaces by lithography processing
Sleshimo et al. Anhydride copolymer top coats for orientation control of thin film block copolymers
Mitra Tuning Melt/Brush Interactions for Functional Polymer Films
Miyashita Fine Pattern Drawing in Polymer Hybrid Thin Film Assemblies

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

R17-X000 Change to representative recorded

St.27 status event code: A-3-3-R10-R17-oth-X000

A201 Request for examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

R18-X000 Changes to party contact information recorded

St.27 status event code: A-3-3-R10-R18-oth-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

R18-X000 Changes to party contact information recorded

St.27 status event code: A-5-5-R10-R18-oth-X000

FPAY Annual fee payment

Payment date: 20220120

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

U11 Full renewal or maintenance fee paid

Free format text: ST27 STATUS EVENT CODE: A-4-4-U10-U11-OTH-PR1001 (AS PROVIDED BY THE NATIONAL OFFICE)

Year of fee payment: 8