KR101191376B1 - Environmentally friendly method for manufacturing buoys - Google Patents

Environmentally friendly method for manufacturing buoys Download PDF

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KR101191376B1
KR101191376B1 KR1020120052077A KR20120052077A KR101191376B1 KR 101191376 B1 KR101191376 B1 KR 101191376B1 KR 1020120052077 A KR1020120052077 A KR 1020120052077A KR 20120052077 A KR20120052077 A KR 20120052077A KR 101191376 B1 KR101191376 B1 KR 101191376B1
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South Korea
Prior art keywords
buoy
mold
film
projection
molded
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KR1020120052077A
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Korean (ko)
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김고명
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김고명
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0053Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/10Forming by pressure difference, e.g. vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/26Component parts, details or accessories; Auxiliary operations
    • B29C51/266Auxiliary operations after the thermoforming operation
    • B29C51/268Cutting, rearranging and joining the cut parts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/40General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
    • B29C66/41Joining substantially flat articles ; Making flat seams in tubular or hollow articles
    • B29C66/43Joining a relatively small portion of the surface of said articles
    • B29C66/436Joining sheets for making articles comprising cushioning or padding materials, the weld being performed through the cushioning material, e.g. car seats
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/91Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/914Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux
    • B29C66/9141Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the temperature
    • B29C66/91421Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux by controlling or regulating the temperature, the heat or the thermal flux by controlling or regulating the temperature of the joining tools
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/91Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/919Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/92Measuring or controlling the joining process by measuring or controlling the pressure, the force, the mechanical power or the displacement of the joining tools
    • B29C66/929Measuring or controlling the joining process by measuring or controlling the pressure, the force, the mechanical power or the displacement of the joining tools characterized by specific pressure, force, mechanical power or displacement values or ranges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/706Buoys

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Farming Of Fish And Shellfish (AREA)

Abstract

PURPOSE: An environment-friendly buoy manufacturing method is provided to reduce the corrosion of the buoy caused by sea wave, salt water, and sun light. CONSTITUTION: An environment-friendly buoy manufacturing method is formed by a two forming films(1-1) and a vacuum pipe. The forming films vacuum-molded in order to prevent the generation of bubbles on the buoy are located in a projection-formed lower mold(65). Minute holes are formed on the forming films by a projection-formed upper mold(55). The edges of the forming film comprising minute holes are arranged to be faced with each other and input to a forming frame. The forming frame is heated in 100 to 200°C and shrunken on and thermally fused on the buoy.

Description

친환경 부표의 제조방법. {Environmentally friendly method for manufacturing buoys}How to make eco-friendly buoys. {Environmentally friendly method for manufacturing buoys}

본 발명은 양식장, 어장표식, 그물표식 등 해상용 어로 표식과 선박의 안전 항해를 위한 항로표지용 부표 및 승선자의 안전을 위한 각종 구명용품을 포함하는 소재의 부력 및 완충성이 요구되는 각종 해상활동 용구인 친환경 부표의 제조방법에 관한 것이다. The present invention provides a variety of marine activities that require buoyancy and cushioning of materials including marine fishery markings such as aquaculture farms, fishery markings, net markings, buoys for safe navigation of ships, and various life preservers for the safety of the crew. The present invention relates to a method for manufacturing an environmentally friendly buoy.

부표란 또는 부구(浮具)라고도 하며, anchor buoy(닻 부표), bell buoy(타종 부표), can buoy(원통형 부표), lighted buoy(등불 부표), mooring buoy(계선 부표), nun buoy(마름모꼴 부표), spar buoy(원주 부표), life buoy(구명 부표) 등을 포함하는 각종양식장, 어장표식, 그물표식 등 해상용 어로 표식과 선박의 안전한 항해를 돕기 위하여 항로를 지시하거나 암초 침몰선 등 항해상의 위험물의 존재를 경고하기 위하여 설치되며, 해저와는 체인으로 연결되어 떠내려가지 않도록 되어 있다. 특히 야간용으로서 등화(燈火)를 설치하며 이를 등부표라고 한다.Also known as a buoy, or buoy, anchor buoy, bell buoy, can buoy, lighted buoy, mooring buoy, nun buoy Maritime fisheries such as buoys), spar buoys, life buoys, life buoys, etc. It is installed to warn of the presence of dangerous goods, and it is connected to the seabed by chains so that it does not float out. In particular, it installs lamps for night use.

또 어구(漁具)나 닻 등 물 속에 있는 물체의 위치를 나타내기 위해서도 사용된다. It is also used to indicate the location of objects in water, such as fishing gear and anchors.

한편, 부이 제조의 종래 기술로는 EVA, PVC 등의 합성수지원료를 발포제, 가교제 등을 포함하는 통상의 첨가원료와 혼합 및 상기 혼합원료를 판상의 성형체로 제조 및 상기 제조된 성형체를 분쇄하여 칩상태로 분쇄하며, 상기 분쇄칩을 제조하고자 하는 부이 형상의 몰드에 충진하고 가압, 가열하므로써 원하는 형상의 부이로 제조하는 제조방법과 합성수지발포비즈의 일종인 EPS발포비즈를 제조하고자 하는 부이 형상의 몰드에 충진 및 팽창 성형시키는 제조하는 방법을 통해서도 제조되고 있다. On the other hand, in the prior art of buoy manufacturing, a synthetic water support material such as EVA and PVC is mixed with a conventional additive raw material including a foaming agent, a crosslinking agent and the like, and the mixed raw material is prepared into a plate-shaped molded product and the manufactured molded product is pulverized to form a chip state. To a buoy-shaped mold to prepare the pulverized chip, and to pressurize and heat the buoy-shaped mold to produce EPS foam beads, which is a kind of synthetic resin foam beads. It is also manufactured through a manufacturing method of filling and expansion molding.

예를 들면, 국내공개특허공보 공개번호 제1020110053305 (20110520)호 및 공개번호 제1020110059913 (20110608)호에는 비즈타입의 합성수지발포비즈(beads type)를 팽창성형시키므로써 제조된 부이 및 상기 제조된 부이의 표면에 피복층을 추가로 구성시키므로써 제조된 부이가 공개되어 있고,  For example, Korean Laid-Open Patent Publication No. 1020110053305 (20110520) and Publication No. 1020110059913 (20110608) are buoys prepared by expanding the beads type synthetic resin beads (beads type) and the buoys prepared above Buoys prepared by further constructing a coating layer on the surface are disclosed,

동 공보 공개번호 제1020010076084 (20010811)호에는 내구성이 우수한 고밀도 폴리에틸렌, 폴리프로필렌, 폴리카보네이트, 폴리에틸렌테레프탈레이트, 폴리비닐클로라이드, 나일론 및 ABS 수지 중에서 선택된 수지를 압출성형하여 부자의 외부재를 제작한 다음, 부자의 내부를 폴리우레탄으로 발포 충전하거나 발포수지 폐기물로 충전함으로써 이중구조의 부자를 제작하여, 종래 단일 발포체를 사용한 경우에 비해 표면의 고밀도로 인한 어패류의 탈리가 용이하고 부력 및 내구성이 우수하여 장기간 사용할 수 있도록 개선된 이중구조 부자의 제조방법이 기재되어 있고,  Publication No. 1020010076084 (20010811) discloses a rich external material by extruding a resin selected from durable high density polyethylene, polypropylene, polycarbonate, polyethylene terephthalate, polyvinyl chloride, nylon and ABS resin. In order to make the rich of foam by filling the inside of the rich with polyurethane or filling with foamed resin waste, it is easy to detach the fish and shellfish due to the high density of the surface and excellent buoyancy and durability compared to the case of using a single foam. It describes a method for producing a dual structure rich to be used for a long time,

동 공보 공개번호 제1019980067833 (19981015)호에는 소정형상으로 주입 성형되고 대칭으로 상호 부착되는 복수개의 우레탄레진주형물(13)과; 상기 우레탄레진주형물(13)내에 배치되는 폐스치로폴 부구(11)와; 상기 상호 대칭되게 부착된 우레탄레진주형물(13)내에 충진되어 형성되는 발포성 우레탄원액층(12)으로 구성되는 것을 특징으로 하며, 수산양식용 부구의 제조방법에 있어서, 주형틀에 우레탄레진을 주입하여 우레탄레진주형물을 성형하는 단계(100)와; 상기 주입성형에 의해 제작된 복수개의 우레탄레진주형물 사이에 폐스치로폴 부구를 넣고 우레탄레진주형물의 맞닿음부를 정밀 부착하는 단계(101)와; 상기 상호 부착된 우레탄레진주형물에 형성된 발포성우레탄원액주입구를 통하여 발포성우레탄원액을 주입하여 발포성우레탄원액층을 성형하는 단계(102)로 구성되는 수산양식용 부구 및 그 제조방법이 공개되어 있고,
Publication No. 1019980067833 (19981015) includes a plurality of urethane resin moldings 13 that are injection molded in a predetermined shape and are symmetrically attached to each other; A waste spiropol sphere 11 disposed in the urethane resin mold 13; It is characterized in that it consists of a foamed urethane stock solution layer 12 is formed by filling in the urethane resin mold 13 attached symmetrically to each other, in the manufacturing method of the aquaculture aquaculture mould, injecting a urethane resin into the mold Forming a urethane resin mold (100); A step (101) of inserting a waste spiropol sphere between the plurality of urethane resin molds produced by the injection molding, and precisely attaching abutting portions of the urethane resin molds; Aquaculture culture parts and manufacturing method is disclosed, comprising the step (102) of forming a foamed urethane stock solution by injecting a foamed urethane stock solution through the foamed urethane stock solution inlet formed in the mutually attached urethane resin casting,

국내등록특허공보 등록번호 제1009855730000 (20100929)호에는 특성이 다양한 폐합성수지에 대한 선별을 따로 하지 않더라도 첨가제의 사용을 통한 물성을 회복시켜 폐고무와 혼합재질을 구성함으로써 이를 부표로 사용하여 물성이 높은 부표를 제공함과 동시에 폐자원의 재활용측면에서 매우 경제적이고 환경개선 효과를 갖는 폐고무와 폐합성수지의 혼합재질의 야광 부표가 기재되어 있으며,  In Korea Patent Publication No. 1009855730000 (20100929), even though it does not separate screening for the various synthetic resins, it is possible to recover the physical properties through the use of additives to form waste rubber and mixed materials and use them as buoys. It provides a buoy and a luminous buoy of a mixed material of waste rubber and synthetic resin, which is very economical and environmentally effective in terms of recycling waste resources.

동 공보 등록번호 제1010651160000 (20110907)호에는 EVA 수지 60~80중량%와, NBR 20~40중량%가 한 번의 발포로 최종적인 부자의 형태를 가진 본체가 통째로 형성된 양식장용 부자와; EVA 수지 60~80중량%와, NBR 20~40중량%를 혼합하여 형틀에 넣어 최종적인 부자의 형태를 가진 예비 성형물을 만드는 제1단계, 형틀을 가온하여 130~170℃가 되게 하고, 20~40분 동안 발포하는 제2단계를 포함하여 구성된 양식장용 부자의 제조방법이 공개되어 있고,  Korean Patent Publication No. 1010651160000 (20110907) discloses a fish farm rich with 60-80% by weight of EVA resin and 20-40% by weight of NBR having a whole body having a final rich form in one foaming; 60 to 80% by weight of EVA resin and 20 to 40% by weight of NBR are added to the mold to form a preform having a final rich form, the mold is heated to 130 to 170 ° C, and 20 to The manufacturing method of the rich for aquaculture including a second step of foaming for 40 minutes is disclosed,

국내등록실용신안공보 등록번호 제2002779650000 (20020529)호에는 나이론직물 다후다에 우레탄으로 방수 코팅한 직물을 스치로폴부(浮)표면에 도표하여 스치로폴부(浮)가 바다 염분이나 햇볕에 노출되지 못하게 하여 산화를 방지하고 또한 마찰 등에 파손이 잘 되지 않게 고안하면서 스치로폴이 파손되어 바다에 떠다니지 못하게 하는 동시에 상기 스치로폴부표의 수명을 연장할 수 있도록 고안된 어구로서 어망에 널리 사용하고 뜸 또는 부표에 관한 기술이 공개되어 있음을 알 수 있다.  In Korea Registered Utility Model Publication No. 2002779650000 (20020529), a urethane waterproofing fabric is coated on the surface of the Styropole to prevent the Schiropol from being exposed to sea salt or the sun. It is widely used in fishing nets and designed to prevent oxidation and to prevent damage to friction and to prevent the Schiropole from floating in the sea while extending the life of the Schiropole buoy. It can be seen that it is open to the public.

선행기술문헌Prior art literature

특허문헌Patent literature

1. 국내공개특허공보 공개번호 제1020110053305호 1. Domestic Publication No. 1020110053305

2. 국내공개특허공보 공개번호 제1020110059913호 2. Korean Patent Publication No. 1020110059913

3. 국내공개특허공보 공개번호 제1020010076084호  3. Korean Patent Publication No. 1020010076084

4. 국내공개특허공보 공개번호 제1019980067833호  4. Korean Patent Publication No. 1019980067833

5. 국내등록특허공보 등록번호 제100985573호  5. Korean Patent Registration Publication No. 100985573

6. 국내등록특허공보 등록번호 제101065116호  6. Korean Patent Registration Publication No. 101065116

7. 국내등록실용신안공보 등록번호 제2002779650000호 7. Registered Utility Model Registration No. 2002779650000 in Korea

종래의 EVA, PVC등을 원료로 사용하여 제조된 부이의 경우 복잡한 제조공정으로 인해 제조원가의 상이 초래되는 단점과In the case of buoy manufactured using conventional EVA, PVC, etc. as a raw material, the disadvantages of the manufacturing cost caused by the complicated manufacturing process

EPS를 제조 원료로 하여 제조된 부이의 경우 자외선에 쉽게 산화되며 내염성, 내약품성이 취약하여 취약한 내구성으로 비경제적이며 폐기물이 해양을 오염시키는 등의 단점이 본 발명이 해결하고자 하는 과제인 것이다.In the case of buoy manufactured by using EPS as a raw material, it is easily oxidized to ultraviolet rays, and is disadvantageous in that it is uneconomical with poor durability due to its weakness of flame resistance and chemical resistance, and waste contaminates the ocean.

상기와 같은 과제를 해결하기 위하여, 본 발명은

Figure 112012039244739-pat00001
형상의 폴리프로필렌재질의 성형필름을 두 개를 서로 마주보게 위치하여 내부에 폴리프로필렌으로 발포된 폴리프로필렌발포제품을 넣어 열융착 시켜 제조하며, 커버용 성형필름은 녹는점 및 연화점(SOFTNING POINT)과의 관계를 고려하여 온도는 변화가 가능하게 하여 제조하며, 커버용 성형필름의 성형시에도 필름의 두께 및 재질에 따라 성형이 가장 안정한 온도로 변화시켜 제조하는 친환경 부표의 제조방법을 제공하는 것이 본 발명이 이루고자 하는 과제 해결수단인 것이다.In order to solve the above problems, the present invention
Figure 112012039244739-pat00001
It is manufactured by heat-sealing polypropylene foamed products with polypropylene foam inside by placing two shaped polypropylene shaped films facing each other. The molded film for cover has a melting point and a softening point. In consideration of the relationship between the temperature is made to be possible to change, and even in the molding of the cover molding film to provide an environmentally friendly buoy manufacturing method to change the molding to the most stable temperature according to the film thickness and material. The invention is to solve the problem to be achieved.

본 발명은 본 발명은 폴리프로필렌폼으로 성형된 부표의 표면에 폴리프로필렌필름을 도포시킴으로서, 파도나, 염수, 태양광선등에 의해 부식되는 현상을 감소시켜 부표의 내후성, 내약품성, 내용제성 및 강도를 강화시킴과 동시에 해양오염방지에 이바지 하고, 사용 후 100% 재활용이 가능하며 폐기를 위한 소각시 유독가스를 발생시키지 않는 효과 등을 제공하는 경제적, 친환경적, 인체에 대한 안정성을 제공하는 효과가 있는 것이다. The present invention is to apply the polypropylene film to the surface of the buoy molded from polypropylene foam, thereby reducing the phenomenon of corrosion by waves, salt water, sunlight, etc. to improve the weather resistance, chemical resistance, solvent resistance and strength of the buoy. At the same time, it contributes to the prevention of marine pollution, is 100% recyclable after use, and provides economic, eco-friendly, and human safety, which provides the effect of not generating toxic gas when incinerated for disposal. .

도1 본 발명의 진공성형에 의한 친환경 부표 제조 공정도
도2 본 발명의 사출성형에 의한 친환경 부표 제조 공정도
1 is an environmentally friendly buoy manufacturing process diagram by vacuum molding of the present invention
Figure 2 eco-friendly buoy manufacturing process drawing by injection molding of the present invention

상기와 같은 목적을 달성하고자, 본 발명은

Figure 112012039244739-pat00002
형상의 폴리프로필렌재질의 성형필름을 두 개를 서로 마주보게 위치하여 내부에 폴리프로필렌으로 발포된 폴리프로필렌발포제품을 넣어 열융착 시켜 제조하며, 커버용 성형필름은 녹는점 및 연화점(SOFTNING POINT)과의 관계를 고려하여 온도는 변화가 가능하게 하여 제조하며, 커버용 성형필름의 성형시에도 필름의 두께 및 재질에 따라 성형이 가장 안정한 온도로 변화시켜 제조하는 친환경 부표의 제조방법에 관한 것이다. In order to achieve the above object, the present invention
Figure 112012039244739-pat00002
It is manufactured by heat-sealing polypropylene foamed products with polypropylene foam inside by placing two shaped polypropylene shaped films facing each other. The molded film for cover has a melting point and a softening point. In consideration of the relationship between the temperature is made to be possible to change, and when forming a cover molding film relates to a method of manufacturing an eco-friendly buoy to change the molding to the most stable temperature according to the film thickness and material.

본 발명에 사용 히는 필름은 폴리프로필렌필름을 사용하며, 필요에 따라 안료를 첨가하여 원하는 색상으로 할 수 있다.  As the film used in the present invention, a polypropylene film is used, and a pigment may be added to a desired color as necessary.

본 발명은 폴리프로필렌폼으로 성형된 부표의 표면에 폴리프로필렌필름을 도포시킴으로서, 파도나, 염수, 태양광선등에 의해 부식되는 현상을 감소시켜 해양오염방지에 이바지 하는 장점이 있는 것이다.The present invention is to apply a polypropylene film to the surface of the buoy formed of polypropylene foam, there is an advantage that contributes to the prevention of marine pollution by reducing the phenomenon of corrosion by waves, salt water, sunlight, and the like.

본 발명은 진공 성형에 의한 필름에 의한 부표 제조방법은 폴리프로필렌재질의 필름을 사이에 두고, 상부금형을 하부금형으로 하강시킴과 동시에 상하부금형의 진공흡입관에서 진공상태로 하여 필름을

Figure 112012039244739-pat00003
형상으로 40~120 ℃에서 진공 성형한 다음, According to the present invention, a method of manufacturing a buoy using a film by vacuum forming is made of a polypropylene film in between, and the upper mold is lowered to the lower mold and at the same time the film is vacuumed in the upper and lower mold vacuum suction tubes.
Figure 112012039244739-pat00003
Vacuum-molded at 40-120 ° C. into the shape,

상기와 같이 진공 성형된 두 개의 성형필름을 제조한 다음,  After the two molding films are vacuum formed as described above,

부표에 기포가 발생하지 않도록 성형필름의 하부에 구멍을 형성하되 미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, (구멍 개수는 많을수록 기포 발생이 적음) 구멍이 형성된 성형필름에 제조한 후에, Form a hole in the lower part of the molded film so that bubbles do not occur in the buoy, but make a small hole so that the molded film does not break during operation. (The more holes, the less bubbles are generated.)

성형필름이 부표와 맞도록 성형을 위한 성형틀을 만들되 수축률을 고려하여 성형틀은 부표보다 부피대비 1~10% 정도 적게 제작하고  Make a molding frame for molding so that the molding film matches the buoy, but in consideration of the shrinkage rate, make the mold about 1 ~ 10% less than the volume of the buoy.

상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름의 테두리가 맞닿게 대칭되게 한 후 내부에 부표를 내장 한 후, 상기 성형틀에 넣되,
As described above, the edges of the two molded films having fine holes formed thereon are symmetrically contacted with each other, and then embedded in a mold, and then embedded in the mold.

첫 번째, 가압방법으로   First, pressurization

성형틀을 오븐에 넣어 100~220℃로 가열 하면 성형필름이 부표 쪽으로 수축하여 부표와 붙도록 하고 컴퓨레샤로 0.5~2kgf/㎠의 압력으로 공기를 주입시켜, 부표에 밀착이 되도록 한다. 이때, 압력이 너무 높을 경우 성형틀이 비틀어 질수 있으므로 조심해야 한다.  When the mold is placed in an oven and heated to 100 ~ 220 ℃, the molded film shrinks toward the buoy and sticks to the buoy. The air is injected at a pressure of 0.5 ~ 2kgf / ㎠ with a compressor so as to be in close contact with the buoy. At this time, if the pressure is too high, the mold may be twisted, so be careful.

두 번째 방법으로, 필름이 부표의 외부를 완전히 감싸게 쌓은 후, 성형틀에 넣되, 먼저 측면테두리를 100~180℃의 온도로 가열하여 테두리를 열융착 시킨 다음, 테두리가 부착된 상태에서 성형틀을 오븐에 넣어 100~220℃로 가열 하면 성형필름이 부표 쪽으로 수축하여 부표에 밀착이 되도록 한다.   In the second method, the film is completely wrapped around the outside of the buoy, and then placed in a molding mold. First, the edges are heated to a temperature of 100 to 180 ° C. to heat-bond the edges, and then the mold is attached while the edge is attached. When placed in an oven and heated to 100 ~ 220 ℃, the molded film shrinks toward the buoy to be in close contact with the buoy.

다른 방법으로, 사출 성형에 의한 필름을 성형하는 방법으로서, Alternatively, as a method of molding a film by injection molding,

사출기를 이용하여 필름을

Figure 112012039244739-pat00004
형상으로 40~180 ℃에서 사출 성형한 다음, 상기와 같이 사출 성형된 두 개의 성형필름을 제조한 후에, 부표에 기포가 발생하지 않도록 성형필름의 하부에 구멍을 형성하되 미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, (구멍 개수는 많을수록 기포 발생이 적음) 구멍이 형성된 성형필름에 제조한 후에, The film using the injection machine
Figure 112012039244739-pat00004
After injection molding at a shape of 40 ~ 180 ℃, after manufacturing the two injection-molded film as described above, forming a hole in the lower part of the molded film so as not to generate bubbles in the buoy, but when forming a small hole when working The film is not broken (the larger the number of holes, the less bubbles are generated), and after manufacturing into the formed film with holes,

성형필름이 부표와 맞도록 성형을 위한 성형틀을 만들되 수축율을 고려하여 성형틀은 부표보다 부피대비 1~10% 정도 적게 제작하고,  Make a molding frame for molding so that the molding film is matched with the buoy, but in consideration of the shrinkage rate, the mold is made 1-10% less than the volume of the buoy.

상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름의 테두리가 맞닿게 대칭되게 한 후 내부에 부표를 내장 한 후, 상기 성형틀에 넣되,
As described above, the edges of the two molded films having fine holes formed thereon are symmetrically contacted with each other, and then embedded in a mold, and then embedded in the mold.

세 번째, 가압방법으로 성형틀을 오븐에 넣어 100~220℃로 가열 하면 성형필름이 부표 쪽으로 수축하여 부표와 붙도록 하고 컴퓨레샤로 0.5~2kgf/㎠의 압력으로 공기를 주입시켜, 부표에 밀착이 되도록 한다. 이때, 압력이 너무 높을 경우 성형틀이 비틀어 질수 있으므로 조심해야 한다.   Third, when the mold is put into the oven by heating method and heated to 100 ~ 220 ℃, the molding film shrinks toward the buoy and sticks to the buoy, and air is injected at a pressure of 0.5 ~ 2kgf / ㎠ with a compressor, so that it adheres to the buoy. To be At this time, if the pressure is too high, the mold may be twisted, so be careful.

네 번째 방법으로, 필름이 부표의 외부를 완전히 감싸게 쌓은 후, 성형틀에 넣되, 먼저 양 사이드(Side)를 100~180℃의 온도로 가열하여 테두리를 열융착 시킨 다음, 테두리가 부착된 상태에서 성형틀을 오븐에 넣어 100~220℃로 가열 하면 성형필름이 부표 쪽으로 수축하여 부표에 밀착이 되도록 한다.
In the fourth method, the film is completely wrapped around the outside of the buoy, and then placed in a molding mold. First, both sides are heated to a temperature of 100 to 180 ° C. to heat-bond the edge, and then the edge is attached. When the mold is put in an oven and heated to 100 ~ 220 ℃, the molding film shrinks toward the buoy to be in close contact with the buoy.

이하 본 발명을 실시예를 참고하여 설명하면 다음과 같다.
Hereinafter, the present invention will be described with reference to Examples.

실시예1Example 1

도1A 와 같이 폴리프로필렌재질의 필름(1)을 사이에 두고, 상부금형(50)을 하부금형(60)으로 하강시킴과 동시에 상하부금형(50,60)에 형성된 다수개의 상,하부금형진공흡입관(51,61)에서 진공펌프(미도시)와 연결된 진공파이프에 의해 진공상태로 하여 필름을

Figure 112012039244739-pat00005
형상으로 40~120 ℃에서 진공성형하여(도1B 참조), 진공성형된 두 개의 성형필름을 제조한 다음, A plurality of upper and lower mold vacuum suction pipes formed on the upper and lower molds 50 and 60 while lowering the upper mold 50 to the lower mold 60 with the polypropylene film 1 interposed therebetween as shown in FIG. 1A. At 51 and 61, the film is vacuumed by a vacuum pipe connected to a vacuum pump (not shown).
Figure 112012039244739-pat00005
Vacuum molding at a shape of 40 ~ 120 ℃ (see Figure 1B), to prepare a vacuum molded two molded film,

부표에 기포가 발생하지 않도록 진공성형된 성형필름을 중앙상부에 하부금형미세돌기(65-1)가 구비된 돌기성형하부금형(65)에 위치시킨 후에, After placing the molded film vacuum-formed to the buoy forming lower mold 65 with the lower mold micro-projection 65-1 in the upper center so that no bubbles are generated in the buoy,

중앙하부에 상부금형미세돌기(55-1)가 구비된 돌기형성상부금형(55)을 돌기형성하부금형(65)으로 하강시켜, 돌기형성하부금형(65)에 안치된 성형필름의 하부에 미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, (구멍 개수는 많을수록 기포 발생이 적음) 구멍이 형성된 성형필름(1-1)에 제조한 후에(도1C 참조),  Lowering the projection-forming upper mold 55 with the upper mold micro-projection 55-1 at the lower center to the projection-forming lower mold 65, the lower part of the molding film placed in the projection-forming lower mold 65 After the hole is formed, the molded film is not broken during operation (the larger the number of holes, the less bubbles are generated), and after the hole is formed in the molded film 1-1 (see Fig. 1C),

상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름(1-1)의 테두리가 맞닿게 대칭되게 한 후(도1D참조), 내부에 폴리프로필렌폼으로 성형된 부표(2)를 내장 한 후, 성형틀(미도시)에 넣고, 상기 성형틀을 오븐에 넣어 100~220℃로 가열 하면서(도1E 참조), 컴퓨레샤로 0.5~2kgf/㎠의 압력으로 공기를 주입시켜, 성형필름이 부표 쪽으로 수축하여 부표에 열융착시켜 친환경 부표(도1G 참조)를 제조하였다.
After the edges of the two molded films (1-1), which are formed with fine holes as described above, are asymmetrically contacted (see FIG. 1D), and then embedded therein the buoy 2 molded with polypropylene foam therein, Put the mold into the mold (not shown), and put the mold into the oven and heated to 100 ~ 220 ℃ (see Fig. 1E), the air is injected at a pressure of 0.5 ~ 2kgf / ㎠ with a compressor, the molding film is directed to the buoy By shrinking and heat-sealing the buoy to prepare an eco-friendly buoy (see Figure 1G).

실시예2Example 2

도1A 와 같이 폴리프로필렌재질의 필름(1)을 사이에 두고, 상부금형(50)을 하부금형(60)으로 하강시킴과 동시에 상하부금형(50,60)에 형성된 다수개의 상,하부금형진공흡입관(51,61)에서 진공펌프(미도시)와 연결된 진공파이프에 의해 진공상태로 하여 필름을

Figure 112012039244739-pat00006
형상으로 40~120 ℃에서 진공성형하여(도1B 참조), 진공성형된 두 개의 성형필름을 제조한 다음, A plurality of upper and lower mold vacuum suction pipes formed on the upper and lower molds 50 and 60 while lowering the upper mold 50 to the lower mold 60 with the polypropylene film 1 interposed therebetween as shown in FIG. 1A. At 51 and 61, the film is vacuumed by a vacuum pipe connected to a vacuum pump (not shown).
Figure 112012039244739-pat00006
Vacuum molding at a shape of 40 ~ 120 ℃ (see Figure 1B), to prepare a vacuum molded two molded film,

부표에 기포가 발생하지 않도록 진공성형된 성형필름을 중앙상부에 하부금형미세돌기(65-1)가 구비된 돌기성형하부금형(65)에 위치시킨 후에, After placing the molded film vacuum-formed to the buoy forming lower mold 65 with the lower mold micro-projection 65-1 in the upper center so that no bubbles are generated in the buoy,

중앙하부에 상부금형미세돌기(55-1)가 구비된 돌기형성상부금형(55)을 돌기형성하부금형(65)으로 하강시켜, 돌기형성하부금형(65)에 안치된 성형필름의 하부에 미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, (구멍 개수는 많을수록 기포 발생이 적음) 구멍이 형성된 성형필름(1-1)에 제조한 후에(도1C 참조),  Lowering the projection-forming upper mold 55 with the upper mold micro-projection 55-1 at the lower center to the projection-forming lower mold 65, the lower part of the molding film placed in the projection-forming lower mold 65 After the hole is formed, the molded film is not broken during operation (the larger the number of holes, the less bubbles are generated), and after the hole is formed in the molded film 1-1 (see Fig. 1C),

상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름(1-1)의 테두리가 맞닿게 대칭되게 한 후(도1D참조), 내부에 폴리프로필렌폼으로 성형된 부표(2)를 내장 한 후, 성형틀(미도시)에 넣되, 먼저 측면테두리를 100~180℃의 온도로 가열하여 테두리를 열융착 시킨 다음(도1F 참조), 테두리가 부착된 상태에서 성형틀을 오븐에 넣어 100~220℃로 가열하여 성형필름이 부표 쪽으로 수축하여 부표에 열융착 시켜 친환경 부표(도1G 참조)를 제조하였다.
After the edges of the two molded films (1-1), which are formed with fine holes as described above, are asymmetrically contacted (see FIG. 1D), and then embedded therein the buoy 2 molded with polypropylene foam therein, Put the mold in a mold (not shown), first heat the side border to a temperature of 100 ~ 180 ℃ to heat-sealed the edge (see Figure 1F), then put the mold in the oven with the edge attached 100 ~ 220 ℃ By heating with a molded film shrink to the buoy to heat-sealed to the buoy to prepare an eco-friendly buoy (see Figure 1G).

실시예3 Example 3

사출기(2A)를 이용하여

Figure 112012039244739-pat00007
형상의 성형필름으로 40~180 ℃에서 사출성형한 다음, 부표에 기포가 발생하지 않도록 사출성형된 성형필름을 중앙상부에 하부금형미세돌기(65-1)가 구비된 돌기성형하부금형(65)에 위치시킨 후에,By using the injection machine 2A
Figure 112012039244739-pat00007
After the injection molding at 40 ~ 180 ℃ with a shaped film of the shape, the projection molding lower mold (65) is provided with a lower mold micro-projection (65-1) in the upper center of the injection molded molded film so as not to generate bubbles in buoys After located in

중앙하부에 상부금형미세돌기(55-1)가 구비된 돌기형성상부금형(55)을 돌기형성하부금형(65)으로 하강시켜, 돌기형성하부금형(65)에 안치된 성형필름의 하부에   Lowering the projection-forming upper mold 55 with the upper mold micro-projection 55-1 at the lower center to the projection-forming lower mold 65, the lower portion of the formed film placed in the projection-forming lower mold 65

미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, (구멍 개수는 많을수록 기포 발생이 적음) 구멍이 형성된 성형필름(100)에 제조한 후에(도2C 참조), After forming a small hole so that the molded film is not broken during the operation (the more the number of holes, the less bubbles are generated) after manufacturing the molded film 100 formed with holes (see Fig. 2C),

상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름(100)의 테두리가 맞닿게 대칭되게 한 후(도2D참조), 내부에 폴리프로필렌폼으로 성형된 부표(2)를 내장 한 후, 성형틀(미도시)에 넣고, 상기 성형틀을 오븐에 넣어 100~220℃로 가열 하면서(도2E 참조), 컴퓨레샤로 0.5~2kgf/㎠의 압력으로 공기를 주입시켜, 성형필름이 부표 쪽으로 수축하여 부표에 열융착시켜 친환경 부표(도2G 참조)를 제조하였다.
After the edges of the two molded films 100 having fine holes formed as described above are symmetrically contacted (see FIG. 2D), the buoy 2 formed of polypropylene foam is embedded therein, and then (Not shown), the mold was placed in an oven and heated to 100-220 ° C. (see Fig. 2E), and the air was injected at a pressure of 0.5-2 kgf / cm 2 with a compressor, and the molded film contracted toward the buoy. Heat-sealing the buoy to prepare an eco-friendly buoy (see Figure 2G).

실시예4Example 4

사출기(2A)를 이용하여

Figure 112012039244739-pat00008
형상의 성형필름으로 40~180 ℃에서 사출성형한 다음, 부표에 기포가 발생하지 않도록 사출성형된 성형필름을 중앙상부에 하부금형미세돌기(65-1)가 구비된 돌기성형하부금형(65)에 위치시킨 후에,By using the injection machine 2A
Figure 112012039244739-pat00008
After the injection molding at 40 ~ 180 ℃ with a shaped film of the shape, the projection molding lower mold (65) is provided with a lower mold micro-projection (65-1) in the upper center of the injection molded molded film so as not to generate bubbles in buoys After located in

중앙하부에 상부금형미세돌기(55-1)가 구비된 돌기형성상부금형(55)을 돌기형성하부금형(65)으로 하강시켜, 돌기형성하부금형(65)에 안치된 성형필름의 하부에   Lowering the projection-forming upper mold 55 with the upper mold micro-projection 55-1 at the lower center to the projection-forming lower mold 65, the lower portion of the formed film placed in the projection-forming lower mold 65

미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, (구멍 개수는 많을수록 기포 발생이 적음) 구멍이 형성된 성형필름(100)에 제조한 후에(도2C참조), After forming a small hole so that the molded film is not broken during work (the more the number of holes, the less bubbles are generated) after manufacturing the formed film 100 formed holes (see Fig. 2C),

상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름(100)의 테두리가 맞닿게 대칭되게 한 후(도2D참조), 내부에 폴리프로필렌폼으로 성형된 부표(2)를 내장 한 후, 성형틀(미도시)에 넣되, 먼저 측면테두리를 100~180℃의 온도로 가열하여 테두리를 열융착시킨 다음(도2F참조), 테두리가 부착된 상태에서 성형틀을 오븐에 넣어 100~220℃로 가열하여 성형필름이 부표쪽으로 수축하여 부표에 열융착시켜 친환경 부표(도2G 참조)를 제조하였다.
After the edges of the two molded films 100 having fine holes formed as described above are symmetrically contacted (see FIG. 2D), the buoy 2 formed of polypropylene foam is embedded therein, and then (Not shown), but first, the side border is heated to a temperature of 100 ~ 180 ℃ to heat-sealed the rim (see Figure 2F), and then put the mold in the oven attached to the mold to heat to 100 ~ 220 ℃ Then, the molded film was shrunk toward the buoy, and thermally fused to the buoy to prepare an eco-friendly buoy (see FIG. 2G).

실험예Experimental Example

본 발명의 실시예1에 의해 제조된 부표의 물리적성질을 실험한 결과 다음과 같은 결과를 얻었다.  Experimental results of the physical properties of the buoy prepared by Example 1 of the present invention were obtained as follows.

Physical PropertiesPhysical properties UnitUnit TestTest GradeGrade 13.5 X13.5 X 15. X15.X 18. X18.X 30. X30.X 40. X40.X 45. X45.X Beads Bulk DensityBeads Bulk Density
(겉보기 밀도)(Apparent density)
g/Lg / L -- 5656 5050 4343 26.526.5 20.520.5 1717
Moulded Molded DensityDensity
(성형 밀도)(Molding density)
g/Lg / L -- 66.766.7 60.060.0 50.050.0 30.030.0 22.522.5 20.020.0
TensileTensile StrengthStrength
(( 인장강도The tensile strength ))
kgf/cmkgf / cm Thickness : 101 mm
50 mm/min
Thickness: 101 mm
50 mm / min
10.0010.00 9.009.00 7.007.00 4.594.59 3.443.44 3.083.08
EtongationEtongation BreakBreak
(( 신율Elongation ))
%% Thickness : 101 mm
50 mm/min
Thickness: 101 mm
50 mm / min
1010 1212 1515 2020 2323 2525
CompressiveCompressive StrengthStrength
(압축강도)(Compressive strength)
kgf/cmkgf / cm 20%
303030 mm, 50mm/min
20%
303030 mm, 50mm / min
5.005.00 4.004.00 3.003.00 1.731.73 1.121.12 1.001.00
50%
303030 mm, 50mm/min
50%
303030 mm, 50mm / min
6.006.00 5.005.00 4.004.00 2.062.06 1.601.60 1.491.49
HeatHeat SagSag
(( 열수화성Thermohydration ))
mmmm 340g, 80, Jh340g, 80, Jh 1One 2.52.5 44 77 88 99
BurningBurning BegaviorBegavior
(연소성)(combustibility)
mm/minmm / min 23,24h23,24h 4040 4545 5050 7070 -- --
80,168h80,168h 3737 4040 5555 7575 -- -- DimensionDimension StabilityStability
(수축성)(contractility)
%% 5050mm, 100,22h5050mm, 100,22h -- 0.39%0.39% -- 0.64%0.64% -- 0.98%0.98%

시 료 명 : EPP양식용부자(60L)Sample name: EPP aquaculture rich (60L) 시 험 결 과 Test result 시험항목Test Items 단위unit 시료구분Sample classification 결과치Results 시험방법Test Methods 겉모양Appearance -- -- 이상없음clear 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 치수(길이)Dimensions (length) mmmm -- 520520 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 치수(직경)Dimensions (diameter) mmmm -- 364364 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 중량weight gg -- 1272.01272.0 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 밀도density kg/mkg / m -- 2424 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 흡수량Absorption g/100cmg / 100cm -- 0.30.3 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 압축강도Compressive strength N/cmN / cm -- 9.19.1 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 부FUR시험FUR test NN -- 518518 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01)

본 발명의 실시예2에 의해 제조된 부표 ; EPP양식용부자(100L)Buoy prepared by Example 2 of the present invention; EPP aquaculture rich (100L) 시 험 결 과 Test result 시험항목Test Items 단위unit 시료구분Sample classification 결과치Results 시험방법Test Methods 겉모양Appearance -- -- 이상없음clear 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 치수(길이)Dimensions (length) mmmm -- 610610 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 치수(직경)Dimensions (diameter) mmmm -- 431431 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 중량weight gg -- 2220.72220.7 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 밀도density kg/mkg / m -- 2626 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 흡수량Absorption g/100cmg / 100cm -- 0.30.3 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 압축강도Compressive strength N/cmN / cm -- 9.39.3 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01) 부FUR시험FUR test NN -- 856856 품질보증검사기준(QM-3808-01)Quality Assurance Inspection Standard (QM-3808-01)

접수번호 : D215-11-00084Reception number: D215-11-00084

쪽 번 호 : 2 OF 2                                                      Page No.: 2 OF 2

본 발명의 실시예 1에 의해 제조된 부표의 실험 Experiment of Buoy Prepared by Example 1 of the Present Invention 성 분ingredient 함 량content 시 험 방 법Test Methods 검 출 한 계Detection limit 카드뮴 (Cd)Cadmium (Cd) 검출안됨Not detected USEPA 30508USEPA 30508 1 mg / kg1 mg / kg 납 (Pb)Lead (Pb) 검출안됨Not detected USEPA 3052USEPA 3052 수은 (Hg)Mercury (Hg) 검출안됨Not detected USEPA 3052USEPA 3052 크롬 VI (Cr VI)Chrome VI (Cr VI) 검출안됨Not detected USEPA 3060AUSEPA 3060A

주 ) NES M 0301에서 규정한 상기 원소에 대하여 각 항목별 시험방법으로 산/알칼리 분해한 후 Note) After decomposing acid / alkali by the test method for each item for the above element specified in NES M 0301

ICP-OES와 UV-VIS SPECTROMETER로 측정하였음.
Measured by ICP-OES and UV-VIS SPECTROMETER.

본 발명의 실시예1에 의해 제조된 부표의 실험 Experiment of buoy prepared by Example 1 of the present invention EPPEPP EPSEPS 항목Item 단위unit 15배15 times 30배30 times 18~33배18-33 times 밀도density g/lg / l 6060 3030 30~5530-55 7인열강도7 tear strength kg/kg / 5.75.7 2.22.2 압축강도Compressive strength kg/kg / 2.62.6 1.31.3 1.8 1.8 부력Buoyancy g/lg / l 950950 970970 흡수력absorptivity g/100g / 100 0.330.33 0.350.35 0.5 0.5 열전도율Thermal conductivity kcal/nhc(0) 0.035
kcal/nhc(20) 0.036
kcal / nhc (0) 0.035
kcal / nhc (20) 0.036
0.031
(비중 30 이상시)
0.031
(At least 30 weights)

본 발명의 실시예1에 의해 제조된 부표  Buoy prepared by Example 1 of the present invention 항목Item 압축강도Compressive strength 파손성Breakage 유연성flexibility 비약품성Non-pharmaceutical 내열성Heat resistance 동적완충
(1차)
Dynamic buffer
(Primary)
동적완충
(반복)
Dynamic buffer
(repeat)
EPPEPP 양호Good 양호Good 양호Good 매우양호Very good 매우양호Very good 양호Good 매우양호Very good EPSEPS 매우양호Very good 불량Bad 블랭Blank 보통usually 보통usually 양호Good 불량Bad EPEEPE 보통usually 양호Good 매우양호Very good 보통usually 보통usually 양호Good 매우양호Very good

필름(1), 성형필름(1-1, 100), 부표(2), 상부금형(50), 상,하부금형진공흡입관(51,61). 돌기성형상부금형(55), 상,하부금형미세돌기(55-1,65-1), 하부금형(60), 돌기성형하부금형(65),Film (1), molded film (1-1, 100), buoy (2), upper mold (50), upper and lower mold vacuum suction pipes (51, 61). Protrusion molding upper mold (55), upper and lower mold micro-projections (55-1, 65-1), lower mold (60), protrusion molding lower mold (65),

Claims (3)

친환경 부표의 제조방법에 있어서,
폴리프로필렌재질의 필름(1)을 사이에 두고, 상부금형(50)을 하부금형(60)으로 하강시킴과 동시에 상부금형(50)에 형성된 다수개의 상부금형진공흡입관(51)과, 하부금형(60)에 형성된 다수개의 하부금형진공흡입관(61) 에서 진공펌프와 연결된 진공파이프에 의해 진공상태로 하여 필름을
Figure 112012070044686-pat00009
형상으로 40~120 ℃에서 진공성형하여, 진공성형된 두 개의 성형필름을 제조한 다음,
부표에 기포가 발생하지 않도록 진공성형된 성형필름을 중앙상부에 하부금형미세돌기(65-1)가 구비된 돌기성형하부금형(65)에 위치시킨 후에,
중앙하부에 상부금형미세돌기(55-1)가 구비된 돌기형성상부금형(55)을 돌기형성하부금형(65)으로 하강시켜, 돌기형성하부금형(65)에 안치된 성형필름의 하부에 미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, 구멍이 형성된 성형필름(1-1)에 제조한 후에,
상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름(1-1)의 테두리가 맞닿게 대칭되게 한 후, 내부에 폴리프로필렌폼으로 성형된 부표(2)를 내장 한 후, 성형틀에 넣고, 상기 성형틀을 오븐에 넣어 100~220℃로 가열하면서 컴퓨레샤로 0.5~2kgf/㎠의 압력으로 공기를 주입시켜, 성형필름(1-1)이 부표쪽으로 수축하여 부표에 열융착시켜 제조함을 특징으로 하는 친환경 부표의 제조방법.
In the manufacturing method of an eco-friendly buoy,
A plurality of upper mold vacuum suction pipes 51 formed on the upper mold 50 while lowering the upper mold 50 to the lower mold 60 with the polypropylene film 1 interposed therebetween, and the lower mold ( The film is vacuumed by a vacuum pipe connected to a vacuum pump in a plurality of lower mold vacuum suction pipes 61 formed in the chamber 60) .
Figure 112012070044686-pat00009
Vacuum molding at a shape of 40 ~ 120 ℃, to produce a vacuum molded two molded film,
After placing the molded film vacuum-formed to the buoy forming lower mold 65 with the lower mold micro-projection 65-1 in the upper center so that no bubbles are generated in the buoy,
Lowering the projection-forming upper mold 55 with the upper mold micro-projection 55-1 at the lower center to the projection-forming lower mold 65, the lower part of the molding film placed in the projection-forming lower mold 65 After punching a hole so that the molded film is not broken during work, and manufactured on the molded film 1-1 with holes,
As described above, the edges of the two molded films 1-1 having the fine holes formed thereon are symmetrically contacted with each other, and thereafter, the buoy 2 formed of polypropylene foam is embedded therein, and then placed in a mold. The mold is placed in an oven and heated to 100 to 220 ° C. while injecting air at a pressure of 0.5 to 2 kgf / cm 2 into the compressor, and the molding film 1-1 shrinks toward the buoy to be manufactured by heat fusion to the buoy. Eco-friendly buoy manufacturing method characterized in that.
친환경 부표의 제조방법에 있어서,
폴리프로필렌재질의 필름(1)을 사이에 두고, 상부금형(50)을 하부금형(60)으로 하강시킴과 동시에 상부금형(50)에 형성된 다수개의 상부금형진공흡입관(51)과, 하부금형(60)에 형성된 다수개의 하부금형진공흡입관(61) 에서 진공펌프와 연결된 진공파이프에 의해 진공상태로 하여 필름을
Figure 112012070044686-pat00010
형상으로 40~120 ℃에서 진공성형하여, 진공성형된 두 개의 성형필름을 제조한 다음,
부표에 기포가 발생하지 않도록 진공성형된 성형필름을 중앙상부에 하부금형미세돌기(65-1)가 구비된 돌기성형하부금형(65)에 위치시킨 후에,
중앙하부에 상부금형미세돌기(55-1)가 구비된 돌기형성상부금형(55)을 돌기형성하부금형(65)으로 하강시켜, 돌기형성하부금형(65)에 안치된 성형필름의 하부에 미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, 구멍이 형성된 성형필름(1-1)에 제조한 후에,
상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름(1-1)의 테두리가 맞닿게 대칭되게 한 후, 내부에 폴리프로필렌폼으로 성형된 부표(2)를 내장 한 후, 성형틀에 넣되, 먼저 측면테두리를 100~180℃의 온도로 가열하여 테두리를 열융착시킨 다음, 테두리가 부착된 상태에서 성형틀을 오븐에 넣어 100~220℃로 가열하여 성형필름(1-1)이 부표쪽으로 수축하여 부표에 열융착시켜 제조함을 특징으로 하는 친환경 부표의 제조방법.
In the manufacturing method of an eco-friendly buoy,
A plurality of upper mold vacuum suction pipes 51 formed on the upper mold 50 while lowering the upper mold 50 to the lower mold 60 with the polypropylene film 1 interposed therebetween, and the lower mold ( The film is vacuumed by a vacuum pipe connected to a vacuum pump in a plurality of lower mold vacuum suction pipes 61 formed in the chamber 60) .
Figure 112012070044686-pat00010
Vacuum molding at a shape of 40 ~ 120 ℃, to produce a vacuum molded two molded film,
After placing the molded film vacuum-formed to the buoy forming lower mold 65 with the lower mold micro-projection 65-1 in the upper center so that no bubbles are generated in the buoy,
Lowering the projection-forming upper mold 55 with the upper mold micro-projection 55-1 at the lower center to the projection-forming lower mold 65, the lower part of the molding film placed in the projection-forming lower mold 65 After punching a hole so that the molded film is not broken during work, and manufactured on the molded film 1-1 with holes,
As described above, the edges of the two molded films 1-1 having the fine holes formed thereon are symmetrically contacted with each other, and thereafter, the buoy 2 formed of polypropylene foam is embedded therein, and then placed in a mold. First, the side edges are heated to a temperature of 100 to 180 ° C., and the edges are heat-sealed. Then, the mold is placed in an oven while the edges are attached and heated to 100 to 220 ° C. so that the molded film 1-1 shrinks toward the buoy. Eco-friendly buoy manufacturing method characterized in that by manufacturing by heat-sealing buoy.
친환경 부표의 제조방법에 있어서,
사출기를 이용하여
Figure 112012039244739-pat00011
형상의 성형필름으로 40~180 ℃에서 사출성형한 다음, 부표에 기포가 발생하지 않도록 사출성형된 성형필름을 중앙상부에 하부금형미세돌기(65-1)가 구비된 돌기성형하부금형(65)에 위치시킨 후에,
중앙하부에 상부금형미세돌기(55-1)가 구비된 돌기형성상부금형(55)을 돌기형성하부금형(65)으로 하강시켜, 돌기형성하부금형(65)에 안치된 성형필름의 하부에
미세한 구멍을 뚫어 작업시 성형필름이 끊어지지 않도록 하며, 구멍이 형성된 성형필름(100)에 제조한 후에,
상기와 같이 미세한 구멍이 형성된 제조된 두 개의 성형필름(100)의 테두리가 맞닿게 대칭되게 한 후, 내부에 폴리프로필렌폼으로 성형된 부표(2)를 내장 한 후, 성형틀에 넣고, 상기 성형틀을 오븐에 넣어 100~220℃로 가열하면서 컴퓨레샤로 0.5~2kgf/㎠의 압력으로 공기를 주입시켜, 성형필름(100)이 부표쪽으로 수축하여 부표에 열융착시켜 제조함을 특징으로 하는 친환경 부표의 제조방법.




In the manufacturing method of an eco-friendly buoy,
Using an injection machine
Figure 112012039244739-pat00011
After the injection molding at 40 ~ 180 ℃ with a shaped film of the shape, the projection molding lower mold (65) is provided with a lower mold micro-projection (65-1) in the upper center of the injection molded molded film so as not to generate bubbles in buoys After located in
Lowering the projection-forming upper mold 55 with the upper mold micro-projection 55-1 at the lower center to the projection-forming lower mold 65, the lower portion of the formed film placed in the projection-forming lower mold 65
After forming a small hole so that the molded film is not broken during the work, and manufactured in the molded film 100 formed with holes,
After making the edges of the two molded films 100 formed with the fine holes as described above asymmetrically contacted, and then embedded buoy (2) molded into a polypropylene foam therein, put in a mold, the molding The mold is put into an oven and heated to 100 to 220 ° C. while injecting air at a pressure of 0.5 to 2 kgf / cm 2 with a compressor, and the molding film 100 shrinks toward the buoy to be manufactured by heat fusion to the buoy. Method of making buoys.




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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180103486A (en) * 2017-03-10 2018-09-19 (주)경인이피에스 Buoys and apparatuses and methods for manufacturing them
KR20180103479A (en) * 2017-03-10 2018-09-19 (주)경인이피에스 Buoy and its manufacturing method
KR101910371B1 (en) 2017-09-27 2018-10-23 아주와이어(주) Environmentally friendly method for manufacturing buoys
KR20210022243A (en) 2019-08-20 2021-03-03 케미코첨단소재 주식회사 Eco-frendly polyproplyene buoy and manufacturing method thereof

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JP2000328315A (en) 1999-05-11 2000-11-28 Kohshin Rubber Co Ltd Floatable rain wear
JP2004082332A (en) 2002-08-22 2004-03-18 Jsp Corp Polypropylene resin foamed molded product with skin layer and its manufacturing method

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Publication number Priority date Publication date Assignee Title
JP2000328315A (en) 1999-05-11 2000-11-28 Kohshin Rubber Co Ltd Floatable rain wear
JP2004082332A (en) 2002-08-22 2004-03-18 Jsp Corp Polypropylene resin foamed molded product with skin layer and its manufacturing method

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180103486A (en) * 2017-03-10 2018-09-19 (주)경인이피에스 Buoys and apparatuses and methods for manufacturing them
KR20180103479A (en) * 2017-03-10 2018-09-19 (주)경인이피에스 Buoy and its manufacturing method
KR101955315B1 (en) * 2017-03-10 2019-03-08 (주)경인이피에스 Buoy and its manufacturing method
KR101955320B1 (en) 2017-03-10 2019-03-12 (주)경인이피에스 Buoys and apparatuses and methods for manufacturing them
KR101910371B1 (en) 2017-09-27 2018-10-23 아주와이어(주) Environmentally friendly method for manufacturing buoys
KR20210022243A (en) 2019-08-20 2021-03-03 케미코첨단소재 주식회사 Eco-frendly polyproplyene buoy and manufacturing method thereof

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