KR101178613B1 - Fertilizer for green peppers containing glycinebetaine and poly aspartic acid to reduce the use of fertilizer usage - Google Patents

Abstract

The present invention utilizes the ion binding capacity of poly aspartic acid (PAA), an eco-friendly biodegradable polymer material, the effect of promoting muscle growth and the osmotic pressure of glycinebetaine, an environmental stress relief agent, to promote nutrient absorption. The present invention relates to an eco-friendly fertilizer for peppers that does not affect the yield or growth even when fertilizing less than the standard fertilizer required for the cultivation of red pepper. In addition, the present invention reduces the amount of nitrogen nitrite (N ₂ O) which is one of the main greenhouse gases of climate warming by reducing the fertilization rate of field crops (horticultural crops), thereby reducing the greenhouse gas generated during farming operations, thereby reducing the national low carbon green growth. It is an environmentally friendly fertilizer that is considered to be able to contribute.

Description

Fertilizer for green peppers containing glycinebetaine and poly aspartic acid to reduce the use of fertilizer usage}

The present invention provides the effect of promoting the absorption of nutrients due to the ion adsorption capacity of the aspartic acid (PAA), an eco-friendly biodegradable polymer material, the effect of promoting muscle growth and the osmotic pressure of glycinebetaine, an environmental stress relieving agent. The present invention relates to an eco-friendly fertilizer for corn, pepper and cabbage that does not affect the yield or growth even when fertilizing less than the standard fertilizer required to grow corn, cabbage and pepper.

In terms of the use of chemical fertilizers in Korea, the amount of use per unit area decreases from 382 kg / ha in 2000 to 340 kg / ha in 2007 and 311 kg / ha in 2008, but is significantly higher than in other developed countries. .

Compared with OECD countries in 2001-2003, fertilizer consumption is 338 kg / ha in the UK, 227 kg / ha in France and 305 kg / ha in Japan, but Korea ranks fifth with 423 kg / ha. In the Environmental Sustainability Index (ESI), which is released every three to four years, Korea ranks low in the fertilizer sector, ranking 138th out of 146 countries. In addition, the continuous increase in farmland input of livestock manure, along with chemical fertilizers, has resulted in salt accumulation and surface water nutrient nourishment due to nutrient surplus, which is the highest nutrient index among OECD countries.

Nitrogen, one of the major components of fertilizers, is a nitrous oxide (N ₂ O), which has 310 times higher global warming effect than carbon dioxide among the six gases of climate warming (CO ₂ , CH ₄ , N ₂ O, HFC, PFC, SF ₆ ). It is an occurrence factor.

Recently, the United Nations Framework Convention on Climate Change is being promoted to prevent global warming due to global warming due to the increase of greenhouse gases.As part of this, Korea aims to reduce greenhouse gas emissions by 4% compared to 2005 by 2020. Came to announce.

However, commercial fertilizers in the market have a problem in that the growth or yield of crops decreases when the fertilizer is reduced below the standard fertilization rate.

On the other hand, as part of an attempt to improve the above problems for the environment, there is also an active research on a method of reducing the amount of chemical fertilizers to an optimal amount by improving various fertilizers put into farmland. In particular, much research has been made on the use of some organic acids, oligomers and the like as chelating means that can promote the absorption of inorganic elements of plants.

Poly aspartic acid (PAA), a type of amino acid, is a peptide chain composed of amide bonds and is generally prepared by thermal polymerization of aspartic acid. Regarding the preparation of such polyaspartic acid, U.S. Pat.No.4839461, U.S. Pat.No.4590260, German Patent No.2253190, U.S. Pat.No.5057597, US Pat.No.5219952, U.S. Pat.No.5288783, Korean Patent No.10-0764933 It is already disclosed in the issue.

Such polyaspartic acid (PAA) is widely used as a water treatment agent or detergent builder by utilizing water retention and ionic bonding ability, but the method of using it in agriculture, especially in fertilizers, is not well known. In some cases, the use of polyaspartic acid (PAA) as a fertilizer is known to be considered as an environmentally friendly material that promotes growth, yield, and root development.

In relation to this, the known foreign publications or published in Korea have generally been inconvenient in the method of fertilizing by using polyaspartic acid alone or fertilizing with fertilizer. In particular, German Patent Application Publication No. 10008738 (August 30, 2001) does not calculate the appropriate content according to the type of fertilizer, and only the problem of excessive application by each species is expected by using polyaspartic acid as a fertilizer extensively. In addition, the effect was also not tested through the crop cultivation test, so there was a limit to the application to the crop. In addition, Korean Patent No. 10-0850186 (2008.07.28) obtains the optimum polyaspartic acid (PAA) content range according to each type of fertilizer to prevent excessive damage of polyaspartic acid (PAA), growth and yield through incorporation into fertilizer Only effects such as enhancement are known.

However, the addition of polyaspartic acid alone does not maximize the nutrient utilization efficiency of crops, so there is no way to drastically reduce the amount of fertilizer.

Therefore, the inventors of the present invention further utilize polyaspartic acid (PAA) in order to further utilize polyaspartic acid (PAA), sugars such as arabinose, polyhydric alcohols such as pinitol, proline or glycinebetaine. A study was made to reduce the amount of fertilizer used by increasing the absorption capacity of plants using osmotic pressure-controlled solutes of amino acids and derivatives thereof. Glycinebetaine lowers the osmotic potential in the cell, promotes water absorption, and increases the intracellular salt concentration to maintain homeostasis at the osmotic level when subjected to environmental stress (low temperature, high temperature, family crest, salt, etc.). It is well known as a substance that controls the osmotic pressure to maintain it.

As a result, the present inventors obtained the optimum content of polyaspartic acid and glycine betaine and the optimum fertilizer composition for each crop, and confirmed the effect of reducing fertilizer consumption through crop cultivation experiments, and by maximizing the nutrient use by optimizing the growth of horticultural crops We have developed fertilizers for corn, red pepper and cabbage that can reduce the amount of fertilizer and reduce problems such as environmental pollution and greenhouse gas generation by reducing fertilizer consumption.

An object of the present invention is to provide a fertilizer for corn, pepper and cabbage that can improve the problems such as environmental pollution or greenhouse gas generated by the fertilizer by reducing the amount of fertilizer without falling and growth of horticultural crops.

In order to achieve the above object, the present invention is 0.75 ~ 1 parts by weight of a composite fertilizer containing nitrogen (N), phosphorus (P) and potassium (K); 0.0015 parts by weight of poly aspartic acid; And 0.0015 parts by weight of glycinebetaine, wherein the nitrogen (N) is 12% by weight of the compound fertilizer, phosphorus (P) is 5% by weight of the compound fertilizer, and potassium (K) is 9% by weight of the compound fertilizer. It provides a dedicated fertilizer for corn, characterized in that%. Here, the fertilizer is preferably for corn fertilizer (manure), the compound fertilizer is preferably 0.75 parts by weight.

In addition, the present invention is 0.75 ~ 1 parts by weight of a composite fertilizer containing nitrogen (N), phosphorus (P) and potassium (K); 0.0015 parts by weight of poly aspartic acid; And 0.0015 parts by weight of glycinebetaine, wherein the nitrogen (N) is 12% by weight of the compound fertilizer, phosphorus (P) is 13% by weight of the compound fertilizer, and potassium (K) is 11% by weight of the compound fertilizer. It provides a dedicated fertilizer for pepper, characterized in that the. Here, the fertilizer is preferably for red pepper fertilizer (manure), the compound fertilizer is preferably 0.75 parts by weight.

Furthermore, the present invention, 0.75 ~ 1 parts by weight of a composite fertilizer containing nitrogen (N), phosphorus (P) and potassium (K); 0.0015 parts by weight of poly aspartic acid; And 0.0015 parts by weight of glycinebetaine, wherein the nitrogen (N) is 11% by weight of the compound fertilizer, phosphorus (P) is 8% by weight of the compound fertilizer, and potassium (K) is 11% by weight of the compound fertilizer. It provides a fertilizer for cabbage, characterized in that%. Here, it is preferable that the fertilizer is for cabbage fertilization (manure), the composite fertilizer is 0.75 parts by weight.

On the other hand, polyaspartic acid (PAA) and glycine betaine (GB) used in the present invention can be used both in accordance with the converted amount without limitation in the form of liquid or powder.

As described above, the present invention is an eco-friendly fertilizer that does not affect the growth, yield, quality, etc. of crops even when the consumption of fertilizer is reduced, which contributes to the national chemical fertilizer reduction policy as well as one of the main ingredients of fertilizer Nitrous oxide (N ₂ O) generation factor, which is 310 times higher than carbon dioxide in global warming effect among _six gases of climate warming (CO ₂ , CH ₄ , N ₂ O, HFC, PFC, SF ₆ ), is 25% of nitrogen treatment. As it decreases, greenhouse gas emissions will also decrease, making it possible to establish itself as a green growth technology for the agricultural sector.

Hereinafter, the configuration of the present invention will be described in more detail through preferred embodiments, but these embodiments are only for illustrating the present invention in detail, and the scope of the present invention is not limited by these embodiments.

<Example 1> polyaspartic acid and the growth effect of the test jeonyongbi fee for a corn containing glycine betaine

Example  1-1.

100kg of NPA composition, 8% -3% -6% corn-only fertilizer, 150g of polyaspartic acid (PAA) and 150g of glycinebetaine (GB), and then 100kg per 10a. Treated with. Soil barrels were made from Jishan barrels (loam), and corn was sown on May 15 with a planting density of 60 × 25 cm. After the fertilization, the manure was treated with the standard fertilization amount of the Rural Development Administration's Agricultural Science and Technology Institute.

Example  1-2.

Except for using 75kg of sprinkles was prepared in a fertilizer for corn in the same manner as in Example 1-1, 75kg per 10a was treated with air (manure).

Example  1-3.

Except that 50kg of spleen was used to prepare a fertilizer for corn in the same manner as in Example 1-1, 50kg per 10a was treated with air (manure).

Comparative example  1-1.

Except for using the gardening general purpose (Dongbu Hi-Tech Co., Ltd.) of 11% -10% -11% of N-P-K composition was prepared in the same manner as in Example 1-1, and then 79kg per 10a was treated with air ratio (base manure).

Comparative example  1-2.

Except not adding glycine betaine (GB) was prepared in the same manner as in Comparative Example 1-1, and then 79kg per 10a was treated with air (bottom).

As a control, 100kg per 10a of corn-only fertilizer with NPK composition of 8% -3% -6% was treated with aeration.

As shown in Table 1, non-fertilizer-free fertilizer-1 decreased by about 30% compared to 460 g of the control group as 320g of dry matter per individual as the fertilizer was not treated.

On the other hand, in Example 1-1 containing 100% of the standard fertilization, the dry weight per individual was 503 g, which was about 9% higher than the control, and in Example 1-2, which reduced the fertilizer amount by 25%, 461 g of the middle ear boiled to 460 g of dry matter per subject in the control group. In Example 1-3, which reduced the amount of fertilizer by 50%, the dry weight per individual was 417 g, which was 9% less than the 460 g of the control group.

Therefore, it can be seen that the corn-only fertilizer of the present invention has an excellent effect of increasing the dry weight despite using a small amount of spleen.

Corn Harvester Growth and Yield Quantity by Fertilization Fertilization Extra long
(cm) ground game
(Individual / object) Yeopsaek also ^♩ Live weight
(g / object) Building
(g / object) ear Foliage system ear Foliage system Ignore -1 301 13.7 47.3 262 680 942 119 201 320 Control group 314 14.1 57.8 320 880 1200 186 274 460 Example 1-1 329 14.2 57.1 356 990 1346 201 302 503 Examples 1-2 323 13.9 55.4 334 920 1254 184 277 461 Example 1-3 305 13.9 56.1 327 820 1147 173 245 417 Comparative Example 1-1 318 14.1 57.5 319 880 1199 185 275 460 Comparative Example 1-2 313 14.1 57.2 316 870 1186 181 272 453

♩ Measuring instrument: SPAD 502 measured value

On the other hand, as shown in Table 2, musibi-1, as the fertilizer is not treated, the weight (root weight) per individual was 2.7g, about 25% less than 3.6g of the control group.

In contrast, in Example 1-1, which contained 100% of the standard fertilization, the weight of the individual was 4.8 g, which was about 33.3% higher than that of the control group. This 4.0g increased about 11% compared to 3.6g of the control. In the case of Example 1-3, which reduced the amount of fertilizer by 50%, the muscle weight per individual was 3.3, which was 11% lower than 3.6 g of the control group.

Therefore, it can be seen that the corn-only fertilizer of the present invention has an excellent root growth promoting effect despite the use of a small amount of spleen.

Root Weight Comparison by Fertilization Fertilization Muscle weight (g / object) Ignore -1 2.7 Control group 3.6 Example 1-1 4.8 Examples 1-2 4.0 Example 1-3 3.2 Comparative Example 1-1 3.7 Comparative Example 1-2 3.6

※ Port experiment: 58 days after sowing

<Example 2> polyaspartic growth effect of the test and only acid fertilizer for the peppers containing glycine betaine

Example  2-1.

Put 100g of aspartic acid (PAA) and 150g of glycinebetaine (GB) as an active ingredient for 100kg of red pepper fertilizer with NPK composition of 10% -11% -9%. Treated with. Soil barrels were made using Jishan barrels (loam), and red peppers were sown on May 15 with a planting density of 100 × 40 cm. After the fertilization, the manure was treated with the standard fertilization amount of the Rural Development Administration's Agricultural Science and Technology Institute.

Example  2-2.

Except that the use of 75kg of spleen was prepared in the same manner as in the fertilizer for pepper in the same manner as in Example 2-1, 75kg per 10a was treated with a nasal air (manure).

Example  2-3.

Except for using 50kg of sprinkles was prepared in the same manner as in the fertilizer for pepper in the same manner as in Example 2-1, 50kg per 10a was treated with air (manure).

Comparative example  2-1.

Except for using pepper fertilizer (Dongbu Hitech Co., Ltd.), which has an NPK composition of 11% -11% -10%, was prepared in the same manner as in Example 2-1, and then 90kg per 10a was treated with air (base). .

Comparative example  2-2.

Except not adding glycine betaine (GB) was prepared in the same manner as in Comparative Example 2-1, and then 90kg per 10a was treated with air (bottom).

As a control group, 100 kg per 10a of spleens with N-P-K composition of 10% -11% -9% were treated with aeration (manure).

As shown in Table 3, musibi-1 had a dry weight of 503g per individual as the fertilizer was not treated, which was about 25% lower than the 671g of the control group, and the dry pepper yield was 378kg per 10a compared to the 426kg of the control group. The yield decreased by about 13%.

In contrast, in Example 2-1 containing 100% of the standard fertilization, the dry weight per individual was 663g, which was higher than the 671g of the control group, but the dry pepper yield increased by 3.5%. In Example 2-2, which reduced the amount of fertilizer by 25%, the dry weight was 579g per individual, and the dry weight was slightly reduced compared to the 671g in the individual of the control group, but the amount per 10a was 425kg, which was higher than the control quantity of 426kg. . In Example 2-3, which reduced the amount of fertilizer by 50%, the dry weight per individual was 493 g, 27% less than the 671 g of the control group, and 390 kg was also shown in the pepper yield per 10a, which was 8% less than the 426 g of the control group.

Therefore, it can be seen that the corn-only fertilizer of the present invention has excellent pepper growth effect despite the use of less amount of seedlings.

Harvester Growth and Quantity by Fertilization Fertilization Extra long (cm) Yeopsaek also ^♩ Residual weight
(g / 5 objects) Among the remnants
(g / 5 objects) Dried red pepper
(kg / 10a) Ignore -1 98 57.6 1,711 503 378 Control group 99 60.0 2,338 671 426 Example 2-1 101 58.6 2,211 663 441 Example 2-2 101 59.1 2,032 579 425 Example 2-3 104 60.1 1,730 493 390 Comparative Example 2-1 100 60 2320 660 425 Comparative Example 2-2 99 59.5 2315 630 422

♩ Measuring instrument: SPAD 502 measured value

On the other hand, as shown in Table 4, musibi-1 showed a weight loss of about 46% compared to 1.3g of the control group as the weight of the individual as the fertilizer was not treated.

In contrast, in Example 2-1, which contained 100% of the standard fertilization, the weight of the individual was boiled to 1.3 g, and in Example 2-2, which reduced the fertilizer amount by 25%, the weight of the individual was 1.2 g. It boiled with 1.3 g. In Example 2-3, which reduced the amount of fertilizer by 50%, the weight gain per individual was 0.9, 31% lower than that of 1.3 g of the control group.

Therefore, the pepper-only fertilizer of the present invention can be seen that even though the amount of spleen is used less than the weight of the control and excellent root growth promoting effect.

Root Weight Comparison by Fertilization Fertilization Muscle weight (g / object) Ignore -1 0.7 Control group 1.3 Example 2-1 1.3 Example 2-2 1.2 Example 2-3 0.9 Comparative Example 2-1 1.3 Comparative Example 2-2 1.3

※ Port experiment: 21 days after sowing

<Example 3> polyaspartic growth effect test of an acid and only a fertilizer for cabbage containing glycine betaine

Example  3-1.

100 kg of cabbage complex fertilizer with 11% -8% -11% NPK composition was put together with 150g of polyaspartic acid (PAA) and 150g of glycinebetaine (GB), then 100kg per 10a. Treated with. Soil barrels were made using Jishan barrels (loam), and on September 3, the Chinese cabbage (variety: CR-luxury) was sown with a planting density of 80 × 40 cm. After the fertilization, the manure was treated with the standard fertilization amount of the Rural Development Administration's Agricultural Science and Technology Institute.

Example  3-2.

Except for the use of 75kg of spleen, after preparing a fertilizer for cabbage in the same manner as in Example 3-1, 75kg per 10a was treated with air (base).

Example  3-3.

Except for the use of 50kg of spleen, after preparing a fertilizer for cabbage in the same manner as in Example 3-1, 50kg per 10a was treated with air (manure).

Comparative example  3-1.

Except for using the cabbage fertilizer (Dongbu Hitech Co., Ltd.) seedlings having an N-P-K composition of 12% -8% -12%, 92kg per 10a was treated with aerobic (bottom manure) after the same preparation.

Comparative example  3-2.

Except not adding glycine betaine (GB) was prepared in the same manner as in Comparative Example 3-1, and then 92kg per 10a was treated with air (bottom).

As a control group, 100 kg per 10a of spleens with NPK composition of 11% -8% -11% were treated with air swelling.

As shown in Table 5, as the fertilizer-1 is not treated with fertilizer, the biomass per week is 1,187 kg, which is about 65% lower than 3,454 kg of the control group, resulting in a yield difference of about 7,000 tons per 10a. Turned out to be very large.

In Example 3-1, the biomass per week was 3,692 kg, which was about 7% higher than the 3,454 kg of the control group, and the dry matter per week was 207 kg, which was about 17% higher than the 171 kg of the control group.

In Example 3-2, the biomass per week was 3,351 kg, which was about 3% less than the 3,454 kg per week of the control group, but the dry matter per week was 182 kg, which was about 171 kg per week. 6% increase. This, as the treatment of polyaspartic acid (PAA) and glycine betaine (GB), as the tissue of the cabbage plant becomes more dense, it is judged that the water content appears to be less, so it can be seen that the quality of the cabbage is excellent.

In Example 3-3, the biomass per week was 2,770 kg, about 20% less than the 3,454 kg of the control group, and the cabbage yield per 10a was 8,656 tons, which was about 2,137 tons less than the 10,793 tons of the control group. The quantity appeared to fall.

Therefore, it can be seen that the cabbage-only fertilizer of the present invention has an excellent cabbage growth effect and quality improvement effect despite the use of less amount of seedlings.

Harvester Growth and Quantity by Fertilization Fertilization Extra long
(cm) ground game
(Individual / object) Biomass (kg) Building quantity (kg) Per week Per 10a Per week Per 10a Ignore -1 27 53.3 1,187 3,709 89 278 Control group 39 77.4 3,454 10,793 171 534 Example 3-1 41 75.2 3,692 11,537 207 647 Example 3-2 40 76.8 3,351 10,471 182 568 Example 3-3 37 72.3 2,770 8,656 148 462 Comparative Example 3-1 39 77.0 3,424 10,684 170 533 Comparative Example 3-2 38 77.2 3,434 10,694 170 536

On the other hand, as shown in Table 6, musibi-1 showed a 10% reduction in the weight of the individual as 4.4g as the fertilizer was not treated compared to 4.9g of the control group.

In contrast, in Example 3-1, which had a standard fertilization amount of 100%, the weight of the individual was 5.0 g, which was slightly increased than that of the control group. boiled to g. In Example 3-3 having a standard fertilization amount of 50%, the muscle weight per individual was 4.5 g, which was 8% lower than that of 4.9 g of the control group.

Therefore, the cabbage-only fertilizer of the present invention can be seen that despite the use of a small amount of spleen, compared with the control group has excellent root growth promoting effect.

Root Weight Comparison by Fertilization Fertilization Muscle weight (g / object) Ignore -1 4.4 Control group 4.9 Example 3-1 5.0 Example 3-2 4.9 Example 3-3 4.5 Comparative Example 3-1 4.8 Comparative Example 3-2 4.8

※ Investigation after 68 days

As a result of the cultivation test of corn, red pepper and Chinese cabbage, the growth and yield of the fertilizer containing polyaspartic acid (PAA) and glycine betaine (GB) were found to be no difference compared to the practice even if the fertilizer application was reduced by 25%. In particular, the quality of cabbage was improved.

Claims (3)

0.75 to 1 part by weight of a compound fertilizer containing nitrogen (N), phosphorus (P) and potassium (K);
0.0015 parts by weight of poly aspartic acid; And
Glycinebetaine 0.0015 parts by weight, wherein the nitrogen (N) is 12% by weight of the compound fertilizer, phosphorus (P) is 13% by weight of the compound fertilizer, potassium (K) is 11% by weight of the compound fertilizer Special fertilizer for pepper, characterized in that the. The method of claim 1,
The fertilizer is a special fertilizer for pepper, characterized in that the pepper for fertilizer (manure). The method according to claim 1 or 2,
The fertilizer is a fertilizer for pepper, characterized in that 0.75 parts by weight.