KR101815664B1 - 고도로 선택적인 에틸렌 옥사이드 촉매의 개시 방법 - Google Patents

고도로 선택적인 에틸렌 옥사이드 촉매의 개시 방법 Download PDF

Info

Publication number
KR101815664B1
KR101815664B1 KR1020127019490A KR20127019490A KR101815664B1 KR 101815664 B1 KR101815664 B1 KR 101815664B1 KR 1020127019490 A KR1020127019490 A KR 1020127019490A KR 20127019490 A KR20127019490 A KR 20127019490A KR 101815664 B1 KR101815664 B1 KR 101815664B1
Authority
KR
South Korea
Prior art keywords
temperature
catalyst
hours
vol
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020127019490A
Other languages
English (en)
Korean (ko)
Other versions
KR20120108029A (ko
Inventor
나빌 리즈칼라
노르마 비. 카스타뇰라
기리쉬 데사이
Original Assignee
사이언티픽 디자인 컴파니 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=44152005&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR101815664(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 사이언티픽 디자인 컴파니 인코포레이티드 filed Critical 사이언티픽 디자인 컴파니 인코포레이티드
Publication of KR20120108029A publication Critical patent/KR20120108029A/ko
Application granted granted Critical
Publication of KR101815664B1 publication Critical patent/KR101815664B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethylene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020127019490A 2009-12-23 2010-12-20 고도로 선택적인 에틸렌 옥사이드 촉매의 개시 방법 Expired - Fee Related KR101815664B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28971909P 2009-12-23 2009-12-23
US61/289,719 2009-12-23
PCT/US2010/061192 WO2011079056A2 (en) 2009-12-23 2010-12-20 A process for initiating a highly selective ethylene oxide catalyst

Publications (2)

Publication Number Publication Date
KR20120108029A KR20120108029A (ko) 2012-10-04
KR101815664B1 true KR101815664B1 (ko) 2018-01-05

Family

ID=44152005

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020127019490A Expired - Fee Related KR101815664B1 (ko) 2009-12-23 2010-12-20 고도로 선택적인 에틸렌 옥사이드 촉매의 개시 방법

Country Status (12)

Country Link
US (1) US8487123B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
EP (1) EP2521718B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JP2013515730A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
KR (1) KR101815664B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CN (1) CN102666515B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR112012015219B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
CA (1) CA2784603C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IN (1) IN2012DN05077A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
MX (1) MX2012007440A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
RU (1) RU2538969C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
TW (1) TWI485142B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
WO (1) WO2011079056A2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103547365B (zh) * 2011-04-11 2016-03-16 陶氏技术投资有限责任公司 调节高效环氧乙烷催化剂的方法
WO2013059225A1 (en) * 2011-10-18 2013-04-25 Al-Ahmadi Hassan Eisa Epoxidation process with added moderator
CN104884443B (zh) * 2012-12-31 2017-07-04 科学设计公司 用于环氧乙烷催化剂的启动方法
CN105008339B (zh) * 2013-01-11 2017-09-12 科学设计公司 具有后调节步骤的环氧化工艺
US9221776B2 (en) * 2013-12-23 2015-12-29 Scientific Design Company, Inc. Epoxidation process
US11059017B2 (en) 2017-09-15 2021-07-13 MultiPhase Solutions, Inc. Halogen selective detection gas chromatography for the on-line analysis and control of selective oxidation chemical production processes
CN114057670B (zh) * 2020-07-29 2024-06-07 中国石油化工股份有限公司 一种用于启动乙烯环氧化工艺的方法
CN114057669B (zh) * 2020-07-29 2023-12-08 中国石油化工股份有限公司 一种乙烯环氧化恒温开车方法
CN114436998A (zh) * 2020-11-05 2022-05-06 中国石油化工股份有限公司 一种乙烯环氧化开车方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002248351A (ja) 2001-02-27 2002-09-03 Mitsubishi Chemicals Corp レニウム含有触媒を用いるオレフィンオキシドの製造方法
US20070032670A1 (en) 2003-09-29 2007-02-08 Liping Zhang Process for the production of alkylene oxide using a gas-phase promoter system
WO2008140714A1 (en) 2007-05-11 2008-11-20 Billig Barry J Start-up of high selectivity catalysts in olefin oxide plants

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2279469A (en) 1942-04-14 Process of making olefin oxides
SE321462B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1962-10-10 1970-03-09 Halcon International Inc
GB1170663A (en) 1967-03-22 1969-11-12 Shell Int Research Process for preparing Silver Catalysts
US3702259A (en) 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4766105A (en) 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4761394A (en) 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4908343A (en) 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
US4874879A (en) * 1988-07-25 1989-10-17 Shell Oil Company Process for starting-up an ethylene oxide reactor
DE68925767T2 (de) 1988-08-30 1996-08-14 Union Carbide Corp Katalysatoren für die Herstellung von Ethylenoxid und Verfahren zur deren Herstellung
US5187140A (en) 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5102848A (en) 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5155242A (en) 1991-12-05 1992-10-13 Shell Oil Company Process for starting-up an ethylene oxide reactor
US5407888A (en) 1992-05-12 1995-04-18 Basf Aktiengesellschaft Silver catalyst
US6492065B2 (en) * 1997-12-05 2002-12-10 Victor Company Of Japan, Limited Hologram color filter, production method of the same hologram color filter and space light modulating apparatus using the same hologram color filter
US6008388A (en) * 1998-04-16 1999-12-28 Arco Chemical Technology, L.P. Epoxidation process
DE60332457D1 (de) 2002-06-28 2010-06-17 Shell Int Research Verfahren zur verbesserung der selektivität eines katalysators und verfahren zum epoxidieren eines olefins
AU2003247652A1 (en) * 2002-06-28 2004-01-19 Shell Internationale Research Maatschappij B.V. A method for the start-up of an epoxidation process and a process for the epoxidation of an olefin
AU2003243758A1 (en) * 2002-06-28 2004-01-19 Shell Oil Company A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin
US6992209B2 (en) 2002-12-09 2006-01-31 Battelle Memorial Institute Methods of forming alpha, beta-unsaturated acids and esters
US8791280B2 (en) 2005-08-10 2014-07-29 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for preparation of catalyst carrier and its use in catalyst preparation
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst
BRPI0912381A2 (pt) * 2008-05-07 2017-07-04 Shell Int Research processo para a partida de um processo de epoxidação, processo para a produção de óxido de etileno, 1,2-diol, 1, 2-diol éter, 1, 2-carbonato, ou uma alcanolamina

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002248351A (ja) 2001-02-27 2002-09-03 Mitsubishi Chemicals Corp レニウム含有触媒を用いるオレフィンオキシドの製造方法
US20070032670A1 (en) 2003-09-29 2007-02-08 Liping Zhang Process for the production of alkylene oxide using a gas-phase promoter system
WO2008140714A1 (en) 2007-05-11 2008-11-20 Billig Barry J Start-up of high selectivity catalysts in olefin oxide plants

Also Published As

Publication number Publication date
CA2784603A1 (en) 2011-06-30
US8487123B2 (en) 2013-07-16
CN102666515B (zh) 2015-05-20
CA2784603C (en) 2018-06-12
TW201139392A (en) 2011-11-16
EP2521718B1 (en) 2014-07-02
EP2521718A4 (en) 2013-06-19
KR20120108029A (ko) 2012-10-04
JP2013515730A (ja) 2013-05-09
BR112012015219B1 (pt) 2018-04-03
TWI485142B (zh) 2015-05-21
RU2538969C2 (ru) 2015-01-10
CN102666515A (zh) 2012-09-12
BR112012015219A2 (pt) 2015-09-22
WO2011079056A3 (en) 2011-11-17
WO2011079056A2 (en) 2011-06-30
MX2012007440A (es) 2012-07-23
RU2012131369A (ru) 2014-01-27
IN2012DN05077A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 2015-10-09
US20110152549A1 (en) 2011-06-23
EP2521718A2 (en) 2012-11-14

Similar Documents

Publication Publication Date Title
KR101815664B1 (ko) 고도로 선택적인 에틸렌 옥사이드 촉매의 개시 방법
JP5496099B2 (ja) エチレンのエポキシ化方法
JP5946772B2 (ja) エポキシ化始動工程
US9067198B2 (en) Calcination process for producing an improved ethylene oxide catalyst
TWI596091B (zh) 用於使高選擇性環氧乙烷觸媒啟動的方法
JP2010537807A (ja) 酸化オレフィン触媒用担体
CN101711239B (zh) 烯烃氧化装置中高选择性催化剂的启动
KR102155073B1 (ko) 후-컨디셔닝 단계를 이용하는 에폭시화 공정
JP2013514975A (ja) 酸化オレフィン製造工程
US11931725B2 (en) Ethylene oxide high selectivity catalyst conditioning process
JP5215992B2 (ja) エチレンオキシドの製造方法

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

P22-X000 Classification modified

St.27 status event code: A-2-2-P10-P22-nap-X000

P22-X000 Classification modified

St.27 status event code: A-2-2-P10-P22-nap-X000

D13-X000 Search requested

St.27 status event code: A-1-2-D10-D13-srh-X000

D14-X000 Search report completed

St.27 status event code: A-1-2-D10-D14-srh-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20201230

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20201230