KR101736513B1 - 에릭슨 깊이 시험에서 양호한 결과를 나타내고 양호한 스톤칩핑 저항 성질을 가지면서 높은 내스크래치성을 갖는 코팅 제제 및 이로부터 형성된 코팅 - Google Patents
에릭슨 깊이 시험에서 양호한 결과를 나타내고 양호한 스톤칩핑 저항 성질을 가지면서 높은 내스크래치성을 갖는 코팅 제제 및 이로부터 형성된 코팅 Download PDFInfo
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- KR101736513B1 KR101736513B1 KR1020117031639A KR20117031639A KR101736513B1 KR 101736513 B1 KR101736513 B1 KR 101736513B1 KR 1020117031639 A KR1020117031639 A KR 1020117031639A KR 20117031639 A KR20117031639 A KR 20117031639A KR 101736513 B1 KR101736513 B1 KR 101736513B1
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- South Korea
- Prior art keywords
- hydroxyl
- coating composition
- mol
- diisocyanate
- coating
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- 238000000576 coating method Methods 0.000 title claims abstract description 80
- 239000011248 coating agent Substances 0.000 title description 46
- 238000012360 testing method Methods 0.000 title description 17
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 68
- 150000001875 compounds Chemical class 0.000 claims abstract description 63
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 42
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- 239000003054 catalyst Substances 0.000 claims description 25
- 239000000178 monomer Substances 0.000 claims description 23
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- 125000000217 alkyl group Chemical group 0.000 claims description 20
- 125000003118 aryl group Chemical group 0.000 claims description 18
- 229910052710 silicon Inorganic materials 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 17
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 17
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
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- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
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- XCOASYLMDUQBHW-UHFFFAOYSA-N n-(3-trimethoxysilylpropyl)butan-1-amine Chemical compound CCCCNCCC[Si](OC)(OC)OC XCOASYLMDUQBHW-UHFFFAOYSA-N 0.000 description 6
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- 238000002444 silanisation Methods 0.000 description 6
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- 125000004430 oxygen atom Chemical group O* 0.000 description 5
- GKASDNZWUGIAMG-UHFFFAOYSA-N triethyl orthoformate Chemical compound CCOC(OCC)OCC GKASDNZWUGIAMG-UHFFFAOYSA-N 0.000 description 5
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
- C08G18/6254—Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/778—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/809—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009030481.9 | 2009-06-24 | ||
| DE102009030481A DE102009030481A1 (de) | 2009-06-24 | 2009-06-24 | Beschichtungsmittel und daraus hergestellte Beschichtungen mit hoher Kratzfestigkeit bei gleichzeitig guten Ergebnissen in der Prüfung der Erichsentiefung und guten Steinschlagschutzeigenschaften |
| PCT/EP2010/001422 WO2010149236A1 (de) | 2009-06-24 | 2010-03-08 | Beschichtungsmittel und daraus hergestellte beschichtungen mit hoher kratzfestigkeit bei gleichzeitig guten ergebnissen in der prüfung der erichsentiefung und guten steinschlagschutzeigenschaften |
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| KR20120102498A KR20120102498A (ko) | 2012-09-18 |
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| EP (1) | EP2445948B1 (enExample) |
| JP (2) | JP5939979B2 (enExample) |
| KR (1) | KR101736513B1 (enExample) |
| CN (1) | CN102803330B (enExample) |
| BR (1) | BRPI1014324B1 (enExample) |
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| DE (1) | DE102009030481A1 (enExample) |
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| PL (1) | PL2445948T3 (enExample) |
| RU (1) | RU2541531C2 (enExample) |
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| CA2671663A1 (en) * | 2006-12-19 | 2008-06-26 | Basf Coatings Ag | Coating compositions with high scratch resistance and weathering stability |
| DE102007061855A1 (de) * | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
| DE102007061856A1 (de) * | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
| DE102007061854A1 (de) * | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
| DE102008030304A1 (de) | 2008-06-25 | 2009-12-31 | Basf Coatings Ag | Verwendung teilsilanisierter Verbindungen auf Polyisocyanatbasis als Vernetzungsmittel in Beschichtungszusammensetzungen und Beschichtungszusammensetzung enthaltend die Verbindungen |
| DE102010015675A1 (de) * | 2010-04-21 | 2011-10-27 | Basf Coatings Gmbh | Beschichtungsmittel mit verbesserter Ablaufneigung |
| JP6099571B2 (ja) * | 2011-01-20 | 2017-03-22 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | 水性ポリウレタン被覆剤および当該被覆剤から製造された、高い耐引掻性および良好な耐化学薬品性を有する被覆 |
| CN103517931B (zh) * | 2011-06-09 | 2015-11-25 | 巴斯夫涂料有限公司 | 涂布剂组合物和由其制得的具有高耐划伤性且同时具有良好的可抛光性的涂层及其用途 |
| US9371469B2 (en) | 2011-06-09 | 2016-06-21 | Basf Coatings Gmbh | Coating agent compositions, coatings made therefrom and exhibiting high scratch resistance and good polishability, and use thereof |
| EP2718342B1 (de) | 2011-06-09 | 2016-08-03 | BASF Coatings GmbH | Beschichtungsmittelzusammensetzungen und daraus hergestellte beschichtungen mit hoher kratzfestigkeit bei gleichzeitig guter polierbarkeit sowie deren verwendung |
| DE102011105676B4 (de) * | 2011-06-22 | 2018-05-09 | Schoeller Technocell Gmbh & Co. Kg | Vorimprägnat und Dekorpapier oder dekorativer Beschichtungswerkstoff daraus |
| CN104487473B (zh) | 2012-07-25 | 2017-05-17 | 巴斯夫涂料有限公司 | 聚氨酯涂料组合物、多阶段涂覆方法 |
| CN104487472B (zh) | 2012-07-25 | 2017-07-14 | 巴斯夫涂料有限公司 | 聚氨酯涂料组合物及其用途、多阶段涂覆方法 |
| JP6363615B2 (ja) | 2012-12-03 | 2018-07-25 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | エフェクト及び／または色彩付与多層塗膜塗装系ならびにそれを製造する方法、ならびにそれを使用する方法 |
| MX365288B (es) | 2012-12-03 | 2019-05-29 | Basf Coatings Gmbh | Composiciones de material de revestimiento y revestimientos producidos a partir de las mismas, que combinan alta resistencia a raspaduras con buena capacidad de pulido y buenas propiedades ópticas, y uso de las mismas. |
| EP2896639A1 (de) | 2014-01-15 | 2015-07-22 | BASF Coatings GmbH | Beschichtete metallisierte Oberflächen |
| EP2993202A1 (de) * | 2014-09-08 | 2016-03-09 | Evonik Degussa GmbH | Composite-Halbzeuge und daraus hergestellte Formteile sowie direkt hergestellte Formteile auf Basis von hydroxyfunktionalisierten (Meth)Acrylaten und Uretdionen, die duroplastisch vernetzt werden |
| JP6011895B2 (ja) * | 2014-09-30 | 2016-10-25 | 荒川化学工業株式会社 | 銅薄膜付基材用アンダーコート剤、銅薄膜付基材及び銅薄膜付基材の製造方法、並びに導電性フィルム |
| JP6619008B2 (ja) | 2014-12-08 | 2019-12-11 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングＢＡＳＦ Ｃｏａｔｉｎｇｓ ＧｍｂＨ | コーティング材料組成物、およびそれらから生成されるコーティング、ならびにその使用方法 |
| EP3230334B1 (de) * | 2014-12-08 | 2019-05-01 | BASF Coatings GmbH | Nichtwässrige beschichtungsmittelzusammensetzungen, daraus hergestellte beschichtungen mit verbesserter haftung und kratzfestigkeit sowie deren verwendung |
| EP3271411B8 (de) | 2015-03-17 | 2024-02-14 | Covestro Deutschland AG | Silangruppen enthaltende polyisocyanate auf basis von 1,5-diisocyanatopentan |
| ES2978136T3 (es) | 2015-04-21 | 2024-09-05 | Covestro Deutschland Ag | Plástico de poliisocianurato que contiene grupos siloxano y método para la producción del mismo |
| JP6608462B2 (ja) * | 2015-06-15 | 2019-11-20 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | ポリウレタン被覆剤組成物及び多層被覆塗装系を製造するためのその使用 |
| CN107743510A (zh) | 2015-06-15 | 2018-02-27 | 巴斯夫涂料有限公司 | 涂覆轮辋的方法及以此得到的防污和防制动粉尘的涂层 |
| CN107771200A (zh) | 2015-06-15 | 2018-03-06 | 巴斯夫涂料有限公司 | 涂覆轮辋的方法及以此得到的防污和防制动粉尘的涂层 |
| KR102555281B1 (ko) | 2015-09-09 | 2023-07-14 | 코베스트로 도이칠란트 아게 | 스크래치-내성 2-성분 폴리우레탄 코팅 |
| WO2017042175A1 (en) | 2015-09-09 | 2017-03-16 | Covestro Deutschland Ag | Scratch-resistant aqueous 2k pu coatings |
| CN109153767B (zh) | 2016-05-24 | 2021-09-24 | 巴斯夫涂料有限公司 | 涂覆剂和由其制备的具有改进抗污性和清洁性的涂层及其用途 |
| EP3275918A1 (en) * | 2016-07-27 | 2018-01-31 | Clariant Plastics & Coatings Ltd | Compositions comprising polyacrylate-polysilane block copolymers |
| US11664491B2 (en) | 2016-09-06 | 2023-05-30 | Johnson Matthey Plc | Anode for an electrochemical cell |
| EP3760658A1 (de) | 2019-07-03 | 2021-01-06 | Covestro Deutschland AG | Beständige 2k-pur-beschichtungen |
| US20230211530A1 (en) | 2020-07-02 | 2023-07-06 | Covestro Deutschland Ag | Coatings from polyisocyanurate coatings (rim) and their use in injection molding processes |
| US11512818B2 (en) | 2020-07-10 | 2022-11-29 | Junming Ding | Multi-mode portable lighting device with novel battery charging unit |
| US12022583B2 (en) | 2020-07-10 | 2024-06-25 | Asiatelco Technologies, Inc. | Portable devices, systems and methods with automated heat control assembly |
| CN118829697A (zh) * | 2022-02-18 | 2024-10-22 | 关西涂料株式会社 | 涂料组合物和涂膜形成方法 |
| JP2023183519A (ja) * | 2022-06-16 | 2023-12-28 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | トップコート層、これを含む積層フィルム、およびこの積層フィルムにより加飾された加飾物品 |
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2009
- 2009-06-24 DE DE102009030481A patent/DE102009030481A1/de not_active Withdrawn
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2010
- 2010-03-08 PL PL10708926T patent/PL2445948T3/pl unknown
- 2010-03-08 WO PCT/EP2010/001422 patent/WO2010149236A1/de not_active Ceased
- 2010-03-08 US US13/378,817 patent/US9017818B2/en active Active
- 2010-03-08 MX MX2011012166A patent/MX2011012166A/es active IP Right Grant
- 2010-03-08 KR KR1020117031639A patent/KR101736513B1/ko active Active
- 2010-03-08 ES ES10708926T patent/ES2444518T3/es active Active
- 2010-03-08 EP EP10708926.0A patent/EP2445948B1/de active Active
- 2010-03-08 CN CN201080025319.XA patent/CN102803330B/zh active Active
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- 2010-03-08 CA CA2759413A patent/CA2759413C/en active Active
- 2010-03-08 RU RU2012102103/04A patent/RU2541531C2/ru active
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2015
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2445948A1 (de) | 2012-05-02 |
| EP2445948B1 (de) | 2013-12-11 |
| KR20120102498A (ko) | 2012-09-18 |
| DE102009030481A1 (de) | 2011-01-05 |
| CN102803330A (zh) | 2012-11-28 |
| CA2759413A1 (en) | 2010-12-29 |
| RU2541531C2 (ru) | 2015-02-20 |
| CN102803330B (zh) | 2016-01-13 |
| ES2444518T3 (es) | 2014-02-25 |
| JP2015155544A (ja) | 2015-08-27 |
| RU2012102103A (ru) | 2013-07-27 |
| PL2445948T3 (pl) | 2014-04-30 |
| BRPI1014324A2 (pt) | 2016-04-05 |
| JP2012530816A (ja) | 2012-12-06 |
| CA2759413C (en) | 2016-09-20 |
| US20120100380A1 (en) | 2012-04-26 |
| US9017818B2 (en) | 2015-04-28 |
| JP5939979B2 (ja) | 2016-06-29 |
| WO2010149236A1 (de) | 2010-12-29 |
| BRPI1014324B1 (pt) | 2019-12-10 |
| MX2011012166A (es) | 2011-12-16 |
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