KR101458877B1 - Hair coloring composition comprising of Gallnut, Salicomia Herbaceal and Persimmon Leaves extracts - Google Patents

Abstract

The present invention relates to a hair coloring composition of a first dosage form oxidative coloring containing natural extracts and, more specifically, a hair coloring composition of a first dosage form oxidative coloring containing natural components like extracts of gallnut, Salicomia Herbaceal and persimmon leaves. The first oxidative coloring, according to the present invention, contains natural extracts with excellent antioxidant activity, accordingly, reduces scalp damage and hair damage caused by coloring, improves the coloring of hair, prevents the change of colors and maintains the coloring of hair.

Description

[0002] Hair coloring compositions comprising of Gallnut, Salicomia Herbacea and Persimmon Leaves extracts,

The present invention relates to a hair dye composition for dyeing keratin fibers, and more particularly, to a hair dye composition for dyeing keratin fibers, which comprises natural components of a mixture of daphnia, green tea, and persimmon leaves to reduce damage to scalp and hair caused by dyeing, And which has high durability and long lasting durability.

The hair dye used in hair can be divided into vegetable, metallic, and oxidative type hair dyes according to the ingredients. Depending on the function, temporary hair dyes, semi-permanent hair dyes, and permanent hair dyes can be categorized.

Temporary colourants temporarily change the color of the hair by applying color only to the surface of the hair. Because these products are pigmented, they are colored only in the outer part of the hair and disappear with one or two shampoos. Types of temporary hair dye include color spray, color mascara, color gel, and calamus.

Semi-permanent colourants are hair dye used to change the color of hair to maintain color until 4 to 6 times shampoo. They are also called direct hair dye, but they do not need to be mixed with oxidizer for the treatment . The color particles of this product are a mixture of large and small molecules, and small molecules penetrate the skin of the eye, so they have color persistence rather than temporary hair dye, but the color particles fall off by water every time the hair is shampooed.

Permanent colourants refer to hair dye that can permanently change hair color by penetrating through follicle of hair and acting on follicle. The oxidation dyeing agent is mainly composed of a dyeing agent for one dye and an oxidizing agent for dyeing two dyes, and dye precursors such as p-phenylenediamine and p-aminophenol are used as dye modifiers or couplers, Aminophenol, m-phenylenediamine, resorcin, and the like to exhibit various colors. Dyes mainly used in oxidative dyeing agents are polar aromatic aromatic compounds such as dihydroxybenzenes, aminophenols and phenylenediamines. Especially, p-phenylenediamine, which is a dihydroxybenzene, is important for coloring in most hair dyeing agents. It plays a role.

Vegetable colourants include Henna. The use of henna dates back thousands of years. Ancient Egyptians are said to have used it to dye hair, nails and palms. Henna is called khenna for Egyptians, mendee for India, and khanna for Arabs. The main ingredient in henna is Lawsone and it tends to become stiff after treatment because it contains tannins. Preparatory process and application are complicated, and hot water and powder are mixed and made into a tight pool state. Put a plastic cap (plastic cap) or a towel over the hair for 30 to 60 minutes to make the hair color strong. It is common for women in the middle east to leave henna in their hair all night.

As a chemical product, hair dye is a careless procedure under the universal recognition that it can be easily done by anyone, even though it should be done by a specialist by experts, which is another cause of hair damage. Hair hair dyeing is a kind of chemical medicine, and research on the effect of hair dyeing on hair and other organs as well as medical aspects has attracted much attention. Therefore, it is widely recognized that it is better to dye the hair using the ingredients extracted from the plant rather than to use the chemical hair dye for the modern man. The hair color is considered considering the color of the hair that matches the skin color, and the hair color is maintained and the hair is healthy. It is in favor of products that have been enhanced with botanical dyes and high-performance treatments.

Korean Patent Publication No. 2010-0067604 entitled " One Formulation Type Oxidative Hair Salvia Composition Containing Natural Ingredients "includes " one type of oxidative type hair dye containing a mixture of one or two or more selected from green tea polysaccharide, Korean Patent Laid-Open Publication No. 2009-0056200, "a hair dye composition for dyeing dyes containing daphnia or pseudomonas sp.," Contains a first agent containing an oxidation dye precursor, a coupler and an alkaline agent, and a second agent containing an oxidant The present invention relates to a hair dye composition for dyeing keratin fibers which is composed of a natural antioxidant and a natural antioxidant as a natural antioxidant in the first agent.

The present inventors have studied various natural extracts useful for a hair dye composition. As a result, it has been found that hair and scalp are protected when mixed with a specific ratio of dumbbell, green tea, persimmon leaf extract of the present invention and added to a hair dye, And the dyeing sustainability is improved. Thus, the present invention has been completed.

Therefore, it is an object of the present invention to provide a hair dyeing composition containing a mixture of dicotyledonous, green tea, and persimmon leaves to reduce the damage of scalp and hair caused by staining.

Another object of the present invention is to provide a hair dye composition which contains a mixture of daphniaceae, green tea, and persimmon leaves to enhance hair dyeability and to prevent discoloration and enhance dyeing sustainability.

To attain the above object, according to the present invention, there is provided a hair dye composition for dyeing one type of composition containing an oxidation dye precursor, a coupler and an oxidizing agent, wherein the hair dye composition for oxidative dyeing contains dapper, / RTI > At this time, the mixed extract of dumbbell, green tea and persimmon as an active ingredient is contained in an amount of 0.1 to 10% by weight based on the total weight of the composition.

In addition, the mixed extracts of dicotyledonous, green tea and persimmon leaves are mixed in a weight ratio of 1: 2: 1 to 2: 1: 2, more preferably 2: 2: 1.

The mixed extract of Opium, Green tea and Persimmon may be a hot water extract or a solvent extract with at least one solvent selected from the group consisting of water, lower alcohol having 1 to 4 carbon atoms, ethyl acetate, glycerin, ethylene glycol, propylene glycol and butylene glycol to be. More preferably, it is an extract by a 70% ethanol solvent.

The hair dye composition containing the active ingredient of the mixed extract of Opium, Green tea and Persimmon leaves may be applied as a powder, paste, cream, lotion or liquid form.

The hair dyes according to the present invention contain a natural extract having antioxidative activity to reduce damages of scalp and hair due to dyeing, improve dyeability to hair, prevent discoloration during dyeing, and enhance durability.

Hereinafter, the present invention will be described in detail.

The present invention relates to an oxidative dyeing agent containing an oxidative dye precursor, a coupler and an oxidizing agent, and it is possible to reduce damages of the scalp and hair damaged by dyeing by adding a mixture of dapper, green tea and persimmon leaf to the dye, The present invention relates to a technique for preventing discoloration and increasing the sustainability of dyeing.

The dwarf used in the present invention is a "parasite insect parasitic on the rhus cotyledon." The rhusin is a tree with red leaves. When the aphid cuts the leaf to lay eggs, a pouch is formed and a larva grows in the pouch. Is called an observer. The larvae are empty or have dead gray worms and secretions left behind. They can be smelled. They are divided into ear-shaped bibs, twig-shaped bibs and flower-shaped bibs depending on the shape of the worms. It is generally known that a thick-skinned dwarf is good. Dwarf is also used as a raw material for making natural dyes and inks that color fabrics, and is also widely used as an anticancer drug. It also has effects on swelling, dermatitis, and itching. Gallotammin 'ingredient in pharmacological action of gall bladder has a convergent action to shrink the skin, so that when contacted with the skin mucosa, the tissue protein coagulates and shows a convergent effect. Dahnin contains a lot of tannin components. Tannin is a function of aggregating proteins as a convergence energy, and when this dwarf powder comes in contact with mucous membrane or ulcer area of dermatitis, it coagulates the protein tissue and eventually forms a thin scab. In particular, it has an excellent effect of restoring the area when it is burned, and it also has the effect of preventing the damage from the secondary site of the burn site.

Green tea contains a large amount of minerals such as sodium, calcium, potassium and iron and contains essential amino acids and polysaccharides such as taurine, valine and leucine, It is said that it is called "Tengtungmadi" because it is a grass which is a wild plant and it is a grass that protruded from each node. It has been widely used in folk medicine since ancient times. There are various references such as constipation, obesity, diabetes, blood pressure, skin disease, It is known to have efficacy.

Persimmon leaves have a lot of vitamin A and vitamin C. Especially vitamin C contains more than other fruits, and the persimmon leaves contain a component called a routine that causes hemostasis and hypotensive effect. Convection caused by the tannin component in the persimmon leaves constricts the surface of the mucous membrane in the body to stop the diarrhea and alleviate the symptoms of gastric ulcer. It is also effective when burned by the convergence of tannic acid.

The mixed extract of Opium, Green tea and Persimmon of the present invention may be used as powder or concentrate, and the extract may be prepared by hot water extraction or solvent extraction.

According to one embodiment of the present invention, the mixed extract is prepared by extracting with water, at least one solvent selected from anhydrous or hydrous alcohol having 1 to 4 carbon atoms, ethyl acetate, glycerin, ethylene glycol, propylene glycol and butylene glycol. Or a mixture of extracts of dulcimer, green tea, and persimmon leaves with the above-mentioned solvent, followed by mixing.

According to another embodiment of the present invention, the mixed extract of Opium, Green tea and Persimmon leaves is a mixture of water, ethanol, methanol, butanol, propanol, butylene glycol, glycerin, chloroform, ethyl acetate, dichloromethane, hexane , Acetone, acetonitrile, petroleum ether, and diethyl ether.

Concretely, it is prepared by immersing three-fold dwarf, green tea, and persimmon leaves in a solvent at a stable temperature or by reflux extraction from an extractor equipped with a cooling condenser, followed by filtration, concentration under reduced pressure and freeze- Also, it may include a process of low-temperature aging or high-temperature aging after the extraction process.

In the hair dye composition of the present invention, the mixed extract of Opium, Green tea and Persimmon can be added to the hair dye in an amount of 0.001 to 10.0% by weight based on the total weight of the hair dye composition, preferably in an amount of 0.001 to 5.0% Can be added. If it is added in an amount of less than 0.001% by weight, the effect is weak. If it exceeds 10% by weight, the activity of the oxidizing agent may be lowered and the dyeability may be lowered.

The mixture of the above-mentioned mixture of dwarf, green tea and persimmon leaves is mixed at a weight ratio of 1: 2: 1 to 2: 1: 2, more preferably 2: 2: 1, , And the dyeability and durability were excellent.

The thus-prepared mixed extract of the present invention was superior in antioxidative activity (Test Example 1) in comparison with the respective components due to the synergistic action thereof, thus being advantageous for hair protection and scalp protection, The oxidized type hair dyeing agent was confirmed to be excellent in durability (Test Example 2). In addition, it was confirmed that excellent effects were obtained also in the staining duration (Test Example 3) and the hair damage inhibiting effect (Test Example 4).

In the present invention, as the oxidation dye precursor to be used, those conventionally used may be used, and the kind thereof is not particularly limited. As the oxidation dye precursor, p-aminophenol, p-phenylenediamine, p-phenylenediamine hydrochloride, p-phenylenediamine sulfate and the like can be used. As the dye modifier, p-amino-o-cresol, 2-methyl-5-hydroxy quilaminophenyl, resorcinol and the like can be used as the coupler, and the kind thereof is not particularly limited . The oxidizing agent may also be a conventional one, and the kind thereof is not particularly limited.

In addition, components commonly used in hair dyeing agents, that is, antioxidants, metal blockers, solvents, surfactants, thickeners, fragrances and conditioning agents can be used within the range not impairing the effects of the present invention.

The hair dye composition containing the active ingredient of the present invention can be applied as a powder, paste, cream, lotion or liquid formulation.

[Example]

Hereinafter, the present invention will be described in detail by way of the following examples and test examples, but the present invention is not limited to these examples.

Example 1: Preparation of mixed extract of obovata, green tea and persimmon leaves

After mixing with 50 g of dried dwarf, 50 g of green tea leaf and 50 g of persimmon leaf (dry weight ratio = 1: 1: 1), 3 kg of 70% aqueous ethanol was added to the extract and boiled for 8 hours at 100 ° C. in an extractor equipped with a cooling condenser The filtrate was filtered through a 300-mesh filter paper, left at room temperature for 1 week, and the precipitate was filtered twice with a filter paper of Edbentek No. 5 and a Wattman GFC 47 mm filter. The mixture was concentrated at 50 ° C using a vacuum concentrator, and then dried using a spray dryer (manufactured by BUCHI) to obtain a mixed extract powder having a dry weight of 12.3 g.

Examples 2 to 7: Production of mixed extract of obovata, green tea and persimmon leaves

As shown in the following Table 1, the mixed extract powder was prepared by extracting and filtering in the same manner as in Example 1, except that the mixing ratio of dwarf, green tea and persimmon leaves was varied.

(Weight ratio) Example 2 Example 3 Example 4 Example 5 Example 6 Example 7 gallnut One One One 2 2 2 Green tea One 2 2 One One 2 Persimmon leaf 2 One 2 One 2 One

Comparative Example  1: Manufacture of Rhus verniciflua extract powder

50 g of dumbbells were placed in 1 kg of 70% ethanol solution and boiled for 8 hours at 100 ° C in a condenser equipped with a condenser. The mixture was filtered through a 300-mesh filter paper and left at room temperature for one week. The precipitate was filtered through Edbentek No. 5 filter paper and Watman GFC 47 mm Filter 2 times with filter paper. Then, the mixture was concentrated at 50 ° C using a vacuum concentrator, and then dried using a spray dryer (manufactured by BUCHI) to obtain a crude extract powder.

Comparative Example 2: Preparation of powder of green tea extract

50 g of green tea was added to 1 kg of 70% ethanol, and the mixture was boiled for 8 hours at 100 ° C. in a condenser equipped with a condenser. The mixture was filtered through 300 mesh filter paper and left at room temperature for 1 week. The precipitate was filtered through Edbentek 5 filter paper and Watman GFC 47 mm filter paper Lt; / RTI > twice. The mixture was concentrated at 50 ° C using a vacuum concentrator, and dried using a spray dryer (manufactured by BUCHI) to obtain a green tea extract powder.

Comparative Example 3: Preparation of persimmon leaf extract powder

50 g of persimmon leaves were weighed into 1 kg of 70% ethanol and boiled for 8 hours at 100 ° C. in a condenser equipped with a condenser. The mixture was filtered through 300 mesh filter paper and left at room temperature for 1 week. The precipitate was filtered through Edbentek 5 filter paper and Watman GFC 47 mm Filter 2 times with filter paper. The mixture was concentrated at 50 ° C using a vacuum concentrator, and then dried using a spray dryer (manufactured by BUCHI) to obtain a persimmon leaf extract powder.

Examples 8 to 14: Production of a hair dye using a mixed extract of daphnia, green tea and persimmon leaves

A hair dye containing a mixture of daphniaceous, green tea and persimmon leaves was prepared according to a conventional method with the composition and content shown in Table 2 below.

(weight%) Control Example Comparative Example Example 4 5 6 8 9 10 11 12 13 14 Obovate extract - 0.5 - - - - - - - - - Green tea extract - - 0.5 - - - - - - - - Persimmon leaf extract - - - 0.5 - - - - - - - The mixed extract (Example 1) - - - - 0.5 - - - - - - The mixed extract (Example 2) - - - - - 0.5 - - - - - The mixed extract (Example 3) - - - - - - 0.5 - - - - The mixed extract (Example 4) - - - - - - - 0.5 - - - The mixed extract (Example 5) - - - - - - - - 0.5 - - The mixed extract (Example 6) - - - - - - - - - 0.5 - The mixed extract (Example 7) - - - - - - - - - - 0.5 Cetyl alcohol 7.0 7.0 7.0 7.0 7.0 7.0 7.0 7.0 7.0 7.0 7.0 paraffin 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 Stearothiomerium chloride 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 Polyoxyethylene cetyl ether 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 EDTA.4Na 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Propylene glycol 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Sodium sulphate 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7 Monoethanolamine 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 ammonia 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 5.0 p-phenylenediamine 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Resorcinol 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 p-Aminophenol 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 p-amino-ocresol 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 2-Methyl-5-hydroxyethylaminophenol 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Purified water To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100 To 100

Test Example 1: Measurement of antioxidative effect using NBT method

Antioxidant activity was measured using the NBT method with other antioxidants, that is, BHT, as a comparative sample under laboratory conditions, in order to confirm the antioxidant effect of the mixed extracts of dumbbells, green tea and persimmon leaves obtained in Examples 1 to 7.

In order to measure the antioxidative effect, the active oxygen produced by xanthine and xanthine oxidase was measured by the NBT method and the effect of the test substance on the removal of active oxygen, that is, the effect of active oxygen scavenging was evaluated. The active oxygen generated by xanthine and xanthine oxidase was reacted with Nitro Blue Tetrazolium (NBT), and the blue color produced thereby was measured at a wavelength of 560 nm to measure the active oxygen scavenging rate. The method of measuring the active oxygen scavenging rate is as follows.

2.4 ml of 0.05 M Na ₂ CO ₃ , 0.1 ml of a 3 mM xanthine solution, 0.1 ml of a 3 mM EDTA solution, 0.1 ml of a BSA solution and 0.1 ml of a 0.72 mM NBT solution were added to a vial (5 ml vial) and thereto was added DMSO 0.1 ml of the sample solution prepared at a concentration of 0.1 (wt / v)% is added, and the mixture is allowed to stand at 25 ° C for 10 minutes. Thereafter, 0.1 ml of xanthine oxidase solution is added, and the mixture is stirred rapidly and incubation is started at 25 ° C for 20 minutes. Then, 0.1 ml of ₆ Mm CuCl ₂ solution is added to stop the reaction, and the absorbance St at 560 nm is measured. The blank test is carried out in the same manner as above using distilled water instead of the sample solution, and the absorbance Bt is measured. Again, the blank of the sample solution is measured by the same procedure using distilled water instead of the xanthine oxidase solution to determine the absorbance Bo. The results of the effects were calculated by the following formula, and the results are shown in Table 3 below.

Inhibition rate (%) = [1- (St-So) / (Bt-Bo)] 100

St: Absorbance at 560 nm after enzyme reaction of sample solution

Bt: Absorbance at 560 nm after enzyme reaction of blank test solution

So: the absorbance at 560 nm before the reaction in the absence of enzyme in the sample solution

Bo: absorbance at 560 nm before the reaction in the absence of enzyme in the blank test solution

Name of sample Treatment concentration (w / v%) Antioxidative effect(%) Leucocyte, Green tea and Persimmon Leaf Extract (Example 1) 0.1 93 Leucocyte, Green tea and Persimmon Leaf Extract (Example 2) 0.1 93 Leucocyte, Green tea and Persimmon Leaf Extract (Example 3) 0.1 92 Green tea, persimmon leaves and persimmon leaves (Example 4) 0.1 93 (Example 5) < tb > < tb > < 0.1 93 (Example 6) < tb > < tb > < 0.1 94 (Example 7) < tb > < sep > 0.1 96 Rhizoma extract (Comparative Example 1) 0.1 85 Green tea extract (Comparative Example 2) 0.1 82 Persimmon leaf extract (Comparative Example 3) 0.1 81 BHT (butylated hydroxyanisole, DUKSAN KOREA) 0.1 90

As shown in Table 3, the antioxidative effect was confirmed in all of the samples tested at a concentration of 0.1 (wt / v)%. Especially, the mixed extracts of Opium, Green tea and Persimmon leaves showed superior antioxidative effect and superior antioxidative effect than BHT. Among them, Example 7 showed the most excellent antioxidative effect.

Test Example 2: Confirmation of stickiness

The hair dye compositions prepared according to the Control Examples, Comparative Examples 4 to 6, and Examples 8 to 14 were applied to human hair, washed and dried after 20 minutes, and then the hair was measured for color using a colorimeter. The colorimetric results were compared with the L value. When the L value is smaller, the color is darker, indicating excellent dyeability. The results are shown in Table 4 below.

Brightness (L) Brightness (L) Control Example 16.23 Example 10 14.75 Comparative Example 4 15.16 Example 11 14.26 Comparative Example 5 15.00 Example 12 14.78 Comparative Example 6 15.16 Example 13 13.99 Example 8 14.26 Example 14 13.21 Example 9 14.33

As can be seen from the above Table 4, the hair dye of Examples 8 to 14 containing the mixed extract of Opaque, Green tea and Persimmon of the present invention showed no significant difference in comparison with Comparative Examples 4 to 5 containing no opioid, 6 than the dyeing agent. Among them, the dyeing agent of Example 14 showed the most excellent dyeing property.

Test Example 3: Confirmation of dye persistence

The hair dyed with the hair dye composition prepared according to the Control Example, Comparative Examples 4 to 6 and Examples 8 to 14 was put in a shampoo solution and shaken at a speed of 300 rpm for 20 minutes using a shaker, For 1 minute and dried with a hair dryer. The color difference was measured using a colorimeter after drying, and the results are shown in Table 5 below.

vitality vitality Control Example △ Example 10 ○ Comparative Example 4 ● Example 11 ● Comparative Example 5 ○ Example 12 ● Comparative Example 6 ● Example 13 ● Example 8 ○ Example 14 × Example 9 ○

(●: less color difference, ○: slight color difference, Δ: significant color difference, ×: no color difference)

As can be seen in Table 5, the hair dye composition of Examples 8 to 14 containing the extract of the present invention, dicotyledonous plant extracts, green tea leaves and persimmon leaves showed better dyed color persistence than the control without dicotyledonous, Respectively. In addition, it was confirmed that the dyed color persistence was superior when mixed with the natural extracts of Opium, Green tea and Persimmon leaf alone. Among them, the dyeing agent of Example 14 exhibited the best dye color persistence.

Test Example 4: Confirmation of damage to hair

In order to evaluate the degree of damage to hair caused by use of the hair dye composition prepared according to the Control Examples, Comparative Examples 4 to 6, and Examples 8 to 14, 39 subjects who were hair dyed with each composition were evaluated, The results are shown in Table 6.

Damage Damage Control Example × Example 10 ○ Comparative Example 4 ○ Example 11 ○ Comparative Example 5 ○ Example 12 ○ Comparative Example 6 ○ Example 13 ○ Example 8 ○ Example 14 ● Example 9 ○

(●: very soft, ○: soft, ×: rough)

As can be seen in Table 6, the hair dye composition of Examples 8 to 14 containing the present invention mixed extract of Opium, Green tea and Persimmon leaves had less sense of damage to hair than the control without the mixed extract of Opium, Green tea and Persimmon . In addition, it was confirmed that the effect of reducing hair damage was more excellent when the natural extract of Opium, Green tea, and Persimmon leaves was mixed than when they were mixed alone. Among them, the hair dye of Example 14 showed the best hair damaging effect.

Claims (9)

1. A hair dye composition for dyeing one type of a composition containing an oxidation dye precursor, a coupler and an oxidizing agent,
A hair dyeing composition for dyeing with oxidation characterized by containing a mixture of dapper, green tea, and persimmon leaves. [2] The hair dyeing composition for dyeing according to claim 1, wherein the mixed extract of Opium, Green tea and Persimmon leaves is contained in an amount of 0.1 to 10% by weight based on the total weight of the composition. [2] The hair dyeing composition for dyeing according to claim 1, wherein the mixture of dumbbell, green tea, and persimmon leaves is mixed at a weight ratio of 1: 2: 1 to 2: 1: 2. 4. The hair dyeing composition for dyeing according to claim 3, wherein the mixture of dumbbell, green tea and persimmon leaves is mixed at a weight ratio of 2: 2: 1. [2] The hair dyeing composition for dyeing with oxidation according to claim 1, wherein the mixed extract of Opium, Green tea and Persimmon leaves has antioxidant activity. [3] The hair dyeing composition for dyeing according to claim 1, wherein the mixture of dumbbell, green tea, and persimmon leaves is used to impart durability to the hair dye composition. [3] The hair dyeing composition for dyeing according to claim 1, wherein the dandruff, green tea, and persimmon leaf blended extracts impart dyeing durability to the hair dye composition. [3] The hair dyeing composition for dyeing according to claim 1, wherein the mixed extract of Opium, Green tea and Persimmon leaves gives hair damaging composition hair reducing ability. 9. The hair dyeing composition according to any one of claims 1 to 8, wherein the hair dye composition containing the active ingredient of the mixed extract of green tea, green tea and persimmon leaves has a formulation of powder, paste, cream, lotion or liquid. Hair dye composition.