KR101873519B1 - Supplementary detergent composition with nipa fruticans wurmb and method for preparing thereof - Google Patents

Abstract

The present invention relates to a detergent composition using a nifa palm phlox and a method of preparing the same, and more particularly to a detergent composition comprising a nifa palm phlox extract and a surfactant.
INDUSTRIAL APPLICABILITY The detergent composition of the present invention has a cleaning power similar to that of a conventional detergent, has an antioxidant and bactericidal activity of the extract of the nihaloptera, has less irritation to the skin and does not cause environmental pollution.

Description

Technical Field [0001] The present invention relates to a detergent composition and a method for manufacturing the detergent composition,

The present invention relates to a detergent composition using a naphthalene palm leaf and a method for preparing the same, and more particularly, to a detergent composition using the extract of a naphthalene palm leaf, The present invention relates to a detergent composition using a coconut palm and to a method for producing the same.

Detergents can be classified into domestic and industrial use depending on the application field, and in particular, they are divided into domestic use, kitchen use, laundry use and cleaning use. In addition, depending on the kind of raw materials used in the detergent, it can be classified into a synthetic detergent and a natural detergent. As consumers increasingly seek well-being and LOHAS, the popularity of natural kitchen detergents using natural ingredients is increasing day by day.

Especially in recent years, as the number of restaurants related to home and food and beverage has increased, the amount of kitchen detergent used for washing dishes has been rapidly increasing. In addition, as the concept of well-being increases, the demand for natural materials, which clean dishwashing detergents and reduce harm to the hands of the family, is also increasing.

However, the conventional kitchen detergent does not have an antibacterial effect or a sterilizing effect at the same time in addition to the cleaning effect. Known as a dishwashing detergent with antimicrobial effect, a kitchen detergent containing an antibacterial ingredient known as Nonoxynol-9 is manufactured and sold. However, it is toxic to the human body when used with strong irritating odor and is used as a kitchen detergent It was unsuitable to be. Such a cleaning agent can not effectively sterilize harmful bacteria or viruses adhering to dishes through food or the like during the cleaning process.

On the other hand, detergents such as lactose, which is mainly used for sterilization and cleaning, are known to sterilize about 50 kinds of bacteria, but they are not used because of their strong irritating odor and toxicity to the human body when consumed.

On the other hand, clothes that come into direct contact with the skin are closely related to the hygiene and health of the individual in terms of being in contact with the body 24 hours a day. In particular, chemicals such as surfactants, fluorescent whitening agents, and synthetic coloring agents in detergents that can have a detrimental effect on humans cause dermatitis, such as atopy and housewife eczema. In other words, washing with a synthetic detergent is like applying chemical contaminants to the skin, so the most important point in selecting a detergent is detergency, but the priority is to find a safe detergent. In particular, children's clothing detergents that directly touch the skin of a baby should be safe, less irritating to the skin, and have good antimicrobial effects. As a result, consumers are increasingly interested in the ingredients and functions of detergents for washing clothing. Recently, as environment-friendly ethical consumption has become a trend in the consumer market, detergents for clothing that minimize environmental pollution have attracted particular attention

Therefore, it is necessary to develop natural detergent which combines not only detergent with low pollution and high functionality but also antibacterial function made by using natural raw material rather than synthetic detergent due to recent seriousness of environmental problems and concern about health, to be.

KR 10-1624951 B1 KR 10-1300632 B1

Accordingly, an object of the present invention is to provide a detergent composition which is excellent in detergency, has an antibacterial and germicidal effect, and has low skin irritation by using a natural substance which is not a chemical synthetic substance.

According to the present invention, water of 10 to 20 times weight is added to an extract-nipahaya flower bed using water as a solvent in a flower bud of Nipaya japonica cut to a size of 3 to 10 cm, Or 10 to 20 hours at a temperature of 100 占 폚, or 8 to 12 times by weight of water is added to a cut nipponia palmate and then pretreated for 20 to 30 minutes at 100 to 150 kHz using an ultrasonic wave extractor. Dried at a temperature of 50 to 60 ° C for 10 to 12 hours, or the cut nippa coconut palms are subjected to natural drying, cold air drying, or hot air drying to have a water content of 10 to 20%, and then pulverized to 100 to 200 mesh , 20 parts by weight of distilled water was added thereto, and the mixture was extracted at 90 to 100 ° C for 20 hours, filtered, and then the solvent was removed at 50 to 60 ° C to concentrate the mixture to 20 to 50 Brix under reduced pressure. , Or the cut nihonpalacophyllus is boiled at 100 < 0 > C After boiling for 10 to 20 minutes in water, extracts of Niepajaya extract, which is dehydrated and extracted with active ingredient, and Disodium Laureth sulfosuccinate (LES), an olive surfactant, Apple Wherein the extract comprises at least one surfactant selected from the group consisting of surfactant, potassium cocoyl glycinate (PCG) and coco-betaine, 20% by weight of the composition, and the surfactant is 20-30% by weight of the total weight of the composition.
The fermented product of the nifa palm phalaenopsis powder is collected by washing the nipaya flower buds and then cut to a length of 3 to 10 cm, Is dipped in water at 80 to 100 ° C for 20 to 40 minutes, the dulled flower buds are soaked in cold water, cooled, torn to a thickness of 0.5 to 1 cm, dewatered in the torn flower bed, dried in hot air, Dried to a moisture content of 5 to 10%, and then the dried peduncle is pulverized by a pulverizer or a mill to 500 to 10,000 mesh, and 50 to 100 g of a nifel palm flower bed powder based on 1 L of purified water, 1 to 10 g of Saccharomyces cerevisiae yeast and 10 to 50 g of an oligosaccharide are added and fermented at 20 to 40 ° C for 6 to 24 hours. After fermentation, the cells are subjected to vacuum concentration, lyophilization or spray drying Can be manufactured.
According to the present invention, when the extract of the present invention is mixed with the surfactant, 5-15 wt% of one or more organic acids selected from citric acid, malic acid, succinic acid, sorbic acid, ascorbic acid, lactic acid, Lemon Essential Oil, Lemongrass Essential Oil, Lime Essential Oil, Orange Essential Oil, Orange Sweet Essential Oil, Grapefruit Essential Oil, Lavender Essential Oil, Jasmine Essential Oil, Rosemary Essential Oil, Chamomile Essential Oil, 0.1 to 0.5% by weight of at least one essential oil selected from ylang essential oil, 5 to 10% by weight of hot water-extracted parsley extract, and a remaining amount of sodium hydrogencarbonate.
According to the present invention, 10 to 20 times by weight of water is added to an extract-nipahaya flower bed using water as a solvent in a flower bud of Nipaya japonica cut to a size of 3 to 10 cm, 20 to 30 hours, or 8 to 12 times by weight of water is added to the cut nipponia palmate, and the mixture is pretreated at 100 to 150 kHz for 20 to 30 minutes using an ultrasonic wave extractor. Dried or hot air dried to obtain a water content of 10 to 20%, and then the resultant is pulverized to 100 to 200 mesh, and 20 parts by weight of distilled water The solution was extracted at 90 to 100 ° C for 20 hours, filtered, and then the solvent was removed at 50 to 60 ° C to concentrate the solution to 20 to 50 Brix under reduced pressure. Then, the active ingredient was extracted from the powder obtained by lyophilization, After the nipponia palms were soaked in boiling water at 100 ° C for 10-20 minutes, Extract the active ingredient to dehydrate the par palm rachis comprising the steps of preparing an extract you dig's spine; A selected one of Disodium Laureth sulfosuccinate (LES), an olive surfactant, an apple surfactant, Potassium Cocoyl Glycinate (PCG) and Coco-betaine Mixing the above-prepared nipah palm phloem extract with a surfactant having the above formula; The present invention provides a method for producing a detergent composition using a nifa palm phlox.
The fermented product of the nifa palm phalaenopsis powder is collected by washing the nipaya flower buds and then cut to a length of 3 to 10 cm, Is dipped in water at 80 to 100 ° C for 20 to 40 minutes, the dulled flower buds are soaked in cold water, cooled, torn to a thickness of 0.5 to 1 cm, dewatered in the torn flower bed, dried in hot air, Dried to a moisture content of 5 to 10%, and then the dried peduncle is pulverized by a pulverizer or a mill to 500 to 10,000 mesh, and 50 to 100 g of a nifel palm flower bed powder based on 1 L of purified water, 1 to 10 g of Saccharomyces cerevisiae yeast and 10 to 50 g of an oligosaccharide are added and fermented at 20 to 40 ° C for 6 to 24 hours. After fermentation, the cells are subjected to vacuum concentration, lyophilization or spray drying Can be manufactured.
When the surfactant is mixed with 5% to 15% by weight of at least one organic acid selected from citric acid, malic acid, succinic acid, tartaric acid, sorbic acid, ascorbic acid, lactic acid, acetic acid and clonic acid, Choose from Lemon Grass Essential Oil, Lime Essential Oil, Orange Essential Oil, Orange Sweet Essential Oil, Grapefruit Essential Oil, Lavender Essential Oil, Jasmine Essential Oil, Rosemary Essential Oil, Chamomile Essential Oil, Location Hazel Essential Oil and Ylang Ylang Essential Oil. 0.1 to 0.5% by weight of at least one kind of essential oil, 5 to 10% by weight of hot water-extracted parsley extract, and the remaining amount of sodium hydrogencarbonate.

delete

delete

delete

delete

delete

delete

INDUSTRIAL APPLICABILITY The detergent composition of the present invention has a cleaning power similar to that of a conventional detergent, has an antioxidant and bactericidal activity of the extract of the nihaloptera, has less irritation to the skin and does not cause environmental pollution.

BRIEF DESCRIPTION OF THE DRAWINGS FIG.
2 to 5 are graphs showing the results of Test Example 2 according to the present invention.

Hereinafter, the present invention will be described in detail.

The detergent composition according to the present invention is characterized in that it contains an extract of a nipponia palm phloem and a surfactant. Here, the detergent composition includes all kinds of detergent for kitchen, laundry, and cleaning, and the type of the detergent composition is not limited, and the formulation may also be in the form of liquid or powder.

Here, the above-mentioned NIPPA FRUTICANS WURMB is originated from India, Malaysia, Southeast Asia and Australia, and grows in wetlands such as mangroves. The roots are divided into several pieces in the ground, and the leaves are gathered on the ground and have a glossy green color. And the flower is one male and one female, and it comes out from the axilla of the ground. Usually, the flower stands rise from October to June of the following year.

The present invention is based on the use of a flower bud of Nipaya, and the reason for using the flower bud of Nipaya is that it contains more antioxidant components such as polyphenols, selenium, and various nutrients Because it contains a large amount of ingredients.

The results of the analysis and the results of the components of the above-mentioned Nihonpalaceae are shown in the following Tables 1 and 2. As shown in Table 1 and Table 2, the Niha-Paya's peduncle contains a large amount of effective components such as polyphenol, flavonoid, saponin, as well as aspartic acid, tyrosine and histidine .

The results of analysis of the components of. Inspection items unit test results Inspection items unit test results moisture % 20.54 Selenium Mu g / kg 154.57 Crude protein % 11.65 manganese mg / kg 82.58 Crude fat % 0.73 Goat mg / kg 18344.65 Views min % 7.95 sulfur mg / kg 3221.83 carbohydrate % 59.15 salt mg / kg 6832.66 calorie kcal / 100g 289.77 Crude saponin mg / kg 110161.07 calcium mg / kg 3009.62 Total polyphenol Brix 173443.90 sign mg / kg 2589.65 Total flavonoid mg / kg 616.24 iron mg / kg 119.57 Per capita % 11.84 potassium mg / kg 26211.57 And sugar % 1.57 magnesium mg / kg 4670.47 glucose % 1.11 Copper mg / kg 0.26 saccharose % 1.19 zinc mg / kg 14.13

Test results of the components of the nipponia palm. Inspection items unit test results Aspartic acid mg / kg 269.01 Threonine mg / kg 30.22 Serine mg / kg 30.59 Glutamic acid mg / kg 171.29 Proline mg / kg 0 Glycine mg / kg 7.98 Alanine mg / kg 25.69 Balin mg / kg 49.06 Isoleucine mg / kg 39.30 Leucine mg / kg 49.73 Tyrosine mg / kg 0 Phenylmalanine mg / kg 14.70 Histidine mg / kg 13.44 Lysine mg / kg 16.26 Arginine mg / kg 302.53 Cystine mg / kg 30.19 Methionine mg / kg 32.46 Tryptophan mg / kg 0

Therefore, the use of the extract of the nifa palm phlox can provide antioxidant and antimicrobial activity to the detergent composition to improve detergency, disinfection and antimicrobial activity of the detergent, as well as to protect the skin and alleviate skin irritation caused by the detergent.

Herein, the extract of the Nihonpalaceae is obtained by hot water extraction or ultrasonic extraction using water as a solvent, which will be described in detail by the following production method.

In the present invention, it is preferable that the extract of the nipponophyllum phalaenopsis is 5 to 20% by weight based on the total weight of the detergent composition. If the content thereof is too small, the detergent, antibacterial and bactericidal properties are not good. I can not.

The detergent composition of the present invention may further comprise a surfactant, wherein the surfactant is disodium laureth sulfosuccinate (LES), an olive surfactant, an apple surfactant, potassium cocoyl glycinate (PCG) and coco-betaine. The use of a natural surfactant not only stimulates skin and eyes, but also has good bubble power and fast biodegradability, .

In the present invention, the amount of the detergent composition is preferably 20 to 30% by weight based on the total weight of the detergent composition. If the amount of the detergent composition is too small, bubbles are not sufficiently formed. .

The detergent composition according to the present invention may further comprise 5 to 20% by weight of the extract of Nephala palmetole and 20 to 30% by weight of a surfactant, 5 to 15% by weight of an organic acid, 0.1 to 0.5% by weight of an essential oil and a remaining amount of sodium hydrogencarbonate .

The organic acid is a deodorant component for eliminating odor, and also helps sterilization. As the organic acid, at least one selected from citric acid, malic acid, succinic acid, tartaric acid, sorbic acid, ascorbic acid, lactic acid, acetic acid and clonic acid may be used. The content of the organic acid is in the range of 5 to 15% by weight. When the content of the organic acid is less, the foaming power is lowered. If the content is excessive, the acid causes irritation to the skin.

The essential oil is an aromatic and antimicrobial ingredient that provides a natural fragrance and acts to enhance the deodorizing effect. These essential oils include lemon essential oils, lemongrass essential oils, lime essential oils, orange essential oils, orange sweet essential oils, grapefruit essential oils, lavender essential oils, jasmine essential oils, rosemary essential oils, chamomile essential oils, Essential Oils and Ylang Ylang Essential Oils can be selected and used. The essential oil is used in an amount of 0.1 to 0.5% by weight. If the content of the essential oil is too small, the effect is insignificant, and if it is excessive, the essential oil is not economical.

Sodium bicarbonate is used as a neutralizing agent. If it is excessive, precipitation may occur, and if used in a small amount, detergency may decrease.

Meanwhile, the detergent composition of the present invention may further contain a fermented product of the above-mentioned nifelmat palm flower powder in an amount of 5 to 10% by weight. When the above-mentioned fermented product is further contained, more effective disinfection and antibacterial effect can be obtained. The method of producing such a fermentation product is described below again.

In addition, the detergent composition of the present invention may further comprise 5 to 10% by weight of a buttercup extract. If the buttercup extract is further included, the bactericidal power and the rinseability are further improved. At this time, the buttercups extract means hot water extract of buttercups.

In addition, the detergent composition of the present invention may further comprise auxiliary components such as a moisturizing agent, a foaming agent, and the like, which may be contained in a known detergent composition, and is not limited as long as it is known in the art.

Hereinafter, the production method thereof will be described in detail.

The method for preparing a detergent composition according to the present invention comprises the steps of preparing a nifa palm phloem extract by extracting a nifa palm phlox, and mixing the prepared nifalia phalaenopsis extract with a surfactant.

Nipa  By extracting the peduncle Nipa  Steps to prepare flower bud extract

An extract of the above-mentioned Nihon palaceae is prepared.

As shown in FIG. 1, the extract of the nifa palm phlox is composed of a step of cutting a flower bud of Nipaya, a step of extracting or ultrasonically extracting the flower bud of the cut Nipaya flower, the step of concentrating the extracted extract, And lyophilizing the concentrated extract.

In detail, the flower bud of Nipaya is cut to a size of about 3 to 10 cm, and the cut flower of Nipaya is subjected to hot water extraction or ultrasonic extraction using water as a solvent, followed by concentration and lyophilization to obtain powder do. Here, the lyophilization follows a known method in the field to which this technique belongs, and thus a detailed description thereof will be omitted.

The hot water extraction is performed by adding 10 to 20 times by weight of water to the spikelets of the nipayanas and then extracting them at a temperature of 80 to 100 ° C for 10 to 20 hours. The ultrasonic extraction is performed at 8 to 12 times And the mixture is pre-treated for 20 to 30 minutes under the condition of about 100 to 150 kHz by using an ultrasonic wave extractor, and further subjected to hot water extraction for 10 to 12 hours at a temperature of 50 to 60 ° C.

In order to increase the extraction efficiency, the cut nipaya is subjected to natural drying, cold air drying or hot air drying to have a water content of 10 to 20%, followed by pulverizing the dried powder to about 100 to 200 mesh, and extracting the active ingredient from the powder . In addition, it is also possible to dehydrate the cut nippa coconut palms in boiling water at 100 ° C for 10 to 20 minutes, dehydrate them, and extract the active ingredient therefrom.

The concentration means concentration under reduced pressure, and the solvent is removed at 50 to 60 ° C to concentrate the solution to about 20 to 50 Brix. It is of course also possible to conduct filtration before concentration, if necessary.

Mixing the prepared nifel palm phloem extract with the surfactant .

Next, the surfactant is mixed with the above-prepared nifedium phalaenopsis extract.

Here, as described above, the surfactant makes use of natural ingredients to lessen skin irritation and prevent environmental pollution.

In addition, at this stage, organic acids, essential oils, parsley extracts and sodium hydrogencarbonate can be further mixed.

At this time, the watercress extract is prepared by adding water 10 to 20 times by weight to the washed watercress and extracting it by heating at 80 to 100 ° C for 10 to 24 hours and then filtering it. The watercress extract is concentrated by filtration and freeze- You can do it further.

The mixture ratio is 5 to 20% by weight of the extract of Nephagosaccharomyces sp., 20 to 30% by weight of surfactant, 5 to 15% by weight of organic acid, 0.1 to 0.5% by weight of essential oil, 5 to 10% by weight of parsley extract, Lt; / RTI >

Further, in this step, a fermented product of the nifedowiczas pulverulent powder may be further mixed. The fermented product is prepared as follows.

First, pick up the nipaya japonica, clean it, and cut it to a length of 3-10cm. Next, the cut flower stalks are heated in hot water, that is, water at 80 to 100 ° C for 20 to 40 minutes, and the dulled flower buds are soaked in cold water and then ripped in the longitudinal direction, At this time, the thickness is preferably about 0.5 to 1 cm. The nipayanaya peduncle is easily torn as easily because it has parallel longitudinal texture. Next, the tears are dewatered, dried by hot air drying, cold air drying or natural drying method by daylight to dry to a moisture content of 5 to 10%, and then the dried flower buds are pulverized or milled at 500 to 10,000 mesh And crushed. At this time, the dewatering method is not limited, and a separate dewatering device may be used, or it may be dewatered by hand. Next, purified water, yeast and sugar are added to the powder, which is then fermented at 20 to 40 ° C for 6 to 24 hours. Here, the amount of the input may be 50-100 g of the nifedowana phalaenopsis powder, 1 ~ 10 g of yeast, 10 ~ 50 g of the same, based on 1 L of purified water. Saccharomyces cerevisiae may be used as the yeast, and oligosaccharides may be used as the saccharide. After the fermentation, it may further comprise a step of concentration under reduced pressure, lyophilization or spray drying. At this time, the above-mentioned reduced pressure concentration, freeze-drying, or spray drying is performed according to a known method in the field of fermentation products, so that detailed description thereof will be omitted.

Hereinafter, the present invention will be described in more detail with reference to specific examples.

(Example 1)

The nipponia palms were picked, cleaned and then cut into 10 cm lengths. Dried by hot air at 50 캜 to have a water content of 15%, and pulverized to about 100 mesh. 20 wt. Parts of distilled water was added thereto, and the mixture was extracted at 90 to 100 캜 for 20 hours. After filtration, the filtrate was concentrated under reduced pressure at 50 ° C using a vacuum concentrator and lyophilized to obtain a powdery extract.

Then, 20 g of the above extract, 50 g of LES, 20 g of vinegar and 1 g of lemon essential oil were added to 109 g of sodium hydrogen carbonate and stirred.

(Example 2)

The same procedure as in Example 1 was carried out except that 10 g of sodium hydrogencarbonate was replaced by 10 g of dried extract.

The extract was prepared by adding 15 parts by weight of water to millet, heating it at 80 to 100 ° C for 20 hours, and then filtering it.

(Comparative Example 1)

The same procedure as in Example 1 was carried out, but no extract was used.

(Comparative Example 2)

A commercial synthetic kitchen detergent was used.

(Test Example 1)

Evaluation of Antioxidative Capacity of Extracts of.

The antioxidative activity of the extracts of Nephala palmetae prepared in Example 1 was measured.

The extract was used in the experiment while being kept frozen.

(1) Measurement of DPPH radical scavenging ability

To determine the antioxidant activity, the Biois method was used to examine the radical scavenging effect of DDPH (1,1-diphenyl-2-picryhydrazyl, Sigma-Aldrich Co.). 1 ml of 0.2 mM DPPH was added to 1 ml of the sample solution prepared from 0.625 to 10 mg / ml of each extract, mixed using a vortex mixer, reacted for 30 minutes in a dark room, and absorbance was measured at 517 nm. Then, free radical scavenging activity curves were generated using the following equation, and IC ₅₀ was calculated. As a positive control, ascorbic acid was used.

Radical scavenging activity (%) = {(control Absorbance - Sample Absorbance) / control Absorbance} × 100

(2) Measurement of ABTS radical scavenging ability

ABTS radical scavenging activity was measured by Pellegrin et al. 5 ml of 7 mM ABTS (2,2'-azinobis (3-ethylenbenzothiazoline-6-sulfonate), Sigma-Aldrich Co.) and 88 μl of 140 mM K ₂ S ₂ O ₈ (Sigma-Aldrich Co.) .

The mixture was mixed with absolute ethanol at a ratio of 1:88, and the ABTS solution was prepared so that the absorbance of the control was adjusted to 0.7 ± 0.002 at 734 nm. 1 ml of ABTS solution was added to 50 μl of the sample solution, and the mixture was allowed to stand in a dark room for 2.5 minutes, and the absorbance was measured at 734 nm.

The results are shown in Tables 3 and 4 below.

Results of measurement of DPPH radical scavenging activity according to Test Example 1. Samples Concentration
(mg / ml) Scavenging activity (%) IC ₅₀
(mg.ml) Nipa 0.025
0.125
0.0625
0.03125
0.15625 85.83 + - 0.22
51.52 ± 1.09
26.74 1.51
13.93 ± 2.09
7.82 + - 0.37 0.017 ± 0.00 Blueberries (dried) One
0.5
0.25
0.125
0.0625 60.70 + - 0.47
44.73 + - 0.74
36.62 ± 0.49
30.87 + - 0.41
28.79 + - 0.41 0.627 + - 0.01 Red ginseng (6 years old, dried) One
0.5
0.25
0.125
0.0625 44.89 + - 0.41
37.41 + - 0.41
32.67 + - 0.43
30.27 + - 0.14
28.98 + - 0.43 1.282 + 0.03

The IC ₅₀ value represents the concentration of the extract which reduces the value of the control without the extract by 50%. The smaller the IC ₅₀ value, the higher the antioxidant activity. Therefore, as shown in Table 3, according to DPPH radical scavenging activity measurement results, the antioxidant activity of the Nypha palm phlox was about 40 times higher than that of blueberry and about 75 times higher than that of red ginseng.

Results of measurement of ABTS radical scavenging activity according to Test Example 1. Samples Concentration
(mg / ml) Scavenging activity (%) IC ₅₀
(mg.ml) Nipa 0.025
0.125
0.0625
0.03125
0.15625 44.44 + - 0.42
23.28 ± 0.99
11.54 + - 0.94
5.87 ± 0.27
2.50 ± 0.56 0.070 ± 0.00 Blueberries (dried) One
0.5
0.25
0.125
0.0625 17.68 ± 0.51
10.05 + 0.48
5.40 ± 0.17
3.12 ± 0.15
2.08 ± 0.59 2.918 ± 0.13 Red ginseng (6 years old, dried) One
0.5
0.25
0.125
0.0625 11.89 + - 0.54
6.09 ± 0.51
3.02 ± 0.31
1.58 ± 0.56
0.25 0.31 4.131 + 0.24

As shown in Table 4, according to the result of ABTS radical scavenging activity measurement, the antioxidant activity of Nypha palm phlox was about 42 times higher than that of blueberry and about 59 times higher than that of red ginseng.

(Test Example 2)

Anti - Inflammatory Effects of Extracts of.

In order to evaluate the antiinflammatory effect of the extracts of Nephala palmetto, the anti-inflammatory effects of the extracts of Nephala palmetae prepared in Example 1 were measured.

IL-1β (interleukin-1beta), IL-6 (interleukin-6, interleukin-6) and TNF-α (tumor necrosis factor-alpha, Or tumor necrosis factor-alpha).

The test method was to investigate whether inflammation was induced by macrophages using LPS (lipopolysaccharide) and the general inflammation index was suppressed when the sample was treated with LPS (lipopolysaccharide). As a positive control, DEX (Dexamethasone) was used as a comparative drug. The above-mentioned samples were diluted to a concentration according to the above-mentioned Example 1 and then used.

The results are shown in Figs. 2 to 5. Fig.

As can be seen in FIG. 2, Nitrite was significantly increased upon induction of inflammation with LPS, but nitrite increased due to the treatment of the sample.

As can be seen from FIGS. 3, 4 and 5, cytokine was significantly increased upon induction of inflammation induced by LPS, but the inflammation was alleviated by the treatment of the sample.

Therefore, it was concluded that the flower bud extract of Nipaya was inhibitory to inflammatory factors in a concentration-dependent manner and had a similar inhibitory effect to that of DEX known as anti-inflammatory component.

(Test Example 3)

The amount of foam, washing power, rinsing ability, skin irritation and stability of the above examples were measured.

(a) Foam volume

In order to measure the amount of foam, a method of diluting the stock solution of the detergent composition prepared in the above example to a concentration of 0.1% by weight, shaking it 50 times in a cylinder of 100 ml, and then measuring the height of the produced foam I choose. The height of the foam was indicated by the volume value indicated in the cylinder.

(b) Evaluation of cleaning power

A specimen having 10 x 10 cm (cm ² ) of rolling oil was immersed in the detergent composition prepared in the above example for 10 seconds to degrease the rolling oil remaining on the specimen surface. The degreased steel sheet was washed with distilled water, dried with a drier, cut into a size of 10 × 2.5 (cm ² ), and the surface residual amount of the specimen was measured five times with RC-212 carbon analyzer.

(c) Evaluation of skin irritation

 The skin irritation of the patch area was evaluated after 5 hours of patching of the detergent composition prepared in the above example to the tops of 10 healthy men and women. All skin irritation test values were compared with the skin irritation level by water, and the skin irritation by water was set as a criterion having a 'very good' value.

The symbol 는 indicates no abnormality, ◯ indicates a slightly reddish phenomenon than other skin, △ indicates a slight allergic symptom, and X indicates a symptom unusual to the skin.

(d) Evaluation of rinsability

The rinseability was evaluated by comparing the amount of the detergent composition prepared in the above example with the amount of water used until the bubbles were removed by washing a certain amount of the dishware with the sponge.

The judgment code x is not good,? Means normal, and? Means very good.

(e) Stability evaluation

The stability evaluation was carried out by repeating the above-mentioned kitchen detergent composition of the present invention for 12 hours at a low temperature of -10 DEG C and for 12 hours at a high temperature of 40 DEG C for 5 cycles, Apparent transparency was evaluated as stability, and bubble power and cleaning power were additionally evaluated

The judgment symbol " o " means that there is no problem in the appearance, the bubble power and the washing power, " B " means that there is no problem in the bubble power and the washing power though the appearance is blurred in appearance, and X means that there is a problem in both appearance, bubble power and washing power.

The results are shown in Table 5 below.

Test Example 3 Results. division Foam volume (ml) Cleaning power Skin irritation Rinseability stability Example 1 90 90.1 ● ○ ○ Example 2 91 94.2 ● ○ ○ Comparative Example 1 80 54.5 ○ △ ○ Comparative Example 2 94 93.4 × × ○

As can be seen from the above Table 5, Examples 1 and 2 according to the present invention were found to have good foamability and detergency as well as good rinseability and less skin irritation than Comparative Example 2, which is a synthetic detergent .

While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it is to be understood that the scope of the present invention is not limited to the disclosed exemplary embodiments. It will also be appreciated that many modifications and variations will be apparent to those skilled in the art without departing from the scope of the present invention.

Claims (7)

Extracting the flower bud of Nippazaya cut into a size of 3-10 cm with water as a solvent - Extracting 10 to 20 times by weight of water to a nipponia flower, extracting it at a temperature of 80 to 100 ° C for 10 to 20 hours, Or 8 to 12 times by weight of water is added to the cut nippa palm phlox, and the mixture is pre-treated for 20 to 30 minutes under the condition of 100 to 150 kHz using an ultrasonic wave extractor, and then pre-treated at 50 to 60 ° C for 10 to 12 hours. Dried or air-dried to obtain a water content of 10 to 20%, which is then pulverized to 100 to 200 mesh, 20-fold weight of distilled water is added thereto, After extraction at 100 ° C for 20 hours and filtration, the solvent was removed at 50 to 60 ° C and concentrated under reduced pressure to 20 to 50 Brix. The active ingredient was extracted from the obtained powder by lyophilization, After boiling for 10 to 20 minutes in boiling water of ℃, And extracting the active ingredient.
A selected one of Disodium Laureth sulfosuccinate (LES), an olive surfactant, an apple surfactant, Potassium Cocoyl Glycinate (PCG) and Coco-betaine By weight of a surfactant,
The detergent composition according to claim 1, wherein the extract is from 5 to 20% by weight of the total weight of the composition, and the surfactant is 20 to 30% by weight of the total weight of the composition.
The method according to claim 1,
The fermented product of the nifalum phalaenopsis powder is further mixed with the surfactant,
The fermented product of the above-
After removing the pedicel of Nipaya, it is cut to a length of 3 to 10 cm, and the cut flower is heated in water at 80 to 100 ° C for 20 to 40 minutes. The corolla is soaked in cold water and then cooled to 0.5 to 1 cm And dried in a hot air drying method or a cold air drying method or a natural drying method by daylight to dry to a moisture content of 5 to 10%, and then the dried flower buds are pulverized to 500 to 10,000 mesh. Crushed and pulverized through a mill, and 50 to 100 g of the nifelmatrice flower powder, 1 to 10 g of Saccharomyces cerevisiae yeast and 10 to 50 g of oligosaccharide were added based on 1 L of purified water at 20 to 40 ° C Fermented for 6 to 24 hours,
Wherein the detergent composition is prepared by further comprising, after fermentation, concentration under reduced pressure, freeze drying, or spray drying.
delete The method according to claim 1,
5 to 15% by weight of at least one organic acid selected from citric acid, malic acid, succinic acid, tartaric acid, sorbic acid, ascorbic acid, lactic acid, acetic acid and clonic acid, lemon essential oil, lemon grass essential oil, lime essential oil, 0.1 to 0.5% by weight of at least one essential oil selected from Orange Sweet Essential Oil, Grapefruit Essential Oil, Lavender Essential Oil, Jasmine Essential Oil, Rosemary Essential Oil, Chamomile Essential Oil, And 5 to 10% by weight of the extracted buttercup extract and the remaining amount of sodium hydrogencarbonate.
Extracting the flower bud of Nippazaya cut into a size of 3-10 cm with water as a solvent - Extracting 10 to 20 times by weight of water to a nipponia flower, extracting it at a temperature of 80 to 100 ° C for 10 to 20 hours, Or 8 to 12 times by weight of water is added to the cut nippa palm phlox, and the mixture is pre-treated for 20 to 30 minutes under the condition of 100 to 150 kHz using an ultrasonic wave extractor, and then pre-treated at 50 to 60 ° C for 10 to 12 hours. Dried or air-dried to obtain a water content of 10 to 20%, which is then pulverized to 100 to 200 mesh, 20-fold weight of distilled water is added thereto, After extraction at 100 ° C for 20 hours and filtration, the solvent was removed at 50 to 60 ° C and concentrated under reduced pressure to 20 to 50 Brix. The active ingredient was extracted from the obtained powder by lyophilization, After boiling for 10 to 20 minutes in boiling water of ℃, Extracting an effective ingredient of the nipaya extract;
A selected one of Disodium Laureth sulfosuccinate (LES), an olive surfactant, an apple surfactant, Potassium Cocoyl Glycinate (PCG) and Coco-betaine Mixing the above-prepared nipah palm phloem extract with a surfactant having the above formula;
≪ RTI ID = 0.0 > 1. ≪ / RTI >
6. The method of claim 5,
The fermented product of the nifalum phalaenopsis powder is further mixed with the surfactant,
The fermented product of the above-
After removing the pedicel of Nipaya, it is cut to a length of 3 to 10 cm, and the cut flower is heated in water at 80 to 100 ° C for 20 to 40 minutes. The corolla is soaked in cold water and then cooled to 0.5 to 1 cm And dried in a hot air drying method or a cold air drying method or a natural drying method by daylight to dry to a moisture content of 5 to 10%, and then the dried flower buds are pulverized to 500 to 10,000 mesh. Crushed and pulverized through a mill, and 50 to 100 g of the nifelmatrice flower powder, 1 to 10 g of Saccharomyces cerevisiae yeast and 10 to 50 g of oligosaccharide were added based on 1 L of purified water at 20 to 40 ° C Fermented for 6 to 24 hours,
The method of manufacturing a detergent composition according to any one of the preceding claims, wherein the detergent composition is prepared by further comprising, after fermentation, concentration under reduced pressure, freeze drying, or spray drying.
6. The method of claim 5,
When the above-described surfactant is mixed with the extract of Nipah,
5 to 15% by weight of at least one organic acid selected from citric acid, malic acid, succinic acid, tartaric acid, sorbic acid, ascorbic acid, lactic acid, acetic acid and clonic acid, lemon essential oil, lemon grass essential oil, lime essential oil, 0.1 to 0.5% by weight of at least one essential oil selected from Orange Sweet Essential Oil, Grapefruit Essential Oil, Lavender Essential Oil, Jasmine Essential Oil, Rosemary Essential Oil, Chamomile Essential Oil, And 5 to 10% by weight of the extracted buttercups extract and the remaining amount of sodium hydrogencarbonate.

Images