KR101505848B1 - 고온 승화를 통하여 소화 물질을 생성하는 소화 조성물 - Google Patents
고온 승화를 통하여 소화 물질을 생성하는 소화 조성물 Download PDFInfo
- Publication number
- KR101505848B1 KR101505848B1 KR1020137009568A KR20137009568A KR101505848B1 KR 101505848 B1 KR101505848 B1 KR 101505848B1 KR 1020137009568 A KR1020137009568 A KR 1020137009568A KR 20137009568 A KR20137009568 A KR 20137009568A KR 101505848 B1 KR101505848 B1 KR 101505848B1
- Authority
- KR
- South Korea
- Prior art keywords
- extinguishing
- fire
- fire extinguishing
- substance
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 239000000126 substance Substances 0.000 title claims abstract description 25
- 238000000859 sublimation Methods 0.000 title claims abstract description 16
- 230000008022 sublimation Effects 0.000 title claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 32
- 239000000443 aerosol Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 230000029087 digestion Effects 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- -1 2,4,6-tribromophenyl Chemical group 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000003814 drug Substances 0.000 claims description 6
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 3
- 229920003169 water-soluble polymer Polymers 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 2
- SWLVFNYSXGMGBS-UHFFFAOYSA-N ammonium bromide Chemical compound [NH4+].[Br-] SWLVFNYSXGMGBS-UHFFFAOYSA-N 0.000 claims description 2
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 claims description 2
- VHHHONWQHHHLTI-UHFFFAOYSA-N hexachloroethane Chemical compound ClC(Cl)(Cl)C(Cl)(Cl)Cl VHHHONWQHHHLTI-UHFFFAOYSA-N 0.000 claims description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- PYOIYKRKAHYOKO-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(bromomethyl)benzene Chemical compound BrCC1=C(Br)C(Br)=C(Br)C(Br)=C1Br PYOIYKRKAHYOKO-UHFFFAOYSA-N 0.000 claims 1
- NZUPFZNVGSWLQC-UHFFFAOYSA-N 1,3,5-tris(2,3-dibromopropyl)-1,3,5-triazinane-2,4,6-trione Chemical compound BrCC(Br)CN1C(=O)N(CC(Br)CBr)C(=O)N(CC(Br)CBr)C1=O NZUPFZNVGSWLQC-UHFFFAOYSA-N 0.000 claims 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical group N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims 1
- AMNIKUDFXYWYSY-UHFFFAOYSA-N dimethyl 4-bromobenzene-1,2-dicarboxylate Chemical compound COC(=O)C1=CC=C(Br)C=C1C(=O)OC AMNIKUDFXYWYSY-UHFFFAOYSA-N 0.000 claims 1
- 239000003063 flame retardant Substances 0.000 claims 1
- 239000012757 flame retardant agent Substances 0.000 claims 1
- AUHHYELHRWCWEZ-UHFFFAOYSA-N tetrachlorophthalic anhydride Chemical compound ClC1=C(Cl)C(Cl)=C2C(=O)OC(=O)C2=C1Cl AUHHYELHRWCWEZ-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 238000012360 testing method Methods 0.000 description 9
- 239000007789 gas Substances 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 5
- 230000001079 digestive effect Effects 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 229920004449 Halon® Polymers 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000012159 carrier gas Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000002401 inhibitory effect Effects 0.000 description 3
- 230000005764 inhibitory process Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- RKIDDEGICSMIJA-UHFFFAOYSA-N 4-chlorobenzoyl chloride Chemical compound ClC(=O)C1=CC=C(Cl)C=C1 RKIDDEGICSMIJA-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 239000002828 fuel tank Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- KQNBRMUBPRGXSL-UHFFFAOYSA-N 1-(bromomethyl)-4-chlorobenzene Chemical compound ClC1=CC=C(CBr)C=C1 KQNBRMUBPRGXSL-UHFFFAOYSA-N 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 235000019621 digestibility Nutrition 0.000 description 1
- 210000002249 digestive system Anatomy 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 210000001035 gastrointestinal tract Anatomy 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0092—Gaseous extinguishing substances, e.g. liquefied gases, carbon dioxide snow
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/06—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires containing gas-producing, chemically-reactive components
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010285513.3 | 2010-09-16 | ||
| CN2010102855133A CN102179025B (zh) | 2010-09-16 | 2010-09-16 | 通过高温升华产生灭火物质的灭火组合物 |
| PCT/CN2011/079424 WO2012034490A1 (zh) | 2010-09-16 | 2011-09-07 | 通过高温升华产生灭火物质的灭火组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20130075775A KR20130075775A (ko) | 2013-07-05 |
| KR101505848B1 true KR101505848B1 (ko) | 2015-03-25 |
Family
ID=44565427
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137009568A Active KR101505848B1 (ko) | 2010-09-16 | 2011-09-07 | 고온 승화를 통하여 소화 물질을 생성하는 소화 조성물 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US8865014B2 (enExample) |
| EP (1) | EP2617471B1 (enExample) |
| JP (1) | JP6173212B2 (enExample) |
| KR (1) | KR101505848B1 (enExample) |
| CN (1) | CN102179025B (enExample) |
| AU (1) | AU2011301570B2 (enExample) |
| BR (1) | BR112013006242B1 (enExample) |
| CA (1) | CA2811743C (enExample) |
| IL (1) | IL225286B (enExample) |
| MX (1) | MX340968B (enExample) |
| MY (1) | MY162646A (enExample) |
| PH (1) | PH12013500493B1 (enExample) |
| RU (1) | RU2554580C2 (enExample) |
| WO (1) | WO2012034490A1 (enExample) |
| ZA (1) | ZA201302693B (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105339052A (zh) * | 2013-06-18 | 2016-02-17 | 国立大学法人横浜国立大学 | 灭火剂和灭火方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102179026B (zh) | 2010-09-16 | 2012-06-27 | 陕西坚瑞消防股份有限公司 | 通过高温分解产生灭火物质的灭火组合物 |
| CN102179027B (zh) * | 2010-09-16 | 2012-06-27 | 陕西坚瑞消防股份有限公司 | 一种二茂铁类灭火组合物 |
| CN103170084B (zh) | 2011-12-20 | 2016-04-06 | 西安坚瑞安全应急设备有限责任公司 | 一种金属羰基灭火组合物 |
| CN102824715A (zh) * | 2012-09-21 | 2012-12-19 | 陕西坚瑞消防股份有限公司 | 一种磷酸盐类灭火组合物 |
| CN103751943B (zh) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | 一种含有含氮类有机化合物的灭火组合物 |
| CN103736238B (zh) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | 一种含有含硫类有机化合物的灭火组合物 |
| CN103736240B (zh) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | 一种含有饱和烃类化合物及其衍生物的灭火组合物 |
| CN103768754B (zh) * | 2014-01-13 | 2020-10-13 | 湖北及安盾消防科技有限公司 | 一种含有不饱和烃类化合物及其衍生物的灭火组合物 |
| WO2018047762A1 (ja) * | 2016-09-12 | 2018-03-15 | ヤマトプロテック株式会社 | 自己消火性成形品 |
| CN116328246B (zh) * | 2023-03-16 | 2024-03-12 | 湖北及安盾消防科技有限公司 | 一种组合式热气溶胶灭火药剂及制备方法 |
| CN116943090B (zh) * | 2023-06-13 | 2024-05-28 | 湖北及安盾消防科技有限公司 | 一种化学冷却剂及其在k型气溶胶灭火剂中的应用 |
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| JPH09500296A (ja) * | 1993-06-24 | 1997-01-14 | オリン コーポレイション | 鎮火のための装置と方法 |
| US5861106A (en) | 1997-11-13 | 1999-01-19 | Universal Propulsion Company, Inc. | Compositions and methods for suppressing flame |
| US6045637A (en) | 1998-07-28 | 2000-04-04 | Mainstream Engineering Corporation | Solid-solid hybrid gas generator compositions for fire suppression |
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| US2901428A (en) * | 1953-05-22 | 1959-08-25 | Chem Fab Grunan Ag | Fire extinguishing method |
| NL98618C (enExample) * | 1958-01-22 | |||
| DE1446918A1 (de) * | 1965-08-14 | 1968-11-28 | Dynamit Nobel Ag | Pyrotechnisches Gemisch |
| US3972820A (en) * | 1973-12-20 | 1976-08-03 | The Dow Chemical Company | Fire extinguishing composition |
| US4207245A (en) * | 1979-01-02 | 1980-06-10 | Exxon Research & Engineering Co. | Organometallic intercalates of metal chalcogenohalides |
| CN1052880A (zh) | 1989-12-30 | 1991-07-10 | 天津市电力工业局市区供电公司 | 系列阻燃绝缘涂料 |
| US5071076A (en) * | 1990-08-10 | 1991-12-10 | Omni Quest Corporation | Method for producing magnetic microparticles from metallocenes |
| US5055208A (en) * | 1991-01-02 | 1991-10-08 | Powsus, Inc. | Fire extinguishing compositions |
| RU2005517C1 (ru) * | 1992-01-30 | 1994-01-15 | Люберецкое научно-производственное объединение "Союз" | Состав для тушения пожара |
| CN1064818A (zh) | 1992-04-16 | 1992-09-30 | 肖振三 | 一种森林灭火剂及其制法 |
| US5423385A (en) * | 1992-07-30 | 1995-06-13 | Spectronix Ltd. | Fire extinguishing methods and systems |
| US5466386A (en) * | 1993-05-03 | 1995-11-14 | Powsus, Inc. | Fire extinguishing compositions |
| US5713964A (en) * | 1993-10-25 | 1998-02-03 | Exxon Chemical Patents Inc. | Low smoke composition and firefighter training process |
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| IL118088A0 (en) * | 1995-06-07 | 1996-08-04 | Anzon Inc | Colloidal particles of solid flame retardant and smoke suppressant compounds and methods for making them |
| RU2091106C1 (ru) | 1996-04-26 | 1997-09-27 | Федеральный центр двойных технологий "Союз" | Аэрозольобразующий огнетушащий состав |
| RU2101054C1 (ru) * | 1996-04-30 | 1998-01-10 | Закрытое акционерное общество "Техно-ТМ" | Аэрозолеобразующий состав для тушения пожаров и способ его получения |
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| CN100435892C (zh) * | 2007-07-10 | 2008-11-26 | 陕西坚瑞化工有限责任公司 | 适用于普通电器设备的气溶胶灭火组合物 |
| CN201262535Y (zh) * | 2008-02-29 | 2009-06-24 | 姜延明 | 灭火炮弹 |
| RU2369592C1 (ru) * | 2008-07-17 | 2009-10-10 | Николай Михайлович Вареных | Пиротехнический состав для образования дымовой маскирующей завесы |
| RU2369591C9 (ru) * | 2008-07-17 | 2015-05-20 | Николай Михайлович Вареных | Аэрозолеобразующий пиротехнический состав |
| CN201260858Y (zh) | 2008-08-28 | 2009-06-24 | 宋永昌 | 脉冲式气溶胶干粉复合灭火装置 |
| CN101822883A (zh) * | 2010-04-12 | 2010-09-08 | 南京理工大学 | 烟火式热气溶胶灭火剂及其制备方法 |
| CN102179023B (zh) * | 2010-09-16 | 2012-06-27 | 陕西坚瑞消防股份有限公司 | 一种灭火方法 |
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| JP6173212B2 (ja) | 2017-08-02 |
| ZA201302693B (en) | 2014-06-25 |
| BR112013006242B1 (pt) | 2020-10-06 |
| MY162646A (en) | 2017-06-30 |
| RU2013115865A (ru) | 2014-10-27 |
| EP2617471A4 (en) | 2014-03-12 |
| IL225286B (en) | 2018-02-28 |
| US20130168593A1 (en) | 2013-07-04 |
| CN102179025B (zh) | 2012-06-27 |
| IL225286A0 (en) | 2013-06-27 |
| EP2617471B1 (en) | 2018-12-12 |
| AU2011301570A1 (en) | 2013-05-02 |
| RU2554580C2 (ru) | 2015-06-27 |
| BR112013006242A8 (pt) | 2017-07-11 |
| CN102179025A (zh) | 2011-09-14 |
| MX340968B (es) | 2016-08-02 |
| WO2012034490A1 (zh) | 2012-03-22 |
| CA2811743A1 (en) | 2012-03-22 |
| US8865014B2 (en) | 2014-10-21 |
| CA2811743C (en) | 2016-03-01 |
| JP2013541361A (ja) | 2013-11-14 |
| AU2011301570B2 (en) | 2014-10-09 |
| BR112013006242A2 (pt) | 2016-06-07 |
| EP2617471A1 (en) | 2013-07-24 |
| PH12013500493B1 (en) | 2017-11-22 |
| MX2013002992A (es) | 2013-09-26 |
| KR20130075775A (ko) | 2013-07-05 |
| PH12013500493A1 (en) | 2013-04-29 |
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