KR101496403B1 - 캐소드 촉매층, 막 전극 접합체, 고분자 전해질형 연료전지 및 그 제조방법 - Google Patents

캐소드 촉매층, 막 전극 접합체, 고분자 전해질형 연료전지 및 그 제조방법 Download PDF

Info

Publication number
KR101496403B1
KR101496403B1 KR1020137015861A KR20137015861A KR101496403B1 KR 101496403 B1 KR101496403 B1 KR 101496403B1 KR 1020137015861 A KR1020137015861 A KR 1020137015861A KR 20137015861 A KR20137015861 A KR 20137015861A KR 101496403 B1 KR101496403 B1 KR 101496403B1
Authority
KR
South Korea
Prior art keywords
catalyst layer
ionomer
fuel cell
cathode catalyst
cathode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020137015861A
Other languages
English (en)
Korean (ko)
Other versions
KR20130086646A (ko
Inventor
노부아키 노노야마
마사노리 아이무
랜달 루이스 페리
마크 게리트 로에롭스
로버트 클레이튼 훼랜드
랄프 먼슨 아턴
Original Assignee
도요타 지도샤（주）
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 도요타 지도샤（주） filed Critical 도요타 지도샤（주）
Publication of KR20130086646A publication Critical patent/KR20130086646A/ko
Application granted granted Critical
Publication of KR101496403B1 publication Critical patent/KR101496403B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8657—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites layered
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8647—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites
    • H01M4/8652—Inert electrodes with catalytic activity, e.g. for fuel cells consisting of more than one material, e.g. consisting of composites as mixture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8663—Selection of inactive substances as ingredients for catalytic active masses, e.g. binders, fillers
    • H01M4/8668—Binders
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1004—Fuel cells with solid electrolytes characterised by membrane-electrode assemblies [MEA]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M2008/1095—Fuel cells with polymeric electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/88—Processes of manufacture
    • H01M4/8825—Methods for deposition of the catalytic active composition
    • H01M4/886—Powder spraying, e.g. wet or dry powder spraying, plasma spraying
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • Inert Electrodes (AREA)
  • Fuel Cell (AREA)
KR1020137015861A 2010-12-20 2011-12-20 캐소드 촉매층, 막 전극 접합체, 고분자 전해질형 연료전지 및 그 제조방법 Expired - Fee Related KR101496403B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JPJP-P-2010-283009 2010-12-20
JP2010283009A JP5660879B2 (ja) 2010-12-20 2010-12-20 カソード側触媒層、膜電極接合体、固体高分子型燃料電池及びその製造方法
PCT/JP2011/007116 WO2012086185A1 (en) 2010-12-20 2011-12-20 Cathode catalyst layer, membrane electrode assembly and polymer electrolyte fuel cell and manufacturing method thereof

Publications (2)

Publication Number Publication Date
KR20130086646A KR20130086646A (ko) 2013-08-02
KR101496403B1 true KR101496403B1 (ko) 2015-02-26

Family

ID=45531911

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020137015861A Expired - Fee Related KR101496403B1 (ko) 2010-12-20 2011-12-20 캐소드 촉매층, 막 전극 접합체, 고분자 전해질형 연료전지 및 그 제조방법

Country Status (8)

Country Link
US (1) US9431661B2 (enExample)
EP (1) EP2656419B1 (enExample)
JP (1) JP5660879B2 (enExample)
KR (1) KR101496403B1 (enExample)
CN (1) CN103270630B (enExample)
CA (1) CA2820866C (enExample)
TW (1) TW201246679A (enExample)
WO (1) WO2012086185A1 (enExample)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5851150B2 (ja) * 2011-08-09 2016-02-03 トヨタ自動車株式会社 燃料電池用電極、燃料電池用電極の製造方法および固体高分子形燃料電池
IN2015DN00746A (enExample) * 2012-08-02 2015-07-10 Toyota Motor Co Ltd
JP6315348B2 (ja) * 2015-10-09 2018-04-25 トヨタ自動車株式会社 燃料電池用触媒層及び燃料電池
JP6222530B2 (ja) * 2015-10-09 2017-11-01 トヨタ自動車株式会社 燃料電池用触媒層及び燃料電池
JP6536477B2 (ja) * 2016-05-13 2019-07-03 トヨタ自動車株式会社 燃料電池
JP6593308B2 (ja) * 2016-11-17 2019-10-23 トヨタ自動車株式会社 燃料電池用触媒層
KR102829803B1 (ko) * 2019-03-28 2025-07-03 현대자동차주식회사 전자절연층이 도입된 막-전극 접합체의 전해질막 및 이의 제조방법
EP4414432A3 (en) 2019-11-01 2024-11-20 Daikin Industries, Ltd. Method for producing fluorine-containing polymer and composition thereof
KR20210089826A (ko) * 2020-01-09 2021-07-19 현대자동차주식회사 산소 투과성이 향상된 촉매 복합체를 포함하는 연료전지용 전해질막 및 이의 제조방법
CN114112835B (zh) * 2021-11-04 2024-01-30 武汉理工大学 一种通过嵌入式微电极在线测试质子交换膜氧渗透情况的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5211984A (en) * 1991-02-19 1993-05-18 The Regents Of The University Of California Membrane catalyst layer for fuel cells
EP1739780A1 (en) * 2005-05-13 2007-01-03 Fuji Photo Film Co., Ltd. Solid electrolyte, membrane and electrode assembly, and fuel cell
US20070286948A1 (en) 2006-06-09 2007-12-13 Asahi Glass Company, Limited Process for producing membrane/ electrode assembly for polymer electrolyte fuel cells
JP2010251086A (ja) 2009-04-15 2010-11-04 Toyota Motor Corp 燃料電池

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3584612B2 (ja) 1996-05-30 2004-11-04 旭硝子株式会社 固体高分子型燃料電池およびその電極の製造方法
EP1223628A4 (en) 1999-09-20 2006-09-27 Asahi Glass Co Ltd LAMINATED ELECTRODE / FILM FOR FESTPOLYMER FUEL CELL AND MANUFACTURING METHOD THEREFOR
JP4887580B2 (ja) * 2001-07-23 2012-02-29 旭硝子株式会社 ガス拡散電極及びこれを備えた固体高分子型燃料電池
US7700211B2 (en) 2002-04-17 2010-04-20 Nec Corporation Fuel cell, fuel cell electrode and method for fabricating the same
WO2003088397A1 (fr) 2002-04-17 2003-10-23 Nec Corporation Pile a combustible, electrode pour pile a combustible et procede de preparation correspondant
WO2004066426A1 (ja) 2003-01-20 2004-08-05 Asahi Glass Company, Limited 固体高分子型燃料電池用電解質材料の製造方法及び固体高分子型燃料電池用膜電極接合体
JP5017902B2 (ja) 2006-03-29 2012-09-05 凸版印刷株式会社 燃料電池用触媒層の製造方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5211984A (en) * 1991-02-19 1993-05-18 The Regents Of The University Of California Membrane catalyst layer for fuel cells
EP1739780A1 (en) * 2005-05-13 2007-01-03 Fuji Photo Film Co., Ltd. Solid electrolyte, membrane and electrode assembly, and fuel cell
US20070286948A1 (en) 2006-06-09 2007-12-13 Asahi Glass Company, Limited Process for producing membrane/ electrode assembly for polymer electrolyte fuel cells
JP2010251086A (ja) 2009-04-15 2010-11-04 Toyota Motor Corp 燃料電池

Also Published As

Publication number Publication date
CN103270630A (zh) 2013-08-28
EP2656419A1 (en) 2013-10-30
KR20130086646A (ko) 2013-08-02
US20140154608A1 (en) 2014-06-05
CN103270630B (zh) 2016-04-06
CA2820866A1 (en) 2012-06-28
WO2012086185A1 (en) 2012-06-28
EP2656419B1 (en) 2017-11-22
JP2012133917A (ja) 2012-07-12
TW201246679A (en) 2012-11-16
WO2012086185A9 (en) 2013-05-30
CA2820866C (en) 2016-02-02
JP5660879B2 (ja) 2015-01-28
US9431661B2 (en) 2016-08-30

Similar Documents

Publication Publication Date Title
KR101496403B1 (ko) 캐소드 촉매층, 막 전극 접합체, 고분자 전해질형 연료전지 및 그 제조방법
US7943249B2 (en) Liquid composition, process for its production and process for producing membrane-electrode assembly for polymer electrolyte fuel cells
Douglin et al. A high-temperature anion-exchange membrane fuel cell with a critical raw material-free cathode
EP1772919B2 (en) Electrolyte membrane for solid polymer fuel cell, method for producing same and membrane electrode assembly for solid polymer fuel cell
Novalin et al. Electrochemical performance of poly (arylene piperidinium) membranes and ionomers in anion exchange membrane fuel cells
US20080118808A1 (en) Electrolyte membrane for polymer electrolyte fuel cell, process for its production and membrane-electrode assembly for polymer electrolyte fuel cell
EP2134768B1 (en) Proton conducting aromatic polyether type copolymers bearing main and side chain pyridine groups and use thereof in proton exchange membrane fuel cells
D'Urso et al. Fuel cell performance and durability investigation of bimetallic radical scavengers in Aquivion® perfluorosulfonic acid membranes
von Kraemer et al. Gas diffusion electrodes and membrane electrode assemblies based on a sulfonated polysulfone for high-temperature PEMFC
CN102468507A (zh) 通过膜中的氧化物担载的贵金属改进了燃料电池耐久性
EP1926165A1 (en) Polymer electrolyte membrane and membrane-electrode assembly for polymer electrolyte fuel cell
Osmieri et al. Impact of fabrication and testing parameters on the performance of a polymer electrolyte fuel cell with platinum group metal (PGM)-Free cathode catalyst
US20150188175A1 (en) Polymer membranes with rare earth or transition metal modifiers
Wang et al. Proton exchange membrane water electrolysis incorporating sulfo-phenylated polyphenylene catalyst coated membranes
Emets et al. Development of hydrogen–air fuel cells with membranes based on sulfonated polyheteroarylenes
Lindström et al. Performance of phosphonated hydrocarbon ionomer in the fuel cell cathode catalyst layer
Punyawudho et al. Advancements and Challenges in Electrode and Electrolyte Materials for Proton Exchange Membrane Fuel Cells: A Comprehensive Review
JP7420629B2 (ja) 高分子電解質
KR100970358B1 (ko) 액상 조성물, 그 제조 방법 및 고체 고분자형 연료 전지용막 전극 접합체의 제조 방법
Mamlouk et al. A study of oxygen reduction on carbon-supported platinum fuel cell electrocatalysts in polybenzimidazole/phosphoric acid
Kiatkittikul A study on nonhumidified fuel cells using fluorohydrogenate ionic liquids
JP2021061219A (ja) 含フッ素高分子電解質
清水瞭 Research on Hydrocarbon Polymer Electrolyte Membranes and Catalyst Layers for High Performance, Highly Durable Fuel Cells
조민경 Single cell characteristics of high temperature polymer electrolyte membrane fuel cell under low humidity conditions
Ingratta et al. Performance of Phosphonated Hydrocarbon Ionomer in

Legal Events

Date Code Title Description
A201 Request for examination
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20180202

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20190201

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

FPAY Annual fee payment

Payment date: 20200205

Year of fee payment: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20230218

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20230218