KR101321217B1 - 제올라이트 촉매 및 방법 - Google Patents

제올라이트 촉매 및 방법 Download PDF

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Publication number
KR101321217B1
KR101321217B1 KR1020077029760A KR20077029760A KR101321217B1 KR 101321217 B1 KR101321217 B1 KR 101321217B1 KR 1020077029760 A KR1020077029760 A KR 1020077029760A KR 20077029760 A KR20077029760 A KR 20077029760A KR 101321217 B1 KR101321217 B1 KR 101321217B1
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ppm
zeolite
catalyst
phosphorus
zsm
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Expired - Fee Related
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Korean (ko)
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KR20080019012A (ko
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애쉼 쿠마르 고쉬
네에타 쿨카르니
파멜라 하비
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사우디 베이식 인더스트리즈 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/68—Catalytic processes with halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/05—Nuclear magnetic resonance [NMR]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020077029760A 2005-05-25 2006-05-24 제올라이트 촉매 및 방법 Expired - Fee Related KR101321217B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US11/136,877 US7399727B2 (en) 2004-04-23 2005-05-25 Zeolite catalyst and method
US11/136,877 2005-05-25
PCT/US2006/020110 WO2006127827A2 (en) 2005-05-25 2006-05-24 Zeolite catalyst and method

Publications (2)

Publication Number Publication Date
KR20080019012A KR20080019012A (ko) 2008-02-29
KR101321217B1 true KR101321217B1 (ko) 2013-10-23

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KR1020077029760A Expired - Fee Related KR101321217B1 (ko) 2005-05-25 2006-05-24 제올라이트 촉매 및 방법

Country Status (6)

Country Link
US (1) US7399727B2 (https=)
EP (1) EP1893530A4 (https=)
JP (1) JP5107906B2 (https=)
KR (1) KR101321217B1 (https=)
CN (1) CN101180239B (https=)
WO (1) WO2006127827A2 (https=)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7304194B2 (en) 2005-05-05 2007-12-04 Saudi Basic Industries Corporation Hydrothermal treatment of phosphorus-modified zeolite catalysts
US7368410B2 (en) * 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
US7662737B2 (en) * 2005-12-22 2010-02-16 Saudi Basic Industries Corporation Bound phosphorus-modified zeolite catalyst, method of preparing and method of using thereof
US8115041B2 (en) * 2008-04-02 2012-02-14 Saudi Basic Industries Corporation Pretreatment of a phosphorus-modified zeolite catalyst for an aromatic alkylation process
US8846559B2 (en) * 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
US8062987B2 (en) 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
AU2010306940A1 (en) 2009-10-12 2012-06-07 Smith, Larry Methods and compositions for modulating gene expression using oligonucleotide based drugs administered in vivo or in vitro
DE102011013908A1 (de) 2011-03-15 2012-09-20 Süd-Chemie AG Modifizierter Katalysator zur Umwandlung von Oxygenaten zu Olefinen
CN104114277B (zh) 2011-10-17 2017-02-15 埃克森美孚研究工程公司 磷改性沸石催化剂
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
WO2014120422A1 (en) 2013-01-31 2014-08-07 Exxonmobile Chemical Patents, Inc. Production of para-xylene
US8969643B2 (en) 2013-05-23 2015-03-03 Saudi Basic Industries Corporation Method for conversion of aromatic hydrocarbons
US9783462B2 (en) 2013-09-10 2017-10-10 Saudi Basic Industries Corporation Toluene methylation with transalkylation of heavy aromatics
US9364815B2 (en) 2013-11-07 2016-06-14 Saudi Basic Industries Corporation Method of preparing an alumina catalyst support and catalyst for dehydrogenation reactions, and its use
US10532962B2 (en) 2016-02-02 2020-01-14 Sabic Global Technologies B.V. Conversion of shale gas to aromatics
GB201615626D0 (en) * 2016-09-14 2016-10-26 Johnson Matthey Plc Alkylation process
CN113526519B (zh) * 2020-04-13 2023-01-13 中国石油化工股份有限公司 含磷的多级孔zsm-5分子筛及其制备方法
TWI894256B (zh) * 2020-04-13 2025-08-21 大陸商中國石油化工科技開發有限公司 含磷的/磷改性的zsm-5分子篩、含其的裂解助劑和裂解催化劑及其製備方法和用途
CN119857520A (zh) * 2023-10-19 2025-04-22 中国石油化工股份有限公司 一种芳烃烷基化催化剂及其制备方法和应用

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5951963A (en) 1997-03-24 1999-09-14 China Petrochemical Corporation Phosphorous containing zeolite having MFI type structure
US20050070749A1 (en) 2003-09-30 2005-03-31 Ghosh Ashim Kumar Toluene methylation process

Family Cites Families (163)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3702886A (en) 1969-10-10 1972-11-14 Mobil Oil Corp Crystalline zeolite zsm-5 and method of preparing the same
US3962364A (en) * 1975-03-28 1976-06-08 Mobil Oil Corporation Alkylation in presence of phosphorus-modified crystalline luminosilicate catalyst
US3965207A (en) 1975-01-06 1976-06-22 Mobil Oil Corporation Selective production of para-xylene
US4049573A (en) * 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
US4115424A (en) 1976-12-22 1978-09-19 Monsanto Company Zeolite catalyst
US4250345A (en) 1978-01-10 1981-02-10 Mobil Oil Corporation Selective production of para-xylene
US4152364A (en) 1978-01-19 1979-05-01 Mobil Oil Corporation Selective production of para-xylene
US4444989A (en) * 1979-04-20 1984-04-24 E. I. Du Pont De Nemours And Company Methylation of toluene to para-xylene catalyzed by crystalline silica
US4278827A (en) 1980-04-07 1981-07-14 Mobil Oil Corporation Shape selective reactions with zeolite catalyst modified with group IVB metal
DE3169731D1 (en) 1980-11-04 1985-05-09 Teijin Petrochem Ind A catalyst composition containing as catalytically active components alumina and a cristalline aluminosilicate zeolite, a process for isomerizing xylenes and ethylbenzene, and use of this catalyst composition
US4704495A (en) 1980-12-29 1987-11-03 Mobil Oil Corporation Catalytic conversions using shape selective metallic catalysts
US4554394A (en) 1982-03-18 1985-11-19 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
US4409132A (en) 1982-03-18 1983-10-11 Mobil Oil Corporation Organophosphorus-treated zeolite catalysts for para-selective aromatics conversion
US4902406A (en) 1982-04-30 1990-02-20 Mobil Oil Corporation Synthesis of zeolite ZSM-22
US5254767A (en) 1982-04-30 1993-10-19 Mobil Oil Corp. Highly siliceous porous crystalline material and its use in conversion of oxygenates
US5248841A (en) 1982-04-30 1993-09-28 Mobil Oil Corporation Hydrocarbon conversion with ZSM-22 zeolite
US5336478A (en) 1982-04-30 1994-08-09 Mobil Oil Corp. Highly siliceous porous crystalline material
US5254770A (en) 1982-09-01 1993-10-19 Mobil Oil Corp. Isomerization of aromatic compounds over ZSM-22 zeolite
US4973781A (en) 1982-11-17 1990-11-27 Mobil Oil Corporation Zeolite ZSM-57 and catalysis therewith
US4914067A (en) 1983-05-02 1990-04-03 Uop Catalytic cracking catalysts and cracking process using mixed catalyst system
US4548914A (en) 1983-08-26 1985-10-22 Mobil Oil Corporation Zeolite catalysts of improved activity and para-selectivity
US4891197A (en) 1983-12-19 1990-01-02 Mobil Oil Corporation Silicophosphoaluminates and related crystalline oxides
US4694114A (en) 1984-01-11 1987-09-15 Mobil Oil Corporation Process for isomerizing alkyl aromatic hydrocarbons utilizing ZSM-23 zeolite and a hydrogenation/dehydrogenation metal
US4623633A (en) 1984-01-17 1986-11-18 Union Oil Company Of California Shock calcined aluminosilicate zeolites
US4758328A (en) 1984-01-17 1988-07-19 Union Oil Company Of California Shock calcined aluminosilicate zeolites
US4716135A (en) 1984-04-09 1987-12-29 Mobil Oil Corporation Organophosphorus-modified zeolites and method of preparation
US4638106A (en) 1984-07-13 1987-01-20 Exxon Research & Engineering Co. Two stage process for improving the catalyst life of zeolites in the synthesis of lower olefins from alcohols and their ether derivatives
US5047141A (en) 1984-07-16 1991-09-10 Mobil Oil Corporation Larger pore molecular sieves of controlled activity
US4912073A (en) 1984-07-16 1990-03-27 Mobil Oil Corp. Larger pore molecular sieves of controlled activity
US4873067A (en) 1984-08-21 1989-10-10 Mobil Oil Corporation Zeolite ZSM-57
IL73146A (en) 1984-10-02 1988-11-15 Yeda Res & Dev Catalysts and process for the production of hydrocarbons and substitution of hydrocarbons
US4891467A (en) 1984-10-15 1990-01-02 Amoco Corporation Selective synthesis of pseudocumene and durene
US4721827A (en) 1985-02-20 1988-01-26 Aristech Chemical Corportion Crystalline magnesia-silica composites and process for producing same
US4623530A (en) 1985-02-20 1986-11-18 United States Steel Corporation Crystalline magnesia-silica composites and process for producing same
JPS61221137A (ja) * 1985-03-28 1986-10-01 Teijin Yuka Kk Ｐ−キシレンの製造法
US4727209A (en) 1985-06-11 1988-02-23 Uop Inc. Hydrocarbon alkylation processes employing a phosphorus-modified alumina composite
US4665251A (en) 1985-06-12 1987-05-12 Mobil Oil Corporation Aromatization reactions with zeolites containing phosphorus oxide
US4590321A (en) 1985-06-12 1986-05-20 Mobil Oil Corporation Aromatization reactions with zeolites containing phosphorus oxide
US4670616A (en) 1985-11-25 1987-06-02 Amoco Corporation AMS-1B crystalline borosilicate molecular sieve-based catalyst compositions and process for toluene methylation
US4673767A (en) 1985-11-25 1987-06-16 Amoco Corporation AMS-1B crystalline borosilicate molecular sieve-based catalyst compositions and process for toluene alkylation
US4695666A (en) 1985-12-09 1987-09-22 Uop Inc. Phosphorus-containing alumina catalyst for the isomerization of aromatics
US4746763A (en) 1987-04-22 1988-05-24 Uop Inc. Process for producing aromatic compounds from C2 -C6 aliphatic hydrocarbons
US4761513A (en) 1987-07-01 1988-08-02 Uop Inc. Temperature control for aromatic alkylation process
FR2623423B1 (fr) 1987-11-23 1990-03-30 Centre Nat Rech Scient Nouveaux catalyseurs a base de zeolithes modifiees par des elements alcalins sous forme metallique, leur preparation et leur application a l'alkylation des derives alkyl-aromatiques
US4935574A (en) 1988-03-29 1990-06-19 E. I. Du Pont De Nemours And Company Preparation of para-xylene by toluene methylation
FR2629444B1 (fr) 1988-04-01 1990-12-07 Rhone Poulenc Chimie Zeolites a base de silice et d'oxyde de germanium et procede de synthese de celles-ci
US4891930A (en) * 1988-04-04 1990-01-09 Schaefer Alan W Apparatus and process for applying a cover, to a round hay bale
US4847223A (en) 1988-04-08 1989-07-11 Concordia University Superacidic catalysts for low temperature conversion of aqueous ethanol to ethylene
US4861930A (en) 1988-09-28 1989-08-29 Uop Combination process for the conversion of a C2 -C6 aliphatic hydrocarbon
GB8829923D0 (en) 1988-12-22 1989-02-15 Ici Plc Zeolites
US5178748A (en) 1988-12-22 1993-01-12 Imperial Chemical Industries Catalytic reactions using zeolites
US5233102A (en) 1989-08-02 1993-08-03 E. I. Du Pont De Nemours And Company Olefin hydration
US5094995A (en) 1989-08-02 1992-03-10 E. I. Du Pont De Nemours And Company Supported perfluorinated ion-exchange polymers
US5124299A (en) 1989-08-02 1992-06-23 E. I. Du Pont De Nemours And Company Catalysis using blends of perfluorinated ion-exchange polymers with perfluorinated diluents
US5105047A (en) 1989-08-02 1992-04-14 E. I. Du Pont De Nemours And Company Catalysis using blends of perfluorinated ion-exchange polymers with perfluorinated diluents
US5043502A (en) 1990-03-16 1991-08-27 Uop Production of xylenes from light aliphatic hydrocarbons via dehydrocyclodimerization and methylation
US5173461A (en) 1990-03-21 1992-12-22 Mobil Oil Corporation Toluene disproportionation catalyst
US5534239A (en) 1990-03-23 1996-07-09 Societe Nationale Elf Aquitaine Process for the synthesis of a silica enriched crystalline aluminosilicate having the offretite structure, the aluminosilicate obtained and its use as a catalyst for the conversion of hydrocarbons
GB9013859D0 (en) 1990-06-21 1990-08-15 Ici Plc Zeolites
GB9013916D0 (en) 1990-06-22 1990-08-15 Ici Plc Zeolites
EP0466545A1 (fr) 1990-06-29 1992-01-15 Rhone-Poulenc Chimie Zéolithes à base de silice et d'oxydes d'éléments tétravalents, leur procédé de synthèse et leur application
JPH06340416A (ja) 1990-08-29 1994-12-13 Rhone Poulenc Chim シリカ及び場合によっては四価元素の酸化物を基材とするゼオライトの製造法
US5366948A (en) 1991-03-12 1994-11-22 Mobil Oil Corp. Catalyst and catalytic conversion therewith
US5456821A (en) 1991-03-12 1995-10-10 Mobil Oil Corp. Catalytic conversion with improved catalyst
US5110776A (en) 1991-03-12 1992-05-05 Mobil Oil Corp. Cracking catalysts containing phosphate treated zeolites, and method of preparing the same
US5348643A (en) 1991-03-12 1994-09-20 Mobil Oil Corp. Catalytic conversion with improved catalyst
US5231064A (en) 1991-03-12 1993-07-27 Mobil Oil Corp. Cracking catalysts comprising phosphorus and method of preparing and using the same
US5171921A (en) 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
US5387732A (en) 1991-10-15 1995-02-07 Fina Technology, Inc. Start-up process for improved selectivity in toluene disproportionation
US5210356A (en) 1991-12-16 1993-05-11 Fina Technology, Inc. Toluene disproportionation employing modified omega zeolite catalyst
US5227558A (en) 1992-02-10 1993-07-13 Fina Technology, Inc. Aromatic alkylation process employing steam modified zeolite beta catalyst
US5475179A (en) 1992-03-12 1995-12-12 Mobil Oil Regioselective production of para-dialkyl benzenes
US5321183A (en) 1992-03-12 1994-06-14 Mobil Oil Corp. Process for the regioselective conversion of aromatics to para-disubstituted benzenes
US5516736A (en) 1992-03-12 1996-05-14 Mobil Oil Corp. Selectivating zeolites with organosiliceous agents
US5571768A (en) 1992-03-12 1996-11-05 Mobil Oil Corporation Zeolite functionalized with organosiliceous groups
US5498814A (en) 1992-03-12 1996-03-12 Mobil Oil Corp. Regioselective methylation of toluene to para-xylene
EP0568913A3 (en) 1992-05-03 1995-03-22 Dalian Chemical Physics Inst Process for the conversion of methanol to light olefins and catalysts used therefor.
US5318696A (en) 1992-12-11 1994-06-07 Mobil Oil Corporation Catalytic conversion with improved catalyst catalytic cracking with a catalyst comprising a large-pore molecular sieve component and a ZSM-5 component
US5294578A (en) 1992-12-23 1994-03-15 Mobil Oil Corp. Supported acid catalysts, their preparation and use in organic compound conversion
US5336824A (en) 1993-01-29 1994-08-09 Fina Technology, Inc. Mordenite catalysts in toluene synthesis
US5365003A (en) 1993-02-25 1994-11-15 Mobil Oil Corp. Shape selective conversion of hydrocarbons over extrusion-modified molecular sieve
US5349113A (en) 1993-02-25 1994-09-20 Mobil Oil Corp. Shape selective hydrocarbon conversion over pre-selectivated, activated catalyst
CN1034223C (zh) 1993-03-29 1997-03-12 中国石油化工总公司 制取低碳烯烃的裂解催化剂
US5378670A (en) 1993-04-16 1995-01-03 W. R. Grace & Co.-Conn. Phosphorus zeolites/molecular sieves
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US5430213A (en) 1993-05-06 1995-07-04 Exxon Chemical Patents Inc. Process for producing 1,4-dienes
US5476823A (en) 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
US5698756A (en) 1993-05-28 1997-12-16 Mobil Oil Corporation Toluene alkylation with ethylene to produce para-ethyloluene
US5523510A (en) 1993-08-30 1996-06-04 Texaco Inc. Treated bound ferrierite zeolites for skeletal isomerization of n-olefins to iso-olefins
US5563310A (en) 1993-09-14 1996-10-08 Mobil Oil Corporation Toluene alkylation with methanol
CA2169963C (en) 1993-10-18 2005-07-05 Ernest W. Valyocsik Synthetic porous crystalline mcm-58, its synthesis and use
EP0655277A1 (en) 1993-11-01 1995-05-31 Csir Amorphous aluminosilicate catalyst
US5457078A (en) 1993-11-29 1995-10-10 Mobil Oil Corporation Manufacture of improved zeolite Beta catalyst
EP0752916B1 (en) 1994-03-31 1999-12-08 Infineum USA L.P. Polymerisation reactions with supported lewis acid catalysts
US5561095A (en) 1994-03-31 1996-10-01 Exxon Chemical Patents Inc. Supported lewis acid catalysts for hydrocarbon conversion reactions
WO1995026814A1 (en) 1994-03-31 1995-10-12 Exxon Chemical Patents Inc. Supported lewis acid catalysts derived from superacids useful for hydrocarbon conversion reactions
US5576256A (en) 1994-05-23 1996-11-19 Intevep, S.A. Hydroprocessing scheme for production of premium isomerized light gasoline
US5689024A (en) 1994-06-03 1997-11-18 Mobil Oil Corporation Use of crystalline SUZ-9
US5939597A (en) 1994-11-10 1999-08-17 Mobil Oil Corporation Fluid bed process for para-xylene production
US5646314A (en) 1994-11-16 1997-07-08 Arco Chemical Technology, L.P. Process for titanium silicalite-catalyzed epoxidation
US5573746A (en) 1995-06-06 1996-11-12 Mobil Oil Corporation Zeolite synthesis with amino acid directing agents
US6060633A (en) 1995-10-20 2000-05-09 Chen; Frank Joung-Yei Supported Lewis acid catalysts derived from superacids useful for hydrocarbon conversion reactions
US5811613A (en) 1996-04-05 1998-09-22 Indian Petrochemicals Corporation Limited Process for the production of para-diethylbenzene
CA2204461C (en) 1996-05-14 2006-07-04 Thomas V. Harris Process for producing an alkylated, non-oxygen-containing aromatic hydrocarbon
EA002376B1 (ru) 1996-05-29 2002-04-25 Эксон Кемикэл Пейтентс Инк. Способ получения параксилола
ZA978671B (en) * 1996-10-02 1999-03-26 Mobil Oil Corp Selective para-xylene production by toluene methylation
US6048816A (en) 1996-10-02 2000-04-11 Mobil Oil Corporation Catalyst and process for converting methanol to hydrocarbons
EP0951443B1 (en) 1996-10-17 2002-09-04 ExxonMobil Chemical Patents Inc. Hydrocarbon conversion using large crystal zeolite catalyst
US5990031A (en) 1996-11-26 1999-11-23 Fina Technology, Inc. Zeolite catalyst with enhanced dealkylation activity and method for producing same
EP0888817B1 (en) 1996-11-27 2004-11-10 Idemitsu Kosan Co., Ltd. Process for producing a catalyst for cleaning exhaust gas
DE19653042A1 (de) 1996-12-19 1998-06-25 Basf Ag Flammgeschützte Formmassen
US5925586A (en) 1996-12-31 1999-07-20 Exxon Chemical Patents, Inc. Phosphorus modified small pore molecular sieve catalysts, and their use in the production of light olefins
US5847255A (en) 1997-05-21 1998-12-08 Fina Technology, Inc. Gas phase alkylation-liquid phase transalkylation process
US5905051A (en) 1997-06-04 1999-05-18 Wu; An-Hsiang Hydrotreating catalyst composition and processes therefor and therewith
US5898089A (en) 1997-07-09 1999-04-27 Phillips Petroleum Company Hydrocarbon aromatization process using a zeolite
US6034283A (en) 1997-07-18 2000-03-07 Asahi Kasei Kogyo Kabushiki Kaisha Process for production of cyclic alcohols
US6047544A (en) 1997-08-20 2000-04-11 Nissan Motor Co., Ltd. Engine exhaust gas purification catalyst and exhaust gas purifier
EP0903178B2 (en) 1997-09-17 2012-05-30 China Petro-Chemical Corporation A pentasil-type molecular sieve containing composition, its preparation method and use
US6423879B1 (en) 1997-10-02 2002-07-23 Exxonmobil Oil Corporation Selective para-xylene production by toluene methylation
JP3927704B2 (ja) 1997-10-15 2007-06-13 中国石油化工集団公司 軽質オレフィンの生産のための接触式熱分解プロセスのための触媒およびその調製
US6040257A (en) 1997-11-07 2000-03-21 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6504074B2 (en) 1997-12-03 2003-01-07 Exxonmobil Chemical Patents Inc. Toluene disproportionation using coated zeolite catalyst
ES2174520T3 (es) 1997-12-03 2002-11-01 Exxonmobil Chem Patents Inc Preparacion de zeolita aglutinada por una zeolieta de tipo de estructura mfi y su uso..
CN1069682C (zh) 1997-12-23 2001-08-15 中国石油化工总公司 重油催化热裂解层柱粘土催化剂及其制备
US6395664B1 (en) 1998-02-19 2002-05-28 Uop Llc Process for reactivating a deactivated dehydrocyclodimerization catalyst with water
US5907073A (en) 1998-02-24 1999-05-25 Fina Technology, Inc. Aromatic alkylation process
US6074975A (en) 1998-03-03 2000-06-13 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6417421B1 (en) 1998-03-03 2002-07-09 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and process therefor and therewith
US6080303A (en) 1998-03-11 2000-06-27 Exxon Chemical Patents, Inc. Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus
US5955641A (en) 1998-03-16 1999-09-21 Chevron Chemical Company Llc Method of making dimethylnaphthalenes
US6303534B1 (en) 1998-05-26 2001-10-16 Exxonmobil Chemical Patents Inc. Silicoaluminophosphates having an AEL structure, and their preparation
US6100437A (en) 1998-07-10 2000-08-08 Albemarle Corporation Alkylation process of alkyl-benzene with olefin using a sodium-and-potassium catalyst
US6124227A (en) 1998-08-28 2000-09-26 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
AU6271299A (en) 1998-09-28 2000-04-17 Bp Amoco Corporation Process for manufacturing olefins using a pentasil zeolite based catalyst
JP3868128B2 (ja) 1998-10-05 2007-01-17 新日本石油株式会社 軽油の水素化脱硫装置及び方法
US6642426B1 (en) 1998-10-05 2003-11-04 David L. Johnson Fluid-bed aromatics alkylation with staged injection of alkylating agents
JP3871449B2 (ja) 1998-10-05 2007-01-24 新日本石油株式会社 軽油の水素化脱硫方法
CN1096296C (zh) 1998-11-13 2002-12-18 中国石油化工集团公司 一种生产中间馏分油的加氢裂化催化剂及其制备
US6057485A (en) 1998-11-17 2000-05-02 Fina Technology, Inc. Gas phase alkylation with split load of catalyst
US6156949A (en) 1998-12-28 2000-12-05 Mobil Oil Corporation Selective pseudocumene production by xylene methylation
US6090274A (en) 1998-12-29 2000-07-18 Phillips Petroleum Company Hydrotreating catalyst composition and processes therefor and therewith
US6090991A (en) 1999-02-27 2000-07-18 Fina Technology, Inc. Gas phase alkylation method and catalyst
US6268305B1 (en) 1999-02-27 2001-07-31 Fina Technology, Inc. Catalysts with low concentration of weak acid sites
US6222084B1 (en) 1999-04-09 2001-04-24 Fina Technology, Inc. Gas phase alkylation-liquid phase transalkylation process
US6699811B1 (en) 1999-05-05 2004-03-02 Exxon Mobil Chemical Patents Inc. Tailored zeolite bound zeolite catalyst and its use for hydrocarbon conversion
US6388156B1 (en) 1999-05-14 2002-05-14 Exxonmobil Chemical Patents Inc. Direct selective synthesis of para-xylene by reacting an aromatic compound with a methylating agent formed from CO, Co2 and H2
US6459006B1 (en) 1999-05-14 2002-10-01 Exxonmobil Chemical Patents Inc. Selective methylation to para-xylene using fuel syngas
US6613708B1 (en) 1999-06-07 2003-09-02 Exxonmobil Chemical Patents Inc. Catalyst selectivation
MXPA01011828A (es) 1999-05-20 2004-12-06 Exxon Chemical Patents Inc Proceso de conversion de hidrocarburos y catalizador util en el mismo.
JP3489049B2 (ja) 1999-07-15 2004-01-19 日産自動車株式会社 排気ガス浄化用触媒
JP3859940B2 (ja) 1999-08-06 2006-12-20 日産自動車株式会社 排気ガス浄化用触媒及びその製造方法
US6613951B1 (en) 1999-09-23 2003-09-02 Mobil Oil Corporation Process for converting methanol to olefins
US6187982B1 (en) 1999-10-15 2001-02-13 Mobil Oil Corporation Process for converting dienes and oxygenates to para-xylene and light olefins
US6726834B2 (en) 1999-10-22 2004-04-27 Intevep, S.A. Process for catalytic cracking of a hydrocarbon feed with a MFI aluminisilcate composition
EP1116775A1 (en) 2000-01-12 2001-07-18 Akzo Nobel N.V. Catalyst composition with high efficiency for the production of light olefins
US6773694B1 (en) 1999-12-22 2004-08-10 Uop Llc Process for synthesizing molecular sieves
JP3489048B2 (ja) 2000-02-01 2004-01-19 日産自動車株式会社 排気ガス浄化用触媒
US6506954B1 (en) 2000-04-11 2003-01-14 Exxon Mobil Chemical Patents, Inc. Process for producing chemicals from oxygenate
JP3904802B2 (ja) 2000-04-26 2007-04-11 日産自動車株式会社 排気ガス浄化用触媒及びその製造方法
US6799089B2 (en) 2000-06-09 2004-09-28 Institut Francais Du Petrole Design of new materials whose use produces a chemical bond with a descriptor of said bond
EP1166856B1 (en) 2000-06-28 2006-08-16 ICT Co., Ltd. Exhaust gas purifying catalyst
TWI240716B (en) 2000-07-10 2005-10-01 Bp Corp North America Inc Pressure swing adsorption process for separating paraxylene and ethylbenzene from mixed C8 aromatics
US7285511B2 (en) * 2004-04-23 2007-10-23 Saudi Basic Industries Corporation Method of modifying zeolite catalyst

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5951963A (en) 1997-03-24 1999-09-14 China Petrochemical Corporation Phosphorous containing zeolite having MFI type structure
US20050070749A1 (en) 2003-09-30 2005-03-31 Ghosh Ashim Kumar Toluene methylation process

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