KR101328876B1 - 고분자량 폴리(테트라메틸렌-코-에틸렌에테르)글리콜로부터제조된 스판덱스 - Google Patents

고분자량 폴리(테트라메틸렌-코-에틸렌에테르)글리콜로부터제조된 스판덱스 Download PDF

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Publication number
KR101328876B1
KR101328876B1 KR1020087012110A KR20087012110A KR101328876B1 KR 101328876 B1 KR101328876 B1 KR 101328876B1 KR 1020087012110 A KR1020087012110 A KR 1020087012110A KR 20087012110 A KR20087012110 A KR 20087012110A KR 101328876 B1 KR101328876 B1 KR 101328876B1
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glycol
tetramethylene
poly
spandex
ethyleneether
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Expired - Fee Related
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Korean (ko)
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KR20080080501A (ko
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제임스 마이클 람버트
찰스 프란시스 주니어 팔머
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인비스타 테크놀러지스 에스.에이.알.엘.
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/70—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
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    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/285—Nitrogen containing compounds
    • C08G18/2865—Compounds having only one primary or secondary amino group; Ammonia
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
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    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
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    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
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    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
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    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
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    • C08G18/3231—Hydrazine or derivatives thereof
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    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
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    • C08G18/3234—Polyamines cycloaliphatic
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    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3237—Polyamines aromatic
    • C08G18/324—Polyamines aromatic containing only one aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
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    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
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    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
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    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
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    • D—TEXTILES; PAPER
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    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
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  • Chemical & Material Sciences (AREA)
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  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Artificial Filaments (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Woven Fabrics (AREA)
KR1020087012110A 2005-11-22 2006-05-08 고분자량 폴리(테트라메틸렌-코-에틸렌에테르)글리콜로부터제조된 스판덱스 Expired - Fee Related KR101328876B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US73890105P 2005-11-22 2005-11-22
US73868405P 2005-11-22 2005-11-22
US60/738,901 2005-11-22
US60/738,684 2005-11-22
PCT/US2006/017724 WO2007061446A1 (en) 2005-11-22 2006-05-08 Spandex from high molecular weight poly (tetramethylene-co-ethyleneether) glycols

Publications (2)

Publication Number Publication Date
KR20080080501A KR20080080501A (ko) 2008-09-04
KR101328876B1 true KR101328876B1 (ko) 2013-11-14

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KR1020087012110A Expired - Fee Related KR101328876B1 (ko) 2005-11-22 2006-05-08 고분자량 폴리(테트라메틸렌-코-에틸렌에테르)글리콜로부터제조된 스판덱스

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Country Link
US (1) US9441314B2 (https=)
EP (1) EP1951782A1 (https=)
JP (1) JP5271085B2 (https=)
KR (1) KR101328876B1 (https=)
CN (1) CN104387545A (https=)
BR (1) BRPI0620534A2 (https=)
HK (1) HK1207873A1 (https=)
WO (1) WO2007061446A1 (https=)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101782726B1 (ko) 2016-04-11 2017-09-29 한양대학교 산학협력단 산화그래핀 방사 용액의 제조 방법, 및 이를 이용한 그래핀 섬유의 제조 방법
KR101782725B1 (ko) * 2016-04-11 2017-09-29 한양대학교 산학협력단 그래핀 섬유 및 그 제조 방법
WO2017179900A1 (ko) * 2016-04-11 2017-10-19 한양대학교 산학협력단 그래핀 섬유 및 그 제조 방법
KR20180021360A (ko) * 2016-08-19 2018-03-02 한양대학교 산학협력단 그래핀 섬유 복합체 및 그 제조 방법
US10995428B2 (en) 2016-04-11 2021-05-04 Iucf-Hyu (Industry-University Cooperation Foundation Hanyang University) Graphene fiber and method of manufacturing the same
US11649566B2 (en) 2016-04-11 2023-05-16 Iucf-Hyu (Industry-University Cooperation Foundation Hanyang University) Graphene fiber and method of manufacturing the same

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8574394B2 (en) * 2007-12-21 2013-11-05 Henkel Ag & Co. Kgaa Method for preparing a moisture curable hot melt adhesive
ES2465519T3 (es) * 2009-04-15 2014-06-06 Invista Technologies S.À.R.L. Procedimiento de fabricación de copoliéter glicol
WO2011071502A1 (en) * 2009-12-11 2011-06-16 Invista Technologies S.A.R.L. Improved elastomeric compositions
JP2013536898A (ja) * 2010-09-10 2013-09-26 インヴィスタ テクノロジーズ エスアエルエル ポリエーテルアミン、ポリエーテルアミン含有組成物および製造方法
US20180305842A1 (en) * 2015-06-30 2018-10-25 Invista North America S.A R.L. Polyurethane fiber including copolymer polyol
CN118871489A (zh) 2022-03-10 2024-10-29 巴斯夫欧洲公司 聚氨酯脲及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3425999A (en) * 1966-07-11 1969-02-04 Wyandotte Chemicals Corp Tetrahydrofuran-ethylene oxide polyether urethane-urea polymers
KR20020039359A (ko) * 1999-10-05 2002-05-25 메리 이. 보울러 장해 디이소시아네이트로 제조된 스판덱스

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4163115A (en) * 1976-03-31 1979-07-31 E. I. Du Pont De Nemours And Company Preparation of esters of poly-(tetramethylene ether) glycol
US4153786A (en) * 1977-03-30 1979-05-08 E. I. Du Pont De Nemours And Company Method for preparing ester end-capped copolyether glycols
US4139567A (en) * 1977-03-30 1979-02-13 E. I. Du Pont De Nemours And Company Method for preparing copolyether glycols
US4120850A (en) * 1977-09-06 1978-10-17 E. I. Du Pont De Nemours And Company Polyether urethane polymers prepared from a copolymer of tetrahydrofuran and ethylene oxide
US4224432A (en) * 1978-12-11 1980-09-23 E. I. Du Pont De Nemours And Company Polyurethanes prepared with tetrahydrofuran-alkylene oxide polymerizates having low oligomeric cyclic ether content
DE2964245D1 (en) * 1978-03-16 1983-01-20 Du Pont Polyurethanes prepared with tetrahydrofuran-alkylene oxide polymerizates having low oligomeric cyclic ether content, processes for preparing the same, and articles and fibers of the polyurethanes
US4383100A (en) * 1980-09-19 1983-05-10 E. I. Du Pont De Nemours And Company Polyurethanes from oligomeric formal diols of THF copolymer glycols
CA1216597A (en) * 1983-05-23 1987-01-13 Atsushi Aoshima Process for producing polyetherglycol
US4658065A (en) * 1984-03-28 1987-04-14 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing polyether polyol and a product
JPS61155417A (ja) * 1984-12-27 1986-07-15 Sanyo Chem Ind Ltd ポリウレタンの製造法
JPH06104116B2 (ja) * 1988-11-29 1994-12-21 三菱化成株式会社 創傷被覆材
DE4104199A1 (de) * 1991-02-12 1992-08-13 Basf Ag Verfahren zur herstellung von polyurethan-elastomeren und hierfuer geeignete mischungen aus polyoxybutylen-polyoxyalkylen-glykolen und glycidylverbindungen
US5340902A (en) * 1993-06-04 1994-08-23 Olin Corporation Spandex fibers made using low unsaturation polyols
KR100239204B1 (ko) * 1995-06-23 2000-01-15 야마모토 카즈모토 폴리우레탄 탄성 섬유 및 그의 제조 방법
DE19625987A1 (de) * 1996-06-28 1998-01-02 Bayer Ag Verfahren zur kontinuierlichen Herstellung von thermoplastisch verarbeitbaren Polyurethanen mit verbessertem Verarbeitungsverhalten
US5998574A (en) 1996-07-10 1999-12-07 Basf Corporation Compositions of polytetramethylene ether glycols and polyoxy alkylene polyether polyols having a low degree of unsaturation
US6050451A (en) * 1998-11-19 2000-04-18 Aptargroup, Inc. Dispensing structure incorporating a valve-containing fitment for mounting to a container and a package with a dispensing structure
TW507028B (en) * 1999-02-12 2002-10-21 Asahi Chemical Ind A moisture-absorbable synthetic fiber with an improved moisture-release property
JP2001098423A (ja) 1999-09-29 2001-04-10 Asahi Kasei Corp 高速吸湿性ポリウレタン系弾性繊維
US6994913B1 (en) 1999-09-30 2006-02-07 Sekisui Chemical Co., Ltd. Thermoplastic elastomer, use thereof, and process for producing the same
JP4487112B2 (ja) * 1999-12-03 2010-06-23 東レ・オペロンテックス株式会社 ポリウレタン弾性繊維およびその製造方法
US6639041B2 (en) * 1999-12-03 2003-10-28 Dupont-Toray Co. Ltd. Spandex having low set at low temperatures
JP4362803B2 (ja) * 1999-12-03 2009-11-11 オペロンテックス株式会社 ポリウレタン弾性繊維およびその製造方法
US6989432B2 (en) * 2002-01-10 2006-01-24 Invista North America S.A.R.L. Copolymers of tetrahydrofuran, ethylene oxide and an additional cyclic ether
JP4449011B2 (ja) 2002-06-04 2010-04-14 東レ・オペロンテックス株式会社 サニタリー用品
US6984708B2 (en) * 2002-10-04 2006-01-10 Invista North America S.A.R.L. Spandex of a particular composition and process for making same
JP2004131861A (ja) * 2002-10-09 2004-04-30 Du Pont Toray Co Ltd ポリウレタン弾性繊維の製造方法
EP1576228B1 (en) 2002-11-04 2011-08-10 INVISTA Technologies S.à.r.l. Articles treated with aqueous dispersions of poly(urea/urethanes)
US20060173151A1 (en) 2002-11-04 2006-08-03 Kim Young H Aqueous dispersions of polyureaurethanes
US7589149B2 (en) 2002-11-04 2009-09-15 Invista North America S.A R.L. Aqueous poly(urea/urethanes) dispersions using polyester glycol
AU2003286898A1 (en) 2002-11-04 2004-06-07 Invista Technologies S.A.R.L. Articles comprising aqueous dispersions using poly(urea/urethanes)
JP2004218096A (ja) 2003-01-09 2004-08-05 Du Pont Toray Co Ltd 伸縮性薄膜用品
JP2004215686A (ja) 2003-01-09 2004-08-05 Du Pont Toray Co Ltd 伸縮性薄膜用品
CN1326902C (zh) 2003-02-14 2007-07-18 陶氏环球技术公司 由基于mdi的异氰酸酯封端预聚物衍生得到的亲水性聚氨酯聚合物
KR101137663B1 (ko) 2003-02-20 2012-04-20 인비스타 테크놀러지스 에스.에이.알.엘 폴리(우레아/우레탄)의 수성 분산액을 포함하는 물품
US6916896B2 (en) * 2003-05-05 2005-07-12 Invista North America S.A.R.L. High productivity spandex fiber process and product
US20060276610A1 (en) * 2005-05-09 2006-12-07 Invista North America S.A R.L. Spandex from poly(tetramethylene-co-ethyleneether)glycols having high ethyleneether content
KR101322054B1 (ko) * 2005-05-09 2013-10-25 인비스타 테크놀러지스 에스.에이.알.엘. 고속 방사용 스판덱스 조성물
US20070117949A1 (en) * 2005-11-22 2007-05-24 Palmer Charles F Jr Spandex from poly(tetramethylene-co-ethyleneether) glycols having low ethyleneether content

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3425999A (en) * 1966-07-11 1969-02-04 Wyandotte Chemicals Corp Tetrahydrofuran-ethylene oxide polyether urethane-urea polymers
KR20020039359A (ko) * 1999-10-05 2002-05-25 메리 이. 보울러 장해 디이소시아네이트로 제조된 스판덱스

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101782726B1 (ko) 2016-04-11 2017-09-29 한양대학교 산학협력단 산화그래핀 방사 용액의 제조 방법, 및 이를 이용한 그래핀 섬유의 제조 방법
KR101782725B1 (ko) * 2016-04-11 2017-09-29 한양대학교 산학협력단 그래핀 섬유 및 그 제조 방법
WO2017179900A1 (ko) * 2016-04-11 2017-10-19 한양대학교 산학협력단 그래핀 섬유 및 그 제조 방법
US10995428B2 (en) 2016-04-11 2021-05-04 Iucf-Hyu (Industry-University Cooperation Foundation Hanyang University) Graphene fiber and method of manufacturing the same
US11649566B2 (en) 2016-04-11 2023-05-16 Iucf-Hyu (Industry-University Cooperation Foundation Hanyang University) Graphene fiber and method of manufacturing the same
KR20180021360A (ko) * 2016-08-19 2018-03-02 한양대학교 산학협력단 그래핀 섬유 복합체 및 그 제조 방법
KR102660907B1 (ko) 2016-08-19 2024-04-26 한양대학교 산학협력단 그래핀 섬유 복합체 및 그 제조 방법

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BRPI0620534A2 (pt) 2011-11-16
HK1207873A1 (en) 2016-02-12
CN104387545A (zh) 2015-03-04
JP2009516770A (ja) 2009-04-23
EP1951782A1 (en) 2008-08-06
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